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    PV NRT MPV MRT: (A) - by Eq. (A)

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    anjar
    The document discusses equations for calculating the compressibility factor (Z) and deviation factor (B) for real gases based on measured quantities of pressure (P), volume (V), temperature (T), mass (m), and molar mass (M). It states that for Z ≈ 0.9 and approximately equal errors in P, V, T, m, and M, a maximum ±1% error in Z requires errors in the variables of less than 0.2%. Similarly, for the same values of Z and equal errors, a maximum ±1% error in B requires errors in the variables of less than about 0.02%. As Z approaches 1, the error in B approaches infinity.

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    PV NRT MPV MRT: (A) - by Eq. (A)

    Uploaded by

    anjar
    9 views2 pages
    The document discusses equations for calculating the compressibility factor (Z) and deviation factor (B) for real gases based on measured quantities of pressure (P), volume (V), temperature (T), mass (m), and molar mass (M). It states that for Z ≈ 0.9 and approximately equal errors in P, V, T, m, and M, a maximum ±1% error in Z requires errors in the variables of less than 0.2%. Similarly, for the same values of Z and equal errors, a maximum ±1% error in B requires errors in the variables of less than about 0.02%. As Z approaches 1, the error in B approaches infinity.

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    The document discusses equations for calculating the compressibility factor (Z) and deviation factor (B) for real gases based on measured quantities of pressure (P), volume (V), temperature (T), mass (m), and molar mass (M). It states that for Z ≈ 0.9 and approximately equal errors in P, V, T, m, and M, a maximum ±1% error in Z requires errors in the variables of less than 0.2%. Similarly, for the same values of Z and equal errors, a maximum ±1% error in B requires errors in the variables of less than about 0.02%. As Z approaches 1, the error in B approaches infinity.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
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    Download as docx, pdf, or txt
    9 views2 pages

    PV NRT MPV MRT: (A) - by Eq. (A)

    Uploaded by

    anjar
    The document discusses equations for calculating the compressibility factor (Z) and deviation factor (B) for real gases based on measured quantities of pressure (P), volume (V), temperature (T), mass (m), and molar mass (M). It states that for Z ≈ 0.9 and approximately equal errors in P, V, T, m, and M, a maximum ±1% error in Z requires errors in the variables of less than 0.2%. Similarly, for the same values of Z and equal errors, a maximum ±1% error in B requires errors in the variables of less than about 0.02%. As Z approaches 1, the error in B approaches infinity.

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    of 2

    Jawab .

    The Compressibility factor is related to the measured quantities by :

    PVt MP V t
    Z= nRT = mRT

    (A)

    By Eq. (3.38)

    ( Z1 ) M V t
    B=(Z-1)V= m

    (B)

    (a). By Eq. (A)

    t
    dZ dM dP dV dm dT
    Z = M + P + Vt - m - T

    (C)

    Thus Max |% Z| | M|+| P|+| V t|+| m|+ T |

    Assumsing a Aproxximately equal error in the fiv variable, a 1 Maximum error in

    Z requires error in the variable of <0,2%.

    dB Z dZ d V t dM dm
    (b). By Eq. (B) = + + t +
    B Z1 Z V M m

    Z dP dT 2 Z 1 d V t dM dm
    By Eq. (C)
    dB
    =
    B Z1 P (

    T
    + )
    Z1 V t
    +
    M (

    m )
    Therefor
    Max |%
    B | Z1
    Z
    |(| P|+| T|)+ 2ZZ1
    1
    t
    (| V |+| M |+| m|)

    For Z 0,9 and for approximately equal error in the five variables, a 1

    maximum error in B requaires errors in the variables of less than about 0,02%.This is

    because the divisor Z-1 0,1thelimit as Z 1, the errorB approaches

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