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Chart Title

0
t Pa Pa/Pa0 ln pa/pao
-0.5 0 f(x)
50= 100
- 0.0094582533x - 0.034936483
150 200 250 300 350 400 45
0 1 1 0 R = 0.9988620064
-1
20 0.8 0.8 -0.223144
-1.5
40 0.68 0.68 -0.385662
-2
60 0.56 0.56 -0.579818 Axis Title
-2.5
80 0.45 0.45 -0.798508
-3
100 0.37 0.37 -0.994252
-3.5
140 0.25 0.25 -1.386294
-4
200 0.14 0.14 -1.966113
-4.5
260 0.08 0.08 -2.525729
Axis Title
330 0.04 0.04 -3.218876
420 0.02 0.02 -3.912023

0.98
-0.0022 -0.002375
-0.000368 -445.4545
473.6667

0
0 50 = 100
f(x) - 0.001
-0.5
R = 0.99984
-1

-1.5
Axis Title
-2

-2.5

-3

-3.5

Ax
Chart Title
Chart Title
4582533x - 0.0349364836
200 250 300 350 400 450 1.2
20064
1

0.8
Column D
Linear (Column D) 0.6 f(x) = - 0.0021566845x + 0.7225935829
Axis Title R = 0.7951349155
0.4

0.2

0
0 50 100 150 200 250 300 350 400 450
xis Title
Axis Title
1.2

0.8

f(x) = - 0.0021566845x +
0.6

0.4

Chart Title 0.2


0
0 50 = 100 150 200 250 300 350 0
-0.5 f(x) - 0.0097054714x - 0.0156295905 0 50 100
R = 0.9998403605
-1

-1.5 Column D
e
-2 Linear (Column D)

-2.5

-3

-3.5

Axis Title
t Title

.7225935829 Column B
Linear (Column B)

00 350 400 450 Chart Title

(x) = - 0.0021566845x + 0.7225935829

50 100 150 200 250 300 350 400 450


R 0.082
T 373.15 K
t Pa Ca Xa dXa dt -ra (dXa/dt)
0 1 0.032682 0 0 0
20 0.8 0.026145 0.2 0.2 20 0.0003268155
40 0.68 0.022223 0.32 0.12 20 0.0001960893
60 0.56 0.018302 0.44 0.12 20 0.0001960893
80 0.45 0.014707 0.55 0.11 20 0.0001797485
100 0.37 0.012092 0.63 0.08 20 0.0001307262
140 0.25 0.00817 0.75 0.12 40 9.804466E-005
200 0.14 0.004575 0.86 0.11 60 5.991618E-005
260 0.08 0.002615 0.92 0.06 60 3.268155E-005
330 0.04 0.001307 0.96 0.04 70 1.867517E-005
420 0.02 0.000654 0.98 0.02 90 7.262568E-006

Chart Title
0
-8 -7.5 -7 -6.5 -6 -5.5 -5 -4.5 -4 -3.5 -3
-2

-4

-6
Axis Title
-8
f(x) = 0.9545758813x - 4.6749216778
R = 0.9901786578 -10

-12

-14

Axis Title
ln(-ra dr dxa/dt) -ra ln (-ra) ln Ca k error

-8.0261146378 0.0003268155 -8.026115 -3.644088 0.011157


-8.5369402616 9.80447E-005 -9.230087 -3.806607 0.009642 -0.001515616
-8.5369402616 6.53631E-005 -9.635553 -4.000763 0.009664 2.20796E-005
-8.6239516386 4.49371E-005 -10.01025 -4.219452 0.009981 0.0003177046
-8.9424053697 2.61452E-005 -10.55184 -4.415197 0.009943 -3.88235E-005
-9.2300874422 2.80128E-005 -10.48285 -4.807239 0.009902 -4.04202E-005
-9.7225639273 1.79749E-005 -10.92654 -5.387057 0.009831 -7.15383E-005
-10.3286997308 7.54190E-006 -11.79504 -5.946673 0.009714 -0.000116223
-10.8883155188 3.96140E-006 -12.43891 -6.63982 0.009754 3.98282E-005
-11.8327771276 1.55626E-006 -13.37322 -7.332967 0.009314 -0.000439829

0
-3.5 -3
Chart Title
-2

-4 -8 -7.5 -7 -6.5 -6 -5.5


0.0093264577
-6
-2.995732274
-8

-10 -113.655155 Axis Title


-12 340.48041599 f(x) = 1.2017489903x - 4.61427674
R = 0.9307272831
-14

Axis T
-2.995732
no V
1.062441
1.062441 285.2683
1.062441 330.1113
1.062441 329.3571
1.062441 318.8737
1.062441 320.1188
1.062441 321.4255
1.062441 323.7646
1.062441 327.6382
1.062441 326.3003
1.062441 341.7084

Chart Title
0
-6.5 -6 -5.5 -5 -4.5 -4 -3.5 -2 -3
-4 k 0.009909
-6 ln (1-xa) -2.995732
-8
.2017489903x - 4.6142767429 -10 V 320.46
9307272831 -12
-14
-16

Axis Title
L
-11
tau (s) Ca0 (mol/L) Caf (mol/L) Xa -ra
50 2 1 0.5 0.02
16 1.2 0.8 0.3333333333 0.025
60 2 0.65 0.675 0.0225
22 1 0.56 0.44 0.02
4.8 0.48 0.42 0.125 0.0125
72 1 0.37 0.63 0.00875
40 0.48 0.28 0.4166666667 0.005
112 0.48 0.2 0.5833333333 0.0025
log -ra log Ca log (-ra) = log K + n log Ca
-1.69897 0
-1.60206 -0.09691 slope = n 1.428008 V = vo.Ca0.Xa/(-ra)
-1.647817 -0.187087 intercept = log K -1.47558
-1.69897 -0.251812 k 0.033452
-1.90309 -0.376751
-2.057992 -0.431798
-2.30103 -0.552842
-2.60206 -0.69897 Chart Title
0
-0.8 -0.7 -0.6 -0.5 -0.4 -0.3 -0.2 -0.1 0
-0.5

-1
Colum
Axis Title -1.5
f(x) = 1.428007921x - 1.4755798334 Linear
R = 0.8791255855 -2

-2.5

-3

Axis Title
= vo.Ca0.Xa/(-ra)

0
1 0
-0.5

-1
Column G
-1.5
34 Linear (Column G)
-2

-2.5

-3
tau (s) Ca0 (mol/L) Caf (mol/L) -ra log Caf log(-ra)
50 2 1 0.02 0 -1.69897
16 1.2 0.8 0.025 -0.09691 -1.60206
60 2 0.65 0.0225 -0.187087 -1.647817
22 1 0.56 0.02 -0.251812 -1.69897
4.8 0.48 0.42 0.0125 -0.376751 -1.90309
72 1 0.37 0.00875 -0.431798 -2.057992
40 0.48 0.28 0.005 -0.552842 -2.30103
112 0.48 0.2 0.0025 -0.69897 -2.60206
Chart Title
0
-0.8 -0.7 -0.6 -0.5 -0.4 -0.3 -0.2 -0.1 0
-0.5

-1
Column G
Axis Title -1.5
f(x) = 1.428007921x - 1.4755798334 Linear (Column G)
R = 0.8791255855 -2

-2.5

-3

Axis Title
umn G
ear (Column G)

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