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313 Chemistry SR Secondary Paper 2014
313 Chemistry SR Secondary Paper 2014
313 Chemistry SR Secondary Paper 2014
CHEMISTRY
T{TFFTfu #+*"' 48/oss/1
General Instructions :
1. Candidate must write his/trer Roll Number on the first page of the question paper. I
2. Please check the question paper to verify that the total pages and total number of questions
contained in the paper are the same as those printed on the top of the first page. Also check to
see that the questions are in sequential order.
3. Making any identification mark in the answer-book or writing roll number anywhere other than
the specified places will lead to disqualification of the candidate.
4. write your Question Paper code No. 48/oSS/1, set llFl on the answer-book.
5' (a) The question paper is in English/Hindi medium only. However, if you wish, you can
answer in any one of the languages listed below :
English, Hindi, Urdu, Punjabi, Bengali, Tamil, Malayalam, Kannada, Telugu,
Marathi, Oriya, Gujarati, Konkani, Manipuri, Assamese, Nepali, Kashmiri, Sanskrit
and Sindhi.
You are required to indicate the language you have chosen to answer in the box provided in
the answer-book,
(b) If you choose to write the answer in the language other than Hindi and English, the
responsibility for any errors/mistakes in understanding the question will be yours only.
amq arTdPr
1. q'ft{qT qFr-rFT +crd y q{ s{TTr sr{#qis' effi{c fu{ii r
2. Fcqr Iff{r-qr s} d.q ii fm q* *'ga Vei aeTr cwi st Tir+ Ei i+w X kr* wre ys + vEt oc{
t
ofi r Fs qr?T st ds rit s'r ii t*'wq *fq- Fc ii + r
3. sfli-gkrsT ii qrqq-flqg q*i e*rqr f{fu tFii *. srfrfirff 66T qt q-{Fci ftryqi c{ qlhrqT di
erqtq atwr Eidfi |
iliffi: F4, T* .@, Eirri{r, dkiT, rffictFic, rrg, +qr5 qq&, sfuql, {sqrfr, sffi,
cfrqrt, srutfrrqr, ffi, sr*fr, di?T olt{.Rrt*fr | .
Tcqr rtr-gnnsT ii tqq rrqqrcFr ii ftrci P*' e+rq fl*s rTrsr if smftre rtt r
313/oss/10s-A ll lllllllllllllllllllllil
",J
CHEMISTRY
Tsrr{flTdr{
(313)
Note : (i) This Question Paper consists of two Sections, viz, rA, and ,Bt.
(ii) A/J questions from Section 'A' are to be attempted.
(iii) Section 'B' has two options. Candidates are required to attempt questions from
one option only.
SECTION -A
Eluit- eT
'frfr61frrrq'qfoilkdqikq r
3. What is 'Gel' ?
'Q6' q1| 7
313/OSS/105-A
4. What do the following symbols (SI units)
represent :
(i) ns (ii) ps
(iii) Gg (iv) Mg
fiErfrkd (SI unirs) {*,o qqr fucfud q.r$ t :
(t ns (ii) ps
(iii) Gg (iv) Mg
(i) Specificiry
(ii) Reversibility
313/OSS/105-A
8. How can you separate pure alumina (A/2O3) from iron (iii) oxide present in bauxite ore ?
dqqEe slzrgr'g sfuo eilrr{ (iii) sTrwr{s t qa qqeiT (A/2o3) si N yqo loqr qr
voar t ? qrcrq s{ftfuqrcTt + frq {qtqfrq- {dtqr{rT fufuq r
9. (a) What type of bonding helps in stabilizing the cr-helix structure of proteins ?
(b) List any two types of RNA molecules found in the cell. 2
(s) q)ztii dt cr-{sffi i{ffiT dr fis{s{t { q6r.rdr o.{-i eTd sr6r;wr rrr yrrf{rFn e}m t t
6e) +iftrfi ii qrq qT+ qrd d s{R.gt.g. qg qh-sh t t r
(iii) Calculate the amount of one of the reactants which remains unreacted. 4
11. (a) An electron is in 4d orbital. What are the possible values of n, /, m, and m. for this
electron ?
(b) Which of the following orbitals are not possible ? Give reason for your answer
1p,2d,3s,4f. 4
lp,2d,3s,4f.
313/OSS/105-A 4
12. (a) State Raoult's law for a solution containing volatile components.
(g) 100.00 s +qt{ { codw ulqwz-q ffiq st 2.00 t *flq 6T lFqis 0.40
sqr*r qrm}
K 6-rr d rrqr r ffiq qqrei qr q)-qrurdrqn qRqfdfr qifqrr r
13. The standard enthalpy of formation of cor(r), Hrot,r and glucose CuHrrou(s) are
-395.0 kJ mol-r, -269.4 kJ mol-1 and -1169.8 kJ mol-l respectively. Calculate the
enthalpy of combustion of glucose.
(c) The sign of AH, AS and AG for the reaction B A at the same temperature.
-+
(d) Predict the possibility of the reaction B
---+ A at a very low temperature. Justify
your answer.
loqfr nrq T w, !t-s'sqrvls 3TRTBrfl A ---+ B Fr?r: qqh * err n-o cnfi t r wa *1fuq :
Cs) qni|*qr*fume'rfu-eq
(g) sTFTfu.qT*funcorfua
CT) 3tfi{hqT B
---+ A +flflr sqt drq q-{ aH, AS sfu Ac +fuT
F) sre|=tr frq'dTq qt erFrfmqr B
---+ A E+ {qTqqr ftqr qFJk "ifuq r e+q+ efr1 *t yfu-
+1fuq r
313/OSS/105-A
15. (a) Arrange the following in the decreasing order of their acid strength :
(i) C+ 2Hr,SOo)*
(ii) 2XeFr+2HrO+ 4
(i) c + 2HzR->
(ii) ZXeFr+2HrO-+
16. (a) Write the structure and one important use of anhydrous aluminium trichloride.
(b) Calculate the oxidation number of the metal atom present in the complex ion of
KolFe (CN)ol
19 FTE{ffid {i5d + {ga enrrt ii sqfisfr $nq + vtlrg dr effir {qr qfit+kfr
qfrtqq sirri$m or en-tqfr.q.S. qrq fafug :
KolFe (CN)ol
313/OSS/105-A
17. (a) Account for the following :
g; srTqfuftTfuHsqmrq*.*oti :
313/oss/105_A
g. (a) State Kohlraush's law of independent migration of ions. Mention its'one
application. Draw a graph showing variation in molar conductivity of weak and
sffong electrolYtes.
(b) For a chemical reaction R -+ P, the variation in the concentration, logro [R] Vs
,l|
4.
a0
Time (S)
Ce1 qm.{rqnkfi sIF{bqT R + P +|f,g, qrFl t, *'qrq qrtril logrofR] ii qfredq qr ende
frq n+Tt fEqr tnn t :
,t
I
tv,
b!
wm(S)-.+
q e${frqr *.ftlq
(i) s{F{fuqT*ifuwttt
313/OSS/10s-A
20' Identify the main product formed when ethanol
is reacted with Soc/, and write the
reaction equation involved. Identify the products
formed when this product is reacted
with each of the following reactants and write the
chemical equations involved :
"uqt**-qrq
313/OSS/105-A
SECTION - B
EIng:_ q
OPTION -I
flas@- I
(Environmental Chemistry)
rqqiqflrfrq {Fm)
(b) Rocks.
wffrq *'reisq'r qrq qotwfiilwf
CO qfi*q
Cel qil+ffrt r
22. List any four human activities through which heavy metals get into the environment. 2
qiq st Hi qlr qfrhftiqt si !f+ed +1|qe fwt'srn'rTfr qq( qqfqiur tf qeai t r
23. Identify the rays that are used in the treatment of cancer. What type of radiations are
these ? Write any two anthropogenic sources of these types of radiations. 2
*vt *eq-qn it qTfi frrprt +1 qcqr+ efreq r q ts- r+n s-iqfupi t r gs s-sT-{ + fur
+q+'$ qi qqqi$r* etd fnfuq r
24. What is 'Eutrophication' ? What are its causes and why does aquatic life get killed bi'it ? 4
25. How is the ozone layer formed in the stratosphere ? How is it helpful to us ? What is
ozone hole ? How is it formed ? Write any two effects of ozone depletion. 6
qd'sfrq{;i s}nh qfi fs-s s-fiR q{* t z .re -i fus q'fiR wqrril t t eMq fu-q RT i; r qa
t*rr r+n {riTr t ? einiT rrcf, ircrrrq +st* qi e*Trs fufiqq
r
313/OSS/105-A 10
OPTION.II
faryq - fl
24. What are dyes ? List three important properties which a good dye must possess. 4
'tqq; eqr t r erd icrn ii iqfun *r qu Wh si q*E- +1fuq r
25. (a) Write two uses of each of the following polymers and also write the structures of
their monomers :
(i) BUNA-S
(ii) Nylon-66
(b) Define biodegradable polymers. Write their two uses. 6
Cs) ffidfuiT *nsegee;i+d-qi svqt'T fufuq sk F{+q*'FTdf st {{qqT qt lafug :
. (i) wr-s
(ii) i1zrmFT-65
11 313/OSS/105-A