Nurfaizah (2315106009)

Bunga Mega Putu I (2315106010)

Handi Wahyu W (23156011)
Luqman Hakim (2315106012)

Problem 5.120
Methanol can be made by catalytic oxidation of methane using the stoichiometric amount
of O2 as shown below with a yield of CH3OH of 30% of theoritical. Determine the
quantitiy of heat required to be introduced into or is given off by the process per 100kg
mol of methanol formed. See Figure P.5.120
Solution:

1
reaksi: CH4(g) + O2 (g) CH3OH(g)
2

Basis 100 kgmol CH3OH

Yield = 100%

100
30% = 100%
4
100
Mol CH4 = = 333.33
0.3

Karena yang bereaksi 30% dari mol awal (masuk)

0.7
Mol O2 sisa = 50 = 116.67
0.3
 Mol O2 masuk = 50 kgmol +116.67 kgmol = 166.67 kgmol
1
CH4(g) + O2 (g) CH3OH(g)
2

M 333.33 166.67 -
R 100 50 100
S 233.33 116.67 100

Data Boiling Point dan Melting Point dari Appendix D.1

Komponen T Boiling Point (K) T Melting Point (K)

CH4 111.67 90.68
O2 90.19 54.40
CH3OH 337.9 175.26

Data Hf dari appendix F

Komponen f (KJ/gmol)
f (J/gmol)

CH4 (g) -74.84 -74840
O2 (g) 0 0
CH3OH(g) -201.25 -201250
 Data Heat Capacity dari Appendix E.1
Suhu (oC) Suhu (K)
Komponen a b.102 c.105 d.109
Tin Tout Tin Tout
CH4 50 200 323 473 g 34.31 5.469 0.3661 -11.00
O2 100 200 373 473 g 29.10 1.158 -0.6076 1.311
- 200 473 473 g 42.93 8.301 -1.87 -8.03
CH3OH
- 200 473 473 l -259.25 0.03358 -1.1639 1.45x104

Proses ini steady state open system, energy balance menjadi:

E = Q + W - [(H + K + P)]
Q = H
Q = H products - H reactants

Produk (Tref 250C = 298 K)

CH2
200
233.33 [( 34.31 + (5.469 102 ) + (0.3661 105 ) 2 (11 109 ) 3 )
25

+ (74840) ]

= - 15808.970 KJ
O2
200
116.67 ( 29.10 + (1.158 102 ) (0.6076 105 ) 2
25

(1.311 109 ) 3 )

=618.915 KJ
CH3OH 473 K (g)

H1
H2 337.9 K (l)

337.9 K (g)
H3
298 K (l)
200
H1 = (64.9 42.93 + (8.301 102 ) (1.87 105 ) 2 (8.03 109 ) 3 )

=7233.884 J
Panas Laten ( ) dari CH3OH didapat dari Appendix D.1= 3.17 KJ/mol
H2 =3170 J

337.9
H3=(298 259.25 + (0.03358 102 ) (1.1639 105 ) 2

(1.4052 105 ) 3 )

= -28479.132 J
CH3OH = H1 + H2 + H3 = 100 x [(7233.884 + 3170 -28479.132) +(-201250)]
=- 21932.525 KJ
Reaktan (Tref 250C = 298 K)
CH4
50
333.33 [( 34.31 + (5.469 102 ) + (0.3661 105 ) 2
25

(11 109 ) 3 ) + (74840)]

= - 24643.264 KJ
O2
200
166.67 ( 29.10 + (1.158 102 ) (0.6076 105 ) 2
25

(1.311 109 ) 3 )

=372.477 KJ

Q=(H produk - HReaktan)

=(- 15808.970 + 618.915 +(- 21932.525)) (-24643.264 + 372.477)

= -12851.793 KJ/100kgmolCH3OH