Scribd Logo
Upload

Welcome to Scribd!

  • 30 views

    Formation Constants of Complex Ions

    Uploaded by

    IuliaHort
    This document lists the formation constants (Kf) of various complex ions at 25°C, organized into categories of halide complexes, ammonia complexes, cyanide complexes, complexes with other monodentate ligands, and complexes with bidentate ligands. The complex ions range from simple halide complexes like [AlF6]3- to more complex ligands binding multiple atoms like [Co(en)3]3+. The values provided are equilibrium constants that represent the strength of binding between metal cations and ligands in complex ion formations.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content

    You might also like

    Formation Constants of Complex Ions

    Uploaded by

    IuliaHort
    30 views1 page
    This document lists the formation constants (Kf) of various complex ions at 25°C, organized into categories of halide complexes, ammonia complexes, cyanide complexes, complexes with other monodentate ligands, and complexes with bidentate ligands. The complex ions range from simple halide complexes like [AlF6]3- to more complex ligands binding multiple atoms like [Co(en)3]3+. The values provided are equilibrium constants that represent the strength of binding between metal cations and ligands in complex ion formations.

    Original Description:

    complex ions

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    This document lists the formation constants (Kf) of various complex ions at 25°C, organized into categories of halide complexes, ammonia complexes, cyanide complexes, complexes with other monodentate ligands, and complexes with bidentate ligands. The complex ions range from simple halide complexes like [AlF6]3- to more complex ligands binding multiple atoms like [Co(en)3]3+. The values provided are equilibrium constants that represent the strength of binding between metal cations and ligands in complex ion formations.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as pdf or txt
    30 views1 page

    Formation Constants of Complex Ions

    Uploaded by

    IuliaHort
    This document lists the formation constants (Kf) of various complex ions at 25°C, organized into categories of halide complexes, ammonia complexes, cyanide complexes, complexes with other monodentate ligands, and complexes with bidentate ligands. The complex ions range from simple halide complexes like [AlF6]3- to more complex ligands binding multiple atoms like [Co(en)3]3+. The values provided are equilibrium constants that represent the strength of binding between metal cations and ligands in complex ion formations.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as pdf or txt
    of 1

    Formation Constants of Complex Ions at 25 C

    Complex Ion Equilibrium Kf


    Halide complexes
    [AlF 6 ]3- 2.5104
    [AlF 4 ] 1-
    2.0108
    [BeF 4 ] 2-
    1.31013
    [SnF 6 ]2- 11025
    [CuCl 2 ] 1-
    3105
    [AgCl 2 ] 1-
    1.8105
    [PbCl 4 ] 2-
    2.51015
    [HgCl 4 ]2- 5.01015
    [CuBr 2 ] 1-
    8.0105
    [AgBr 2 ] 1-
    11011
    [HgBr 4 ] 2-
    3104
    [CuI 2 ]1- 8108
    [AgI 2 ] 1-
    11011
    [PbI 4 ] 2-
    3104
    [HgI 4 ] 2-
    1.91030
    Ammonia complexes
    [Ag(NH 3 ) 2 ]1+ 1.6107
    [Zn(NH 3 ) 4 ] 2+
    7.8108
    [Cu(NH 3 ) 4 ] 2+
    1.11013
    [Hg(NH 3 ) 4 ] 2+
    1.81019
    [Co(NH 3 ) 6 ]2+ 5.0104
    [Co(NH 3 ) 6 ] 3+
    4.61033
    [Cd(NH 3 ) 6 ] 2+
    2.6105
    [Cd(NH 3 ) 4 ] 2+
    1.0107
    [Ni(NH 3 ) 6 ]2+ 2108
    Cyanide complexes
    [Fe(CN) 6 ]4- 1.01035
    [Fe(CN) 6 ] 3-
    9.11041
    [Ag(CN) 2 ] 1-
    5.31018
    [Cu(CN) 2 ]1- 1.01016
    [Cd(CN) 4 ] 2-
    7.71016
    [Au(CN) 2 ] 1-
    21038
    [Ni(CN) 4 ] 2-
    11031
    Complexes with other monodentate ligands
    [Ag(CH 3 NH 2 ) 2 ]1+ 7.8106
    [Ag(S 2 O 3 ) 2 ] 3-
    2.91013
    [Cd(SCN) 4 ] 2-
    1103
    [Cu(SCN) 2 ] 5.6103
    [Fe(SCN) 3 ] 2106
    [Hg(SCN) 4 ]2- 5.01021
    [Cu(OH) 4 ] 2-
    1.31016
    [Zn(OH) 4 ] 2-
    2.81015
    Complexes with bidentate ligands (en = ethylenediamine )
    [Mn(en) 3 ]2+ 6.5105
    [Fe(en) 3 ] 2+
    5.2109
    [Co(en) 3 ] 2+
    1.31014
    [Co(en) 3 ] 3+
    4.81048
    [Ni(en) 3 ]2+ 4.11017
    [Cu(en) 2 ] 2+
    3.51019
    [Co(C 2 O 4 ) 3 ] 4-
    4.5106
    [Fe(C 2 O 4 ) 3 ] 3-
    3.31020

    You might also like