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  • Lembar Perhitungan HMJ

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    Rendy Renaldy Firdaus
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    This document contains calculations for an experiment on transesterification of palm oil. It summarizes: 1) Calculations for the reagents sodium hydroxide solution and hydrochloric acid used in the experiment. 2) Experimental results showing conversion of glycerides to fatty acids over time for 3 variables where the molar ratio of methanol to sodium hydroxide was varied. 3) Determination of the reaction equilibrium constant for each variable by linearizing the integrated rate law expression and calculating conversions from experimental data.

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    Lembar Perhitungan HMJ

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    This document contains calculations for an experiment on transesterification of palm oil. It summarizes: 1) Calculations for the reagents sodium hydroxide solution and hydrochloric acid used in the experiment. 2) Experimental results showing conversion of glycerides to fatty acids over time for 3 variables where the molar ratio of methanol to sodium hydroxide was varied. 3) Determination of the reaction equilibrium constant for each variable by linearizing the integrated rate law expression and calculating conversions from experimental data.

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    16 views6 pages

    Lembar Perhitungan HMJ

    Uploaded by

    Rendy Renaldy Firdaus
    This document contains calculations for an experiment on transesterification of palm oil. It summarizes: 1) Calculations for the reagents sodium hydroxide solution and hydrochloric acid used in the experiment. 2) Experimental results showing conversion of glycerides to fatty acids over time for 3 variables where the molar ratio of methanol to sodium hydroxide was varied. 3) Determination of the reaction equilibrium constant for each variable by linearizing the integrated rate law expression and calculating conversions from experimental data.

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    © All Rights Reserved
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    of 6

    LEMBAR PERHITUNGAN REAGEN

    1. Perhitungan NaOH 0,125 N 300 ml

    gr 1000
    x eq
    N= BM x V x 98%

    gr 1000
    x1
    0,125 = 40 x 300 x 98%

    Gr = gram NaOH

    2. Densitas Minyak Jarak


    M 2M 1
    = 25
    46,33021,51
    = 25 = 0,9928 g/ml

    3. Densitas Katalis (HCl)


    M 2M 1
    = 25
    43,76315,269
    = 25 = 1,13976 g/ml

    4. Volume HCl
    N x V basis x BM
    VHCl = x e x

    0,125 x 0,27 x 36,5


    VHCl = 25 x 1 x 1,13976

    VHCl = 4,3233 ml
    5. Perhitungan variabel 1 (Mol mj : Mol aq = 1 : 8)
    mj x V mj aq x V aq 1
    ( ) : ( ) =
    BM BM 8
    0,9928 x V mj 1 x V aq 1
    ( ) : ( ) =
    1067 18 8

    ( 9,3046 x 104 ) Vmj 1


    0,055Vaq = 8

    Vmj = 7,3888 Vaq

    VBasis = Vmj + Vaq + Vemulsifier + VHCl


    270 = Vmj + Vaq + 15 + 4,3233
    Vmj + Vaq = 250,6767
    7,3888 Vaq + Vaq = 250,6767
    Vaq = 29,8016 ml
    Vmj = 220 ml
    6. Perhitungan variabel 2 (Mol mj : Mol aq = 1 : 9)
    ( 9,3046 x 104 ) Vmj 1
    0,055Vaq = 9

    Vmj = 6,5678 Vaq


    Vmj + Vaq = 250,6767
    (7,3888+1) Vaq = 250,6767
    Vaq = 33,124 ml
    Vmj = 217,55 ml
    7. Perhitungan variabel 3 (Mol mj : Mol aq = 1 : 10)
    ( 9,3046 x 104 ) Vmj 1
    0,055Vaq = 10

    Vmj = 5,911 Vaq


    Vmj + Vaq = 250,6767
    (5,911+1) Vaq = 250,6767
    Vaq = 36,27 ml
    Vmj = 214,4067 ml
    LEMBAR PERHITUNGAN

    1. Analisis Kadar Asam Lemak dalam Minyak

    ( VxN ) NaOH x BM
    x 100
    % kadar asam lemak = ( x V ) MJ

    ( 9,3 x 0,125 ) x 40
    x 100
    = ( 0,9928 x 10 )

    = 4,68 %

    % gliserida = 100% - %kadar asam lemak

    = 100% - 4,68% = 95,32%

    2. Perhitungan Asam Lemak Awal

    ( V x N ) NaOH 9,3 x 0,125


    CAo Asam lemak = ( x V ) MJ = 0,9928 x 10
    mol asam lemak
    = 0,117 /gr mj
    gliserida
    Gliserida = %asam lemak x CAo

    95,32
    mol asam lemak
    = 4,68 x 0,117 /gr mj
    mol gliserida
    = 2,38 /gr mj
    3. Perhitungan setelah Hidrolisa
    ( V x N ) NaOH V ml x 0,125 N
    CA Asam lemak = ( x V ) MJ = 0,9928 gr /ml x 10 ml
    mol asam lemak
    = 0,0125V /gr mj
    CAs = CA CAo
    = 0,0125V 0,117
    4. Perhitungan Nilai Konstanta Reaksi
    dC B
    dt = k.CB
    CB t
    dC B

    dt =k dt
    C B0 0

    CB
    ln = k.t
    CB0

    C B 0 (1 X A )
    ln = k.t
    C Bo

    ln ( 1X A )=k .t

    y=mx

    5. Menghitung Konversi (XA)


    C As ( 0,0125 V 0,117 )
    X A= =
    MolGliserida 2,38

    6. Hasil Percobaan
    a. Variabel 1 (Mol mj : Mol aq = 1 : 8)

    t (Menit) V NaOH CA CAs XA 1 - XA


    (ml)
    0 24 0,3 0 0 1
    5 25 0,3125 0,1955 0,082 0,918
    10 27 0,3375 0,2205 0,093 0,907
    15 29 0,3625 0,2455 0,103 0,897

    Variabel 1
    0.4
    0.35
    0.3
    0.25 LN(1-XA)
    0.2
    0.15
    0.1
    0.05
    0
    0 2 4 6 8 10 12 14 16

    b. Variabel 2 (Mol mj : Mol aq = 1 : 9)

    t (Menit) V NaOH CA CAs XA 1 - XA


    (ml)
    0 19 0,2375 0 0 1
    5 20,2 0,2525 0,1355 0,057 0,943
    10 21 0,2625 0,1455 0,061 0,939
    15 25 0,3125 0,1955 0,082 0,918

    Variabel 2
    0.3

    0.25

    0.2
    LN(1-XA)
    0.15

    0.1

    0.05

    0
    0 2 4 6 8 10 12 14 16

    c. Variabel 3 (Mol mj : Mol aq = 1 : 10)

    t (Menit) V NaOH CA CAs XA 1 - XA


    (ml)
    0 17,5 0,21875 0 0 1
    5 18 0,225 0,108 0,0454 0,9546
    10 18,4 0,23 0,113 0,0474 0,9526
    15 18,5 0,23125 0,1142 0,048 0,952
    Grafik Linearisasi Variabel
    0.12
    f(x) = 0.01x + 0.02
    R = 0.78
    Variabel 1 0.1 Linear (Variabel 1) Variabel 2 Linear (Variabel 2)
    0.08 f(x) = 0.01x + 0.01
    R = 0.85
    0.06
    -ln (1-XA) f(x) = 0x + 0.01
    0.04 R = 0.64

    Variabel 30.02 Linear (Variabel 3)

    0
    0 2 4 6 8 10 12 14 16

    Waktu (Menit)

    7. Perhitungan Kesetimbangan Reaksi


    XA
    K = XA1

    a. Variabel 1
    0,103
    K = 0,1031 = 0,1148
    b. Variabel 2
    0,082
    K = 0,0821 = 0,0893
    c. Variabel 3
    0,048
    K = 0,0481 = 0,2076

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