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Chemical Bonding Solution PDF
Chemical Bonding Solution PDF
6) (D)
7) (A) HS+ OS
u
u C C H
S+
u H O
S
O22 1 ; O2 2
8) Bond order of
O 2 = 1.5 ; O 2+ 2.5
Hence, Stability O2 O2 O2 O22 ; Ans : (B)
2
18) (B) NH3 Sp3 ; PHl4 dSp 2 (Square planar)
PCl5 Sp3d ; BCl3 sp 2 .
23) (B) More than number of H atoms, more is the H Bonding hence, Due to higher intermolecular
forces of attraction, higher is the M. pt. H C CH 3 3
O
H 3C OH
24) (A) Lead Oxide PbO2. N
OH
3 11
25) (D) 12 12 1 8
2 10 aa 6
4 5 7 NH 2
OH
OH O OH O
O
26) (C)
u
u
27) (C) Dipole Moment of u
u
3 1.5 D p12 p22 2 p1 p2 cos 600
2.6 D. P1 P2 .
28) (D) O H bond is more polar than N H bond. & SO + on H is more in O H bond. Also N is
better donor than O
29) (C) H H
C C
120 0
H CH3
Comprehension Type
Passage 1:
e
3) (D) PI5 and PBr6 donot exist due to steric factors. In PH5, Because of its low electronegative
H atom cannot effect the contraction of dz2 orbital to form Sp 3 hybridized P = atom.
e
4) (B) PBr6 doesnot exist since P cannot accommodate 6 Br atoms around it due to steric
hindrance.
5) (D) 30
P Cl + P Cl + P Cl + P Cl 4
35
5
30 37
5
31 35
5
31 37
5
i) 31
P Cl Cl
35 37
P Cl Cl 31 35 37
1 4 ax 4eq
= 2 forms
31
P Cl
35 37
Cl3 Cl
eq
37
ax
ii) 31
P Cl Cl
35
2
37
3
31
Pax Cl Cl
35
2 eq
37
3
3 = 31
P Cl Cl Cl Cl
35 37 35 37
2 eq
ax
forms 31
P Cl Cl Cl
37 35 37
2
ax eq
iii) 31
P Cl Cl 3 forms ; same as (ii)
35
3
37
2
iv) 31
P Cl Cl 2 forms ; same as (ii)
35 37
4
Similarly with 30P atom as central Atom, 10 forms will be there. Total = 24.
6) SF4 has 4 G.P + 1 L. P ; Hence (C).
Passage 2:
7) (C) NC CN NC CN
i) C C C
NC CN NC CN
bonds = 8 bonds = 9
bonds = 8 bonds = 9
H H O H O H
ii)
CH CH CHO = H C
3 2
C C H CH COCH = H C C C H
; 3 3
H H H H
P ropan al Propauone
ii) XeF4 is square planar in shape.
SF4 has See saw Shape.
iv) Due to smaller orbital size, effective overlapping take place in u u bond.
Passage 3:
1) (D)
3) (B)
Passage 4:
1) A) BeCl2 has maximum covalent character because of smallest size of cation Be2
3) C) Highest positive change and smallest size of cation (Al 3 ), hence maximum polarization and
covalent character.
4) B) Liu has maximum covalent character, hence it will be most soluble in non polar solvent ether.
Passage 5:
1) A) and B) These are planar molecules. XeF4 has square planar shape.
XeF4 has trigonal planar shape.
2) p q l
p 1.2 1018 esu cm
q
l 108 cm
q 1.2 1010 esu.
1.2 1010 1
Fraction of change 0.25 .
4.8 1010 4
3) (C)
u u CH3 u
u
o-dichloco u toluene
m -dichlone
benxene b en zene u
p-dichloro
ben zen e
4) (D)
N N
H H H F F F
1.5 10 29 C.m
5) % Ionic character 100 62.5%
1.6 10-19 C 150 10 12 m
Passage 6:
1) B
2) A
3) A.
5) (B)
6) (D)
9) (C)
8-
10) (A) CH 3 CH 2 O H
11) (C) H
C H
H Sp 2.
12) (A)
CH 3
16) (A) 2 B.P + 2 L. P ; Sp3 hybridized.
17) (B)
18) (C) Least oxidation state, least polarization, least covalent character.
20) (C)
N
O
F F F H H H
O F
N B
O O F F
2
21) (B) Ca +2 C C 1 2
23) (A) O
C Sp 2
H O O H
24) (C)
25) (D)
26) (B)
27) (A)
28) (C)
30) (A) S
H H
F
F F F
31) (D) S F C Xe
F F
32)
F F F F F
4 BP + 1 L.P 4 B.P + 0 L.P 4 B.P + 2 L.P
+
33) (B) NO+2 Sp ONO ; NH 4 Sp3
O +
NO3 Sp2 H
N
N
O O H H H
34) (A)
35) (B)
36) (A)
H F
H N B F
H F
37) (C)
(4) B, C. H CH 2 CH 3 H H
C C C C
H 3C H H 3C CH 2 CH 2 CH 3
tra n s -2 -p e n te n e cis-3 -H e x e n e
(6) (B)
(7) (A)
(8) (B)
(10) B, C, D
(11) A, B, D
(13) A, C, D Cl Hg Cl ; ; S=C=S
u I u
14) B, D
15) A, D
16) A, B, C H ; FC CF ; F
F
C C C
H H H F F
17) A, B, C, D.
19) A, C
20) Al OH 3 NaOH Al OH 4 Pu 5 Pu 4 Pu 6
Sp 3 Solid Sp3 Sp 3d2
2
SiF4 2HF SiF6 Hence, A, C, D.
Sp3 Sp 3d 2
O O
O
22) C, D HCO 2 H C
HCO 2 H C
H C O H C O
O O
B.O of HCl 2 1.5 B.O of CO 32 1.33
formate ion Carbonate ion
Bond length of HCO2 Bond length of CO32
F H
23) A, C F
S C
F H
F
24) A, B H H u u u
H
B B Al Al
H H u u u
H
2
25) A, C, D N N O N N N O N N O
Resonating Shushes with formal charges.
26) A, B, C, D.
27) A, B, C, D
More electronegative element in each case, i.e. O and F occupy axial position in I & II respectively.