TIU CHUN VIT NAM

TCVN 6213 : 2004

NC KHONG THIN NHIN NG CHAI
BOTTLED/ PACKAGED NATURAL MINERAL WATERS
1. Phm vi p dng
Tiu chun ny p dng cho nc khong thin nhin ng chai dng cho mc ch gii kht.
Tiu chun ny khng p dng cho nc khong thin nhin dng cho cc mc ch khc.
2. Ti liu vin dn
TCVN 2652 - 78, Nc ung. Phng php ly mu, bo qun v vn chuyn mu.
TCVN 2653 - 78, Nc ung. Phng php xc nh mi, v, mu sc v c.
TCVN 4560 - 88, Nc thi. Phng php xc nh hm lng cn.
TCVN 5991: 1995 (ISO 5666/3: 1984), Cht lng nc. Xc nh thu ngn tng s bng
quang ph hp th nguyn t khng ngn la. Phng php sau khi v c ho vi Brom.
TCVN 6002 : 1995 (ISO 6333: 1986), Cht lng nc. Xc nh mangan. Phng php trc
quang dng Fomaldoxim.
TCVN 6053: 1995 (ISO 9696: 1992), Cht lng nc. o tng phng x anpha trong nc
khng mn. Phng php ngun dy.
TCVN 6178: 1996 (ISO 6777: 1984), Cht lng nc; Xc nh nitrit. Phng php trc ph
hp th phn t.
TCVN 6180: 1996 (ISO 7890/3: 1988), Cht lng nc. Xc nh nitrat. Phng php trc ph
dng axitosunfosalixylic.
TCVN 6181: 1996 (ISO 6703/1: 1984), Cht lng nc. Xc nh xyanua tng.
TCVN 6182: 1996 (ISO 6595: 1982), Cht lng nc. Xc nh asen tng. Phng php quang
ph dng bc diety-dithiocacbamat.
TCVN 6183: 1983 (ISO 9965: 19930, Cht lng nc. Xc nh selen. Phng php trc ph
hp th nguyn t (k thut hydrua).
TCVN 6184: 1996 (ISO 7072: 1990), Cht lng nc. Xc nh c.
TCVN 6185: 1996 (ISO 7887: 1985), Cht lng nc. Kim tra v xc nh mu sc.
TCVN 6187-1: 1996 (ISO 9308/1: 1990), Cht lng nc. Pht hin v m vi khun Coliform,
vi khun Coliform chu nhit v Eschrichia coli gi nh. Phn 1: Phng php mng lc.
TCVN 6189-2: 1996 (ISO 7899/2: 1984), Cht lng nc. Pht hin v m khun lin cu
phn. Phn 2: Phng php mng lc.
TCVN 6191-2: 1996 (ISO 6461/2: 1986), Cht lng nc. Pht hin v m s bo t vi khun
k kh kh sunphit (Clostridia). Phn 2: Phng php mng lc.
TCVN 6193: 1996 (ISO 8288: 1986), Cht lng nc. Xc nh coban, niken, ng km, caimi
v ch. Phng php trc ph hp th nguyn t ngn la.
TCVN 6195: 1996 (ISO 10359/1: 1992), Cht lng nc. Xc nh florua. Phng php d in
ho i vi nc sinh hot v nc b nhim nh.
TCVN 6196-3: 2000 (ISO 9964/3: 1993), Cht lng nc. Xc nh natri v kali. Phn 3: Xc
nh natri v kali bng o ph pht x ngn la.
TCVN 6198: 1996 (ISO 6058: 1984), Cht lng nc. Xc nh hm lng canxi. Phng php
chun EDTA.
TCVN 6222: 1996 (ISO 9174: 1990), Cht lng nc. Xc nh crom tng. Phng php trc
ph hp th nguyn t.
TCVN 6224: 1996 (ISO 6059: 1984), Cht lng nc. Xc nh tng s canxi v magie.
Phng php chun EDTA.
TCVN 6622-1: 2000 (ISO 7875/1: 1984), Cht lng nc. Xc nh cht hot ng b mt.
Phn 1: Xc nh cht hot ng b mt anion bng phng php o ph dng metylen xanh.
TCVN 6635: 2000 (ISO 9390: 1990), Cht lng nc. Xc nh borat. Phng php o ph
dng azometin-H.
TCVN 7087: 2002 [CODEX STAN 1- 1985 (Rev.1 - 1991, Amd. 1999 & 2001)], Ghi nhn thc
phm bao gi sn.
ISO 8360/2: 1988, Water quality - Detection an enumeration of Pseudomonas aeruginosa - Part
2: Membrane fitration method (Cht lng nc - Pht hin v m pseudomonas aeruginosa -
Phn 2: Phng php mng lc).
AOAC 920.194, Carbonate and bicarbonate in water. Titrimetric method (Cacbonat v bicacbonat
trong nc. Phng php chun ).
AOAC 920.201, Barium in water. Gravimetric method (Bari trong nc. Phng php khi
lng).
AOAC 920.204, Bromide and iodide in water. Colorimetric method (Bromua v Iodua trong nc.
Phng php so mu).
AOAC 960.40, Copper in foods. Colorimetric method (ng trong thc phm. Phng php so
mu).
AOAC 964.16, Antimony in foods. Spectrophotometric method (Atimon trong thc phm. Phng
php quang ph).
AOAC 973.30, Polycyclic aromatic hydrocarbons and Benzo[a] pyrenne in food.
Spectrophotometric method (Hydro cacbon thm a vng v benzo[a] pyren trong thc phm.
Phng php quang ph).
AOAC 974.27, Cadmium, chromium, copper, iron, lead, magnesium, manganese, silver, zinc in
water - Atomic absorption spectrophotometric method (Cadimi, crom, ng, st, ch, mangan,
bc, km trong nc. Phng php quang ph hp th nguyn t).
AOAC 977.22, Mercury in water - Flameless atomic absorption spectrophotometric method (Thu
ngn trong nc. Phng php quang ph hp th nguyn t khng ngn la).
AOAC 986.15, Asenic, cadmium, lead, selenium and zinc in human and pet foods (Asen, cadimi,
ch, selen v km trong thc phm v thc n chn nui).
AOAC 990.06, Organocholorine pesticides in water. Gas chromatograhic method (Thuc bo v
thc vt cha gc clo hu c trong nc. Phng php sc k kh).
AOAC 991.07, Nitrogen - and phosphorua - containing pesticides in finished drinking water. Gas
chromatographic method (Thuc bo v thc vt cha gc nit v gc phospho trong nc
ung. Phng php sc k kh).
AOAC 992.14, Pesticides in water. Liquid chromatographic method with ultraviolet detector
(Thuc bo v thc vt trong nc. Phng php sc k kh lng vi u d tia cc tm).
APHA 2120, Color (Xc nh mu sc).
APHA 2320, Alkalinity (Xc nh tnh kim).
APHA 3111, Metals by flame atomic absorption spectrometry (Xc nh kim loi bng quang ph
hp th nguyn t ngn la)
APHA 3112, Metals by cold-vapor atomic absorption spectrometry (Xc nh kim loi bng quang
ph hp th nguyn t hi lnh).
APHA 3113, Metals by electrothermal atomic absorption spectrometry (Xc nh kim loi bng
quang ph hp th nguyn t nhit in).
APHA 3114, Arsenic and selenium by hydride generation/ atomic absorption spectrometry (Xc
nh asen v selen bng quang ph hp th nguyn t/ to hidrua).
APHA 4110, Determination of anions by ion chromatography (Xc nh cc anion bng sc k
ion).
APHA 4500-I_, Iodide (Xc nh idua).
APHA 4500-B, Boron (Xc nh Bo).
APHA 4500-CN_, Cyanide (Xc nh xyanua).
APHA 4500-F_, Fluoride (Xc nh florua).
APHA 4500-NH3, Ammonia (Xc nh amoniac).
APHA 6440, Polynuclear aromatic hydrocarbons (Xc nh hidrocacbon thm a vng).
ASTM D 2330-82, Standard test method for methylene blue active subtances (Phng php th
chun i vi cht hot ng bng xanh methylen).
ASTM D 3086-95, Standard test method for Organochlorine pesticides in water (Phng php
th chun v thuc bo v clo hu c).
EPA 507, Determination of nitrogen and phosphorus - containing pesticides in water by gas
chromatography with a nitrogen-phophorus detector (Xc nh thuc bo v thc vt cha gc
nit v phospho trong nc bng sc k kh c u d nit-phospho).
USEPA 7041A, Antimony. Atomic absorption, furnace technique (Antimon. Phng php hp th
nguyn t, k thut nung).
USEPA 7740A, Selenium. Atomic absorption, furnace technique (Selen. Phng php hp th
nguyn t, k thut nung).
NF T90-112, Dosage de dix lments mtalliques (Cr, Mn, Fe, Co, Ni, Cu, Zn, Ag, Cd, Pb) pas
spectromtrie d absorption atomique dans la flame - Mthodes de dosage directe et aprs
complexation et extraction.
NF T90-414, Essais des eaux - Recherche et denombrement des coliforms et des coliformes
thermotolerants - Method generale par ensemencement en milieu liquide (NPP).
NF Y90-416, Essais des eaux - Recherche et denombrement des streptocoques du groupe D -
Method generale par filtration sur membrane (NEQ ISO 7899/2).
NF T90-417, Essais des eaux - Recherche et denombrement des spores de bacteries anaerobies
sulfito - Reductrices de clostridium sulfito - Reducteurs - Method generale par filtration sur
membrane.
NF T90-421, Essais des eaux - Examens microbiologique des eaux de piscines.
Tiu chun v sinh nc n ung ban hnh km theo Quyt nh s 1329/2002/BYT-Q.
3. Thut ng v nh ngha
Trong tiu chun ny p dng cc thut ng v nh ng sau:
3.1. Nc khong thin nhin ng chai (Bottled/packaged natural mineral water)
Loi nc c th phn bit r vi nc ung thng thng do:
a) c c trng bi hm lng mt s mui khong nht nh v cc t l tng i ca
chng v cc nguyn t vi lng hoc cc thnh phn khc;
b) c ly trc tip t cc ngun thin nhin hoc ging khoan t cc mch nc ngm c
bo v thch hp khng b nhim hoc nh hng n cht lng ca nc khong thin
nhin;
c) Bn vng v thnh phn, n nh v lu lng v nhit cho d c bin ng ca thin
nhin;
d) c ly trong cc iu kin m bo sch ban u v vi sinh vt v thnh phn ho hc
ca cc thnh phn c bn;
e) c ng chai gn ngun vi cc h thng ng dn khp kn m bo cc yu cu v
sinh nghim ngt.
3.2.Nc khong thin nhin cha cacbon dioxit (CO2) t nhin (Naturally carbonated natural
mineral water)
Nc khong thin nhin sau khi c x l v ti hp cacbon dioxit ca chnh ngun v sau
khi ng chai c hm lng kh cacbon dioxit (CO2) nh ti ngun nc.
3.3. Nc khong thin nhin khng cacbon dioxit (CO2) (Non-carbonated natural mineral water)
Nc khong thin nhin sau khi x l v ng chai khng cha cacbon dioxit (CO2) t do vt
qu lng cn thit duy tr s tn ti cc mui hydrocacbonat ho tan trong nc.
3.4. Nc khong thin nhin kh cacbon dioxit (CO2) (Decarbonated natural mineral water)
Nc khong thin nhin sau khi x l v ng chai c cha hm lng cacbon dioxit (CO2)
nh hn ti ngun nc v khng ng thi pht ra cacbon dioxit di cc iu kin nhit v
p sut bnh thng.
3.5. Nc khong thin nhin c b sung cacbon dioxit (CO2) t ngun (Natural mineral water
fortified ith carbon ioxide from the source)
Nc khong thin nhin sau khi x l v ng chai c cha hm lng cacbon dioxit (CO2) ln
hn ti ngun, lngCO2 c b sung l CO2 t ngun.
3.6. Nc khong thin nhin cha cacbon dioxit (Carbonated natural mineral water)
Nc khong thin nhin sau khi x l v ng chai c np thm cacbon dioxit (CO2) thc
phm.
4. Yu cu k thut
4.1. Ngun nc
Ngun nc s dng sn xut nc khong thin nhin ng chai c quy nh bi c
quan c thm quyn.
4.2. X l
4.2.1. Cc bin php x l cho php bao gm vic tch cc thnh phn khng n nh nh cc
hp cht cha st, mangan, lu hunh hoc asen bng phng php gn v/ hoc lc, nu cn
c tng cng bng qu trnh sc kh cacbonic trc.
4.2.2. Cc bin php x l c p dng i vi iu 4.2.1 v cc sn phm nu trong cc iu
t 3.2 n 3.6 ch c thc hin trong iu kin khng lm thay i hm lng khong c
trng ca nc.
4.2.3. Nghim cm vn chuyn nc khong thin nhin trong cc vt cha ri ng chai
hoc tin hnh bt c mt qu trnh no khc trc khi ng chai.
4.2.4. Ngoi cc bin php x l trn, nc khong thin nhin ng chai c th c x l theo
cc quy trnh cng ngh c quy nh bi c quan c thm quyn.
4.3. Yu cu cm quan i vi nc khong thin nhin ng chai, c quy nh trong Bng 1.
Bng 1. Yu cu cm quan i vi nc khong thin nhin ng chai
 Tn ch tiu Yu cu
1. Mu sc, TCU, khng ln hn 15
2. c, NTU, khng ln hn 2
3. Mi, v Khng c mi, v l
4.4. Tng cht rn ho tan ca nc khong thin nhin ng chai (TDS): Nh sn xut t cng
b.
4.5. Cc ch tiu lin quan n an ton sc kho i vi nc khong thin nhin ng chai,
c quy nh trong Bng 2.
Bng 2. Cc ch tiu lin quan n an ton sc kho i vi nc khong thin nhin
ng chai
Tn ch tiu Mc
1. Antimon, mg/l, khng ln hn 0,05
2. Asen, mg/l tnh theo asen tng s, khng ln hn 0,01
3. Bari. mg/l, khng ln hn 0,7
4. Borat, mg/l tnh theo B, khng ln hn 5
5. Cadimi, mg/l, khng ln hn 0,003
6. Crom, mg/l tnh theo crom tng s, khng ln hn 0,05
7. ng, mg/l, khng ln hn 1
8. Xyanya, mg/l, khng ln hn 0,07
9. Florua, mg/l 1)
10. Ch, mg/l, khng ln hn 0,01
11. Mangan, mg/l, khng ln hn 0,5
12. Thu ngn, mg/l, khng ln hn 0,001
13. Niken, mg/l, khng ln hn 0,02
14. Nitrat, mg/l tnh theo nitrat, khng ln hn 50
15. Nitrit, mg/l tnh theo nitrit, khng ln hn 0,02
16. Selen, mg/l, khng ln hn 0,01
17. Cc hydrocacbon thm a vng 2)
18. Cht hot ng b mt 3)
19. Du khong 3)
1) Xem 6.2.3.
2) Theo Tiu chun v sinh nc n ung ban hnh km theo Quyt nh s
1329/2002/BYT-Q
3) Phi nh hn gii hn quy nh trong cc phng php th tng ng
4.6. D lng thuc bo v thc vt trong nc khong thin nhin ng chai: Theo Tiu chun
v sinh nc n ung ban hnh km theo Quyt nh s 1329/2002/BYT-Q.
4.7. Yu cu vi sinh vt i vi nc khong thin nhin ng chai
Trong qu trnh tiu th, nc khong thin nhin ng chai:
a) Phi m bo cht lng khng gy ri ro cho sc kho ngi tiu dng (khng c c cc
vi sinh vt gy bnh);
b) Ngoi ra phi tun th cc yu cu v vi sinh vt sau y:
Kim tra ln u Quyt nh
E.Coli hoc coliform chu nhit 1 x 250 ml Khng c pht hin trong bt k
mu no
Coliform tng s 1 x 250 ml Nu 1 hoc 2 th tin hnh kim
tra ln th hai
Streptococci feacal 1 x 250 ml
Pseudomonas aeruginosa 1 x 250 ml Nu > 2 th loi b
Bo t vi khun k kh kh sunphit 1 x 50 ml

Kim tra ln th hai

n c* m M
Coliform tng s 4 1 0 2
Streptococci feacal 4 1 0 2
Bo t vi khun k kh kh sunphit 4 1 0 2
Pseudomonas aeruginosa 4 1 0 2
Kim tra ln th hai c thc hin s dng cng th tch nh dng kim tra ln u.
n: s n v mu ly t l hng kim tra
c: s lng mu ti a c th chp nhn hoc s lng n v mu ti a cho php vt qu
chun m v vi sinh vt. Nu vt qu s ny th l hng c coi l khng t.
m: l s lng ti a hoc mc ti a ca vi khun tng ng/g; cc gi tr trn mc ny c th
c chp nhn hoc khng c chp nhn.
M: l lng thc phm c chp nhn trong s thc phm khng c chp nhn. Gi tr bng
M hoc ln hn M trong bt k mu no u khng c chp nhn v nh hng ti sc kho
con ngi.
5. Phng php th
5.1. Ly mu, theo TCVN 2652-78.
5.2. Xc nh mu sc, theo TCVN 6185;1996 (ISO 7887:1985) hoc APHA 2120.
5.3. Xc nh c, theo TCVN 6184: 1996 (ISO 7027: 1990) hoc APHA 2120.
5.4. Xc nh mi, v, theo TCVN 2653 - 78.
5.5. Xc nh hm lng tng cht rn ho tan, theo ph lc A ca TCVN 6053: 1995 (ISO 9696:
1992) hoc TCVN 4560: 1988.
5.6. Xc nh hm lng natri, theo TCVN 6196-3: 2000 (ISO 964/3; 1993) hoc APHA 3111.
5.7. Xc nh hm lng kali, theo TCVN 6196-3: 2000 (ISO 9964/3: 1993) hoc APHA 3111.
5.8. Xc nh hm lng canxi, theo TCVN 6198: 1996 (ISO 6058: 1984) hoc APHA 3111.
5.9. Xc nh hm lng magi, theo TCVN 6224: 1996 (ISO 6059: 1984) hoc APHA 3111.
5.10. Xc nh hm lng it, theo AOAC 920.204 hoc APHA 4500-I_.
5.11. Xc nh HCO3, theo AOAC 920.194 hc APHA 2320.
5.12. Xc nh hm lng antimon, theo AOAC 964.16 hoc APHA 3114 hoc USEPA 7041 A.
5.13. Xc inh hm lng asen, theo TAVN 6182: 1996 (ISO 6595: 1982) hoc AOAC 986.15
hoc APHA 3114.
5.14. Xc nh hm lng bari, theo AOAC 920.201 hoc APHA 3114.
5.15. Xc nh hm lng borat, theo TCVN 6635: 2000 (ISO 9390: 1990) hoc APHA 4500 - B.
5.16. Xc nh hm lng cadimi, theo TYCVN 6193: 1996 (ISO 8288: 1986) hoc AOAC 986.15
hoc AOAC 974.27 hoc APHA 3113.
5.17. Xc nh hm lng crom, theo TCVN 6222: 1996 (ISO 9174: 1990) hoc APHA 3111.
5.18. Xc nh hm lng ng, theo TCVN 6193: 1996 (ISO 8288: 1996) hoc AOAC 960.40
hoc APHA 3111.
5.19. Xc nh hm lng xyanua, theo TCVN 6181: 1996 (ISO 6703/1: 1984) hoc APHA 4500 -
CN_.
5.20. Xc nh hm lng florua, theo TCVN 6195: 1996 (ISO 10359/1: 1992) hoc APHA 4500 -
F_.
5.21. Xc nh hm lng ch, theo TCVN 6193: 1996 (ISO 8288: 1996) hoc AOAC 974.27 hoc
APHA 3113.
5.22. Xc nh hm lng mangan theo TCVN 6002: 1995 (ISO 6333: 1986) hoc APHA 3111
hoc NF T90-112.
5.23. Xc nh hm lng thy ngn, theo TCVN 5991: 1995 (ISO 5666/3: 1984) hoc AOAC
977.22 hoc APHA 3112.
5.24. Xc nh hm lng niken, theo TCVN 6193: 1996 (ISO 8288: 1996) hoc APHA 3111.
5.25. Xc nh hm lng nitrat, theo TCVN 6180: 1996 (ISO7890/3: 1988) hoc APHA 4110.
5.26. Xc nh hm lng nitrit, theo TCVN 6178: 1996 (ISO 6777: 1984).
5.27. Xc nh hm lng selen, theo TCVN 6183: 1996 (ISO 9965: 1993) hoc APHA 3114 hoc
USEPA 7740.
5.28. Xc nh hm lng hydrocacbon thm a vng, theo AOAC 973.30 hoc APHA 6440.
5.29. Xc nh d lng thuc bo v thc vt, theo AOAC 922.14 hoc AOAC 990.06 v AOAC
991.07 hoc ASTM D 3086 - 95 v EPA 507.
5.30. Xc nh cht hot ng b mt, theo TCVN 6622-1: 2000 (ISO 7875/1: 1984) hoc ASTM
D 2330 - 82.
5.31. Xc nh E.Coli hoc Coliforms chu nhit, theo TCVN 6187 - 1: 1996 (ISO 9308/1: 1990).
5.32. Xc nh Coliforms, theo TCVN 6187-1: 1996 (ISO 9308/1:1990) hoc NF T90-414.
5.33. Xc nh Streptococci feacal, theo TCVN 6189-2: 1996 (ISO 7899/2:1984) hoc NF T90-
416.
5.34. Xc nh Pseudomonas aeruginosa, theo ISO 8360/2: 1988 hoc NF T90-421.
5.35. Xc nh bo t vi khun k kh kh sunphit, theo TCVN 6191-2:1996 (ISO 6461/2: 1986)
hoc NF T90-417.
6. ng gi, ghi nhn, bo qun, vn chuyn
6.1. ng gi
6.1.1. Nc khong thin nhin c ng trong cc chai, bnh chuyn dng cho thc phm,
m bo yu cu v sinh.
6.1.2. Nc khong thin nhin c ng trong cc chai, bnh c dung tch thch hp, kn,
khng b r r bt c t th no, khng lm thay i hoc nh hng n cht lng ca nc
khong thin nhin trong qu trnh bo qun v vn chuyn.
6.2. Ghi nhn
6.2.1. Vic ghi nhn i vi nc khong thin nhin ng chai phi thc hin theo TCVN 7087:
2002 [CODEX STAN 1-1985 (Rew.1 - 1991, Amd. 1999 v 2001)] Ghi nhn thc phm bao gi
sn.
6.2.2. Vic ghi nhn i vi nc khong thin nhin ng chai, ngoi nhng quy nh ti 6.2.1.
ca Tiu chun ny cn b sung cc ni dung sau y:
6.2.2.1.Tn gi ca sn phm phi l "Nc khong thin nhin" kt hp vi tn gi thng mi
hoc a danh ca ngun nc. Ngoi ra, tu theo bn cht ca tng loi nc khong nh nh
ngha 3.2 n 3.6 m ghi r:
- Nc khong thin nhin cha cacbon dioxit (CO2) t nhin;
- Nc khong thin nhin khng cha cacbon dioxit (CO2);
- Nc khong thin nhin kh cacbon dioxit (CO2);
- Nc khong thin nhin c b sung cacbon dioxit (CO2) t ngun;
- Nc khong thin nhin cha cacbon dioxit.
6.2.2.2. Ghi ln nhn cc thnh phn c trng ca nc khong thin nhin:
- Hm lng tng cht rn ho tan;
- Hm lng natri;
- Hm lng canxi
- Hm lng kali;
- Hm lng magi;
- Hm lng it;
- Hm lng florua;
- Hm lng HCO3_.
6.2.2.3. Khi sn phm cha nhiu hn 1 mg/l florua th phi ghi trn nhn l "c cha florua". Khi
sn phm cha nhiu hn 2.0 mg/l florua th phi ghi trn nhn l "sn phm khng thch hp
cho tr di 7 tui".
6.2.2.4. Pha di tn gi phi ghi r cc bin php x l p dng.
6.2.2.5. Khng ghi nhn xc nhn lin quan n dc l hoc hiu qu iu tr bnh l.
6.3. Bo qun
Nc khong thin nhin ng chai c bo qun iu kin bnh thng. Trnh nh nng
trc tip ca mt tri.
6.4. Vn chuyn
Nc khong thin nhin ng chai c vn chuyn bng cc phng tin vn chuyn kh,
sch, c mui che trnh c ma nng, khng lm nh hng n cht lng sn phm.
 TIU CHUN VIT NAM TCVN 6096 : 2004 NC UNG NG CHAI
BOTTLED/ PACKAGED DRINKING WATERS
1. Phm vi p dng
Tiu chun ny p dng cho nc ung ng chai dng cho mc ch gii kht. Tiu chun ny
khng p dng cho nc khong thin nhin ng chai c quy nh trong TCVN 6213: 2004
2. Ti liu vin dn
TCVN 2652 - 78, Nc ung. Phng php ly mu, bo qun v vn chuyn mu.
TCVN 2653 - 78, Nc ung. Phng php xc nh mi, v, mu sc v c.
TCVN 4559 - 78, Nc thi. Phng php xc nh pH.
TCVN 4560 - 88, Nc thi. Phng php xc nh hm lng cn.
TCVN 5988: 1995 (ISO 5664: 194), Cht lng nc. Xc nh Amoni. Phng php chng ct
v chun .
TCVN 5991: 1995 (ISO 5666/3: 1984), Cht lng nc. Xc nh thu ngn tng s bng
quang ph hp th nguyn t khng ngn la. Phng php sau khi v c ho vi Brom.
TCVN 6002 : 1995 (ISO 6333: 1986), Cht lng nc. Xc nh mangan. Phng php trc
quang dng Fomaldoxim.
TCVN 6053: 1995 (ISO 9696: 1992), Cht lng nc. o tng phng x anpha trong nc
khng mn. Phng php ngun dy.
TCVN 6177: 1996 (ISO 6332: 1988), Cht lng nc. Xc nh st bng phng php trc ph
dng thuc th 1,10 - phenantrolin.
TCVN 6178: 1996 (ISO 6777: 1984), Cht lng nc. Xc nh nitrit. Phng php trc ph
hp th phn t.
TCVN 6180: 1996 (ISO 7890/3: 1988), Cht lng nc. Xc nh nitrat. Phng php trc ph
dng axitosunfosalixylic.
TCVN 6181: 1996 (ISO 6703/1: 1984), Cht lng nc. Xc nh xyanua tng.
TCVN 6182: 1996 (ISO 6595: 1982), Cht lng nc. Xc nh asen tng. Phng php quang
ph dng bc diety-dithiocacbamat.
TCVN 6183: 1983 (ISO 9965: 19930, Cht lng nc. Xc nh selen. Phng php trc ph
hp th nguyn t (k thut hydrua).
TCVN 6184: 1996 (ISO 7072: 1990), Cht lng nc. Xc nh c.
TCVN 6185: 1996 (ISO 7887: 1985), Cht lng nc. Kim tra v xc nh mu sc.
TCVN 6187-1: 1996 (ISO 9308/1: 1990), Cht lng nc. Pht hin v m vi khun coliform,
vi khun coliform chu nhit v Escherichia coli gi nh. Phn 1: Phng php mng lc.
TCVN 6189-2: 1996 (ISO 7899/2: 1984), Cht lng nc. Pht hin v m khun lin cu
phn. Phn 2: Phng php mng lc.
TCVN 6191-2: 1996 (ISO 6461/2: 1986), Cht lng nc. Pht hin v m s bo t vi khun
k kh kh sunphit (Clostridia). Phn 2: Phng php mng lc.
TCVN 6193: 1996 (ISO 8288: 1986), Cht lng nc. Xc nh coban, niken, ng km, cadimi
v ch. Phng php trc ph hp th nguyn t ngn la.
TCVN 6`94: 1996 (ISO 9297: 1989), Cht lng nc. Xc nh clorua. Chun bc nitrat vi
ch th cromat (phng php Mo).
TCVN 6195: 1996 (ISO 10359/1: 1992), Cht lng nc. Xc nh florua. Phng php d in
ho i vi nc sinh hot v nc b nhim nh.
TCVN 6196-3: 2000 (ISO 9964/3: 1993), Cht lng nc. Xc nh natri v kali. Phn 3: Xc
nh natri v kali bng o ph pht x ngn la.
TCVN 6219: 1995 (ISO 697: 1992), Cht lng nc. o tng phng x beta trong nc
khng mn.
TCVN 6200: 1996 (ISO 9174: 1990), Cht lng nc. Xc nh sunfat. Phng php trng
lng s dng bari clorua.
TCVN 6222: 1996 (ISO 9174: 1990), Cht lng nc. Xc nh crom tng. Phng php trc
ph hp th nguyn t.
TCVN 6635: 2000 (ISO 9390: 1990), Cht lng nc. Xc nh borat. Phng php o ph
dng azometin-H.
TCVN 6657: 2000 (ISO 12020: 1990), Cht lng nc. Xc nh nhm. Phng php o ph
hp th nguyn t.
TCVN 7087: 2002 [CODEX STAN 1- 1985 (Rev.1 - 1991, Amd. 1999 & 2001)], Ghi nhn thc
phm bao gi sn.
ISO 8360/2: 1988, Water quality - Detection an enumeration of Pseudomonas aeruginosa - Part
2: Membrane fitration method (Cht lng nc - Pht hin v m pseudomonas aeruginosa -
Phn 2: Phng php mng lc).
AOAC 920.201, Barium in water. Gravimetric method (Bari trong nc. Phng php khi
lng).
AOAC 960.40, Copper in foods. Colorimetric method (ng trong thc phm. Phng php so
mu).
AOAC 964.16, Antimony in foods. Spectrophotometric method (Atimon trong thc phm. Phng
php quang ph).
AOAC 973.30, Polycyclic aromatic hydrocarbons and Benzo[a] pyrenne in food.
Spectrophotometric method (Hydro cacbon thm a vng v benzo[a] pyren trong thc phm.
Phng php quang ph).
AOAC 973.41, pH of Water (pH ca nc).
AOAC 974.27, Cadmium, chromium, copper, iron, lead, magnesium, manganese, silver, zinc in
water - Atomic absorption spectrophotometric method (Cadimi, crom, ng, st, ch, mangan,
bc, km trong nc. Phng php quang ph hp th nguyn t).
AOAC 977.22, Mercury in water - Flameless atomic absorption spectrophotometric method (Thu
ngn trong nc. Phng php quang ph hp th nguyn t khng ngn la).
AOAC 986.15, Asenic, cadmium, lead, selenium and zinc in human and pet foods (Asen, cadimi,
ch, selen v km trong thc phm v thc n chn nui).
AOAC 990.06, Organocholorine pesticides in water. Gas chromatograhic method (Thuc bo v
thc vt cha gc clo hu c trong nc. Phng php sc k kh).
AOAC 991.07, Nitrogen - and phosphorua - containing pesticides in finished drinking water. Gas
chromatographic method (Thuc bo v thc vt cha gc nit v gc phospho trong nc
ung. Phng php sc k kh).
AOAC 992.14, Pesticides in water. Liquid chromatographic method with ultraviolet detector
(Thuc bo v thc vt trong nc. Phng php sc k kh lng vi u d tia cc tm).
APHA 2120, Color (Xc nh mu sc).
APHA 3111, Metals by flame atomic absorption spectrometry (Xc nh kim loi bng quang ph
hp th nguyn t ngn la)
APHA 3112, Metals by cold-vapor atomic absorption spectrometry (Xc nh kim loi bng quang
ph hp th nguyn t hi lnh).
APHA 3113, Metals by electrothermal atomic absorption spectrometry (Xc nh kim loi bng
quang ph hp th nguyn t nhit in).
APHA 3114, Arsenic and selenium by hydride generation/ atomic absorption spectrometry (Xc
nh asen v selen bng quang ph hp th nguyn t/ to hidrua).
APHA 4110, Determination of anions by ion chromatography (Xc nh cc anion bng sc k
ion).
APHA 4500-Cl_, Chloride (Xc nh clorua).
APHA 4500-F_, Fluoride (Xc nh florua).
APHA 4500-B, Boron (Xc nh Bo).
APHA 4500-CN_, Cyanide (Xc nh xyanua).
APHA 4500-NH3, Ammonia (Xc nh amoniac).
APHA 6440, Polynuclear aromatic hydrocarbons (Xc nh hidrocacbon thm a vng).
ASTM D 3086-95, Standard test method for Organochlorine pesticides in water (Phng php
th chun v thuc bo v clo hu c).
EPA 507, Determination of nitrogen and phosphorus - containing pesticides in water by gas
chromatography with a nitrogen-phophorus detector (Xc nh thuc bo v thc vt cha gc
nit v phospho trong nc bng sc k kh c u d nit-phospho).
USEPA 7041A, Antimony. Atomic absorption, furnace technique (Antimon. Phng php hp th
nguyn t, k thut nung).
USEPA 7740A, Selenium. Atomic absorption, furnace technique (Selen. Phng php hp th
nguyn t, k thut nung).
NF T90-112, Dosage de dix lments mtalliques (Cr, Mn, Fe, Co, Ni, Cu, Zn, Ag, Cd, Pb) pas
spectromtrie d absorption atomique dans la flame - Mthodes de dosage directe et aprs
complexation et extraction.
NF T90-414, Essais des eaux - Recherche et denombrement des coliforms et des coliformes
thermotolerants - Method generale par ensemencement en milieu liquide (NPP).
NF Y90-416, Essais des eaux - Recherche et denombrement des streptocoques du groupe D -
Method generale par filtration sur membrane (NEQ ISO 7899/2).
NF T90-417, Essais des eaux - Recherche et denombrement des spores de bacteries anaerobies
sulfito - Reductrices de clostridium sulfito - Reducteurs - Method generale par filtration sur
membrane.
NF T90-421, Essais des eaux - Examens microbiologique des eaux de piscines.
Tiu chun v sinh nc n ung ban hnh km theo Quyt nh s 1329/2002/BYT-Q.
3. Thut ng v nh ngha
Trong tiu chun ny p dng cc thut ng v nh ng sau:
3.1. Nc ung ng chai (Bottled/packaged drinkingwater)
Nc ng chai c s dng ung trc tip v c th cha khong cht v cacbon dioxit
(CO2) t nhin hoc b sung nhng khng phi l nc khong thin nhin ng chia v c
cha ng, cc cht to ngt, cc cht to hng hoc bt k loi thc phm no khc.
4. Yu cu k thut
4.1. Ngun nc
Ngun nc s dng sn xut nc ung ng chai c quy nh bi c quan c thm
quyn.
4.2. X l
Nc ung ng chai c sn xut theo quy trnh cng ngh c quy nh bi cc c quan
c thm quyn.
4.3. Ch tiu cm quan i vi nc ung ng chai, c quy nh trong Bng 1.
Bng 1. Ch ti cm quan i vi nc ung ng chai
Tn ch tiu Yu cu
1. Mu sc, TCU, khng ln hn 15
2. c, NTU, khng ln hn 2
3. Mi, v Khng c mi, v l
4.4. Ch tiu ho - l ca nc ung ng chai, c quy nh trong Bng 2.
Bng 2. Ch tiu ho - l ca nc ung ng chai
Tn ch tiu Mc
1. pH 6,5 - 8,5
2.Tng cht rn ho tan, mg/l, khng ln hn 500
3. Clorua, mg/l, khng ln hn 250
4. Sunphat, mg/l tnh theo B, khng ln hn 250
5. Natri, mg/l, khng ln hn 200
6. Florua, mg/l, khng ln hn 1,5
7. Amoni, mg/l, khng ln hn 1,5
8. Km, mg/l, khng ln hn 3
9. Nitrat, mg/l, khng ln hn 50
10. Nitrit, mg/l, khng ln hn 0,02
11. ng, mg/l, khng ln hn 1
12.St, mg/l, khng ln hn 0,5
13. Nhm tng s, mg/l, khng ln hn 0,2
14. Mangan, mg/l, khng ln hn 0,5
15. Bari, mg/l, khng ln hn 0,7
16. Borat, mg/l, tnh theo B, khng ln hn 5
17. Crm, mg/l, khng ln hn 0,05
18. Asen, mg/l, khng ln hn 0,01
19. Thu ngn, mg/l, khng ln hn 0,001
20. Cadimi, mg/l, khng ln hn 0,003
 21. Xyanua, mg/l, khng ln hn 0,07
22. Niken, mg/l, khng ln hn 0,02
23. Ch, mg/l, khng ln hn 0,01
24. Selen, mg/l, khng ln hn 0,01
25. Antimon, mg/l, khng ln hn 0,005
26. Hydrocacbon thm a vng 1)
27. Mc nhim x:
- Tng phng x , Bq/l, khng ln hn 0,1
- Tng phng x , Bq/l, khng ln hn 1

1) Theo "Tiu chun v sinh nc n ung" ban hnh km theo Quyt nh s

1329/2002/BYT-Q

4.5. D lng thuc bo v thc vt trong nc khong thin nhin ng chai: Theo Tiu chun
v sinh nc n ung ban hnh km theo Quyt nh s 1329/2002/BYT-Q.
4.6. Ch tiu vi sinh vt i vi nc khong thin nhin ng chai
Trong qu trnh tiu th, nc khong thin nhin ng chai:
a) Phi m bo cht lng khng gy ri ro cho sc kho ngi tiu dng (khng c c cc
vi sinh vt gy bnh);
b) Ngoi ra phi tun th cc yu cu v vi sinh vt sau y:
Kim tra ln u Quyt nh
E.Coli hoc coliform chu nhit 1 x 250 ml Khng c pht hin trong bt k
mu no
Coliform tng s 1 x 250 ml Nu 1 hoc 2 th tin hnh kim
tra ln th hai
Streptococci feacal 1 x 250 ml
Pseudomonas aeruginosa 1 x 250 ml Nu > 2 th loi b
Bo t vi khun k kh kh sunphit 1 x 50 ml

Kim tra ln th hai

n c* m M
Coliform tng s 4 1 0 2
Streptococci feacal 4 1 0 2
Bo t vi khun k kh kh sunphit 4 1 0 2
Pseudomonas aeruginosa 4 1 0 2
Kim tra ln th hai c thc hin s dng cng th tch nh dng kim tra ln u.
n: s n v mu ly t l hng kim tra
c: s lng mu ti a c th chp nhn hoc s lng n v mu ti a cho php vt qu
chun m v vi sinh vt. Nu vt qu s ny th l hng c coi l khng t.
m: l s lng ti a hoc mc ti a ca vi khun tng ng/g; cc gi tr trn mc ny c th
c chp nhn hoc khng c chp nhn.
M: l lng thc phm c chp nhn trong s thc phm khng c chp nhn. Gi tr bng
M hoc ln hn M trong bt k mu no u khng c chp nhn v nh hng ti sc kho
con ngi.
5. Phng php th
5.1. Ly mu, theo TCVN 2652-78.
5.2. Xc nh mu sc, theo TCVN 6185;1996 (ISO 7887:1985) hoc APHA 2120.
5.3. Xc nh c, theo TCVN 6184: 1996 (ISO 7027: 1990) hoc APHA 2120.
5.4. Xc nh mi, v, theo TCVN 2653 - 78.
5.5. Xc nh pH, theo TCVN 4559: 1988 hoc AOAC 973.41.
5.6. Xc nh hm lng clorua, theo TCVN 6194: 1996 (ISO 9297:1989) hoc APHA 4500-Cl_
5.7. Xc nh hm lng sunfat, theo TCVN 6200:1996 (ISO 9280: 1990)
5.8. Xc nh hm lng natri, theo TCVN 6196-3: 2000 (ISO 964/3; 1993) hoc APHA 3111.
5.9. Xc nh hm lng nhm, theo TCVN 6657: 2000 (ISO 12020: 1997)
5.10. Xc nh hm lng bari, theo AOAC 920.201 hoc APHA 3114.
5.11. Xc nh hm lng tng cht rn ho tan, theo ph lc A ca TCVN 6053: 1995 (ISO
9696: 1992) hoc TCVN 4560: 1988.
5.12. Xc nh hm lng nitrat, theo TCVN 6180: 1995 (ISO 7890/3: 1998) hoc APHA 4110.
5.13. Xc nh hm lng nitrit, theo TCVN 6178: 1996 (ISO 6777:1984).
5.14. Xc nh hm lng ng, theo TCVN 6193: 1996 (ISO 8288: 1996) hoc AOAC 960.40
hoc APHA 3111.
5.15. Xc nh hm lng km, theo TCVN 6193: 1996 (ISO 8288: 1996) hoc APHA 3111.
5.16. Xc nh hm lng st, theo TCVN 6177: 1996 (ISO 6332: 1988 hoc APHA 3111.
5.17. Xc nh hm lng florua, theo TCVN 6195: 1996 (ISO 10359/1: 1992) hoc APHA 4500 -
F_.
5.18. Xc nh hm lng mangan theo TCVN 6002: 1995 (ISO 6333: 1986) hoc APHA 3111
hoc NF T90-112.
5.19. Xc nh hm lng crom, theo TCVN 6222: 1996 (ISO 9174: 1990) hoc APHA 3111.
5.20. Xc inh hm lng asen, theo TAVN 6182: 1996 (ISO 6595: 1982) hoc AOAC 986.15
hoc APHA 3114.
5.21. Xc nh hm lng thy ngn, theo TCVN 5991: 1995 (ISO 5666/3: 1984) hoc AOAC
977.22 hoc APHA 3112.
5.22. Xc nh hm lng cadimi, theo TYCVN 6193: 1996 (ISO 8288: 1986) hoc AOAC 986.15
hoc AOAC 974.27 hoc APHA 3113.
5.23. Xc nh hm lng xyanua, theo TCVN 6181: 1996 (ISO 6703/1: 1984) hoc APHA 4500 -
CN_.
5.24. Xc nh hm lng niken, theo TCVN 6193: 1996 (ISO 8288: 1996) hoc APHA 3111.
5.25. Xc nh hm lng ch, theo TCVN 6193: 1996 (ISO 8288: 1996) hoc AOAC 974.27 hoc
APHA 3113.
5.26. Xc nh hm lng selen, theo TCVN 6183: 1996 (ISO 9965: 1993) hoc APHA 3114 hoc
USEPA 7740.
5.27. Xc nh hm lng borat, theo TCVN 6635: 2000 (ISO 9390: 1990) hoc APHA 4500 - B.
5.28. Xc nh hm lng antimon, theo AOAC 964.16 hoc APHA 3114 hoc USEPA 7041 A.
5.29. Xc nh hm lng amoni, theo TCVN 5988: 1995 (ISO 5664: 1984) hoc APHA 4500-
NH3.
5.30. Xc nh hm lng hydrocacbon thm a vng, theo AOAC 973.30 hoc APHA 6440.
5.32. Xc nh tng phng x anpha, theo TCVN 6053: 1995 (ISO 9696: 1992).
5.32. Xc nh tng phng x beta, theo TCVN 6219: 1995 (ISO 9697: 1992).
5.33. Xc nh d lng thuc bo v thc vt, theo AOAC 922.14 hoc AOAC 990.06 v AOAC
991.07 hoc ASTM D 3086 - 95 v EPA 507.
5.34. Xc nh E.Coli hoc Coliforms chu nhit, theo TCVN 6187 - 1: 1996 (ISO 9308/1: 1990).
5.35. Xc nh Coliforms, theo TCVN 6187-1: 1996 (ISO 9308/1:1990) hoc NF T90-414.
5.36. Xc nh Streptococci feacal, theo TCVN 6189-2: 1996 (ISO 7899/2:1984) hoc NF T90-
416.
5.37. Xc nh Pseudomonas aeruginosa, theo ISO 8360/2: 1988 hoc NF T90-421.
5.38. Xc nh vi khun k kh kh sunphit, theo TCVN 6191-2:1996 (ISO 6461/2: 1986) hoc NF
T90-417.
6. ng gi, ghi nhn, bo qun, vn chuyn
6.1. ng gi
6.1.1. Nc ung c ng trong cc chai, bnh chuyn dng cho thc phm, m bo yu cu
v sinh.
6.1.2. Nc ung c ng trong cc chai, bnh c dung tch thch hp, kn, khng b r r bt
c t th no, khng lm thay i hoc nh hng n cht lng ca nc khong thin nhin
trong qu trnh bo qun v vn chuyn.
6.2. Ghi nhn
Vic ghi nhn i vi nc ung ng chai phi thc hin theo TCVN 7087: 2002 [CODEX STAN
1-1985 (Rew.1 - 1991, Amd. 1999 & 2001)] Ghi nhn thc phm bao gi sn v b sung cc ni
dung sau y:
- Tn gi ca sn phm l "Nc ung " kt hp vi tn gi thng mi hoc a danh ca
ngun nc.
- Pha di tn gi phi ghi r cc bin php x l p dng.
6.3. Bo qun
Nc ung ng chai c bo qun iu kin bnh thng. Trnh nh nng trc tip ca mt
tri.
6.4. Vn chuyn
Nc ung ng chai c vn chuyn bng cc phng tin vn chuyn kh, sch, c mui che
trnh c ma nng, khng lm nh hng n cht lng sn phm./.