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States If the concentrations of all the substances present at equilibrium are raised to the
power of the number of moles they appear in the equation, the product of the
concentrations of the products divided by the product of the concentrations of the
reactants is a constant, provided the temperature remains constant ... WOW!
The partial pressure expression can be used for reactions involving gases
[A]a . [B]b
Q.3 Write expressions for the equilibrium constant, Kc of the following reactions.
Remember, equilibrium constants can have units.
Calculating
value of Kc construct the balanced equation, including state symbols (aq), (g) etc.
determine the number of moles of each species at equilibrium
divide moles by volume (dm3) to get the equilibrium concentrations in mol dm-3
Knockhardy Publishing
(If no volume is quoted, use a V; it will probably cancel out)
from the equation constructed in the first step, write out an expression for Kc.
substitute values from third step and calculate the value of Kc with any units
Example 1 Ethanoic acid (1 mol) reacts with ethanol (1 mol) at 298K. When equilibrium is
reached, two thirds of the acid has reacted. Calculate the value of Kc.
initial moles 1 1 0 0
equilibrium concs. 1/ /V 1/ /V 2/ /V 2/ /V
3 3 3 3
1 mol of P and 1 mol of Q are mixed. Once equilibrium has been achieved, 0.6 mol
of P are present. How many moles of Q, R and S are present at equilibrium ?
P + 2Q R + S
Initial moles 1 1 0 0
At equilibrium 06 02 04 04
(04 reacted) (2 x 04 reacted) (get 1 R and 1 S for every P that reacts)
1- 06 remain 1- 08 remain
Explanation if 0.6 moles of P remain of the original 1 mole, 0.4 moles have reacted
the equation states that 2 moles of Q react with every 1 mole of P
this means that 0.8 (2 x 0.4) moles of Q have reacted, leaving 0.2 moles
one mole of R and S are produced from every mole of P that reacts
this means 0.4 moles of R and 0.4 moles of S are present at equilibrium
Knockhardy Publishing
(a) If the original number of moles of A and B are both 1 and 0.4 moles of A are
present at equilibrium, how many moles of B, C and D are present?
(b) At a higher temperature, the original moles of A and B were 2 and 3 respectively.
If 1 mole of A is present at equilibrium, how many moles of B, C and D are present?
What else does this tell you about the reaction?
Knockhardy Publishing
then (at constant temperature) PCc = a constant, ( Kp )
PAa x PBb
Q.5 Write expressions for the equilibrium constant, Kp of the following reactions.
Remember, equilibrium constants can have units. (assume the pressure is in MPa)
Example 1 A mixture of 16g of O2 and 42g of N2 , exerts a total pressure of 20000 Nm-2.
What is the partial pressure of each gas ?
Example 2 Nitrogen (1 mol) and hydrogen (3 mol) react at constant temperature at a pressure of
1MPa. At equilibrium, half the nitrogen has reacted. Calculate Kp .
initial moles 1 3 0
at equilibrium 1 - 0.5 = 0.5 mol 3 - 1.5 = 1.5 mol 2 x 0.5 = 1 mol
Knockhardy Publishing
Example 3 0.102g of solid ammonium sulphide is heated in a closed container at 100C until
equilibrium is reached at a pressure of 0.1MPa. It is found that 75% of the ammonium
sulphide has dissociated. Calculate the equilibrium constant Kp for the reaction at 100C.