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Fehlings Solution
Fehlings Solution
Fehling Test
Fehling's reagent, a blue colored basic solution of bistartratocuprate(II)
complex, is added to three different aqueous sugar solutions immersed
in beakers of warm water. A brick-red precipitate forms in the solutions
containing glucose and fructose. There is no reaction in the test tube
containing sucrose solution.
Curriculum Notes
This demo is appropriate for use in an organic chemistry or biochemistry
course when the reactions of carbohydrates are being studied. The
fructose reaction could also be used earlier in an organic chemistry
course as an illustration of a reaction that proceeds via a pathway that
relies upon keto-enol tautomerism. This demo can easily be scaled up
for visibility if video projection is unavailable in the classroom.
Discussion
Fehling's solution is used as a chemical test used to differentiate
between water-soluble aldehyde and ketone functional groups, and as a
test for monosaccharides. The test was developed by German
[1]
chemist Hermann von Fehling in 1849.
Equal volumes of the two mixtures are mixed together to get the final
Fehling's solution, which is a deep blue colour. In this final mixture,
aqueous tartrate ions from the dissolved Rochelle salt chelate to
2+
Cu (aq) ions from the dissolved copper sulfate crystals,
as bidentate ligands giving the bistartratocuprate(II)complex as shown
in the accompanying illustration.
Prep. Notes
Topics:
Complex Ions Organic Chemistry Precipitation Reactions Redox Reactions
Copyright 2012 Email: Randy Sullivan, University of Oregon Chemistry Department and UO Libraries Interactive Media Group
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