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Cambridge International General Certificate of Secondary Education
Cambridge International General Certificate of Secondary Education
CHEMISTRY 0620/42
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use an HB pencil for any diagrams or graphs.
Do not use staples, paper clips, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.
The syllabus is approved for use in England, Wales and Northern Ireland as a Cambridge International Level 1/Level 2 Certificate.
IB17 03_0620_42/3RP
UCLES 2017 [Turn over
2
A B C
H H H H H H H H H H H H
H C C C C H H C C C C H C C C C H
H H H H H H H H H
D E
H H H H H
Br C C Br Br C C C Br
H H H H H
........................................................................................................................................ [1]
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(vi) Name the two products made during the complete combustion of compound C.
........................................................................................................................................ [1]
(b) Petroleum can be separated into useful substances using the apparatus shown.
refinery gas
gasoline fraction
naphtha fraction
petroleum
lubricating fraction
and bitumen
........................................................................................................................................ [1]
........................................................................................................................................ [1]
(iii) Name the fraction which has the weakest attractive forces between molecules.
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Name fraction X.
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[Total: 11]
Silver dichromate can be made by reacting silver nitrate solution with ammonium dichromate
solution. The chemical equation for the reaction is shown.
(a) Describe how you could obtain pure dry solid silver dichromate after mixing silver nitrate
solution and ammonium dichromate solution.
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............................................................................................................................................... [3]
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(ii) Write the ionic equation for the formation of silver dichromate in this reaction.
State symbols are not required.
........................................................................................................................................ [1]
(c) Dilute aqueous sodium hydroxide was added to the ammonium nitrate solution made in the
reaction. The mixture was then warmed and damp Universal Indicator paper was held above
the mixture.
State and explain what would happen to the Universal Indicator paper.
.....................................................................................................................................................
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............................................................................................................................................... [2]
plastic trough
S
solid silver nitrate solid
ammonium dichromate
water
After five minutes, a red solid appeared along the line marked S on the diagram.
(i) Explain why a red solid appeared along the line marked S.
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........................................................................................................................................ [3]
What effect, if any, would this have on the time taken for the red solid to appear? Explain
your answer.
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........................................................................................................................................ [2]
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(ii) Write a chemical equation for the thermal decomposition of ammonium dichromate.
........................................................................................................................................ [2]
[Total: 16]
3 Nitryl chloride, NO2Cl, reacts with nitric oxide, NO. The forward reaction is exothermic.
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............................................................................................................................................... [2]
(b) Explain why increasing the temperature increases the rate of reaction.
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(c) State and explain the effect, if any, of increasing the temperature on the position of equilibrium.
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(d) State and explain the effect, if any, of decreasing the pressure on the position of equilibrium.
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............................................................................................................................................... [2]
(e) Nitrosyl chloride, NOCl, is a gas at room temperature. It has the structure shown.
O N Cl
(i) Complete the dot-and-cross diagram to show the arrangement of the outer shell electrons
in nitrosyl chloride.
O N Cl
[2]
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[Total: 13]
copper(II) sulfate
solution
(a) (i) Draw an arrow on the diagram to show the direction of movement of electrons in the wire.
Label the arrow A. [1]
(ii) Draw an arrow on the diagram to show the direction of movement of positive ions in the
copper(II) sulfate solution.
Label the arrowB. [1]
(b) Oxygen was formed at the anode and copper was formed at the cathode.
4OH O2 + 2H2O + 4e
........................................................................................................................................ [1]
(ii) Write the ionic half-equation for the formation of copper at the cathode.
........................................................................................................................................ [2]
(c) The electrolysis was repeated using copper electrodes in place of carbon electrodes.
State and explain what happens to the masses of the anode and the cathode during this
electrolysis.
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[Total: 9]
(a) In the blast furnace, coke burns in oxygen to produce heat energy and carbon dioxide.
How is this carbon dioxide converted into carbon monoxide in the blast furnace?
............................................................................................................................................... [1]
(b) Calcium carbonate added to the blast furnace decomposes to form calcium oxide.
Calcium oxide removes silicon(IV) oxide impurities from the iron in a neutralisation reaction.
Write a chemical equation for the reaction of calcium oxide with silicon(IV) oxide. Suggest why
it is a neutralisation reaction.
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.....................................................................................................................................................
............................................................................................................................................... [3]
(c) The main impurity in iron obtained from the blast furnace is carbon.
(i) Why must the high levels of carbon be lowered before the iron becomes a useful material?
........................................................................................................................................ [1]
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(d) Z
inc is extracted from its ore. The ore contains zinc sulfide. The zinc sulfide is roasted in air to
produce zinc oxide and sulfur dioxide.
Zinc is then obtained from the zinc oxide using a blast furnace.
(i) Give the name of the ore of zinc that contains zinc sulfide.
........................................................................................................................................ [1]
(ii) W
rite a chemical equation for the reaction that takes place when zinc sulfide is roasted in
air.
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(iii) Suggest why the sulfur dioxide should not be released into the atmosphere.
..............................................................................................................................................
........................................................................................................................................ [2]
(iv) The temperature inside the blast furnace in which zinc is extracted is about 1000C.
The table gives some information about substances in the blast furnace in which zinc is
extracted.
Use the data in the table to explain why the zinc obtained does not contain high levels of
impurities such as silicon(IV) oxide and carbon.
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........................................................................................................................................ [2]
[Total: 12]
(a) A student heated a 10.0g sample of barium carbonate until it was fully decomposed.
(i) Calculate the number of moles of barium carbonate the student used.
(ii) Calculate the volume of carbon dioxide gas produced at room temperature and pressure.
Give your answer in dm3.
(b) The student added 2.00g of the barium oxide produced to water.
Calculate the mass of barium hydroxide that can be made from 2.00g of barium oxide. The Mr
of Ba(OH)2 is 171.
(c) A 1.50g sample of barium hydroxide was dissolved in water. The total volume of the solution
was 100cm3.
A 25.0 cm3 portion of the barium hydroxide solution was titrated against hydrochloric acid. The
volume of hydrochloric acid required was 18.75cm3.
(i) Calculate how many moles of barium hydroxide were in the 25.0cm3 portion used in the
titration.
[Total: 7]
H Cl H Cl H Cl
C C C C C C
H H H H H H
(i) Draw a circle around one repeat unit of the polymer. [1]
(ii) Draw the structure of the monomer from which this addition polymer is made.
[1]
(iii) Aqueous bromine is added to both the polymer and the monomer.
O O O O
C C N N C C N N
H H H H
........................................................................................................................................ [1]
(ii) On the diagram, draw a circle around one repeat unit of the polymer. [1]
(iii) Draw the structures of the two monomers from which the condensation polymer is made.
[2]
(c) Hydrolysis of a polymer gave a compound with the following composition by mass: C,34.61%;
H,3.85%; O,61.54%.
(ii) What additional information is needed to calculate the molecular formula of the compound?
..............................................................................................................................................
........................................................................................................................................ [1]
[Total: 12]
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the live examination series.
Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local
Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
UCLES 2017
I II III IV V VI VII VIII
1 2
H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
16
85 88 89 91 93 96 101 103 106 108 112 115 119 122 128 127 131
55 56 5771 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
0620/42/F/M/17
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209
87 88 89103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
232 231 238
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).