This document is the lesson plan for a course on alcohols, phenols, and ethers. It covers 8 lectures that describe the definitions, classifications, nomenclature, preparation methods, chemical properties, reactions, and distinguishing tests of alcohols, phenols, and ethers. It also lists homework questions at multiple difficulty levels for each lecture to help students test their understanding.
This document is the lesson plan for a course on alcohols, phenols, and ethers. It covers 8 lectures that describe the definitions, classifications, nomenclature, preparation methods, chemical properties, reactions, and distinguishing tests of alcohols, phenols, and ethers. It also lists homework questions at multiple difficulty levels for each lecture to help students test their understanding.
This document is the lesson plan for a course on alcohols, phenols, and ethers. It covers 8 lectures that describe the definitions, classifications, nomenclature, preparation methods, chemical properties, reactions, and distinguishing tests of alcohols, phenols, and ethers. It also lists homework questions at multiple difficulty levels for each lecture to help students test their understanding.
No. 1 i) Alcohol MCQs : a) Definition Level I : 1, 2, 5, 6, 8, 10, 12, 13, 15 b) Classification Level II : 1, 5 1) Based on number of OH group presnt 2) Based on mode of hybridisation of * Csp3 OH (10/20/30) * Csp2 OH * CspCsp OH ii) Nomenclature a) (I) Common Name Alkyl alcohol b) (II) IUPAC Name Alkanol c) (III) Carbinol system Alkyl carbinol iii) Method of preparation (I) From Alkyl halide a) By Aq.KOH or NaOH (Alkaline hydrolysis) b) Moist Ag2O MCQs Level I : 3, 4, 7, 9, 11, 16, 19, 27 Level II : 2, 4
Solution and Colligative PropertiesAlcohols, Phenols and Ethers
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Lect Description H.W.
No. 2 (II) From Alkene MCQs : i) Acid catalysed hydration Level I : 17 a) Mechanism of hydration of alkene b) C+ rearrangement ii) Oxymercuration - Demercuration iii) Hydroboration - Oxidation (HBO reaction) (III) From 10 amine : (IV) From Ether MCQs Level I : 18 Level III : 6 PCQ : 8
3 (V) From Grignard reagent :
i) With Formaldehyde ii) With Aldehyde iii) With Ketone iv) With Acyl chloride v) With Ester vi) With Ethylene oxide vii) With Substituted epoxide * Hydroxylation i) Syn addition (KMnO4/OsO4) ii) Anti addition (Peroxy acid) MCQs Level I : 20, 21, 22 Level II : 6 Level : 2
Alcohols, Phenols and Ethers
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Lect Description H.W.
No. 4 (VI) From Carbonyl group MCQs : i) By reduction of Level I : 23, 49, 51, 54, 55, 57, 60, a) With Aldehyde & Ketones 62, 63, 64, 65, 84 b) With Acyl chloride Level II : 8, 27, 33, 35 c) With Acid Level III : 15 d) With Ester PCQ : 7 (Usin - H2/Ni, NaHg + H2O, LiAlH4 & NaBH4) * Importance of LiAlH4 * Physical properties * Chemial properties (A) Reaction involving breaking of OH bond a) Reactivity order of Alcohol b) Acidic strength i) Action of Metal (Na/K/Al) ii) Esterification : Action of ROH with a) Acid b) Acyl chloride c) Acid anhydride MCQs Level I : 24, 50, 53, 56, 61 Level II : 9, 28 Level III : 19
Solution and Colligative PropertiesAlcohols, Phenols and Ethers
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Lect Description H.W.
No. 5 (B) Reaction involving breaking of MCQs : CO bond Level I : 58, 69, 70, 73 * Reactivity order o f Level II : 11, 13, 15, 20, 21, 22, 24, alcohol 31, 32, 38 iii) Dehydration of Alcohol (10/20/30) Level III : 18 a) Using conc H2SO4 PCQ : 1 (with mechanism) b) Using Al2O3 e.g. 1) Methyl & Hydride shift 2) Ring expansion 3) Cyclic alcohol iv) Reaction with HX : (X =Cl, Br, I) * With mechanism involving rearrangement v) Reaction with PCl3 & PCl5 vi) Reaction with SOCl2 MCQs Level I : 59 Level II : 12, 14, 19, 29, 30, 36, 37 Level III : 7, 9, 12, 17
Alcohols, Phenols and Ethers
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Lect Description H.W.
No. 6 vii) Oxidation of 10/20/30 MCQs : Using Level I : 74, 77, 79, 81, 82, 83, 86, a) KMnO4 88, 89, 91, 92, 93, 94, 95, 96, 98 b) K2Cr 2O 7 Level II : 18, 23, 40 c) Collin reagent Level III : 8, 11, 14 d) PCC and PDC PCQ : 2, 9 e) Cu metal at 573 K f) Jones reagent viii) Oxidation using HIO4 a) With unsubstituted diol b) With substituted diol c) With triol ix) Distinguish tsest of Alcohol (10/20/30) a) Lucas test b) Victor - Meyer test MCQs Level I : 71, 72, 76, 78, 80, 85, 87, 90, 97 Level II : 17, 25, 26, 89 Level III : 4, 13 PCQ : 5
Solution and Colligative PropertiesAlcohols, Phenols and Ethers
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Lect Description H.W.
No. 7 Phenol MCQs : i) Definition Level I : 1, 3, 5 ii) Classification of phenol iii) Nomenclature a) Common name (10 example) b) IUPAC name (4/5 example) iv) Preparation of phenol a) From chlorobenzene 1) Dows process 2) Raschig process b) From Benzene sulphonic acid c) From Cumene d) From Aniline e) From Salicylic acid MCQs Level I : 2, 4, 6, 7
Alcohols, Phenols and Ethers
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Lect Description H.W.
No. 8 v) Chemical properties MCQs : a) Bromination Level I : 10, 13, 14, 15, 17, 18, 20, 1) CS2 or CCl4 21, 23, 24 2) H 2O Level II : 4, 5, 8, 9 b) Nitration Level III : 1 1) Using dil HNO3 PCQ : 4, 6, 9 2) Using conc. HNO3 + conc. H2SO4 c) Sulphonation 1) At low temp 2) At high temp d) Reimer - Tiemann reaction e) Kolbe-Schmidt reaction f) Reduction g) Oxidation h) Formation of Phenol phthalein vi) Distinguish test between Alcohol and Phenol MCQs Level I : 8, 9, 11, 12, 16, 19, 22, 25 Level II : 2, 3, 6, 7, 10, 11 Level III : 2, 4 PCQ : 1, 2, 3, 5, 8, 10
Solution and Colligative PropertiesAlcohols, Phenols and Ethers
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Lect Description H.W.
No. 9 i) Definition MCQs : ii) Classfication Level I : 1, 2, 4, 5, 6, 8, 10, 11, 14, iii) Isomerism 19 iv) Nomenclature Level II : 2, 8, 22 a) Common name PCQ : 9, 11, 17, 20, 30, 44 (6 example) b) IUPAC name (8 example) v) Method of preparation a) From alcohols (Intermolecular dehydration) * With mechanism b) From Alkyl halide (Williamsons Synthesis) MCQs Level I : 3, 7, 9, 12, 13, 15, 17, 18 Level II : 1, 20, 24 Level III : PCQ : 14, 41, 43
Alcohols, Phenols and Ethers
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Lect Description H.W.
No. 10 v) Method of preparation MCQs : c) Fro m Al co ho l and Level I : 16, 20, 23, 25, 26, 27, 28, Diazomethane 32, 36, 44, 45, 46, 48, 49, 50 vi) Chemical properties Level II : 9, 11, 12, 13, 14 a) Action of HX PCQ : 25 1) HOT 2) COLD 3) With Mechanism b) Hydrolysis c) Action of PCl5 d) Electrophilic substitution reaction 1) Halogenation 2) Friedel-Crafts reaction 3) Nitration e) Ring opening of Ether 1) Acid catalysed 2) Base catalysed vii) Introduction to Crown ether MCQs Level I : 22, 24, 29, 30, 31, 39, 40 Level II : 3, 4, 6, 10, 15, 19, 21 PCQ : 3, 40, 42
Solution and Colligative PropertiesAlcohols, Phenols and Ethers