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Ceramic Microchannel Heat Exchangers
Ceramic Microchannel Heat Exchangers
Ceramic Microchannel Heat Exchangers
Solis materials used in heat exchangers can be divided into four categories-
polymers, metals, ceramics and carbonaceous materials. Doubtlessly the most widely
adopted material is metal due to its high thermal conductivity. Instead of depending upon
monolithic materials composite materials can also be employed. Composite materials offer
engineers an ability to create a limitless number of new material systems having unique
properties that cannot be obtained using a single monolithic material. This approach to
construction holds tremendous promise for future heat exchanger designs rather than
selecting a single material, multiple materials may be selected and then tailored to meet the
specific requirements of the application. Composite materials are constructed of two or more
materials, commonly referred to as constituents, and have characteristics derived from the
individual constituents. The constituent that is continuous and which is often, but not
always, present in the greater quantity in the composite istermed the matrix. The second
constituent is referred to as the reinforcing phase, or reinforcement, as it enhances or
reinforces the properties of the matrix.
2.1 CERAMICS
The American Society for Testing and Materials (ASTM) definesa ceramic material
as "an article [whose] body is produced fromessentially inorganic, non- metallic substances
and either is formedfrom a molten mass which solidifies on cooling, or is formed
andsimultaneously or subsequently matured by the action of the heat. "Most ceramic
materials are hard, porous and brittle so the use ofceramics in application often requires
methods for mitigating theproblems associated with these characteristics. Ceramic
materialsare usually ionic or covalently bonded and may be
The two main advantages for using ceramic materials in heat exchanger construction
over more traditional metallic materials are their temperature resistance and corrosion
resistance. First, ceramic materials can withstand operating temperatures (i.e.1400 0C) that far
exceed those of conventional metallic alloys. For example, the bulk material temperature of a
heat exchanger made of carbon steel should not exceed 4250C. Similarly, the bulk material
temperature of a heat exchanger manufactured from stainless steel typically should not exceed
6500C. As a result, the heat exchanger must be protected in some applications. Thermal
protection can be accomplished by means of an environmental barrier coating that overlays the
metal which has the effect ofadding a thermal resistance to the transfer of heat thereby reducing
the overall performance of the unit. In other cases, the unit is operated in the parallel flow mode
rather than the counterflow mode to maintain a lower overall material temperature. This mode
of operation has the effect of increasing the lifetime of the heat exchanger at the expense of
lowering the overall thermal efficiencyof the unit. Another commonly employed technique is
air dilution, where ambient air is added to the hot upstream exhaust gases upstream of the heat
exchanger. This technique also has the effect of lowering the overall efficiency of the heat
exchanger.
Although the impetus behind the use of ceramics in the manufacturing and design of
heat exchangers arises from their excellent corrosive properties, their ability to withstand
extremely high operating temperatures, and the economics of their use in heat recovery
systems, radiant heating applications, and microreactors, major obstacles facing the
incorporation and use ofceramics in these systems remain. These obstacles include ceramic
metallicmechanical sealing, manufacturing costs and methods, and their brittleness in
tension. Therefore, to help meet the specific requirements of the application, ceramic matrix
composites (CMCs) were developed to overcome the intrinsic brittleness and lack of
reliability of monolithic ceramics.
Heat exchangers are classified the basis of various parameters such as flow
arrangement, compactness, construction etc. Based upon the degree of compactness it is
broadly classified into compact and non-compact heat exchangers. but a more accurate
classification differentiates compact heat exchangers as compact, meso and micro heat
exchangers based upon the their surface area density or hydraulic diameter [3]. The surface
area density factor, is defined as A gas-to-fluid exchanger is referred to as a compact heat
exchanger if it incorporates a heat transfer surface having a surface area density greater than
about 700 or a hydraulic diameter, Dh 6mm for operating in a gas stream and 400 for
operating in a liquid or phase-change stream. A laminar flow heat exchanger (also referred to as
a meso heat exchanger) has a surface area density greater than about 3000 or 100 m D h 1
mm. The term micro heat exchanger is used if the surface area density is greater than about
15,000 (or 1 m Dh 100 m) [3].
designs
Fig 4.1. Ceramic microchannel heat exchangerFig 4.2.Exploded view showing internal [1] channel structure [1]
A third beneficial effect of the rib gaps is to cause local entry-length boundary-layer
behavior as the flow enters the microchannel sections, which serves to increase local heat-
transfer coefficients.As illustrated in Fig. 4.2 the hot and cold fluids enter through central
holes from the bottom and exit via outboard holes at the top. Each of the internal layers is
identical, but with alternating layers rotated 180 0 relative to the underlying layer. The feed
and exhaust manifolds at the ends of the layers are designed such that there is exact
alignment upon layer rotation. Using identical layers reduces the manufacturing cost. One of
flow directions can be reversed (i.e., inlet flow through the outboard holes), producing a
coflow configuration. The heat exchangers to date have been fabricated with four flow layers
(two hot and two cold), but are designed to accommodate more flow layers. The relatively
large diameters of the central inlets and the outboard exhausts enable the use of many heat-
exchanger layers. The large diameters also enable the staging of several heat exchangers
without significant pressure drops in the connecting tubing.
Fig 5.1 Vertical cut through a three-dimensional simulation, showing gas and solid
temperature fields. [1]
dynamics(CFD), including the conjugate heat transfer between fluids and solidmaterials. The
CFD models are implemented in FLUENT. Temperature-dependent properties are used for
air and for alumina.The results in Figs. 5.1 and 5.2 are for balanced air flow (i.e., thesame
mass-flowrates through both the hot and cold inlets). The hotair enters at 500 0C and the cold
flow enters at 30 0C. The simulationsare based upon assuming that all external surfaces
areperfectly insulated. The results in Fig. 5.1 are for flow rates of1.58 x10 -3 kg s-1 (80
standard liters per minute of air, slm) andFig. 5.2 is for flow rates of 4.93 x 10 -4 kg s- 1 (25
slm). Both airstreams enter from below, flow in opposite directions through
themicrochannels, and then exhaust through tubes at the top. Fig. 5.1shows predicted
temperature fields on a vertical cut near theheat-exchanger centerline, in the middle of the first
flow channelaway from the heat-exchanger centerline. Fig. 5.2shows
temperaturefields at the mid-planes of a hot and a cold layer.The design process is assisted
greatly by three-
dimensionalsimulations that are used to predict quantitatively the influence ofmanifold and
channel geometry on heat exchanger performance.
For example, there are practical tradeoffs between increased heat transfer performance and
increased pressure drop. Manufacturing processes also introduce practical tradeoffs that must be
considered.
It is evident from both Figs. 5.1 and 5.2 that the axial temperaturevariations are
essentially one-dimensional (i.e., varying primarily inthe axial direction with little
variation across the short dimension).This is a desired result, leading to similar heat
transfer performancewithin all channels. Fig. 5.2 shows that the floor layer (i.e.,
between hotand cold flows) is nearly uniform in the vertical direction and essentiallyat
the average temperature between the local mean temperaturesof the hot and cold air.
Again, this is a desired result, indicatingrelatively little heat-transfer resistance through
the layer floors
.
ANALYSIS
where Dh is the channel hydraulic diameter and kf is the thermalconductivity of the fluid. It is
interesting to compare the relativethermal resistances of the convection and conduction.
Assuming airas the fluid and a hydraulic diameter of D h= 500 ^m, the convectiveheat-transfer
coefficient is h = 550 W m -2 K-1 Assuming anaverage thermal conductivity of 10 W m -1 K-1
(alumina at around 250 oC) and a wall thickness of t = 500 ^m, the ratio of conductivethermal
resistance offered by the wall and the total thermal resistance(i.e., conduction and convection)
is
In other words, even with low-conductivity ceramics, the influenceof conduction across
the wall is very small.Although conduction across the wall (i.e., normal to the
flowdirections) does not contribute significantly to performance, longitudinalheat
conduction (i.e., parallel to the flow directions) can significantlydegrade counter-flow
heat exchanger performance. The effect of longitudinal conduction can be particularly
important in compactheat exchangerswith short distances L between inlet and outlet
ports.The dimensionless longitudinal conduction parameter can be used to estimate the
effect of longitudinal conduction onperformance. In this equation, Ac is the longitudinal
cross-sectionalarea of the wall and Cmin= ' Cp is the minimumcapacity rate ( ' isthe mass-
flow rate and Cp is the heat capacity of the fluid)
.
PERFORMANCE EVALUATION
n
ceramic heat exchangerbody. The graphite is compressed using molybdenum
bolts.Molybdenum is chosen because it has low thermal expansion, thustending to retain
compression at high temperature. Thermocouplesare positioned at the centerline of the inlet
and outlet tubes, justupstream and downstream of the heat exchanger itself. Prior totesting,
thick fiberglass insulation is packed around the assembly(heat exchanger and manifold).
Although heat loss through theinsulation is not directly measured, the heat transfer from the
hotflow is always measured to be within a few percent of the heattransferred to the cold
stream.In addition to reporting inlet and outlet temperatures, the netheat transferred and heat-
exchanger effectiveness are also evaluated.The maximum heat that can possibly be transferred
is given as where is the minimum capacity rate and and arethe hot and cold inlet temperatures,
respectively. The capacity ratesare evaluated as C = ' C p, where ' is the mass-flow rate and C p
is the heat capacity of the fluid. The heat exchanger effectivenessis defined as where Q is the
actual heat transferred. The actual heat transferred isevaluated in terms of the enthalpy change
between inlet and outlet flows.
1. Inlet temperature
Cold inlet-
2. FlowRates
Fig. 7.3illustrates measured performance as a function ofbalanced inlet flow rates, with
the hot- and cold- side inlettemperatures fixed at 500 0
C
and 400C, respectively. At low flowrates, the
differences between inlet and outlet temperatures
arehigh. As the flow rates increase, the hot-side
outlet temperatureincreases, the cold-side outlet
temperature decreases, and there isa net increase in
Mas* flow rale xlO-' (kg s ')
heat transferred. The effectiveness decreases Fig. 7.3. Measured performance as a function of cold-side inlet
flow rate with hot-side inlet temperature and flow rate fixed.
fromapproximately 70% at low flow rates of 4.93 [4]
x 10-4 kg s-1 (25 slm)to approximately 50% at the
highest flow rates of 150 slm.
3. Unbalanced Flow
Fig. 7.4illustrates performance with unbalanced flow. In thiscase, the hot inlet flow is
fixed at 700 oC and 1.58 x 10-3 kg s-1 (80 slm), while the cold inlet flow rate varies from1.18
x10-3 kg s-1 to 1.97 x 10-3 kg s-1 (60-100 slm). Both the hotandcold- side outlet temperatures
decrease as the cold-side flowrate increases. According to heat exchanger theory,
theeffectiveness is minimum when the ratio of inlet capacity rates is unity. Inthe experiments
shown in Fig. 8, the mass-flow rates arecontrolled by mass-flow controllers. However, because
the specificheat of air varies with temperature (for air at 700 0C,Cp=1140 J kg-1 K-1; at 50 0C,
Cp=1008 J kg-1 K-1) and the averagetemperatures are different on the two sides, the capacity
rates arenot equal when the mass-flow rates are equal.
4. Pressure Drop
incorporates a relatively large heattransfersurface area into a small volume. At these flow
rates, theeffectiveness is high and the pressure drop is quite low for the NTUsdelivered.
Indeed, achieving these attributes is a primary objectiveof compact heat exchangers.
/ Following an analysis introduced by Kays and London [1] the "friction power per unit
of surface area" can be represented a
s
Where is the pressure drop, is the heat transfer area, is the mean fluid velocity, and is
the channel cross-sectional area. The pumping power is
' ,where ' is the volumetric flow rate. For a rectangular channel with height H and
widthW, the heat-transfer surface area is = WL (i.e., the floor area between the
FABRICATION METHODS
CONCLUSION
Current research on microchannels may represent only the tip of the iceberg of future
possibilities for their expanded use. Rapid advancements in micro-machining and micro-
deformation techniques are reducing the cost of fabrication while improving the reliability
of microchannel systems, thus minimizing one of the main limitations of microchannels.
process has the potential to reduce manufacturing costs relative to a comparable metal
heat exchanger. Compared to approaches in which layers are fabricated by diffusion
bonding multiple thin metal shims, the PLIS approach requires fabricating and handling
far fewer parts. Scaling from the current kilowatt-scale systems to much larger capacities
presents some significant challenges. The manifold design enables layering up with
negligible effect on pressure drop. However, further scaling probably requires serial
staging of multiple units. Serial staging of thermally isolated small units in a counter-flow
configuration can improve overall effectiveness. However, because the microchannel flow
length is increased, serial staging also increases pressure drop.
Micro heat exchangers are becoming an important area of interest in many fields of
developing technology that require compact high heat energy removal solutions. Fields
such as Micro Electro Mechanical Systems (MEMS), microelectronics, biomedical, fuel
processing, and aerospace are all pushing the limits of thermal control and are finding
ways to make smaller devices with higher heat flux potential - requiring more efficient
smaller heat exchangers tocool their key working components.
REFERENCES
Marco Hartmann Neal P. Sullivan ,Huayang Zhu , Anthony R. Manerbin, Sophie Menzer
, W. Grover Coors , Jerry L. Martin THE DESIGN, FABRICATION, AND EVALUATION
OF A CERAMIC COUNTER- FLOW MICRO-CHANNEL HEAT EXCHANGER Applied
Thermal Engineering 31 (2011) 2004e2012
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