ORGANIC CHEMISTRY

TARGET : JEE (Main) 2017

Course : ABHINAV (EA) Date : 18-05-2015 NO. 03
TEST INFORMATION

DATE : 31.05.2015 PART TEST-1 (PT-1) (MAIN)

Syllabus : IUPAC nomencalture of non-chain terminating Functional group.

This DPP is to be discussed in the week (18-05-2015 to 23-05-2015)

DPP No. # 03 (JEE-MAIN)
Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]

1. How many carbon atoms are present in the principle chain of following compound .
uhps fn;s x;s ;kSfxd dh eq[; J`a[kyk esa fdrus dkcZu ijek.kq ekStqn gSaA

(1) 8 (2) 10 (3*) 11 (4) 12

2. How many methyl as substituent attached on principle chain in

mijksDr ;kSfxd esa eq[; J`a[kyk ij fdrus esfFky lewg izfrLFkkih ds :Ik esa mifLFkr gSa \

(1) 1 (2) 3 (3*) 4 (4) 5

3. Which of the following has correct numbering :

fuEu esa ls fdldk vadu lgh fn;k x;k gS \

4 Cl
2 4 4
6 3 6 3 1
7 5 3
(1) (2) 1 5 (3*) 2
(4)
2 2
1 Br Cl 1

4. The IUPAC name of (CH3)3CCH(CH3)2 is

(1) 2 , 3 , 3 Trimethyl pentane (2) 2 , 3 , 3 Trimethyl butane
(3*) 2 , 2 , 3 Trimethyl butane (4) 1 , 1 , 1 Trimethyl propane

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 1
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
 (CH3)3 CCH(CH3)2 dk IUPAC uke gS A
(1) 2 , 3 , 3 VkbesfFky isUVsu (2) 2 , 3 , 3 VkbesfFky C;wVsu
(3*) 2 , 2 , 3 VkbesfFky C;wVsu (4) 1 , 1 , 1 VkbesfFky izksisu

CH3 CH3
CH

5. CH3CHCHCH3 How many C atoms present in principle chain

CH
CH3 CH3

CH3 CH3
CH

CH3CHCHCH3 ;kSfxd dh eq[; J`a[kyk esa fdrus C ijek.kq ik;s tkrs gSaA
CH
CH3 CH3

(1) Four (2*) Six (3) Seven (4) Eight

(1) pkj (2*) N% (3) lkr (4) vkB

6. Which of the following has longest chain of carbon :

fuEu esa ls fdlesa dkcZu dh lokZf/kd yEch J`a[kyk gS %

CH2 CH3
|
(1) CH3 CH CH2 CH CH3 (2)
|
CH2 CH3

CH3
|
(3*) (4) CH3 CH CH2 CH2 CH CH2 CH3
|
CH2 CH3

7. The correct IUPAC name of the following compound is

fuEu ;kSfxd dk lgh IUPAC uke gSA

(1) 4Ethyl3,5dimethylhexane (2) 2,4Dimethyl3ethylhexane

(3) 3sopropyl4methylhexane (4*) 3Ethyl2,4dimethylhexane

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 2
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
 (1) 4,fFky3,5MkbZesfFkygSDlsu (2) 2,4MkbZesfFky3,fFkygSDlsu
(3) 3vkbZlksizksfiy4esfFkygSDlsu (4*) 3,fFky2,4MkbesfFkygSDlsu
8. What is the correct IUPAC name of (C2H5)4 C is ?
(1) Tetraethyl methane (2*) 3,3-Diethyl pentane (3) Triethylethane (4) Octane
(C2H5)4 C dk lgh IUPAC uke D;k gS \
(1) VsVk,sfFky esFksu (2*) 3,3-Mkb,sfFky isUVssu (3) Vkb,sfFky ,sFksu (4) vkWDVsu

9. What is the correct IUPAC name of ?

(1)1- Methyl-2-ethylcyclopropane (2*) 1- Ethyl-2-methylcyclopropane

(3) 1- Ethyl-3-methylcyclopropane (4) None of these

dk lgh IUPAC uke D;k gS \

(1)1- esfFky-2-,fFkylkbDyksizki
s us (2*) 1- ,fFky-2-esfFkylkbDyksizksisu
(3) 1-,fFky-3-esfFkylkbDyksizki
s us (4) buesa ls dksbZ ugha

10. Which of the following is correct IUPAC name ?

(1) 1,1,1-Dimethyl ethane (2) 2- Methyl-3-ethylpentane
(3) 3- Methyl-4-ethylhexane (4*) 3- Ethyl-4-methylhexane
fuEufyf[kr esa dkSulk lgh IUPAC uke gS \
(1) 1,1,1- MkbZesfFky ,sFksu (2) 2- esfFky-3-,fFkyisUVsu
(3) 3-esfFky-4-,fFkygsDlsu (4*) 3-,fFky-4-esfFkygsDlsu

11. Which of the following is incorrect IUPAC name ?

(1) 1- Ethyl-2-methylcyclopropane
(3*) 1,3,4- Trimethylcyclohexane
fuEufyf[kr esa dkSulk xyr IUPAC uke gS \
(1) 1- ,fFky-2-esfFkylkbDyksizksisu
(3*) 1,3,4- VkbesfFkylkbDyksgsDlsu
(2) 1-Ethyl-3-propyl cyclopentane
(4) 4-Ethyl-1,1-dimethylcyclohexane
(2) 1- ,fFky-3-izksfiylkbDyksiUs Vu
(4) 4-,fFky-1,1-MkbZesfFkylkbDyksgsDlsu

12. and are ?

(1*) Identical (2) Homologs (3) Isomers (4) none of these

rFkk gS \

(1*) le:i (2) letkr (3) leko;oh (4) dksbZ ugha

13. IUPAC name of the compound is

;kSfxd dk IUPAC uke gS

(1) 2-Ethyl-2-butene (2) 3-Ethyl-2-butene (3) 3-Methyl-3-pentene (4*) 3-Methyl-2-pentene

(1) 2-,fFky-2-C;wVhu (2) 3-,fFky-2-C;wVhu (3) 3-esfFky-3-isUVhu (4*) 3-esfFky-2-isUVhu

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 3
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
14. The IUPAC name of compound CH3C(CH3)2 CH2CH=CH2 is
(1) 2, 2-Dimethylpent-4-ene (2) 2, 2-Dimethyl-2-pentene
(3) 1,1,1-Trimethylbut-3-ene (4*) 4,4-Dimethylpent-1-ene
CH3C(CH3)2 CH2CH=CH2 ;kSfxd dk IUPAC uke gS
(1) 2, 2-MkbZesfFkyisUV-4-bZu (2) 2, 2-MkbZesfFkyisUV-2-isUVhu
(3) 1,1,1-VkbesfFkyC;wV-3-bZu (4*) 4, 4-MkbZesfFkyisUV -1-bZu

15. IUPAC name of

CH3CH2C(Br) = CH Cl is
(1*) 2-Bromo-1-chlorobut-1-ene (2) 1-Chloro-2-bromobut-1-ene
(3) 3-Chloro-2-bromobut-1-ene (4) 3-Bromo-4-chlorobut-3-ene
CH3CH2C(Br) = CH Cl ;kSfxd dk IUPAC uke gS
(1*) 2-czkseks-1-DyksjksC;wV-1-bu (2) 1-Dyksjks-2-czke
s ksC;wV-1-bu
(3) 3-Dyksjks-2-czke
s ksC;wV-1-bu (4) 3-czkseks-4-DyksjksC;wV-3-bu

16. IUPAC name of the following compound will be

CH3CH=CCH2CH3
CH2CH2CH3
CH3CH=CCH2CH3
;kSfxd dk IUPAC uke gSA
CH2CH2CH3
(1*) 3-Ethyl-2-hexene (2) 3-Propyl-2-hexene (3) 3-Propyl-3-hexene (4) 4-Ethyl-4-hexene
(1*) 3-,fFky-2-gSDlhu (2) 3-izkfs iy-2-gSDlhu (3) 3-izkfs iy-3-gSDlhu (4) 4-,fFky-4-gSDlhu

17. The name of according to IUPAC nomenclature system is :

(1*) 2,3-Dibromo-1,4-dichlorobut-2-ene (2) 1,4-Dichloro-2,3-dibromobut-2-ene

(3) Dichlorodibromobutene (4) Dichlorodibromobutane
;kSfxd dk IUPAC i)fr ds vuqlkj uke gS

(1*) 2,3-MkbZckz e
s ks-1,4-MkbDyksjksC;wV-2-bZu (2) 1,4-MkbDyksjks-2,3-MkbZczkseksC;wV-2-bZu
(3) MkbZDyksjksMkbczkseksC;wVhu (4) MkbZDyksjksMkbczkseksC;wVsu

18. IUPAC name of

CH2=CHCH(C2H5)C=CH2 is .....
Br
(1) 4-Bromo-3-ethyl-1,4- pentadiene (2*) 2-Bromo-3-ethyl-1,4-pentadiene
(3) 2-Bromo-3-ethyl-1,5- pentadiene (4) None of these
CH 2=CHCH(C 2H 5)C=CH 2 ;kSfxd dk IUPAC uke gS
Br
(1) 4-czkseks-s 3-,fFky-1,4-isUVkMkbbZu (2*) 2-czkseks-s 3-,fFky-1,4-isUVkMkbbZu
(3) 2-czkseks-s 3-,fFky-1,5-isUVkMkbbZu (4) buesa ls dksbZ ugha
19. Consider the following compound

IUPAC name of this compound is

(1) 5,6-Diethyl-3,8-dimethyldecane (2*) 5,6-Diethyl-3,8-dimethyldec-4-ene
(3) 3,5,6,8-Tetramethyldec-6-ene (4) 2,4,5,7-Tetraethyloct-3-ene

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 4
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
 fuEu ;kSfxd dk voyksdu dhft,

fuEu ;kSfxd dk IUPAC uke gksxk&

(1) 5,6-MkbZ,fFky-3,8-MkbZesfFkyMsdsu (2*) 5,6-MkbZ,fFky-3,8-MkbZesfFkyMsd-4-bZu
(3) 3,5,6,8-VsVkesfFkyMsd-6-bZu (4) 2,4,5,7-VsVk,fFkyvkWDV-3-bZu

20. The IUPAC name of the following compound

CH3CH(C2H5)CH=CHCH3 is
(1) 4-Ethyl-2-pentene (2*) 4-Methyl-2-hexene
(3) 3-Ethyl-2-pentene (4) 2-Ethyl-3-pentene
CH3CH(C2H5)CH=CHCH3 ;kSfxd dk IUPAC uke gS
(1) 4-,fFky-2-isUVhu (2*) 4-esfFky-2-gSDlhu
(3) 3-,fFky-2-isUVhu (4) 2-,fFky-3-isUVhu

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 5
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029