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    Chemistry2015 160926175504 PDF

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    Esai Stephen

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    © All Rights Reserved
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    FORM TP 2615159 ae CARIBBEAN EXAMINATIGNS COUNCIL CARIBBEAN ADVANCED PROFICIENCY EXAMINATION® CHEMISTRY UNIT 2 - Paper 92 Zhours 30 wanes test cope 02212620 MAYHUNE 2015 READ TRE FOLLOWING INSTRUCTIONS CAREFULLY. 1. This paper consists of SIX questions in TWO sections. Answer ALL questions, 2. Write your answers in the spaces provided in this booklet. 3. DoNOT write in the margins. 4. Where appropriate, ALL WORKING MUST BE SHOWN in this booklet 5, A data booklet is provided. 6. You may use silent, non-programmable calculator to answer questions. 7. If-you need to rewrite any answer and there is not enough space to do so on the original page, you must use the extra lined page(s) provided at the back ofthis booklet. Remember to draw a line through your original answer. 8. Ifyou use the extra page(s) you MUST write the question number clearfy in the box provided at the top of the extra page(s) and, where relevant, include the question part beside the answer. DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO. Copyright © 2014 Caribbean Examinations Council, All rights reserved, a wee am SECTION A, Answer ALL questions. MODULE! ‘THE CHEMISTRY OF CARBON COMPOUNDS Propane is one ofthe major components of liquefied petroleum gas (LPG). The petroleum industry uses a process to produce anather alkane and two alkenes from propane according tothe equation below. 2.CH,CH,CH, (@) —A—> B (@)+C(@)+ CHL=CH®) +H, @) Identify the process represented by the equation. i mark} State the conditions at A Tt mark] Writ the condensed structural formulae of B @ ‘Account for the tetavaleney ofthe carbon atom, [2 marks} GO ON TO THE NEXT PAGE, (02212020/C APE 2015 L 0221202008 03 _| oe ‘Aqueous bromine will only react with propane in sunlight but equeous bromine reacts quickly with propene without sunlight. Using appropriate notation and equations, explain the steps involved in the ‘mechanism of the chemical reaction of aqueous bromine with propane (in sunlight) ‘OR aqueous bromine with propene (without sunlight). Gil) Name the mechanism of the reaction selected in (b) (i). [mark] GO ON TO THE NEXT PAGE 12712020/CAPE 2015 109 (6) Deserite the observations expected when (6) aqueous bromine is added to liquid heptane (in sunlight) mari} i) acidified potassium permanganate solution is added to liquid heptene (without sunlight il marks} | “otal 1 marke GO ON TO THE NEXT PAGE, I uo 02212020/C APE 2015, i MODULE2 ANALYTICAL METHODS AND SEPARATION TECHNIQUES a) __ Ina trims analysis, state ONE operation wich can affect Gy aceuraey Gi) precision aise (b)_LiscT WO requirements which primary standard reagent that's! sed in titrimetric analysis must satisfy.) GOON TO THE NEXT PAGE (02212020/CAPE 2015 In a thecmometric titration, 25 em? of 2 mol dm” NaOH were used to determine the coneentation of hydrochloric acid (Using the results in Table 1, plot a graph of temperature against volume of acid ‘on the axes provided on page 7. ‘TABLE I: RESULTS OF TITRATION Volume of Aci (em?) | Terperatureco_ | 5.00 300 10.00 320 15.00 325 20.00 (ii) Hence, determine the end-point volume of the acid, (Git) Calculate the concentration ofthe acid [2 marks} GOON TO THE NEXT PAGE 02212020/CAPE 2015 L a | Volume of acid (em) GO ON TO THE NEXT PAGE 02212020/CAPE 2015 usd Outline the experimental steps fr this type oftitetion [a marks] ‘Total #5 marks GOON TO THE NEXT PAGE m4 | (02212020/CAPE 2015 5 MODULES INDUSTRY AND THE ENVIRONMENT ‘Sulfure acid is manufactured in industry by a process known asthe Contact Process. The ‘slowest step during the process isthe conversion of SO, 10SO, which ean be represented by the equation: 280, (8) +0, (@) <=> 280,(@, AH=-197kI mot List the THREE ways in whieh the rate of SO, production ean be improved. " : ji Bmarks} () The manufacturing conditions utilized during the Contact Process can be optimized by ‘considering Le Chatelie's principle. (State Le Chatlier's principle. ; (mark) ‘What general conditions of temperature and pressure are predicted by Le Chatelie's principe in order forthe MAXIMUM yield of SO, to be obtained? “Temperature Pressure GOON TO THE NEXT PAGE p212020/CAPE 2015 il) Describe how the subir te ioxide produced is converted to concentrated sulfuric seid 1 mares} (%) Wite TWO equations to represnt the process that you described in (by i) marks) co) Outline the safety considerations that guide the proces in () (i), “(3 mari} Total 1S marks GOON TO THE NEXT PAGE 02212020/CAPE 2015, A eno we] i. SECTION B Answer ALL questions. MODULE 1 ‘THE CHEMISTRY OF CARBON COMPOUNDS (2) Distinguish between ‘addition polymerization’ and ‘condensation polymerization’ GOON TO THE NEXT PAGE 02212020/CAPE 2015, wl “2. I () List TWO classes of naturally occurring polymers, giving an example of ONE. (B maria] ©) Terylene is a co-polymer formed from the monomers ethane-I, 2-diol and benzene-I, ‘icarboxylie sei. Using &chemiea! equation, show how teylene can be formed from the two monomers. | 4 marke GO ON TO THENEXT PAGE (02212020/C APE 2015 L eco us J les 13 (The structure, A, shown below represents the repeating unit ofa polymerie substance, cH, I i a Deduce the structural formulae ofthe monomers used to form the polymer. [6 marks} ‘Total 15 mars GO ON TO THE NEXT PAGE 02212020/CAPE 2015 nq t oe MODULE? ANALYTICAL METHODS AND SEPARATION TECHNIQUES (2) Explain how chromatography can be used to separate a mixture of dyes. GOON TO THE NEXT PAGE, (02212020/CAPE 2015 _ Le EL 20 | ‘0221202016 (&) Figure 1 shows the separation of'a mixture of amino acids, obtained inthe hydrolysis of a dipeptide, ona thin layer chromatography (TLC) plate Mixture of amino acids igure £. The separation of a mixture of amino acids (Explain how the presence ofthe components ean be detected. GO ON TOTHE NEXT PAGE 02212020/CAPE 2015 I NE iad a16- Gi) Caleulate the R, retention factor values oF Q and R marks} fi) Suggest TWO reasons forthe lference in the R values of and GOON TO THE NEXT PAGE 022120201CAPE 2015 pero 2] and column chromatography are both similar (©) The methods of thin layer chromatography ‘Bf these two types of chromatography in elation {0 and different, Assess the methods their uses, [a marks) ‘Total 1S marks GOON TO THE NEXT PAGE eantamoicare 015 wal | _—SSSSS=R MoDULE 3 INDUSTRY AND THE ENVIRONMENT 6. (a) Chlorine is considered tobe the most important halogen. Using an appropriate annotated

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