CHEM 1413.

001 - Exam 4 November 18, 2015 - Part 1 - Version A

Constants: h = 6.63x10-34 Js c = 3.00x108 cm/s NA = 6.02x1023 mol-1

Conversion Factors: 1 = 1x10-10 m

Molar Masses: C3H8 - 44.

 CHEM 1413.001 - Exam 4 November 18, 2015 - Part 1 - Version A

Name______________________________

(42) MULTIPLE CHOICE (Circle the ONE correct answer)

1. For the reaction 2 Fe2O3(s) + 6 CO(g) 4 Fe(s) + 6 CO2(g) , H = -48 kJ. The
Enthalpies of Formation of Fe2O3(s) and CO2(g) are -825 kJ/mol and -394 kJ/mol,
respectively. Therefore, the enthalpy of formation of CO(g) is
(A) -127 kJ/mol (B) -166.5 kJ/mol (C) -111 kJ/mol
(D) Cannot be determined without the Enthalpy of Formation of Fe(s)

2. For the reaction, 6 CO2(g) + 8 H2O(l) 2 C3H8(g) + 10 O2(g), the enthalpy

change is Ho = +4440 kJ. What is the Fuel Value of C3H8(g)?
(A) +100 kJ/g (B) +50 kJ/g (C) +38 kJ/g (D) -2220 kJ/mol

3. A stellar object is emitting photons with a frequency of 2.0x1014 s-1. If a detector

is capturing 5x108 photons/s, what is the total energy of the photons detected in
one hour?
-7
(A) 3.0x10 J (B) 6.6x10-11 J (C) 110 J (D) 2.4x10-7 J

4. A lamp rated at 60 W (1 W = 1 J/s) emits red light with a wavelength of

6,900 (Angstroms). Approximately how many photons of red light will be
emitted in 100 seconds?
(A) 2.1x1022 photons (B) 6.3x1024 photons (C) 2.1x1023 photons
(D) None of the above

5. Which of the following sets of quantum numbers are allowed for an electron in a
hydrogen atom?

(i) n = 4, l = 3, ml = -2, ms = - (ii) n = 3, l = -1, ml = 0, ms = +

(iii) n = 5, l = 1, ml = -1, ms = -
(A) i & ii (B) ii & iii (C) i & iii (D) i, ii & iii

6. How many orbitals are contained in the n = 3 shell of an atom?

(A) 9 (B) 16 (C) 18 (D) 32

7. The complete electron configuration of the Co3+ [Z(Co)=27] ion is:

(A) 1s22s22p63s23p64s23d7 (B) 1s22s22p63s23p63d6
(C) 1s22s22p63s23p64s23d4 (D) 1s22s22p63s23p63d10
 Version A

8. The condensed electron configuration of Sn (Z=50) is

(A) [Kr]5s24d105p2 (B) [Kr]5s25p2
(C) [Kr]5s25d105p2 (D) [Kr]4d104p4

9. The condensed electron configuration of Tl (Z=81) is

(A) [Xe]6s25d106p1 (B) [Xe]6s24f145d106p1
(C) [Xe]6s26p1 (D) [Rn]6s24f145d106p1

10. Of the four atoms, K, Ca, As and Se, ___ has the most unpaired electrons and
____ has the least unpaired electrons.
(A) Se , K (B) As , Ca (C) Se , Ca (D) As , K

11. Of the four atoms, As, Cl, Br, Ga, ____ has the largest radius and ____ has the
largest First Ionization Energy.
(A) Cl , Ga (B) Be , Ga (C) Cl , As (D) Ga , Cl

12. Arrange the following atoms in order of increasing First Ionization Energies:
Pb , Br , Te , Sb
(A) Te < Br < Sb < Pb (B) Pb < Te < Sb < Br
(C) Pb < Sb < Te < Br (D) Br < Te < Sb < Pb

- + 2-
13. Rank the following atoms and ions in order of increasing radius: Ne, F , Na , O
(A) Na+<Ne<F-<O2- (B) Ne<O2-<F-<Na+
(C) O2-<F-<Na+<Be (D) O2-<F-<Ne<Na+

14. The Third Ionization Energy of an atom is E for the process:

M4+ + e- (B) M3+ + e- M2+-

3+
(A) M
(C) M M3+ + 3 e (D) M2+ M3+ + e-

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There is one (1) problem on Part 1

 Version A

(10) 1. From the following enthalpies of reaction,

2 C(s) + H2(g) C2H2(g) H = +226.8 kJ

8 C(s) + 8 O2(g) 8 CO2(g) H = -3148.0 kJ
2 H2(g) + O2(g) 2 H2O(l) H = -571.6 kJ

Calculate H for the reaction, 2 C2H2(g) + 5 O2(g) 4 CO2(g) + 2 H2O(l)

 CHEM 1413.001 - Exam 4 November 18, 2015 - Part 1 - Version B

Constants: h = 6.63x10-34 Js c = 3.00x108 cm/s NA = 6.02x1023 mol-1

Conversion Factors: 1 = 1x10-10 m

Molar Masses: C3H8 - 44.

 CHEM 1413.001 - Exam 4 November 18, 2015 - Part 1 - Version B

Name______________________________

(42) MULTIPLE CHOICE (Circle the ONE correct answer)

1. For the reaction, 6 CO2(g) + 8 H2O(l) 2 C3H8(g) + 10 O2(g), the enthalpy

change is Ho = +4440 kJ. What is the Fuel Value of C3H8(g)?
(A) +100 kJ/g (B) -2220 kJ/mol (C) +38 kJ/g (D) +50 kJ/g

2. For the reaction 2 Fe2O3(s) + 6 CO(g) 4 Fe(s) + 6 CO2(g) , H = -48 kJ. The
Enthalpies of Formation of Fe2O3(s) and CO2(g) are -825 kJ/mol and -394 kJ/mol,
respectively. Therefore, the enthalpy of formation of CO(g) is
(A) -111 kJ/mol (B) -166.5 kJ/mol (C) -127 kJ/mol
(D) Cannot be determined without the Enthalpy of Formation of Fe(s)

3. How many orbitals are contained in the n = 3 shell of an atom?

(A) 32 (B) 18 (C) 9 (D) 16

4. Which of the following sets of quantum numbers are allowed for an electron in a
hydrogen atom?

(i) n = 4, l = 3, ml = -2, ms = - (ii) n = 3, l = -1, ml = 0, ms = +

(iii) n = 5, l = 1, ml = -1, ms = -
(A) i & ii (B) i & iii (C) ii & iii (D) i, ii & iii

5. A lamp rated at 60 W (1 W = 1 J/s) emits red light with a wavelength of

6,900 (Angstroms). Approximately how many photons of red light will be
emitted in 100 seconds?
(A) 2.1x1023 photons (B) 6.3x1024 photons (C) 2.1x1022 photons
(D) None of the above

14
6. A stellar object is emitting photons with a frequency of 2.0x10 s-1. If a detector
8
is capturing 5x10 photons/s, what is the total energy of the photons detected in
one hour?

(A) 2.4x10-7 J (B) 6.6x10-11 J (C) 110 J (D) 3.0x10-7 J

7. The condensed electron configuration of Sn (Z=50) is

(A) [Kr]4d104p4 (B) [Kr]5s25p2
(C) [Kr]5s25d105p2 (D) [Kr]5s24d105p2
 Version B

8. The condensed electron configuration of Tl (Z=81) is

(A) [Xe]6s25d106p1 (B) [Rn]6s24f145d106p1
(C) [Xe]6s26p1 (D) [Xe]6s24f145d106p1

7. The complete electron configuration of the Co3+ [Z(Co)=27] ion is:

(A) 1s22s22p63s23p64s23d7 (B) 1s22s22p63s23p63d6
(C) 1s22s22p63s23p64s23d4 (D) 1s22s22p63s23p63d10

10. Of the four atoms, As, Cl, Br, Ga, ____ has the largest radius and ____ has the
largest First Ionization Energy.
(A) Ga , Cl (B) Be , Ga (C) Cl , As (D) Cl , Ga

11. Arrange the following atoms in order of increasing First Ionization Energies:
Pb , Br , Te , Sb
(A) Te < Br < Sb < Pb (B) Pb < Sb < Te < Br
(C) Pb < Te < Sb < Br (D) Br < Te < Sb < Pb

- + 2-
12. Rank the following atoms and ions in order of increasing radius: Ne, F , Na , O
(A) O2-<F-<Ne<Na+ (B) Ne<O2-<F-<Na+
(C) O2-<F-<Na+<Be (D) Na+<Ne<F-<O2-

13. The Third Ionization Energy of an atom is E for the process:

(A) M2+ M3+ + e- (B) M3+ + e- M2+-

(D) M3+ M4+ + e-
3+
(C) M M +3e

14. Of the four atoms, K, Ca, As and Se, ___ has the most unpaired electrons and
____ has the least unpaired electrons.
(A) As , Ca (B) As , Ca (C) Se , Ca (D) As , K

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There is one (1) problem on Part 1

 Version B

(10) 1. From the following enthalpies of reaction,

2 C(s) + H2(g) C2H2(g) H = +226.8 kJ

2 C(s) + 2 O2(g) 2 CO2(g) H = -787.0 kJ
4 H2(g) + 2 O2(g) 4 H2O(l) H = -1143.2 kJ

Calculate H for the reaction, 4 CO2(g) + 2 H2O(l) 2 C2H2(g) + 5 O2(g)

 CHEM 1413.001 - Exam 4 November 18, 2015 - Part 2 - Version A

Constants: h = 6.63x10-34 Js c = 3.00x108 cm/s NA = 6.02x1023 mol-1

Conversion Factors:
Molar Masses:
 CHEM 1413.001 - Exam 4 November 18, 2015 - Part 2 - Version A

Name______________________________

(30) MULTIPLE CHOICE (Circle the ONE correct answer)

15. What is the total number of electron pairs around the central atom in ArCl3-1 ?
(A) 4 (B) 3 (C) 6 (D) 5

16. The total number of lone pairs of electrons in the PO+1 ion is/are:
(A) 4 (B) 3 (C) 1 (D) 2

17. In the AsS-1 ion, the Arsenic-Sulfur bond is a ____ bond and there is/are _____
lone pairs of electrons around the Sulfur atom.
(A) double, 1 (B) double , 2 (C) triple , 1 (D) triple , 2

18. What are the formal charges on the Tin (Sn) and Sulfur (S) atoms in SnS?
(A) Sn: -1, S: +1 (B) Sn: -4, S: +2 (C) Sn: 0, S: 0 (D) Sn: +1, S: -1

19. Which of the following molecule(s) do NOT obey the octet rule?
BrS2 , TeF2 , SeF4
(A) BrS2 (B) BrS2 & TeF2 (C) SeF4 (D) BrS2 & SeF4

20. Which of the following molecules CAN exist? OF2 , SbBr5 , NCl5 , NeBr3-1
(A) NCl5 , NeBr3-1 (B) SbBr5 , NeBr3-1
(C) OF2 , SbBr5 (D) OF2 , NCl5

21. For the transition metal complex, Tc(CO)4(CN)n, use the 18 electron rule to
determine n, the number of CN ligands in the complex.
Note: The CO ligand contributes two (2) electrons to the metal and the CN
ligand contributes one (1) electron to the metal.
(A) n = 2 (B) n = 3 (C) n = 4 (D) n = 5

22. In the molecule with the condensed structural formula, CH3C(NH)CHO , the total
number of bonds in the molecule is _____ and the total number of lone pairs of
electrons in the molecule is _____.
(A) 11 , 2 (B) 10 , 2 (C) 11 , 3 (D) 8 , 3

23. What are the C-N and C-O Bond Orders in the ion with the condensed structural
formula, CH3CH(NH2)C(O)O-1 ?
(A) 2 , 1 (B) 1 , 2 (C) 2 , 1.5 (D) 1 , 1.5
 Version A

24. What is the total number of lone pairs of electrons in the molecule with the
condensed structural formula, CH3C(O)CH2CN ?
(A) 3 (B) 2 (C) 4 (D) 5

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There are Two (2) Problems below: Show your work for credit

(8) 2. The C=N Bond Energy is 615 kJ/mol.

(6) (a) What is the approximate frequency of a photon of light with just enough energy
to break the C=N bond?

(2) (b) Higher frequencies than the value in part (a) CAN or (b) CANNOT break the
C=N bond. Choose one

(10) 3. Consider a microwave oven which emits photons of radiation with a wavelength of
1.50 cm. If a cup containing 200 g of water, originally at 25 oC, is placed in the
microwave oven, and the oven is turned on, the water absorbs
2.1x1025 photons/second. Determine the final temperature of the water two minutes
after the oven is turned on.
Note: The specific heat capacity of water is Cs = 4.18 J/g-oC.
 CHEM 1413.001 - Exam 4 November 18, 2015 - Part 2 - Version B

Constants: h = 6.63x10-34 Js c = 3.00x108 cm/s NA = 6.02x1023 mol-1

Conversion Factors:
Molar Masses:
 CHEM 1413.001 - Exam 4 November 18, 2015 - Part 2 - Version B

Name______________________________

(30) MULTIPLE CHOICE (Circle the ONE correct answer)

15. What is the total number of lone pairs of electrons in the molecule with the
condensed structural formula, CH3C(O)CH2CN ?
(A) 5 (B) 2 (C) 4 (D) 3

16. What are the C-N and C-O Bond Orders in the ion with the condensed structural
formula, CH3CH(NH2)C(O)O-1 ?
(A) 2 , 1 (B) 1 , 1.5 (C) 2 , 1.5 (D) 1 , 2

17. In the molecule with the condensed structural formula, CH3C(NH)CHO , the total
number of bonds in the molecule is _____ and the total number of lone pairs of
electrons in the molecule is _____.
(A) 11 , 2 (B) 10 , 2 (C) 11 , 3 (D) 8 , 3

18. For the transition metal complex, Tc(CO)4(CN)n, use the 18 electron rule to
determine n, the number of CN ligands in the complex.
Note: The CO ligand contributes two (2) electrons to the metal and the CN
ligand contributes one (1) electron to the metal.
(A) n = 3 (B) n = 2 (C) n = 4 (D) n = 5

19. What are the formal charges on the Tin (Sn) and Sulfur (S) atoms in SnS?
(A) Sn: -1, S: +1 (B) Sn: -4, S: +2 (C) Sn: 0, S: 0 (D) Sn: +1, S: -1

20. The total number of lone pairs of electrons in the PO+1 ion is/are:
(A) 4 (B) 3 (C) 2 (D) 1

21. What is the total number of electron pairs around the central atom in ArCl3-1 ?
(A) 4 (B) 3 (C) 5 (D) 6

22. In the AsS-1 ion, the Arsenic-Sulfur bond is a ____ bond and there is/are _____
lone pairs of electrons around the Sulfur atom.
(A) double, 2 (B) double , 1 (C) triple , 1 (D) triple , 2

23. Which of the following molecules CAN exist? OF2 , SbBr5 , NCl5 , NeBr3-1
(A) NCl5 , NeBr3-1 (B) SbBr5 , NeBr3-1
(C) OF2 , NCl5 (D) OF2 , SbBr5
 Version B

24. Which of the following molecule(s) do NOT obey the octet rule?
BrS2 , TeF2 , SeF4
(A) BrS2 & SeF4 (B) BrS2 & TeF2 (C) SeF4 (D) BrS2

----------------------------------------------------------------------------------------------------------------------------
There are Two (2) Problems below: Show your work for credit

(8) 2. The N=N Bond Energy is 420 kJ/mol.

(6) (a) What is the approximate frequency of a photon of light with just enough energy
to break the N=N bond?

(2) (b) Higher frequencies than the value in part (a) CAN or (b) CANNOT break the
N=N bond. Choose one

(10) 3. Consider a microwave oven which emits photons of radiation with a wavelength of
1.50 cm. If a cup containing 200 g of water, originally at 25 oC, is placed in the
microwave oven, and the oven is turned on, the water absorbs
2.4x1025 photons/second. Determine the final temperature of the water two minutes
after the oven is turned on.
Note: The specific heat capacity of water is Cs = 4.18 J/g-oC.