BQ GIAO DUC VA DAO TAO KY THI TRUNG HQC PHO THONG QUOC GIA NAM 2017 DE THI CHINH THUC Bai thi: KHOA HQC TY (Bé thi cé 04 trang) Mén thi thanh phan: HOA HQC Thoi gian lam bai: 50 phult, hing ké thoi gian phat db 1 Ma dé thi 216 st nguyén tit kh6i cia cée nguyén td: | H= 1; Li=7; C= 12; N= 14; 0 = 16; Na= 23; Mg = 24; Al =27; S = 32; Cl = 35,5; K= 39; Ca=40; Cr = 52; Fe = 56; Cu= 64; Zn = 65; Rb = 85,5; Ag = 108. Cau 41. Xa phong héa CHsCOOC2Hs trong dung dich NaOH dun| néng, thu duge mudi 6 eéng thite 1a | A. CoHsONa. B, CH:COONa. C.HCOONa. | D. CoHsCOONa. Cu 42. Crom(VI) oxit (CrOs) c6 mau gi? | A. Mau vang. B. Mau xanh lye. C. Manu da cam.) D. Mau dé thim. Cau 43. Dung dich ndo sau day o6 phan img tring bac? | A. Metyl axetat. B. Fructozo. C.Saccarozo. | D. Glyxin. ‘CAu 44, Kim loai din dign t6t nit 1a A.Au. BAL C.Ag. | D.Cu. Cau 45, Céng thite phan tir cla dimetylamin 1a | A.C. B. CaHuiN. CCN. | D. CHaN2. Cfiu 46. To nao sau day thude logi to thién nhién? | A. Tonitron. B. To nilon-6,6. €.Tonilon-6. | D. To tim. Cau 47. 6 nhidt d6 thudng, dung dich Ba(HCOs)2 lofing tic dung durge véi dung dich nao sau day? AKCL B. KNOs. C.NaxCOs. | D. NaCl. Cu 48, MGt miu Ichi thai cng nghigp o6 chita cdc khf: CO, S02, NO2, HS. Dé logi bé cfc khi 46 mot cdch higu qua nhit, c6 thé ding dung dich nao sau day? A. CaCh. B.HCL C.Ca(OH. | D.NaCl. Cfu 49, Dung dich nao sau day téc dung duge voi kim logi Cu? | ‘A. H2S0s loaing, B.HCl. C.HINO> Joaing, D. KOH. CAu 50. Hoa tan hoan todn m gam Fe bing dung dich HCI du, thu durge 2,24 lit kh He (Akte). Gia trj cha m 1a A.LL2. B.84. C.28. | D.5.6. ‘CAu 51. Kim logi Fe bj thy déng béi dung dich ‘A. HCI lodng. B. HzSOs long. C.HNOs dic, ngudi. D. HCI dtc, ngudi. Cfu 52. Quing nio sau day cé thanh phan chinh 1a Al2O3? | A. Criolit. B. Manhetit. C.Boxit. | D. Hematit 46. Cau 53. Hidro héa hodn toan 17,68 gam triolein cin vira du V lit Khi Ha (dkte), Gif trj eta V 1a A.4,032. B. 2,688. ..0,448. D. 1,344. ‘Cu 54, Phat biéu nado sau day sai? ‘A. Dung djch glyxin khong lam di mau phenolphtalein. B. Anilin thc dung vi myéc brom tgo thanh két tia mau vang. C. Dung dich axit glutamic lam quy tim chuyén mau héng. D. Amino axit 18 hgp chét hitu co tap chr. Trang 1/4 - Ma a8 thi 216Cau 55, Thi nghigm nao sau day khOng xay ra phan img hod hoc? ‘A. Cho kim loai Fe vao dung djch FeCl, B. Cho AlOs vao dung dich NaOH. C. Cho BaSOx vio dung dich HCI long. D. Cho CaO vio dung dich HCI. CAu 56. Hén hop X gm axit axetic va metyl fomat. Cho m gam X téc dung vita dit v6i 300 ml dung dich NaOH IM. Gié tr cia m 1a A.9. B. 12, C27. D, 18. CAu 57. Cho céc chit sau: saccarozo, glucozo, ety! fomat, Ala-Gly-Ala. Sé cht tham gia phan img thiy phan 1a AL. B.4, C3, D2. Cau 58. Cho hén hop Zn, Mg va Ag vao dung dich CuCl, sau khi ede phan tmg xay ra hodn toan, thu duge hén hop ba kim logi. Ba kim loai dé 1 A. Zn, Mg va Cu. B.Zn,MgviAg. —C. Zn, Ag vACu. D. Mg, Cu va Ag. Cau 59. Dét chay hon todn m gam hén hgp Mg va Al cdn vita dui 2,8 lit kh{ Oe (dtc), thu duge 9,1 gam hén hop hai oxit. Gia trj cla m la A.G,1. B.5,1. C39, D.7,. (CAu 60. Cho 2,24 lit khi CO (dkte) phin img vita di v6i 10 gam hn hop X gdm CuO va MgO. Phan trim khéi Iugng ctia MgO trong X 1a A. 40%. B. 60%. C. 20%. D. 80%, Cu 61. Cho 26,8 gam hdn hop KHCOs va NaHCOs téc dung véi dung dich HCI du, thu duge 6,72 lit khi (dkte) va dung dich chita m gam mu6i, Gid tri cba m 1a A. 19,15. B. 24,55. €.20,75. D, 30,10. ‘CAu 62. Trong phong thi nghiém, khi X duge diéu ché va thu vao binh tam ux, gide nhu hin vé bén. Khi X duge tao ra tir phan ‘img héa hoc nao sau day? f A. 2Al + 2NaOH + 2H20 —> 2NaAlO2 + 3H29 B. Cu + 4HINOs(5:) —> Cu(NOs)2 + 2NOzgo + 2H20 C. CoHsOH ESSE, Cray + HzO D. CHsCOONa@) + NaOH) —“"> CHaiy + NazCOs ‘Cfu 63. Saccarozo va glucoze déu cé phan img A. véi CuOH). B. thily phiin. C. trang bac. D. cng Ho (Ni, ). ‘Cau 64. Cho 30 gam h&n hop hai amin don chite tic dyng vita di véi V ml dung djch HCI 1,5M, thu duge dung dich chita 47,52 gam hn hgp mu6i. Gia trj cia V 1a A329, B. 320. C. 160. D. 720. Cu 65. Thye hién cdc thi nghiém sau: (@) Cho Fes04 vao dung djch HCl. (b) Cho FesOs vao dung dich HNOs du, tgo sn pham khit duy nbdt 14 NO. (©) Suc khi SO2 dén dur vao dung dich NaOH. @ Cho Fe vao dung dich FeCl du, (©) Cho hén hgp Cu va FeCl (ti 18 mol 1 : 1) vao HO du, (g) Cho Al vao dung dich HNOs lofing (kh6ng c6 khi thot ra). ‘Sau Khi cdc phan img xay ra hoan toén, s6 th nghigm thu duge dung djch chita hai mudi la A4 B.3. C2. D.S. ‘CAu 66. Cho céc phat biéu sau: (@) Crom bén trong khéng khi do o6 lép mang oxit bao vé. () 6 digu kién thuong, crom({I1) oxit 1a chét rin, mau luc thém. (©) Crom(Ill) hidroxit cé tinh Iuéng tinh, tan dugc trong dung dich axit manh va kiém, (@) Trong dung djch HeSOs lofing, ion cromat chuyén thanh ion dicromat, Sé6 phat biéu ding 18 Ad Bl. G2. D.3. ‘Trang 2/4 - Ma dé thi 216Cu 67. Thyc hién cdc phan mg sau: | (1)X+CO2 —+ Y (2)2X+ CO: —> Z+H20 ()¥+T —+ Q+X+m0 2 ey cece toe Hai chét X, T tuong tng 1a: A.Ca(OH),, NaOH. —B. Ca(OH)2,NaxCOs._ C. NaOH, NaHCOs. —D. NaOH, Ca(OH). fu 68. Thiy phan khdng hoiin toin peptit Y mgch hé, thu duge hén hop sn phim trong 46 ¢6 chita cdc dipeptit Gly-Gly va Ala-Ala. Dé thiy phan hoan toan 1 ot Y cn 4 mo! NaOH, thu duge mudi va nude. $6 céng te ee to pha hop cia Y 1a | A CAs | D.4. Cu 69. Cho cde phat vida sau: | (a) Trong dung dich, glyxin tn tai chit yu 6 dang ion luéng cyte. | (b) Amino axit 1a chat rin két tinh, dé tan trong nuéc. | (c) Glucozo va saccarozo déu cé phan img trang bac. (@ Hidro héa hoan toan triolein (xtc téc Ni, t°), thu duge tripanmitin (¢) Triolein va protein cé cling thanh phan nguyén t6. | (g) Xenlulozo trinitrat dugc ding lam thudc simg khong khéi. | 86 phat biéu ding 1a | A3. B.6. | D.5. CAu 70. Cte 03 mol inp X ebm est don ci ng vin i 50m ing eh KOHN, thu duge chat hiru co Y (no, don chit, mach hé cé tham gia phn img trang bac) va 53 gam hin hop muéi. Dét chéy toan b6 ¥ can vita dui 5,6 lit khi O2 (dkte). Khdi hgng cia 0,3 mol X 1a ‘A. 41,0 gam. B. 33,0 gam. C.29,4 gam. D. 31,0 gam. Cau 71. Chat X téc dung voi dung djch NaOH via da, thu duge hai chit Y va Z. Cho Z tée dung v6i dung djch AgNOs trong NHB thu duge chat httu co T. Cho T té¢ dung véi dung dich NaOH Iai thu duge Y. Chat X 1 A. HCOOCH=Cis. B. CHsCOOCH> C.HCOOCHS. D. CHsCOOCH+CH-CHb. Cu 72. Dign phn 100 ml dung dich hén hgp g8m CuSOs a mol/l vA NaCl 2M (din eve tro, mang ngfin xép, higu sudt dign phiin 100%, bé qua sy hda tan oia khi trong nude va sy bay hoi cia nue) v6i cutng 4 dong dién khéng di 1,25A trong 193 phuit, Dung dich sau dign phan c6 khéi Ingng gidm 9,195 gam so véi dung djch ban du. Gia tri cba a la | A.0,45. B. 0,60. €.0,40. | D.0,50. Cu 73. Cho cae phat biéu sau: (@) Ding Ba(OH)s e6 thé phan bigt hai dung dich AICIs va NazSOt. (®) Cho dung dich NaOH vio dung dich AICh du, thu duge két ti (c) Nhém 1a kim loai nhe, mau tring bac, dan dién t6t, dan nhigt to. (@ Kim loai Al tan trong dung dich H2SOs dc, ngugi. (©) 6 nhigt 4§ cao, NaOH va AI(OH)s déu khdng bj phan hity. ‘$6 phat biéu ding 1a A.3. B.1. Cau 74, Két qua thi nghiém cla cdc dung dich X, of a Tv6i nse wit dug a & bang sau: Miu thir Thude thir Hign twgng x Dung dich AgNOs trong NH | Kéttia Ag | ¥ ‘Quy tim ‘Chuyén mau xanh_ Zz ‘CuQOH)2 Mau xanh lan T ‘Nude brom Ké tia tring ‘Cfc dung dich X, Y, Z, T Tan Iuot Ia: ‘A. Anilin, glucozo, Iysin, etyl fomat B. Etyl fomat, abilin, glucozo, lysin. C. Glucoze, lysin, etyl fomat, anilin. D. Etyl fomat, lysin, glucozo, anilin. Trang 3/4 - Ma dé thi 216Cau 75. Héa tan hoan toan a gam hén hgp X g8m AlOs va NazO vo nude, thu duge dung dich Y, Cho tir tir dung djch HCl 1M vio Y, Iugng két tha AI(OH)s (m gam) phy thuge vao thé tich dung dich HCl (V ml) duge biéu dign bing 43 th bén, Gia trj cia ala A. 29,25. B. 14,40. C. 24,60, D. 19,95. C4u 76. Cho m gam hén hop X gém axit glutamic va valin tac dung véi dung dich HCI du, thu duge (m + 9,125) gam mudi, Mat khée, cho m gam X téc dung véi dung dich NaOH du, thu durge (m+ 7,7) gam mudi. Biét cdc phan img xdy ra hoan toan. Gid trj cha m 1a A. 39,60. B. 33,75. C. 26,40. D. 32,25. CAu 77. Hoa tan hét 8,16 gam hén hop E gdm Fe va hai oxit sét trong dung dich HCI du, thu duge dung dich X. Suc khi Ch dén du vao X, thu duge dung dich Y chita 19,5 gam muéi, Mit khéc, cho 8,16 gam E tan hét trong 340 ml dung dich HNOs 1M, thu duge V lit khi NO (sin phdm khir duy nht cia N*%, & dktc). Gia tri cia VIA A. 0,896. B. 2,688. C. 0,672. D. 1,792, C4u 78. Chia m gam hn hop T gdm céc peptit mach héthanh hai phn bing nhau. Bét chay hoan toan phin mét, thu duge No, CO2 va 7,02 gam H20. Thiy phan hoan toan phan hai, thu duge hin hgp X gdm alanin, glyxin, valin. Cho X vio 200 ml dung dich chia NaOH 0,5M va KOH 0,6M, thu duge dung dich Y chira 20,66 gam chit tan. Dé tic dung via di véi Y cin 360 ml dung dich HCI 1M. Biét cde phan img xay ra hoan toan, Gid tr} ctia m 1a A. 21,32. B. 24,20, C. 19,88. D. 24,92. Cau 79, Thyc hign phan tng nbiét nhOm hén hgp Al va FezOs (trong diéu kign kh6ng c6 khéng khi), thu duge 36,15 gam hdn hop X. Nghién nhé, tron déu va chia X thinh hai phn. Cho phan mdt tae » dung vi dung dich NaOH du, thu duge 1,68 lit khi He (dktc) va 5,6 gam chat rin khéng tan. Hoa tan hét phan hai trong 850 ml dung dich HNOs 2M, thu dure 3,36 lit kh{ NO (dktc) va dung dich 0 150 350 = 750 chi chira m gam hén hyp mu6i. Biét cdc phan img xay ra hoan toan. Gid trj cua m gn nhdt voi gid tj ndo sau day? A. 110. B.95. C. 103. D. 113. ‘CAu 80. Dét chay hoan toan 9,84 gam hén hop X gdm mét ancol va mot este (4éu don chtte, mach hi), thu duge 7,168 lit khi CO2 (dktc) va 7,92 gam HO. Mit khéc, cho 9,84 gam X tic dung hoan ton véi 96 ml dung dich NaOH 2M, cé can dung dich thu duge m gam chit rin khan. Gié trj cla m 1a A.13,12. B. 14,24, C.6,80. D. 10,48. HET — ‘Trang 4/4 - Ma dé thi 216