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3DayPIPonMetallurgyforNonMetallurgist

from10th to12th April2017

SolidificationofMetalsand
Alloys

Mr.Udayan Pathak

Pune Chapter
CRYSTALSTRUCTURES

BCC
ALFA
IRON
Cr
MowV
SIMPLE CUBIC BCC

FCC
Al
Mg Graphite
FCC
Cu
Ni HCP
2

Pune Chapter
COOLINGCURVEOFPUREMETAL

Pune Chapter
COOLINGCURVEFORPUREMETAL

Pune Chapter
COOLINGCURVEFORPUREMETALAND
ALLOYS

Pune Chapter
ALLOTROPICTRANSFORMATIONINPURE
IRON

Pune Chapter
IRONCARBONEQUILIBRIUMDIAGRAM

Pune Chapter
PHASESINIRONCARBONEQUILIBRIUM DIAGRAM

STEELS

1. DELTA IRON It is an 2. Gamma iron or Austenite It


interstitial solid solution of is an interstitial solid solution
carbon in delta iron. It is stable of carbon in Gamma iron. It is
between 1539 to 14000 C stable between 1498 to 7230C .
It has FCC structures. It has
maximum solubility of carbon
2% at 11300 C

Mechanicalproperties
Tensilestrength 150000psi
Hardness RC40
Percentageelongation 40%
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Pune Chapter
PHASESINIRONCARBONEQUILIBRIUMDIAGRAM

STEELS

3. ALPHA IRON or FERRITE It is an 4.IRONCARBIDEOR


interstitial solid solution of carbon in CEMENTITE Itisintermetallic
Alpha iron having BCC structure and compoundofironandcarbon
stable below 9100C with maximum havingformulaFe3C.Itis
solubility of carbon in alpha iron metastable phase.Maximum
0.025 % at 723 0 C solubilityofcarbonis6.67%.

Mechanicalproperties:
Mechanical properties:
Tensilestrength 5000 psi
Tensile strength 40000 psi
Hardness 550BHL
Hardness 100 BHL
Percentageelongation 0%
Percentage elongation 25 %

Pune Chapter
PHASESINIRONCARBONEQUILIBRIUM DIAGRAM

STEELS
5.PERLITE Itisformedbyeutectoidreactionat7230C at0.8%carbon
composition.
Itisamechanicalmixtureofferriteandcementite havingaratio7:1.
Mechanicalproperties:

Tensilestrength 1,20,000 psi


Hardness RC20
Percentageelongation 10%

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Pune Chapter
PHASESINIRONCARBONEQUILIBRIUMDIAGRAM
REACTIONS
LIQUIDTOSOLID

1. Monoeutectic :
L1 L2+S
L1 L2+DeltaIron
2.Peritectic 14980Cand0.18%C:
L+S1 S2
L+Delta Austenite
3.Eutectic11300 Cat4.3%C:
L S1+S2
L Austenite+Cementite
(Ledeburite)

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Pune Chapter
PHASESINIRONCARBONEQUILIBRIUMDIAGRAM

REACTIONS
SOLIDTOSOLID
1. Eutectoide at7230 C:
S1 S2+S3
Austenite Ferrite+Cementite
(.8%C)(.025%C)(6.67%C)
(100%) (87.5%)(12.5%)
(PERLITE)
Thisreactionisveryimportantfromheattreatmentofsteelandcastirons.

Anyequilibriumdiagramhavingeutectoide reactioncanbeheattreated
similartosteelfore.g.Aluminium Bronze

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Pune Chapter
THANKS!!

Pune Chapter

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