M-S-O System

Oksidasi Mn => 3Mn(s) + 2O (g) = MnO (s)

3Mn(s) + 2O (g) = MnO

MnO
G = G + RT In Mn.O

1
= G + RT In PO

= G + 2RT In PO
Setimbang => G=0

G = GMnO - 3GMn - 2GO

2RT In PO = G

G
PO = Exp [ ]
2RT

1
Sulfidasi Mn => Mn(s) + S(g) = MnS (s)
2

1
Mn(s) + S(g) = MnS (s)
2

MnS
G = G + RT In Mn.S

1
= G + RT In PS

1
= G + RT In PS
2

Setimbang => G=0

1
G = GMnS - GMn - GS
2

1
RT In PS = G
2

2G
PS = Exp [ ]
RT
 3
3MnS (s) + 2O (g) = MnO (s) + S(g)
2

MnO . S
G = G + RT In
MnS3 . O

PS
= G + RT In
PO

= G + RT [ ]
3
= G - 2 RT ln PO + RT Ln PS
2

Setimbang => G=0

G = G - 3G
3
= G - 3G - 2 RT ln PO + RT Ln PS
2

PO
G - 3G = RT Ln
PS

G 3G PO
= Ln
RT PS

PO G 3G
= Exp [ ]
PS RT