Professional Documents
Culture Documents
Volume Contents and Subject Index For Volumes 83 86 2004 Polymer Degradation and Stability
Volume Contents and Subject Index For Volumes 83 86 2004 Polymer Degradation and Stability
www.elsevier.com/locate/polydegstab
S01413910(04)003003
IV Contents of Volumes 8386 / Polymer Degradation and Stability 86 (2004) IIIXXIV
,PSDFWRIWKHUPDODJHLQJRQWKHWLQFDWDO\VWVSHFLHVLQURRPWHPSHUDWXUHYXOFDQLVHGSRO\VLOR[DQHUXEEHUV
03$7(/$56.,11(5$&+$8'+5<1&%,//,1*+$08. %0$+,(8%HOJLXP
7HFKQRORJLFDOSDUDPHWHUVRIS\URO\VLVRIZDVWHSRO\WHWUDIOXRURHWK\OHQH
(0(,661(5$:5%/(:6.$ (0,/&+(573RODQG
6WXGLHVRQW\UHFRUGVGHJUDGDWLRQRISRO\HVWHUGXHWRIDWLJXH
$.1$6.$5$.08.+(5-(( 508.+23$'+<$<,QGLD
7KHUPDOGHJUDGDWLRQDQGIODPPDELOLW\FKDUDFWHULVWLFVRIVRPHSRO\VW\UHQHVDQGSRO\PHWK\OPHWKDFU\ODWHV
FKHPLFDOO\PRGLILHGZLWKVLOLFRQFRQWDLQLQJJURXSV
-5(%'21%-+817 3-26(3+8.
$QLQHUWVROLGPHGLXPIRUVLPXODWLRQRIPDWHULDOELRGHJUDGDWLRQLQFRPSRVWDQGDFKLHYHPHQWRIFDUERQEDODQFH
$/21*,(5$6$&23,1(7*%85($8 /7,*+=(57)UDQFH
&KHPLFDOGHJUDGDWLRQRIIOXRURHODVWRPHULQDQDONDOLQHHQYLURQPHQW
60,75$$*+$1%$5,6,$+.$/,3.,1*6+277.$/0'$/
+.5(+0(,(5 $*&+5,67(16(1'HQPDUN
6\QWKHVLVFKDUDFWHUL]DWLRQWKHUPDOSURSHUWLHVDQGIODPHUHWDUGDQFHRIQRYHOSKHQROLFUHVLQVLOLFDQDQRFRPSRVLWHV
&/&+,$1* &&00$5HSXEOLFRI&KLQD
'LVFRORXUDWLRQLQILUHUHWDUGDQWIOH[LEOHSRO\XUHWKDQHIRDPV3DUW,&KDUDFWHULVDWLRQ
03/8'$3%5$&&2/&267$,WDO\ 69/(9&+,.86$
6WUXFWXUDOFKDQJHRIDSRO\PHULFKLQGHUHGDPLQHOLJKWVWDELOL]HULQSRO\SURS\OHQHGXULQJ89LUUDGLDWLRQVWXGLHGE\
UHDFWLYHWKHUPDOGHVRUSWLRQJDVFKURPDWRJUDSK\
<7$*8&+,<,6+,'$6768*(+2+7$1,..,085$
7<26+,.$:$ +0$768%$5$-DSDQ
6WXGLHVRQWKHWKHUPDOGHJUDGDWLRQRISRO\SKHQ\OHQHVXOILGHVXOIRQH
+:$1*-<$1*6/21*;:$1*=<$1* */,35&KLQD
6XUIDFHFURVVOLQNLQJRISRO\FDUERQDWHXQGHULUUDGLDWLRQDWORQJZDYHOHQJWKV
%&/$8'(/*2121-'8&+(799(51(< -/*$5'(77()UDQFH
,QYHVWLJDWLRQRIPHFKDQLFDOSURSHUW\IODPHUHWDUGDQF\DQGWKHUPDOGHJUDGDWLRQRI//'3(ZRRGILEUHFRPSRVLWHV
%/, -+(35&KLQD
6WXGLHVRIELRGHJUDGDWLRQRIELQDU\EOHQGVRISRO\K\GUR[\EXW\UDWHFRK\GUR[\YDOHUDWH3+%+9ZLWK
SRO\K\GUR[\HWK\OPHWDFULODWH3+(0$
-*5$&,'$-$/%$-&$5'262 )3(5(=*8(9$5$0H[LFR
6\QWKHVLVFKDUDFWHUL]DWLRQDQGWKHUPDOGHJUDGDWLRQRIVRPHFRSSHU,,]LQF,,DQGFREDOW,,FRPSOH[HVZLWK
ROLJRVDOLF\ODOGHK\GH
+0$577XUNH\ $59,/$<(72*/8$]HUEDLMDQ
5DGLDWLRQHIIHFWVRQSRO\ODFWLGHFRJO\FROLGH3/*$DQGSRO\/ODFWLGH3//$
6&-/22&322, <&)%2(<6LQJDSRUH
3RO\PHUGHJUDGDWLRQWRIXHOVRYHUPLFURSRURXVFDWDO\VWVDVDQRYHOWHUWLDU\SODVWLFUHF\FOLQJPHWKRG
.*2%,1 *0$1268.
'LUHFWREVHUYDWLRQRISRO\K\GUR[\DONDQRDWHJUDQXOHDVVRFLDWHGSURWHLQVRQQDWLYHJUDQXOHVDQGRQ
SRO\K\GUR[\EXW\UDWHVLQJOHFU\VWDOVE\DWRPLFIRUFHPLFURVFRS\
.68'(6+0DOD\VLD$0$(+$5$=*$17,:$7$ <'2,-DSDQ
6ROLGVWDWHVWUXFWXUHVDQGWKHUPDOSURSHUWLHVRIDOLSKDWLFDURPDWLFSRO\EXW\OHQHDGLSDWHFREXW\OHQHWHUHSKWKDODWH
FRSRO\HVWHUV
=*$1..8:$%$5$-DSDQ0<$0$0272*HUPDQ\+$%( <'2,-DSDQ
$FDUERFDWLRQVXEVWLWXWHGFOD\DQGLWVVW\UHQHQDQRFRPSRVLWH
-=+$1* &$:,/.,(86$
:HDWKHULQJUHVLVWDQFHRIZDWHUEDVHG89FXUHGSRO\XUHWKDQHDFU\ODWHFRDWLQJV
&'(&.(5)0$6621)UDQFH 56&+:$/0*HUPDQ\
3RO\PHWK\OPHWKDFU\ODWHSRO\SURS\OHQHDQGSRO\HWK\OHQHQDQRFRPSRVLWHIRUPDWLRQE\PHOWEOHQGLQJ
XVLQJQRYHOSRO\PHULFDOO\PRGLILHGFOD\V
668''-,$1* &$:,/.,(86$
Contents of Volumes 8386 / Polymer Degradation and Stability 86 (2004) IIIXXIV V
1RYHOSRO\PHULFDOO\PRGLILHGFOD\VSHUPLWWKHSUHSDUDWLRQRILQWHUFDODWHGDQGH[IROLDWHGQDQRFRPSRVLWHV
RIVW\UHQHDQGLWVFRSRO\PHUVE\PHOWEOHQGLQJ
668''-,$1* &$:,/.,(86$
7KHWKHUPDOGHJUDGDWLRQRIQDQRFRPSRVLWHVWKDWFRQWDLQDQROLJRPHULFDPPRQLXPFDWLRQRQWKHFOD\
668 &$:,/.,(86$
)ODPHUHWDUGDQWDQGPHFKDQLFDOSURSHUWLHVRIQDWXUDOILEUH33FRPSRVLWHVFRQWDLQLQJPDJQHVLXPK\GUR[LGH
06$,16+3$5.)68+$5$ 6/$:&DQDGD
2QWKHNLQHWLFRUGHURIGHFRPSRVLWLRQRISRO\PHULFK\GURSHUR[LGHV
/=/$7.(9,&+86$
'HWHUPLQDWLRQRIR[LGDWLYHVWDELOLW\RISRO\SURS\OHQHXVLQJFKHPLFDOVHQVRUV
5$327<5$,/25-:52&=<16.,:*0255,6 *5%5$'7.(86$
7KHUPDODQDO\VLVRIDQDFU\ORQLWULOHEXWDGLHQHVW\UHQH6:17FRPSRVLWH
6<$1*-5&$67,//(-$(9%$55(5$ ./2=$1286$
6WXGLHVRQWKHGHFRPSRVLWLRQEHKDYLRURIQ\ORQLQVXSHUFULWLFDOZDWHU
/0(1*<=+$1*<+8$1*&KLQD06+,%$7$ 5<2620,<$-DSDQ
7KHV\QWKHVLVFKDUDFWHUL]DWLRQDQGWKHUPDOVWDELOLW\RIROLJRK\GUR[\EHQ]DOGHK\GH
+0$57+<5.0~ 6$~
&$.9085$'2*/87XUNH\
$59,/$<(72*/8$]HUEDLMDQ
6\QWKHVLVDQGGHJUDGDWLRQRISRO\K\GUR[\HWK\OPHWKDFU\ODWHgraftSRO\FDSURODFWRQHFRSRO\PHUV
$&5(785*$77,1/%5$&+$,6 '%$5%,(5%$8'5<)UDQFH
3UHGLFWLQJWKHSHUIRUPDQFHVRIEDVHFRDWFOHDUFRDWDXWRPRWLYHSDLQWV\VWHPVE\WKHXVHRIDGKHVLRQ
VFUDWFKDQGPDUUHVLVWDQFHPHDVXUHPHQWV
17$+0$66(%, 6025$',$1,UDQ
&KDUDFWHUL]DWLRQRIWDOFFDOFLXPFDUERQDWHILOOHGSRO\SURS\OHQHK\EULGFRPSRVLWHVZHDWKHUHG
LQDQDWXUDOHQYLURQPHQW
<:/(21*0%$%8%$.$5=$02+',6+$. $$5,)),10DOD\VLD
7KHUPRJUDYLPHWULFHYDOXDWLRQRI3&$%6PRQWPRULOORQLWHQDQRFRPSRVLWH
5=21*<+86:$1* /621*35&KLQD
5DGLRO\WLFGHJUDGDWLRQDQGVWDELOL]DWLRQRISRO\YLQ\OFKORULGH
*09,1+$650628720$,25 < 0%'($/0(,'$%UD]LO
3RO\SKHQ\ODFU\ODWHDQG3RO\SPHWK\OSKHQ\ODFU\ODWHDVSKRWRVWDELOL]HUV,,3URWHFWLRQRI3(7
DJDLQVWSKRWRR[LGDWLRQ
&7/((&+:8 06/,17DLZDQ
7KHNLQHWLFRUGHURIGHFRPSRVLWLRQRISRO\PHUK\GURSHUR[LGHVDVVHVVHGE\FKHPLOXPLQHVFHQFH
1&%,//,1*+$0 01*5,**8.
0HFKDQLFDOSURSHUWLHVDQGHQ]\PDWLFGHJUDGDWLRQRISRO\>R@K\GUR[\EXW\UDWHco>R@K\GUR[\KH[DQRDWH
XQLD[LDOO\FROGGUDZQILOPV
--),6&+(5<$2<$*,0(12.,<'2, 7,:$7$-DSDQ
(IIHFWRIRUJDQLFSHUR[LGHVRQWKHWKHUPDOGHFRPSRVLWLRQRIH[SDQGHGSRO\VW\UHQHZLWKWKHDGGLWLRQ
RIPHWK\OVW\UHQH
);8('7$.('$7.,085$ 00,1$%(-DSDQ
(IIHFWRIHOHFWURQLUUDGLDWLRQRQWKHSURSHUWLHVRISRO\K\GUR[\EXW\ULFDFLGILEUHVDQGWKHLULQYLWURGHJUDGDWLRQ
*6&+0$&.6.5$0(5+'256&+1(5 .*/,(6&+(*HUPDQ\
(YDOXDWLRQRIWKHHIIHFWLYHQHVVRIDOFRKROERUQHUHDJHQWVRQWKHJUHHQFRORXUSURWHFWLRQRIPDNLQREDPERR
Phyllostachys makinoi
-+:80-&+81* 67&+$1*7DLZDQ
'HFRPSRVLWLRQUHDFWLRQVRISODVWLFPRGHOFRPSRXQGVLQVXEDQGVXSHUFULWLFDOZDWHU
<6+,%$6$.,7.$0,025,-,.$'2.$:$%+$7$12
+7$*$<$-DSDQ
4XDQWLWDWLYHGHWHUPLQDWLRQRIGHJUDGDWLRQSURGXFWVDQHIIHFWLYHPHDQVWRVWXG\HDUO\VWDJHVRI
GHJUDGDWLRQLQOLQHDUDQGEUDQFKHGSRO\EXW\OHQHDGLSDWHDQGSRO\EXW\OHQHVXFFLQDWH
$/,1'6750$&$/%(576621 0+$..$5$,1(16ZHGHQ
VI Contents of Volumes 8386 / Polymer Degradation and Stability 86 (2004) IIIXXIV
(IIHFWRIGLIIHUHQWWKHUPDOWUHDWPHQWVRQWKHVHOIDVVHPEOHGQDQRVWUXFWXUHVRID
VW\UHQHEXWDGLHQHVW\UHQHVWDUEORFNFRSRO\PHU
(6(55$12$=8%(/',$0/$55$$*$35(0,52 ,021'5$*216SDLQ
&KDQJHVLQWKHFU\VWDOOLQHSKDVHGXULQJWKHWKHUPRR[LGDWLRQRIDPHWDOORFHQHLVRWDFWLF
SRO\SURS\OHQH$'6&VWXG\
0(/9,5$37,(0%/2 -0*0(=(/9,5$6SDLQ
7KHUPDOVWDELOLW\RISRO\DQLOLQHHWK\OHQHSURS\OHQHGLHQHUXEEHUEOHQGVSUHSDUHGE\VROYHQWFDVWLQJ
96&+0,'76&'20(1(&+0662/',($3,1+(,52 962/',%UD]LO
7KHHIIHFWVRIFRSSHUR[LGHVRQWKHWKHUPDOGHJUDGDWLRQRIELVPDOHLPLGHWULD]LQHSUHSUHJ
6*+21* &6<(+7DLZDQ
7KHUPDOVWDELOLW\RISRO\mFDUERUDQHVLOR[DQHHODVWRPHUV
03$7(/ $&6:$,18.
'HVLJQV\QWKHVLVDQGILEUHUHDFWLYLW\VWXG\RIDZDWHUVROXEOHPRQRFKORURsWULD]LQ\OKLQGHUHG
QLWUR[LGHRQPHFKDQLFDOSXOSV
74+8'$26021' -$6&+0,'7&DQDGD
/LTXLGSKDVHFDWDO\WLFGHJUDGDWLRQRIPL[WXUHVRIZDVWHKLJKGHQVLW\SRO\HWK\OHQHDQGSRO\VW\UHQHRYHU
VSHQW)&&FDWDO\VW(IIHFWRIPL[LQJSURSRUWLRQVRIUHDFWDQWV
.+/(('+6+,1 <+6(26RXWK.RUHD
(IIHFWVRIFXOWXUHFRQGLWLRQVRQWKHFRPSRVLWLRQRISRO\K\GUR[\EXW\UDWHcoK\GUR[\EXW\UDWH
V\QWKHVL]HGE\Comamonas acidovorans
:+/((010$=,=$1 .68'(6+0DOD\VLD
0ROHFXODUPRELOLW\DQGFU\VWDOOLQHSKDVHVWUXFWXUHRIELRGHJUDGDEOHSRO\>RK\GUR[\EXW\OLF
DFLGFRRK\GUR[\KH[DQRLFDFLG@
..8:$%$5$=*$171$.$085$+$%( <'2,-DSDQ
7KHUPDOVWDELOLW\RISRO\/ODFWLGHLQIOXHQFHRIHQGSURWHFWLRQE\DFHW\OJURXS
<)$1+1,6+,'$<6+,5$, 7(1'2-DSDQ
'HWHUPLQDWLRQRIHQGJURXSVWUXFWXUHVDQGE\SURGXFWVRIV\QWKHVLVRISRO\PDOLFDFLGE\GLUHFW
SRO\FRQGHQVDWLRQ
7.$-,<$0$+.2%$<$6+,.025,6$.877$*8&+,..$7$2.$ -7$1$.$-DSDQ
7KHUPDOGHJUDGDWLRQDQGIODPHUHWDUGDQF\RIKH[DDFU\ODWHGKH[DHWKR[\OF\FORSKRVSKD]HQHDQG
WKHLUEOHQGVZLWKHSR[\DFU\ODWH
-',1* :6+,35&KLQD
7KHUPDOGHJUDGDWLRQRISKRWRSRO\PHUL]HG%LV*0$7(*'0$EDVHGGHQWDOUHVLQV
:7(6+,0$<12085$$,.('$7.$:$+$5$
02.$=$., <1$+$5$-DSDQ
7KHUPDOGHJUDGDWLRQNLQHWLFVRIYLQ\OSRO\SHUR[LGHFRSRO\PHUV
*6,9$/,1*$03'(5.$57+,. *0$'5$6,QGLD
Calendar of events
3RO\XUHWKDQHIRDPUHVSRQVHWRILUHLQSUDFWLFDOJHRPHWULHV
0/+2%%6 *+/(002186$
&KHPLOXPLQHVFHQFHIURPR[LGDWLRQRISRO\DPLGH
,,7KHHIIHFWRIPHWDOVDOWV
3&(5587,,WDO\-5<&+/z</0$7,6295<&+/6ORYDNLD &&$5)$*1$,WDO\
7KHUPDOGHJUDGDWLRQRIPHUFXU\FKHODWHGSRO\DFU\ODPLGR[LPH
*0252,'%,/%$ 1%,/%$5RPDQLD
3UHSDUDWLRQRIQDQRFRPSRVLWHVIURPVW\UHQHDQGPRGLILHGJUDSKLWHR[LGHV
)08+/ &$:,/.,(86$
&KHPLFDOGHJUDGDWLRQRIDSRO\SURS\OHQHPDWHULDOH[SRVHGWRVLPXODWHGUHF\FOLQJ
$-$16621.0//(5 7+-(57%(5*6ZHGHQ
7KHHIIHFWRISKRWRR[LGDWLYHGHJUDGDWLRQRQIUDFWXUHLQ$%6SLSHUHVLQV
3'$9,6%(7,*$1,6 /6%851$XVWUDOLD
(IIHFWVRIFKDLQHQGVWUXFWXUHVRQS\URO\VLVRISRO\/ODFWLFDFLGFRQWDLQLQJWLQDWRPV
7025,+1,6+,'$<6+,5$, 7(1'2-DSDQ
&DSLOODU\]RQHHOHFWURSKRUHVLVDVDWRROWRPRQLWRUWKHK\GURO\WLFGHJUDGDWLRQ
RIDZDWHUVROXEOHSRO\HVWHUDPLGH
&%5$8'09(57,03,1,//$)UDQFH0%0$57,1(= -$*3(5(=6SDLQ
'HWHULRUDWLRQRISRO\HWK\OHQHSLSHVH[SRVHGWRFKORULQDWHGZDWHU
-+$66,1(10/81'%&.0,):$5621 8:*(''(6ZHGHQ
6WXG\RQWKHWKHUPDOVWDELOLW\RISRO\VW\U\OVXUIDFWDQWVDQGWKHLUPRGLILHGFOD\QDQRFRPSRVLWHV
668''-,$1* &$:,/.,(86$
3RO\EXWDGLHQHPRGLILHGFOD\DQGLWVQDQRFRPSRVLWHV
668''-,$1* &$:,/.,(86$
7KHUPDOSURSHUWLHVRISRO\YLQ\OFKORULGHPRQWPRULOORQLWHQDQRFRPSRVLWHV
)*21*0)(1*&=+$26=+$1* 0<$1*35&KLQD
7KHHIIHFWRIWRV\ODWHVDOWVDQG]LQFVXOIRQDWHGSRO\VW\UHQHLRQRPHURQWKHWKHUPDOVWDELOLW\
RIELVSKHQRO$SRO\FDUERQDWH
/;8 5$:(,6686$
VIII Contents of Volumes 8386 / Polymer Degradation and Stability 86 (2004) IIIXXIV
7KHUPDOVWDELOLW\RIVRPHQDSKWKDOHQHDQGSKHQ\OEDVHGHSR[\UHVLQV
<)'8$1170/,8.&&+(1* :)687DLZDQ
7KHXVHRIWKH,.3PHWKRGIRUHYDOXDWLQJWKHNLQHWLFSDUDPHWHUVDQGWKHFRQYHUVLRQIXQFWLRQ
RIWKHWKHUPDOGHK\GURFKORULQDWLRQRI39&IURPQRQLVRWKHUPDOGDWD
3%8'58*($&(6(*$/5RPDQLD/$35(=0$48('$ -0&5,$'26SDLQ
2[LGDWLYHGHJUDGDWLRQRIcisDQGtransSRO\EXWDGLHQHVE\KRUVHUDGLVK
SHUR[LGDVHK\GUR[\EHQ]RWULD]ROH
0(12.,6.$,7$<:$.$768.,<'2, 7,:$7$-DSDQ
,RQLFGHVRUSWLRQIURP300$LUUDGLDWHGZLWKPXOWLEXQFKV\QFKURWURQUDGLDWLRQLQ
WKHH9SKRWRQHQHUJ\UDQJH
0/052&&2)&3217(6*6)$5$8'2 **%'(628=$%UD]LO
,VRODWLRQDQGFKDUDFWHUL]DWLRQRIFHOOXORVHIURPVXJDUFDQHEDJDVVH
-;681;)681+=+$2 5&681&KLQD
(IIHFWRIWHPSHUDWXUHRQWKHXOWUDVRQLFGHJUDGDWLRQRISRO\DFU\ODPLGHDQGSRO\HWK\OHQHR[LGH
639,-$<$/$.6+0, *0$'5$6,QGLD
%OHQGVRISRO\FDSURODFWRQHDQGSRO\YLQ\ODFHWDWHPHFKDQLFDOSURSHUWLHVDQGWKHUPDOGHJUDGDWLRQ
*6,9$/,1*$05.$57+,. *0$'5$6,QGLD
$NLQHWLFVWXG\RQWKHWKHUPDOGHJUDGDWLRQRINNNWULPHWK\OFKLWRVDQ
''(%5,772 63&$03$1$),/+2%UD]LO
&RPPHQWVRQ7KHHIIHFWRI89UDGLDWLRQRQWKHWKHUPDOSDUDPHWHUVRIFROODJHQGHJUDGDWLRQE\.DPLQVND$DQG
6LRQNRZVND$3RO\P'HJUDG6WDE
+0$$/0$<'$0$
5HVSRQVHWR&RPPHQWVE\+XVVHLQ0$$O0D\GDPDRQ7KHHIIHFWRI89UDGLDWLRQRQWKH
WKHUPDOSDUDPHWHUVRIFROODJHQGHJUDGDWLRQE\.DPLQVND$ DQG6LRQNRZVND$3RO\P'HJUDG6WDE
$6,21.2:6.$
I Calendar of events
7KHUPDOVWDELOLWLHVDQGWKHWKHUPDOGHJUDGDWLRQNLQHWLFVRISRO\LPLGHV
//,&*8$1$=+$1*'&+(1 =4,1*&KLQD
3UHSDUDWLRQDQGSURSHUWLHVRISRO\GLPHUDFLGGRGHFDQHGLRLFDFLGFRSRO\PHU
DQGSRO\GLPHUDFLGWHWUDGHFDQHGLRLFDFLGFRSRO\PHU
:;*82 .;+8$1*35&KLQD
89GHJUDGDELOLW\RIDU\OVXEVWLWXWHGSRO\VLO\OHQHV
)6&+$8(5,.85 ,7.$ 61(6 385(.&]HFK5HSXEOLF
7KHUPDOGHJUDGDWLRQRIELQDU\SK\VLFDOPL[WXUHVDQGFRSRO\PHUVRISRO\FDSURODFWRQH
SRO\'/ODFWLGHSRO\JO\FROLGH
*6,9$/,1*$0 *0$'5$6,QGLD
.LQHWLFVRIWKHUPDOGHJUDGDWLRQRISRO\PHWK\OPHWKDFU\ODWHVWXGLHGZLWKWKHDVVLVWDQFHRIWKH
IUDFWLRQDOFRQYHUVLRQDWWKHPD[LPXPUHDFWLRQUDWH
=*$27.$1(.2&KLQD'+28 01$.$'$-DSDQ
2QWKHV\QWKHVLVDQGSKRWRVWDELOLW\RIVRPHQHZQDSKWKDOLPLGHG\HV
7.2167$17,129$5/$=$529$$9(1.29$ 99$66,/(9$%XOJDULD
(IIHFWVRIVWRUDJHRIDPDWXUHFRPSRVWRQLWVSRWHQWLDOIRUELRGHJUDGDWLRQRISODVWLFV
+6<$1*-6<221 01.,0.RUHD
&RQGLWLRQPRQLWRULQJDSSURDFKHVDSSOLHGWRDSRO\FKORURSUHQHFDEOHMDFNHWLQJPDWHULDO
.7*,//(15$$66,1. 5%(5167(,186$
'HJUDGDWLRQRISRO\/ODFWLFDFLGE\DQHZO\LVRODWHGWKHUPRSKLOH
.720,7$71$.$-,0$<.,.8&+, 10,:$-DSDQ
3K\VLRFKHPLFDOGHJUDGDWLRQRIWKHUPDOO\DJHGK\SDORQJORYHVDPSOHV
.9:,/621-U%/60,7+-00$&'21$/'-56&+22129(5-0&$67520(60,7+
0(&28512<(550$5; :367(&./(-U86$
Contents of Volumes 8386 / Polymer Degradation and Stability 86 (2004) IIIXXIV IX
8OWUDVRQLFGHJUDGDWLRQRISRO\EXWDGLHQHDQGLVRWDFWLFSRO\SURS\OHQH
-&+$.5$%257<-6$5.$55.80$5 *0$'5$6,QGLD
3UHSDUDWLRQDQGSURSHUWLHVRISRO\EXW\OHQHWHUHSKWKDODWHcoF\FORKH[DQHGLPHWK\OHQH
WHUHSKWKDODWHbSRO\HWK\OHQHJO\FROVHJPHQWHGUDQGRPFRSRO\PHUV
<=+$1*=)(1*4)(1* )&8,35&KLQD
+\GURO\VLVRISRO\HWK\OHQHWHUHSKWKDODWHLQDIOXLGLVHGEHGUHDFWRU
**5$86(:.$0,16.< *)$+5%$&+*HUPDQ\
$QHZFREDOWFKHODWHDVIODPHUHWDUGDQWIRUSRO\SURS\OHQHILOOHGZLWKPDJQHVLXPK\GUR[LGH
$%6+(+$7$(J\SW
)ODPPDELOLW\DQGWKHUPDOVWDELOLW\VWXGLHVRIVW\UHQHEXW\ODFU\ODWHFRSRO\PHUJUDSKLWHR[LGHQDQRFRPSRVLWH
5=+$1*<+8-;8:)$1 =&+(135&KLQD
$PHFKDQLVWLFPRGHORIWKHUHODWLRQEHWZHHQPROHFXODUVWUXFWXUHRIDP\ORSHFWLQDQGPDFURPROHFXODU
GHJUDGDWLRQGXULQJKHDWLQJVKHDULQJSURFHVVHV
59$1'(1(,1'((9$1'(5/,1'(1$-9$1'(5*227 5%2207KH1HWKHUODQGV
3RO\HVWHUDPLGHVGHULYHGIURPEXWDQHGLRODGLSLFDFLGDQGDPLQRKH[DQRLFDFLG
3DUW,,,VXEVWLWXWLRQRIDGLSLFDFLGXQLWVE\WHUHSKWKDOLFDFLGXQLWV
0/2=$12/)5$1&2$52'5*8(=*$/1 -38,**$/6SDLQ
0HFKDQLVWLFLQYHVWLJDWLRQRIWKHR[LGDWLYHSRO\PHUL]DWLRQRIDQLOLQHK\GURFKORULGHLQGLIIHUHQWPHGLD
60$+0('(J\SW
.LQHWLFVWXG\RQWKHUPDOGHJUDGDWLRQRIORZGHQVLW\SRO\HWK\OHQHVWDELOL]HGZLWKFKDOFRQHGHULYDWLYHV
9',12,8/0*25*+,86-,3$7=$+$5(6&856(71(6&8 &'80,75(6&85RPDQLD
6WDWLVWLFDODQDO\VLVRIWKHSHUIRUPDQFHRIWKHIODPHUHWDUGDQWILQLVKLQJV\VWHPFRQVLVWLQJRIDK\GUR[\IXQFWLRQDO
RUJDQRSKRVSKRUXVROLJRPHUDQGWKHPL[WXUHRI'0'+(8DQGPHODPLQHIRUPDOGHK\GHUHVLQ
::8 &4<$1*86$
X Contents of Volumes 8386 / Polymer Degradation and Stability 86 (2004) IIIXXIV
6\QHUJLVWLFIODPHUHWDUGDQWPHFKDQLVPRIIXPHGVLOLFDLQHWK\OHQHYLQ\ODFHWDWHPDJQHVLXPK\GUR[LGHEOHQGV
0)8 %4835&KLQD
,QIOXHQFHRI6E2 SDUWLFOHVDVILOOHURQWKHWKHUPDOVWDELOLW\DQGIODPPDELOLW\SURSHUWLHVRI
SRO\PHWK\OPHWKDFU\ODWH300$
$/$$&+$&+,0&2&+(=0)(55,2/(/(52<-0/&8(67$ 12*(7)UDQFH
,QYLWURK\GURO\VLVRISRO\/ODFWLGHFU\VWDOOLQHUHVLGXHVDVH[WHQGHGFKDLQFU\VWDOOLWHV
,,,(IIHFWVRIS+DQGHQ]\PH
+768-, .,.$5$6+,-DSDQ
7KHUPDOGHJUDGDWLRQEHKDYLRXURI3(FOD\QDQRFRPSRVLWHV
0=$1(77,3%5$&&2 /&267$,WDO\
/RJLVWLFDSSURDFKWRSRO\PHUGHJUDGDWLRQLQG\QDPLF7*$
5&$261$<$5$57,$*$$*$5&$ $9$5(/$6SDLQ
(QKDQFHGELRVWDELOLW\RISRO\XUHWKDQHFRQWDLQLQJJROGQDQRSDUWLFOHV
6K+68 &:&+2852&
5HYHUVLEOHSRVWH[SRVXUH\HOORZLQJRIZHDWKHUHGSRO\PHUV
-(3,&.(7786$
0RGLILFDWLRQRISRO\FDSURODFWRQHLQWKHSUHVHQFHRISRO\IXQFWLRQDOPRQRPHUVE\LUUDGLDWLRQDQGLWVELRGHJUDGDELOLW\
+$$%'(/5(+,0(J\SW)<26+,, 7.80(-DSDQ
'LVFRORUDWLRQRIFHOOXORVHVWUHDWHGZLWKSRO\HWK\OHQLPLQHV
08'(/$25'(10&0$7$6 -0$571(=855($*$6SDLQ
6\QWKHVLVFKDUDFWHUL]DWLRQDQGGHJUDGDWLRQRISRO\GLPHWK\OWULPHWK\OHQH
FDUERQDWHcoFDSURODFWRQHcoJO\FROLGH
<+8 .-=+8&KLQD
7KHHIIHFWRIDFXULQJDJHQWRQWKHWKHUPDOGHJUDGDWLRQRIILUHUHWDUGDQWEURPLQDWHGHSR[\UHVLQV
$,%$/$%$129,&+*HUPDQ\%HODUXV$+25181*'0(5= +6(,)(57*HUPDQ\
(IIHFWVRIDPELHQWWHPSHUDWXUHFXULQJDJHQWVRQWKHWKHUPDOVWDELOLW\RISRO\PHWK\OSKHQ\OVLOR[DQH
-7681<'+8$1*+/&$2 *)*21*35&KLQD
7KHHIIHFWRIVRPHSRO\PHULFPHWDOFKHODWHVRQWKHIODPPDELOLW\SURSHUWLHVRISRO\SURS\OHQH
0$+$66$1 $%6+(+$7$(J\SW
, &DOHQGDURIHYHQWV
7KHHIIHFWRIJDPPDUDGLDWLRQRQWKHSURSHUWLHVRISRO\SURS\OHQHEOHQGVZLWK
VW\UHQHEXWDGLHQHVW\UHQHFRSRO\PHUV
53(5(5$&$/%$12-*21=/(=36,/9$ 0,&+$=29HQH]XHOD
$JHLQJRIHODVWRPHUVDPROHFXODUDSSURDFKEDVHGRQUKHRORJLFDOFKDUDFWHUL]DWLRQ
$.80$56&200(5(8& 99(51(<)UDQFH
0RGHOOLQJHQGFKDLQVFLVVLRQDQGUHFRPELQDWLRQRIOLQHDUSRO\PHUV
-(-67$**68.
6WXGLHVRQWKHDPLQRO\VLVRI579VLOLFRQHUXEEHUDQGPRGLILFDWLRQVRIGHJUDGDWLRQSURGXFWV
&/&+$1*70'21+6-/(( <26+$7DLZDQ
+\GURO\WLFGHJUDGDWLRQRIEOHQGVRISRO\K\GUR[\DONDQRDWHVDQGIXQFWLRQDOL]HGSRO\K\GUR[\DONDQRDWHV
(5(1$5'0:$//63*85,1 9/$1*/2,6)UDQFH
6\QWKHVLVDQGSKRWRSK\VLFDOLQYHVWLJDWLRQVRIQRYHOFRPELQHGEHQ]R>de@DQWKUDFHQRQH
WHWUDPHWK\OSLSHULGLQHVDVIOXRUHVFHQWVWDELOLVHUVIRUSRO\PHUPDWHULDOV
9%2-,129 ,*5$%&+(9%XOJDULD
8VLQJSHDNSURSHUWLHVRID'7*FXUYHWRHVWLPDWHWKHNLQHWLFSDUDPHWHUVRIWKHS\URO\VLVUHDFWLRQDSSOLFDWLRQ
WRKLJKGHQVLW\SRO\HWK\OHQH
6.,0(6-$1*'+6+,1 .+/((6RXWK.RUHD
7KHUPDOVWDELOLW\DQGIODPPDELOLW\RISRO\SURS\OHQHPRQWPRULOORQLWHFRPSRVLWHV
+4,16=+$1*&=+$20)(1*0<$1*=6+8 6<$1*35&KLQD
%LRGHJUDGDWLRQVWXGLHVRISRO\K\GUR[\EXW\UDWHcoK\GUR[\KH[DQRDWH
<::$1*:02+<$24:8-&+(1 *4&+(1&KLQD
(IIHFWRIPHOWSURFHVVLQJRQWKHUPRPHFKDQLFDOGHJUDGDWLRQRISRO\YLQ\ODOFRKROV
3$/(;<,/$&.%6,0.29'%$.2
61351$<297/,37$-6+$1=(/29
09526296ORYDN5HSXEOLF
Contents of Volumes 8386 / Polymer Degradation and Stability 86 (2004) IIIXXIV XI
,QIOXHQFHRIYDULRXVVWDELOL]HUVRQDJHLQJRIGLFXP\OSHUR[LGHFXUHGSRO\SURS\OHQHHWK\OHQHSURS\OHQHGLHQH
WKHUPRSODVWLFYXOFDQL]DWHV
.1$6.$5'.2.27 -:01225'(50((57KH1HWKHUODQGV
%LRILOPVRQVLOLFRQHUXEEHULQVXODWRUVPLFURELDOFRPSRVLWLRQDQGGLDJQRVWLFVRIUHPRYDOE\XVHRI
(6(0('6&RPSRVLWLRQRIELRILOPVLQIHFWLQJVLOLFRQHUXEEHULQVXODWRUV
6:$//6750 6.$5/66216ZHGHQ
6LPXOWDQHRXVGHWHUPLQDWLRQRIWKHFRQWHQWDQGDFWLYLW\RIVWHULFDOO\KLQGHUHGSKHQROLFDQG
DPLQHVWDELOL]HUVE\PHDQVRIDQR[LGDWLYHPRGHOUHDFWLRQ
(%=(<1$/29$]HUEDLMDQ 16$//(18.
6RLOEXULDODQGHQ]\PDWLFGHJUDGDWLRQLQVROXWLRQRIDOLSKDWLFFRSRO\HVWHUV
35,==$5(//,&38*/,6, *0217$8'2,WDO\
%LRGHJUDGDELOLW\RIDURPDWLFEXLOGLQJEORFNVIRUSRO\HWK\OHQHWHUHSKWKDODWHFRSRO\HVWHUV
0&(5'&8//$5'35.,176082=*8(55$
062/('$'0$5486&$/926SDLQ
5HOD[DWLRQVDQGWKHUPDOVWDELOLW\RIORZPROHFXODUZHLJKWSUHGRPLQDQWO\LVRWDFWLFPHWDOORFHQHDQG
=LHJOHU1DWWDSRO\SURS\OHQH
-0*0(=(/9,5$37,(0%/20(/9,5$6SDLQ/0$7,629$5<&+/$
-5<&+/<6ORYDN5HSXEOLF
9LQ\ODFHWDWHEXW\ODFU\ODWHFRSRO\PHUV3DUW)LUHUHWDUGDQF\XVLQJSKRVSKRUXVFRQWDLQLQJDGGLWLYHVDQGPRQRPHUV
6'848(61(-/()(%95()UDQFH*6((/(<8.*&$0,12,WDO\5'(/2%(/ 0/(%5$6)UDQFH
7KHGHIRUPDWLRQRIWKHFKDLQPROHFXOHVDQGFU\VWDOOLWHVLQSRO\>R@K\GUR[\EXW\UDWHDQG
SRO\K\GUR[\EXW\UDWHXQGHUWHQVLOHVWUHVV
)7$1$.$<'2, 7,:$7$-DSDQ
,QYHVWLJDWLRQRIWKHUPDOVWDELOL]DWLRQRISRO\YLQ\OFKORULGHE\OHDGVWHDUDWHDQGLWVFRPELQDWLRQ
ZLWKV\QWKHWLFK\GURWDOFLWH
5.$/286.29$0129271$ =9<0$=$/&]HFK5HSXEOLF
7KHUPDODQGG\QDPLFPHFKDQLFDOEHKDYLRXURIFDOFLXPFRQWDLQLQJFRSRO\XUHWKDQHV
5$58135$6$7+61$1-81'$1,QGLD73$.8/$ 0./$33(5*HUPDQ\
, &DOHQGDURIHYHQWV
6SHFLDO,VVXHQG,83$&0LFURV\PSRVLXPRQ'HJUDGDWLRQ6WDELOLVDWLRQDQG5HF\FOLQJRI3RO\PHUV3UDJXH&]HFK
5HSXEOLF-XO\DQGQG,QWHUQDWLRQDO&RQIHUHQFHRQ0RGLILFDWLRQ'HJUDGDWLRQDQG6WDELOLVDWLRQRI3RO\PHUV
0R'H6W%XGDSHVW+XQJDU\-XO\
(GLWRULDO
'HJUDGDWLRQDQGVWDELOLVDWLRQRISRO\PHUVDQGFRDWLQJVQDQRYHUVXVSLJPHQWDU\WLWDQLDSDUWLFOHV
16$//(10('*($257(*$*6$1'29$/&0/,$8:-9(55$1
-675$7721 5%0&,17<5(8.
0HOWUHDFWLRQLQEOHQGVRISRO\K\GUR[\EXW\UDWHcoK\GUR[\YDOHUDWH
DQGHSR[LGL]HGQDWXUDOUXEEHU
&&+$1-,60$,/0DOD\VLD +:.$00(5*HUPDQ\
&KHPLOXPLQHVFHQFHLVVKHGGLQJOLJKWRQGHJUDGDWLRQDQGVWDELOLVDWLRQRISODVWLFLVHGSRO\YLQ\OFKORULGH
<.$1186$ 1&%,//,1*+$08.
'HJUDGDWLRQVWXG\RIGDWHSDOPILEUHSRO\SURS\OHQHFRPSRVLWHVLQQDWXUDODQGDUWLILFLDOZHDWKHULQJPHFKDQLFDO
DQGWKHUPDODQDO\VLV
%)$%86+$5.+ ++$0,'6DXGL$UDELD
$QHIILFLHQWPHWKRGRIPDWHULDOUHF\FOLQJRIPXQLFLSDOSODVWLFZDVWH
,)257(/1z <'0,&+/.29 =.58/,6 &]HFK5HSXEOLF
)HHGVWRFNUHF\FOLQJRISODVWLFVLQ-DSDQ
$2.8:$.,-DSDQ
*XHVWHGLWRULDO
/DXURODFWDPDVDVWDELOL]HUDJDLQVWWKHWKHUPRR[LGDWLYHGHJUDGDWLRQRISRO\HWKHUHVWHUV
*%27(/+23RUWXJDO3*,-60$17KH1HWKHUODQGV$90$&+$'2 $48(,563RUWXJDO
XII Contents of Volumes 8386 / Polymer Degradation and Stability 86 (2004) IIIXXIV
7KHHIIHFWRIVRPHWKLRVHPLFDUED]LGHFRPSRXQGVRQWKHUPDOR[LGDWLRQRISRO\SURS\OHQH
56(71(6&8&%$5&87($16-,3$76(71(6&801(*2,8,0,+$/&($
0'80,758 7=$+$5(6&85RPDQLD
7KHDQWLR[LGDQWHIIHFWLQFRQWUROOLQJWKHUPDOGHJUDGDWLRQRIDORZGHQVLW\SRO\HWK\OHQHEORZQILOP
30$5,$1,*&$5,$11, )3/$0$17,$,WDO\
3KRWRR[LGDWLRQRIspherilene OLQHDUORZGHQVLW\SRO\HWK\OHQHILOPVVXEMHFWHGWRHQYLURQPHQWDOZHDWKHULQJ
&KDQJHVLQPHFKDQLFDOSURSHUWLHV
&1$''(2/*8$'$*12 99,7725,$,WDO\8(
(IIHFWRIFKDLQVWUXFWXUHRQWKHSURFHVVLQJVWDELOLW\RIKLJKGHQVLW\SRO\HWK\OHQH
(32&.&.,66-$1(&6.$((3$&+(5 %38.16=.<+XQJDU\
0LFUR5DPDQDQGDWRPLFIRUFHPLFURVFRS\DQDO\VLVRIQDWXUDOO\DJHGSRO\HWK\OHQH
$6=33$11$,&621726*\0$526,6]0$7. *\%(57$/$1+XQJDU\
7KHUPDOVWDELOLW\RIFDWLRQLFDOO\DOO\ODWHGSRO\YLQ\OFKORULGHDQG
SRO\YLQ\OFKORULGHcoFKORURSURSHQHFRSRO\PHU
76=$.&6%,91 -.83$,+XQJDU\
(SR[LGDWLRQRIWKHUPDOO\GHJUDGHGSRO\YLQ\OFKORULGH
76=$.&6 %,91+XQJDU\
3KRWRUHVWDELOLVDWLRQRIUHF\FOHGSRVWFRQVXPHUILOPVIURPJUHHQKRXVHV
17=$1.29$',17&+(9$ )3/$0$17,$,WDO\
)HHGVWRFNUHF\FOLQJRISRO\PHUVE\S\URO\VLVLQDIOXLGLVHGEHG
:.$0,16.<035('(/ $6$',.,*HUPDQ\
%HGGHIOXLGLVDWLRQGXULQJWKHIOXLGLVHGEHGS\URO\VLVRISODVWLFZDVWHPL[WXUHV
0/0$67(//21( 8$5(1$,WDO\
/LJKWLQGXFHGIUHHUDGLFDOVLQFURZQHWKHUUHDFWLYHG\HLQJV\VWHPV
$9*3%$.$52&.(1%$8(5/.25(&=+XQJDU\.6,5%,/$'=(*HRUJLD
,586=1. /72 .(+XQJDU\
3RO\PHUILOPVIRUVRODUHQHUJ\DSSOLFDWLRQVWKHUPRDQDO\WLFDODQGPHFKDQLFDOFKDUDFWHULVDWLRQ
RIDJHLQJEHKDYLRXU
*0:$//1(5&:(,*/5/(,7*(% 5:/$1*$XVWULD
, &DOHQGDURIHYHQWV
6XUIDFHFKHPLVWU\FKDQJHVRIZHDWKHUHG+'3(ZRRGIORXUFRPSRVLWHVVWXGLHGE\
;36DQG)7,5VSHFWURVFRS\
1067$5. /00$78$1$8QLWHG6WDWHV
7KHUPDODQGSKRWRR[LGDWLRQRIKLJKVW\UHQHEXWDGLHQHFRSRO\PHU6%&
16$//(1$%$5&(/21$0('*($:,/.,16218.&*0(5&+$1
95648,7(5,$6SDLQ
(IIHFWVRIUHPRYLQJVPDOOIUDJPHQWVZLWKXOWUDILOWUDWLRQWUHDWPHQWDQGXOWUDVRQLFFRQGLWLRQVRQWKHGHJUDGDWLRQ
NLQHWLFVRIFKLWRVDQ
0/76$,+/=76(1* 5+&+(17DLZDQ52&
5HOHYDQWIDFWRUVLQVFRUFKJHQHUDWLRQLQILUHUHWDUGHGIOH[LEOHSRO\XUHWKDQHIRDPV,$PLQRJURXSUHDFWLYLW\
03/8'$31$'$/&267$3%5$&&2,WDO\ 69/(9&+,.86$
5HOHYDQWIDFWRUVLQVFRUFKJHQHUDWLRQLQILUHUHWDUGHGIOH[LEOHSRO\XUHWKDQHIRDPV,,5HDFWLYLW\RILVRF\DQDWH
XUHDDQGXUHWKDQHJURXSV
03/8'$/&267$3%5$&&2,WDO\ 69/(9&+,.86$
6WUXFWXUHSURSHUWLHVDQGELRGHJUDGDELOLW\RIZDWHUUHVLVWDQWUHJHQHUDWHGFHOOXORVHILOPVFRDWHGZLWK
SRO\XUHWKDQHEHQ]\ONRQMDFJOXFRPDQQDQVHPL,31FRDWLQJ
</8/=+$1* 3;,$23HRSOH
V5HSXEOLFRI&KLQD
(IIHFWRISKRWRR[LGDWLRQFUDFNVRQEHKDYLRXURIWKLFNSRO\SURS\OHQHVDPSOHV
,<$.,0(76'/$, 0*8,*21)UDQFH
7KHHIIHFWRIGHFDEURPRGLSKHQ\OR[LGHDQGDQWLPRQ\WULR[LGHRQWKHIODPHUHWDUGDWLRQRI
HWK\OHQHSURS\OHQHGLHQHFRSRO\PHUSRO\SURS\OHQHEOHQGV
/<8::$1* :;,$2&KLQD
7KHUPDOGHJUDGDWLRQEHKDYLRXURISRO\R[\PHWK\OHQH'HJUDGDWLRQDQGVWDELOL]HUFRQVXPSWLRQ
90$5&+2'28/$.,6/)7/ 66(,'/(5$XVWULD
Contents of Volumes 8386 / Polymer Degradation and Stability 86 (2004) IIIXXIV XIII
0ROHFXODUPRGHOLQJRIPHWDWKHVLVGHJUDGDWLRQRISRO\DONHQDPHUV'HJUDGDWLRQRISRO\QRUERUQHQHYLD
FURVVPHWDWKHVLVZLWKOLQHDUROHILQV
-9257(*$6)20,1( 0$7/(1.23$7&+(90H[LFR
'HJUDGDWLRQRISRO\FDSURODFWRQHVWDUFKEOHQGVDQGFRPSRVLWHVZLWKVLVDOILEUH
&5',)5$1&293&<5$6-3%86$/0(15$586(&.$,7( $9=48(=$UJHQWLQD
&RPSDUDWLYHVWXG\RQELRGHJUDGDELOLW\RISRO\HWK\OHQHZD[E\EDFWHULDDQGIXQJL
).$:$,0:$7$1$%(06+,%$7$6<2.2<$0$<68'$7( 6+$<$6+,-DSDQ
$QLQIOXHQFHRIPLFURQDQGQDQRSDUWLFOHWLWDQLXPGLR[LGHVRQWKHHIILFLHQF\RIDQWLR[LGDQW,UJDQR[
LQDPRGHOR[LGDWLYHUHDFWLRQ
(%=(<1$/29$]HUEDLMDQ 16$//(18.
&DWDO\WLFGHJUDGDWLRQRIKLJKGHQVLW\SRO\HWK\OHQHRYHUPHVRSRURXVDQGPLFURSRURXVFDWDO\VWVLQD
IOXLGLVHGEHGUHDFWRU
<+/,10+<$1*7)<(+ 0'*(57DLZDQ52&
89VHQVLWLVDWLRQRISRO\HWK\OHQHVIRUJUDIWLQJRIPDOHLFDQK\GULGH
-*0$571(=5%(1$9,'(6&*8(55(52 %(5(<(60H[LFR
1RYHOWKHUPRVHWWLQJUHVLQVEDVHGRQNPDOHLPLGRSKHQ\OJO\FLG\OHWKHU,,,6WXGLHVRQWKHWKHUPDO
GHJUDGDWLRQNLQHWLFVDQGPHFKDQLVPVRIWKHFXUHGUHVLQV
<//,8:/:(,<-&+(1&6:8 0+76$,7DLZDQ
0HWKDQRO\VLVLQYHVWLJDWLRQRIFRPPHUFLDOO\DYDLODEOHSRO\XUHWKDQHIRDP
1$6$+,.6$.$,1.80$*$,71$.$1,6+,.+$7$6.$72+ 7025,<26+,-DSDQ
1RYHOWKHUPDOO\GHJUDGDEOHGLHSR[\FURVVOLQNHUVFRQWDLQLQJVXOIRQDWHHVWHUJURXSVIRUSKRWRFURVVOLQNLQJ
<'6+,1$.$:$8(+2.$085$ 06+,5$,-DSDQ
6\QWKHVLVRIPHOWVWDEOHDQGVHPLFU\VWDOOLQHSRO\GLR[DQRQHE\ULQJRSHQLQJFRSRO\PHULVDWLRQRI
GLR[DQRQHZLWKGLIIHUHQWODFWRQHV
-05$48(=%HOJLXP86$3'(*(%HOJLXP51$5$<$186$ 3'8%2,6%HOJLXP
7KHUPDOGHJUDGDWLRQRISRO\DFU\OLFDFLGFRQWDLQLQJFRSSHUQLWUDWH
6'8%,16.<*6*5$'(5*(6+7(5 066,/9(567(,1,VUDHO
)7,5VSHFWURVFRSLFDQGFRQGXFWLYLW\VWXG\RIWKHWKHUPDOGHJUDGDWLRQRISRO\DQLOLQHILOPV
(1.29(72%2/.29 -67(-6.$/&]HFK5HSXEOLF
075&+29,6('
3RO\DQLOLQHSUHSDUHGLQWKHSUHVHQFHRIYDULRXVDFLGV7KHUPDOVWDELOLW\RIFRQGXFWLYLW\
-352.(6 -67(-6.$/&]HFK5HSXEOLF
, &DOHQGDURIHYHQWV
&KHPLOXPLQHVFHQFHIURPSDSHU,,7KHHIIHFWRIVDPSOHFU\VWDOOLQLW\PRUSKRORJ\DQGVL]H
'.2&$56ORYHQLD-/3('(562/,-57KH1HWKHUODQGV0675/,
&
-.2/$56ORYHQLD-5<&+/z< /0$7,6295<&+/6ORYDNLD
(IIHFWRIWKHWKHUPDOGHJUDGDWLRQRI6%6FRSRO\PHUVGXULQJWKHDJHLQJRIPRGLILHGDVSKDOWV
06&257,=2'2/$56(1+%,$1&+(772 -/$/(66$1'5,1,$UJHQWLQD
%LRGHJUDGDWLRQRIW\SH%JHODWLQHE\EDFWHULDLVRODWHGIURPFLQHPDWRJUDSKLFILOPV$YLVFRPHWULFVWXG\
&$%586&,$0$571*21=/(=$'(/$027&255$/(6 )&$7$/,1$6SDLQ
3UHOLPLQDU\VWXG\RQWKHVXSSUHVVLRQFKHPLVWU\RIZDWHUPLVWVRQSRO\PHWK\OPHWKDFU\ODWHIODPHV
=-,$1*&KLQD:.&+2:+RQJ.RQJ-7$1* 6)/,&KLQD
'HJUDGDWLRQHIIHFWVRQWKHUKHRORJLFDODQGPHFKDQLFDOSURSHUWLHVRIPXOWLH[WUXGHGEOHQGVRI
LPSDFWPRGLILHGSRO\SURS\OHQHDQGSRO\HWK\OHQHFRYLQ\ODFHWDWH
(5$05(=9$5*$6'1$9$55252'5*8(=$,%/$148(720(1&+$&$
%0+8(57$0$571(= 03$/$&,260(=7$0[LFR
'HWHUPLQDWLRQRIWKHUPDOR[LGDWLRQUDWHFRQVWDQWVE\DQLQYHUVHPHWKRG
$SSOLFDWLRQWRSRO\HWK\OHQH
;&2/,1/$8'28,1 -9(5'8)UDQFH
6WXGLHVRQFKDLQVFLVVLRQDQGH[WHQVLRQRISRO\DPLGHPHOWLQWKHSUHVHQFHRIXOWUDVRQLFLUUDGLDWLRQ
-/,0/,$1*6*82 </,1&KLQD
/RQJWHUPSHUIRUPDQFHRIFDEOHVEDVHGRQFKORURVXOSKRQDWHGSRO\HWK\OHQH
0-6$1'(/,1 8:*(''(6ZHGHQ
([SDQGDEOHJUDSKLWHV\VWHPVIRUSKRVSKRUXVFRQWDLQLQJXQVDWXUDWHGSRO\HVWHUV,
(QKDQFHGWKHUPDOSURSHUWLHVDQGIODPHUHWDUGDQF\
<)6+,+<7:$1*5--(1* .0:(,7DLZDQ
7KHUPDOR[LGDWLYHDQGUDGLDWLRQVWDELOLW\RISRO\LPLGHV,,,3RO\LPLGHVEDVHGRQ
N>GLR[RGLK\GUR+S\UURO\OSKHQ\O@DFHWDPLGHDQGGLIIHUHQWGLDPLQHV
00$5,129,z z
&&,1&29,&('
=818=29,z &'%$%,z&.323293(5*$/ 03(5*$/6HUELD
7KHUPDOGHJUDGDWLRQRIPXQLFLSDOSODVWLFZDVWHIRUSURGXFWLRQRIIXHOOLNHK\GURFDUERQV
10,6.2/&=,/%$57+$*'(. %-9(5+XQJDU\
2QWKHDFWLRQRIR]RQHRQWKHKDHPRJORELQSURVWKHWLFJURXSKDHPLQDQGKDHPDWRSRUSK\ULQ
DFRPSDULVRQZLWKWKHV\QWKHWLFFRSSHUSKWKDORF\DQLQHV
)&$7$/'2,WDO\
'LIIHUHQWGHJUDGDELOLW\RIWZRVLPLODUSRO\SURS\OHQHVDVUHYHDOHGE\PDFURPROHFXOHVFLVVLRQ
DQGFURVVOLQNLQJUDWHV
$96+<,&+8.3RODQG7-785721-5:+,7(8. ,'6<527<16.$8NUDLQH
(IIHFWRIVHFRQGDU\VWUXFWXUHRQSK\VLFDOEHKDYLRXUDQGSHUIRUPDQFHRIKLQGHUHGSKHQROLF
DQWLR[LGDQWVLQSRO\SURS\OHQH
-72&+&(.&]HFK5HSXEOLF
, &DOHQGDURIHYHQWV
1HZFRPELQHGSKHQROKLQGHUHGDPLQHVWDELOL]HUVIRUSRO\PHUVEDVHGRQGLSKHQ\OPHWKDQHGLLVRF\DQDWH
DQGGLF\FORKH[\OPHWKDQHGLLVRF\DQDWH
&6.6$
6&+0(/$6ORYDN5HSXEOLF*7+(80(5 :'+$%,&+(5*HUPDQ\
%LRGHJUDGDWLRQRIDOLSKDWLFSRO\HVWHUFRPSRVLWHVUHLQIRUFHGE\DEDFDILEHU
17(5$0272.85$7$.2=$:$ 06+,%$7$-DSDQ
6WXG\RQELRGHJUDGDELOLW\RISURWHLQILOOHGSRO\PHUFRPSRVLWHVXVLQJGLHOHFWULFPHDVXUHPHQWV
,7&+087,115<9.,1$&]HFK5HSXEOLF5XVVLD16$+$ 36$+$&]HFK5HSXEOLF
$7*$)7,5DQGPDVVVSHFWUDOVWXG\RQWKHWKHUPDOGHJUDGDWLRQRIELVSKHQRO$SRO\FDUERQDWH
%1-$1* &$:,/.,(86$
5DGLRO\WLFGHJUDGDWLRQRISRO\YLQ\OFKORULGHV\VWHPV
*09,1+$650628720$,25<0%'($/0(,'$ %%1(72%UD]LO
&DOFXODWLQJWKHFKDLQVFLVVLRQGLVWULEXWLRQIXQFWLRQ&6')XVLQJWKHFRQFHQWUDWLRQPHWKRG
&$&&(5(6 69&$1(9$52/2%UD]LO
7KHUROHRIFKDLQVFLVVLRQDQGFKDLQEUDQFKLQJLQKLJKGHQVLW\SRO\HWK\OHQH
GXULQJWKHUPRPHFKDQLFDOGHJUDGDWLRQ
/$3,1+(,520$&+,1(/$772 69&$1(9$52/2%UD]LO
Contents of Volumes 8386 / Polymer Degradation and Stability 86 (2004) IIIXXIV XV
)UHHUDGLFDOGHJUDGDWLRQRIJXDUJXP
775(''< 67$00,6+(77,,QGLD
6WXG\RQGHSRO\PHULVDWLRQRISRO\WULPHWK\OHQHWHUHSKWKDODWHLQVXSHUFULWLFDOPHWKDQROE\*3&+3/&,5
&=+$1*-<$1+=+$1*-<$1* =/,835&KLQD
2[LGDWLRQRIQDWXUDOUXEEHUEDVHGPDJQHWRUKHRORJLFDOHODVWRPHUV
0/2.$1'(575(,7%(5*(5 %67(1%(5*6ZHGHQ
2QWKHDFWLRQRIR]RQHRQPHWKDHPRJORELQ
)&$7$/'2,WDO\
7KHUPDOGHJUDGDWLRQRISRO\SURS\OHQHVWDUFKEDVHGPDWHULDOVZLWKHQKDQFHGELRGHJUDGDELOLW\
;5$0,6$&$'(1$72-06$//$-0025$1&+2$9$//6/&217$7 $5,%(66SDLQ
(QKDQFHPHQWRIWKHWKHUPRR[LGDWLYHGHJUDGDELOLW\RISRO\VW\UHQHE\FKHPLFDOPRGLILFDWLRQ
*%27(/+2$48(,56$0$&+$'23RUWXJDO3)5$1*,26$%UD]LO -)(55(,5$3RUWXJDO
3\URO\VLVRISRO\HWK\OHQHWHUHSKWKDODWHLQDIOXLGLVHGEHGSODQW
7<26+,2.$-DSDQ**5$86(&(*(5:.$0,16.<*HUPDQ\ $2.8:$.,-DSDQ
7KHUPDOO\VWDEOHPHWDOFRQWDLQLQJSRO\XUHDVIURPKH[DGHQWDWH6FKLIIEDVH
PHWDOFRPSOH[HVDQGGLLVRF\DQDWHV
1&+$17$5$6,5,&&+8/$0$1((70$1$1816$3 108$1*6,17KDLODQG
7KHUPDOVWDELOLWLHVDQGG\QDPLFPHFKDQLFDOSURSHUWLHVRIVXOIRQHFRQWDLQLQJ
HSR[\UHVLQFXUHGZLWKDQK\GULGH
6-3$5. )/-,16RXWK.RUHD
(IIHFWVRISOHURVSKHUHVRQWKHDWRPLFR[\JHQUHVLVWDQFHRIDSKHQROLFUHVLQFRPSRVLWH
0:$1*;=+$2=6+(160$ <;,1*35&KLQD
&DWDO\WLFGHJUDGDWLRQRISRO\EXWDGLHQH
6/*837( *0$'5$6,QGLD
3UHSDUDWLRQDQGSURSHUWLHVRIKDORJHQIUHHIODPHUHWDUGHGSRO\DPLGHRUJDQRFOD\QDQRFRPSRVLWH
/621*<+8=/,16;8$16:$1*=&+(1 :)$135&KLQD
$ONDOLQHGHFKORULQDWLRQRISRO\YLQ\OFKORULGHLQRUJDQLFVROYHQWVXQGHUPLOGFRQGLWLRQV
7<26+,1$*$0<$0$<(7.,727,&+,.,02*$7$-&+(1+)8-,12
77$1,085$ 7<$0$12%(-DSDQ
7KHUPDODQGPHFKDQLFDOSURSHUWLHVRISRO\XUHWKDQHPRQWPRULOORQLWHQDQRFRPSRVLWHV
EDVHGRQDQRYHOUHDFWLYHPRGLILHU
-;,21*</,8;<$1* ;:$1*35&KLQD
7KHHIIHFWRIEDVHVWDELOL]DWLRQRQWKHUHF\FODELOLW\RISRO\SURS\OHQHDVVWXGLHGE\
PXOWLFHOOLPDJLQJFKHPLOXPLQHVFHQFHDQGPLFURFDORULPHWU\
0+$06.2*0./*(/')2566750%7(56(/,86 3*,-60$16ZHGHQ
6XJDUFDQHEDJDVVHDQGFXUDXDOLJQLQVR[LGL]HGE\FKORULQHGLR[LGHDQGUHDFWHG
ZLWKIXUIXU\ODOFRKROFKDUDFWHUL]DWLRQDQGVWDELOLW\
:+2$5($8)UDQFH:*75,1'$'()UDQFH%UD]LO%6,(*081'
$&$67(//$1)UDQFH ()52//,1,%UD]LO
, &DOHQGDURIHYHQWV
,,, &RQWHQWVRI9ROXPHV
;9, 6XEMHFW,QGH[IRU9ROXPHV
Polymer Degradation and Stability 86 (2004) IIIXXIV
www.elsevier.com/locate/polydegstab
S01413910(04)003003
Subject Index for Volumes 8386 / Polymer Degradation and Stability 86 (2004) IIIXXIV XVII
Glass transition temperature (Tg) 305 Photostability of dyes and coloured PMMA 405
Graphite oxide 215 Phylogenetic analysis 115
Physical blends 393
Halogen-free flame retardant 533 PLLA 143, 243
Hindered amine stabilisers 475 PMMA coloured in mass 405
Hindered phenol antioxidant 499 PMMA 399, 405, 545
HIPS 279 Poly (L-lactic acid) 143
Horseradish peroxidase 321 Poly (L-lactide) 143
Hydrolysis 515 Poly(, -malic acid) 151
Hydrolytic degradation 41 Poly(butylene adipate) 105
Hydroperoxides 227 Poly(butylene succinate) 105
Hypalon 439 Poly(D, L-lactide) 393
Poly(dimer aciddodecanedioic acid) copolymer 375
Inner-valence 327 Poly(dimer acidtetradecanedioic acid) copolymer 375
Invariant kinetic parameters method (IKP method) 311 Poly(dimethylsiloxane) 1
Iodides 199 Poly(-caprolactone) 345, 393
Iodometry 227 Poly(esteramide) 253
IR spectroscopy 207 Poly(ethylene adipate) 1
Isolation 331 Poly(ethylene oxide) 1, 349
Isotactic polypropylene degradation 61 Poly(ethylene succinate) 105
Poly(glycolide) 393
Kinetic analysis 31, 243 Poly(hydroxyalkanoate) 95
Kinetic parameter 243 Poly(lactic acid) 515
Kinetic 483 Poly(L-lactic acid) 243, 433
Kinetics 143, 399 Poly(L-lactide) 243
Poly(methyl methacrylate) 87, 269, 327
LDPE 493 Poly(n-butyl acrylate) 505
Limited oxygen index (LOI) tester 305 Poly (vinyl acetate) 345
Linear regression method 173 Poly(vinyl chloride) 289
Liquid product composition 123 Poly[(R)-3-hydroxybutylic acid-co-(R)-3-hydroxyhexanoic acid] 135
Low molecular weight polyethylene 499 Polyacrylamide 349
L-malic acid 151 Polyacrylamidoxime fibre 207
Polyamide 6,6 199
Mathematical analysis 13 Polychloroprene 419
Mechanical properties 345 Polyetheresteramide 41
Melamine 451 Polyethylene copolymer 533
Melt free radical grafting 499 Polyethylene pipes 261
Melting behavior 61 Polyethylene 279, 475
Mercury ions 207 Polyethylenes 7
Mesophilic bacteria 115 Polyhydroxyalkanoates 129
Metals 7 Polyimide 369
Misinterpretation 363 Polylactide 515
Mixture (HDPE, PS) 123 Polymer degradation 253
Modulus 419 Polymer-bound antioxidant 499
Molecular weight distribution 61 Polymeric modifiers 23, 31
Montmorillonite 289 Polypropylene 279
Polysilylenes 383
N,N,N-trimethylchitosan 353 Polystyrene 87, 215, 269, 483
Nanocomposite 289, 483 Polyurethane 69, 183
Nanocomposites 215, 269, 279, 287, 533 PP 227, 493
NMR relaxation 419 Pressure dependence 79
Non-isothermal kinetics 311 PS/ABS-Br 459
Numerical errors 363 PVC thermal degradation 311
PVC 79
Organo-clay 483 PVC/CPE blends 23, 31
Oxidation 321 Pyrolysis 143, 243, 345