CHNGIV

NHHNGCANHITLNTCPHNNG
I.MU

II.MTSQUYTCKINHNGHIM

1.Hsnhit

2.PhngtrnhVan'tHoff

3.Trongkhongnhitrng,ngitacnsdngphngphpkinh
nghim

III.PHNGTRNHARRHENIUS

1.PhngtrnhthcnghimvcslthuytcaArrhenius

2.ThitlpphngtrnhArrheniusdng(4.8)

IV.NGHACANNGLNGHOTNG

BitpchngIV

CHNGIV
NHHNGCANHITLNTCPHNNG

I.MU
 Hnh4.1:Sphthuccatcvonhit

II.MTSQUYTCKINHNGHIM

1Hsnhit TOP

2PhngtrnhVan'tHoff TOP
3Trongkhongnhitrng,ngitacnsdngphngphpkinhnghim TOP

III.PHNGTRNHARRHENIUS

1PhngtrnhthcnghimvcslthuytcaArrhenius TOP

StngtnitrnmngchoArrheniusitixydngmtcslthuytchophng
trnhkinhnghimcamnh.

Cslthuytgm4ginh:

GinhthnhtlginhcbncaArrhenius,chorng:khngphittcmiphnt
ucthphnngmchnhngphntnodnghotng(*)(haydngtautom)thmic
khnngphnngchiuqu.Dngphnthotngchnhthnhtccphntphn
ngbnhthngnhhpthnnglngdidngnhit.
2ThitlpphngtrnhArrheniusdng(4.8) TOP

Davoquanimnhitnghc(phngtrnhngp,ngtchcaphnnghahc)ta
cthbiudinsphthuccahngscnbngvinhitdngchung:

yKhngscnbngcaphnng,(Hnhitcaphnng.
 iucnghalkhinhittngthktnghaytcphnngtng.Phngtrnh
Arrehniusgiithchctisaokhinhittngtcphnngtng.iucminhha
bnghnh(4.2).

Cnhthc(4.9)vdngngbiudincan(ngthngiviphnngngin)
cngphnnhquylut,sthayitcphnngtheonhit,tcltcphnng(cthl
hngsstc)thayinhthnotheonhit.
IV.NGHACANNGLNGHOTNGHA
TheoArrehnius,chcnhngphntnocnnglngdtithiusovinnglngtrung
bnhcaphntthmickhnngcphnnghiuqu.Nnglnggilnnglnghot
ha.

Nicchkhc,nnglnghotnghalphnnnglngdcamiphntcnc
lcphnngdnnbinhahahc(ngoiracthtrnhbynghannglnghotngha
theoquanimthuytvchmhotngvphchotng,snghincusau).

Tacthhnhdungnnglnghotnghatheoginsau:

Hnh4.3:Nnglnghotnghacaphnng.

ngconggilngphnng.
HchuynttrngthiI(A+B)sangtrngthiII(X+Y)ckmtheosphthaythunhit.
 HchuynttrngthiI(A+B)sangtrngthiII(X+Y)ckmtheosphthaythunhit.
Nukhiu:

BitpchngIV

1.Dngkimxphnghaetylaxetat,thuc:

T(oK)273293298

k(mol1,l,ph1)1,175,086,65

a)Xcnhnnglnghotnghacaphnng.

b)TnhthigianbnhycaphnngkhinngbanucaEstevkimbngnhauv
bng:0,025mol/l,0,0125mol/l.