Professional Documents
Culture Documents
CML 100 Questions PDF
CML 100 Questions PDF
Using the given molecular formula (C4H8O), write four different functional isomers with
their names.
What should be the observed specific rotation of a sample having 82% eeR?
(The pure S enantiomer in the sample has a specific rotation of 23.7)
a) b) OH HO
Name the following Cycloalkanes
Calculate the relative proportions of (+)-2-butanol, []D = +13.5o, and (-)-2-butanol, []D = -
13.5o, required to give a specific rotation of +0.54o.
A. 0
B. 1
C. 2
D. 3
E. 4
F
H
H Cl F I
Cl H
Which diene reacts faster in Diels-Alder reaction with acrolein, arrange them fastest to slowest.
Give one example of [2,3] sigmatropic rearrangement. Write the names of the reagent and
product formed in this example.
On heating allyl alcohol with triethyl orthoacetate in presence of catalytic propionic acid produced ethyl pent-4-
enoate in good yield. Discuss this transformation with mechanism and tell the type of pericyclic reaction involve
in the same.
Write the structure of product formed with correct stereochemistry.
Why retro synthesis is important in organic synthesis. Explain it with suitable example.