REVISION

TOPIC: LIQUID SOLUTIONS,SURFACE CHEMISTRY,SOLID STATE

1. An azeotropic solution of two liquids has a boiling point lower than either of them when it:
(a)Shows negative deviation from Roaults law
(b)Shows positive deviation from Roaults law
(c)Shows ideal behaviour
(d)is saturated

2. What is the density (in g mL1) of a 3.60 M aqueous sulfuric acid solution that is 29.0% H2SO4 by mass?
(a)1.22 (b)1.45 (c)1.64 (d)1.88

3. The normal boiling point of water is 373 K(at 760 mm), vapour pressure of water at 298 K is 23 mm. then boiling point of
water at 23 mm pressure will be :
(a)373 K (b)298K (c)51.6 K (d)12.5 K
4. Potassium crystallises in a bcc lattice with a unit cell length . Distance between nearest neighbour is
o o o o
(a) 5.2 A (b) 4.5A (c) 2.8A (d) 3.8A
5. When a b c, 90, the unit cell is known as
(a)Tetrahedral (b)Orthorhombic (c)Triclinic (d)Monoclinic

6. A metal X has fcc structure. The length of unit cell is 409 pm. If the density of the metal is 2.7 gm / cc. Calculate the
atomic mass of X atom.
(a)62.9 gm mol-1 (b)16.80 gm mol-1 (c)28.8 gm mol-1 (d)36.80 gm mol-1

7. The tetrahedral voids formed by ccp arrangement of Cl- ions in rock salt structure are
(a)occupied by Na+ ions (b)occupied by Cl- ions
+ -
(c)occupied by either Na or Cl ions. (d)vacant.
8. Which of the following expressions is correct for an NaCl unit cell with lattice parameter a?

(A) (b) (C) (d)

9. In a compound oxide ions have cubic close packing arrangement. Cations A are present in half of the tetrahedral holes and
cation B occupy the octahedral holes. The simplest formula of the compound
(a)AB2O4 (b)A2BO4 (c)ABO2 (d)ABO

10. A crystal of lead (II) sulphide has NaCl structure. In this crystal the shortest distance between a Pb 2+ ion and S2- ion is 297
pm. What is the volume of unit cell in lead sulphide?
(a)209.6 10-24 cm3 (b)207.810 - 23 cm3 (c)22.310 - 23 cm3 (d)209.810 - 23 cm3

11. The separation of colloidal particles (or purification of sol) from particles of molecular dimensions is known as:
(a) photolysis (b) dialysis (c) pyrolysis (d) peptization

12. Fog is a colloidal solution of:

(a) liquid particles dispersed in gas (b) gaseous particles dispersed in a liquid
(c) solid particles dispersed in a liquid (d) solid particles dispersed in gas

13. The dispersed phase in colloidal iron (III) hydroxide and colloidal gold is positively and negatively charged respectively,
which of the following statement is not correct?
(a) solution coagulates gold sol more readily than iron (III) hydroxide sol
(b) solution causes coagulation in both sols
(c) Mixing of two sols have no effect
(d) Coagulation in both sols can be brought about by electrophoresis

14. The vant Hoffs factor (i) for a dilute aqueous solution of Na2 SO4 is
(a) (b) (c) (d)
15. In a mixture A and B components show negative deviation as:
(a)
(b)
(c) A B interaction is weaker than A A and B B interaction
(d) none of the above reason is correct

16. A 0.5 molal aqueous solution of a weak acid (HX) is 20 per cent ionized. The lowering in freezing point of this solution is:
K f = 1.86K/m for water
(a) 0.56 K (b) -0.56 K (c) 1.12 K (d) -1.12 K

17. Lowering in vapour pressure is the highest for:

(a) 0.2 m Urea (b) 0.1 m Glucose (c) 0.1 m MgSO4 (d) 0.1 m BaCl2
18. A solution containing 4 g of a non-volatile organic solute M.W. = 280, per of 100 mL was found to be isotonic with a 5%
(wt./vol.) solution of an organic non-valatile solute. The molecular weight of latter is:
(a) 350 (b) 35 (c) 3500 (d) 860

19. An ideal solution was obtained by mixing methanol and ethanol. If the partial vapour pressure of methanol and ethanol are
2.619 KPa and 4.556 KPa respectively, the composition of vapour (in terms of mole fraction) will be:
(a) 0.635 MeOH, 0.365 EtOH (b) 0.365 MeOH, 0.635 EtOH
(c) 0.574 MeOH, 0.326 EtOH (d) 0.173 MeOH, 0.827 EtOH

20. On the basis of intermolecular forces predict the correct order of decreasing boiling points of the compounds:
(a) (b)
(c) (d)

21. A binary solid with B- ions constituting the fcc lattice and A+ ions occupying 25% tetrahedral holes. The formula of solid is
(a)AB (b)A2B (c)AB2 (d)AB4

22. CsBr has CsCl structure with edge length 4.3. The shortest inter atomic distance in between Cs + and Br- is
(a)3.72 (b)1.86 (c)7.44 (d)4.3

23. A mineral having the formula AB2 crystallizes in the cubic close packed lattice, with the A atom occupying the lattice
points. The co-ordination number of B atoms and the fraction of the tetrahedral sties occupied by B atoms are
(a)4,100% (b)6,75% (c)1,25 % (d)6,50 %

24. Graphite is a soft solid lubricant extremely difficult to melt. The reason for this anomalous behaviour is that graphite:
(a) is a non-crystalline substance
(b) is an allotropic form of diamond
(c) has molecules of variable molecular masses like polymers
(d) has carbon atoms arranged in large plates of rings of strongly bound carbon atoms with
weak interpolate bonds

25. If Z is the number of atoms in the unit cell that represents the closest packing sequence ABC ABC -, the number of
tetrahedral voids in the unit cell is equal to :
Z Z
(a) Z (b) 2Z (c) (d)
2 4

26. Total volume of atoms present in a face-centred cubic unit cell of a metal is (r is atomic radius):
(a) (b) (c) (d)

27. A catalyst for a reversible reaction is a substance that:

(a) supplies energy to the reaction
(b) decreases the time to reach equilibrium
(c) increases the equilibrium concentration of the products
(d) change the equilibrium constant of the reaction

28. An increase in the concentration of adsorbate at the surface relative to its concentration in bulk phase is called:
(a) adsorption (b) enthalpy (c) absorption (d) none of these
29. Chemisorption is:
(a) multimolecular in nature (b) reversible
(c) often highly specific and directional (d) not very specific

30. BaSO4 acts as .. for Pd catalyst in Rosenmunds reaction:

(a) promoter (b) poison (c) auto-catalyst (d) none of these

ANSWER KEY:

1. B 2. A 3. B 4. B 5. C
6. C 7. D 8. A 9. D 10. A
11. B 12. A 13. C 14. C 15. B
16. C 17. D 18. A 19. B 20. B
21. C 22. A 23. A 24. D 25. B
26. D 27. B 28. A 29. C 30. B