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Trial Chemistry Sem 3
Trial Chemistry Sem 3
Name : . Form :
SUMMATIVE ASSESSMENT
THIRD TERM
STPM
2013
CHEMISTRY
SECTION A [ 15 marks ]
Four suggested answers labelled A, B, C and D are given for each question.
Choose one correct answer.
1 A compound with the molecular formula CH3CH(NH2)COOH exists in two shapes. What is
it called?
A Isotopes.
B Cis trans isomers.
C Optical isomers.
D Structural isomers.
CH2OH OH
A Bromine water
B Carbon dioxide
C Ethanoyl chloride
D Diluted hydrochloric acid
3 Which reaction shows the propagation step during the reaction between methane and
chlorine in the presence of light?
A H + Cl2 HCl + Cl
B CH4 + Cl+ CH3Cl + H+
C CH4 + Cl+ CH3+ + HCl
D CH4 + Cl CH3 + HCl
3
CH2Br
H3C
D
COCH3
B C
5 Which one of the followings will be produced through the reaction between phenol and
chlorine solution?
A CH3
B
OCl
C
OH
Cl
D
OH
Cl
Cl
Cl
4
| |
6 Which compound can change the C = O group in propanone to C Cl ?
| |
A Chlorine gas
B Phosphorous (V) chloride
C Sodium chloride
D Dilute hydrochloric acid
7 One component of beeswax, which is used as a car polish, has the formula
CH3(CH2)24COO(CH2)29CH3. What are the products of the acidic hydrolysis of this
component?
O O
|| ||
H2N CH C NH CH C OCH3
| |
CH2 CH2
| |
COOH
C
6
D
A 1
B 1,2
C 2,3
D 1,2,3
12 What are the compounds produced when butan-2-ol is refluxed with acidified potassium
manganate(VII) solution?
1 Butanone
2 Butanoic acid
3 Butanol
A 1
B 1,2
C 2,3
D 1,2,3
13 What is the type of reaction that will occur to the compound below?
CH3
CO CH3
CH = CHCH3
1 Electrophilic addition
2 Nucleophilic addition
3 Electrophilic substitution
7
A 1
B 1,2
C 2,3
D 1,2,3
A 1
B 1,2
C 2,3
D 1,2,3
15 There are saturated and unsaturated polymers. Which polymer(s) decolourise(s) an acidified
solution of potassium manganate( VII)?
1 Poly(2-methylbuta-1 ,3-diene)
2 Poly(ethene).
3 Poly(phenylethene)
A 1
B 1,2
C 2,3
D 1,2,3
8
16 (a) Draw the structure of the major product of each of the following reactions.
Ethanol
(i) -Br + NH3
(i) CH3CH2MgBr
(iii) -CHO (ii) H3O+
[3 Marks]
HO CH2CHCH3
OH
Draw the structural formula of the organic product(s) formed when the compound
reacts with each of the following reagents:
[1 mark]
(ii) Write a balance equation for the reaction the reaction taking place.
[2 marks]
(ii) State the types of polyrnerisation involved in the formation of polymers X and Y.
Polymer X:
Polymer Y:
[2 marks]
10
18 (a) Identify the type of isomerism shown by 2-butanol and butenedioic acid.
Explain why these compounds exhibit isomerism. Draw the pair of isomers for
each compound.
[6 Marks]
19 (a) (i) Write the mechanism of the reaction when 1-chloropropane is refluxed with
aqueous sodium hydroxide. Name the type of reaction involved.
[3 marks]
(ii) State and explain how the rate of this reaction changes when
1-chloropropane is replaced by 1-bromopropane.
[3 marks]
(iii) Write the equations to show how you would change 1-chloropropane to
2-chloropropane.
[5 marks]
(b) Catalytic cracking is a process where long chained alkanes are broken into mixture
of short chained molecules.