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SECTION-I (Multiple Choice Questions) : Faculty Test Topic:Co-Ordination Compounds - 1
SECTION-I (Multiple Choice Questions) : Faculty Test Topic:Co-Ordination Compounds - 1
SECTION-I (Multiple Choice Questions) : Faculty Test Topic:Co-Ordination Compounds - 1
FACULTY TEST
TOPIC:COORDINATION COMPOUNDS - 1
2. In the isoelectronic series of metal carbonyl, the CO bond strength is expected to increase in the
order.
(a) [ Mn(CO)6 ]+ < [Cr(CO)6] < [V(CO)6] (b) [V(CO)6] < [Cr(CO)6] < [ Mn(CO)6 ]+
(c) [V(CO)6] < [Mn(CO)6]+ < [Cr(CO)6] (d) [Cr (CO)6 ] < [ Mn(CO)6 ]+ < [V(CO)6]
3. In which of the following pairs both the complexes show optical isomerism?
(a) cis-[Cr(C2O4)2Cl2]3, trans-[Co(NH3)4Cl2]
(b) [Co(en)3]Cl3, cis-[Co(en)2Cl2]Cl
(c) [PtCl (dien)]Cl, [NiCl2Br2]2
(d) [Co(NO3)3 (NH3)3], cis-[Pt(en)2Cl2]
4. Effective atomic number of Co(CO)4 is 35, hence it is less stable. It attains stability by
(a) Oxidation of Co (b) Reduction of Co (c) Dimerization (d) Both (B) & (C)
5. [Cr(H2O)6]Cl3 (atomic number of Cr = 24) has a magnetic moment of 3.83 B.M. The correct
distribution of 3d electrons in the chromium present in the complex is:
(a) 3d1xy ' 3d1yz ' 3d1zx (b) 3d1xy ,3d1yz ,3d1z2
(c) 3d1x 2 y2 ,3d1z2 ,3d1xz (d) 3d1xy, ,3d1x 2 y2 ,3d1yz
( ) ( )
6. Select incorrect statement(s) for [Cu(CN)4]3, [Cd(CN)4]2 and [Cu(NH3)4]2+ complex ion.
(a) Both [Cd(CN)4]2 and [Cu(NH3)4]2+ have square planar geometry
(b) [Cu(CN)4]3 and [Cu(NH3)4]2+ have equal no. of unpaired electron
(c) Mixture of [Cu(CN)4]3 and [Cd(CN)4]2 can be separated on passing H2S gas.
(d) All the three complexes have magnetic moment equal to zero.
9. (a) A = no. of unpaired electron(s) is/are present in t2g orbital of [Fe(NH3)6]2+ complex ion
(b) B= co-ordination number of central atom of cis-platin.
(c) C = no. of d-orbital(s) is / are involve in hybridisation of Fe in K4[Fe(CN)5O2].
(d) D = no. of electron(s) is / are present in eg orbitals of [Co(C2O4)3]3.
Find A+B+C+D
11. Find out the total number of stereoisomer possible for [Cr(C2O4)(en)(NO2)Cl] is
12. How many unpaired electron(s) is / are present in Brown ring complex.
13. Barium ions, CN and Co2+ form an ionic complex. If that complex is supposed to be 75% ionised in
water with vant Hoff factor i equal to four, then the coordination number of Co2+ in the complex
can be
16.
Column I Column - II
(A) Zn Fe ( CN )5 NO (P) Blue colour due to charge transfer.
(ANSWER KEY)