Department of Chemistry Prepared: Prof. R.C.

Jagessar

Date: 18th/April/17 CHM 2201 Organic Chemistry

Tutorial # 7

Aldehydes and Ketones:

1. (a) Provide the IUPAC nomenclature for the following compounds:

O

(b)
(a)
CH3

CH3

O
OH

(c) H3 C (d) CHO

H

2. Complete the syntheses below by providing the structure of the lettered intermediates,
products and side products where necessary. Also, a mechanism resulting in product (E).

(a)
OH
Na2Cr2O7
(A)
H2SO4

(b) OH PCC HCN

(B) (C)

(c) CH3 O3 (CH3)2S

(D) (E)

CH3

(d)
Hg2+

(F)
H2SO4, H2O
 3. Indicate the hydridisation of the carbon depicted by the arrows.

(a) (b) (c)

CH3