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D is k r im in ie r u n g v o n G a s e n m it d n n e n m ik r o p o r s e n
P o ly m e r film e n z u r S te ig e r u n g d e r S e le k tiv it t v o n S e n s o r a r r a y s
G e o r g B e lg e , C a r m e n B e ts c h , F r a n k D ie te r le , G n te r G a u g litz
In s titu t f r P h y s ik a lis c h e u n d T h e o r e tis c h e C h e m ie , A u f d e r M o r g e n s te lle 8 , D - 7 2 0 7 6 T b in g e n , F .R .G

M o tiv a tio n M e s s p r in z ip ie n
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B e r e ic h d e r U m w e lt- u n d P r o z e a n a ly tik z u n e h m e n d a n
B e d e u tu n g . S e it l n g e r e m m a c h t m a n s ic h d ie
R IfS - R e fle k to m e tr is c h e In te r fe r n z s p e k tr o s k o p ie
G a s p e r m e a b ilit t z u r T r e n n u n g v o n G a s e n z u N u tz e n .
D a s e in g e s e tz te m ik r o p o r s e P o ly m e r ( U ltr a s o n 2 0 1 0 ) S p e k tr o m e te r
z e ig t d u r c h K o n tr o lle d e r A n a ly tb e w e g u n g e n in d e r L ic h tq u e lle A u s w e r tu n g d e r R IfS - M e s s u n g e n
M a tr ix S e le k tiv it t a ls c h e m is c h e r S e n s o r z u r
D is k r im in ie r u n g v o n v o la t ile o r g a n ic c o m p o u n d s
K o n tin u ie r lic h e M e s s u n g d e s
( V O C s ) , d .h . d a s h ie r v e r w e n d e te P o ly m e r z e ig t
P r o d u k te s a u s S c h ic h td ic k e d u n d
M o le k u la r s ie b e ig e n s c h a fte n , w e lc h e d ie F a s e r k o p p le r B r e c h u n g s in d e x n o p tis c h e r
D is k r im in ie r u n g s f h ig k e ite n e n o r m s te ig e r n . U m d e n
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m a n d ie T e ilc h e n g r e d e s A n a ly t e n , d e n n je g r e r Q u e llu n g v o n P o ly m e r e n
d a s p o te n tie lle A n a ly t m o le k l, d e s t o s t r k e r w ir d s e n s itiv e
d e s s e n S o r p tio n a u fg r u n d d e r P o r e n g r e n v e r te ilu n g M e z e lle S c h ic h t
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P o ly m e r e A n a ly te D is k r im in ie r u n g d e r G a s e
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R 1 3 4 a
r e l. S ig n a l [1 e - 3 ]

r e l. S ig n a l [1 e - 3 ]

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K o n z e n tr a tio n [V o l.-% ]
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M u ltiv a r ia te D a te n a n a ly s e d e r A n a ly tg e m is c h e Z u s a m m e n fa s s u n g
S ta n d a r d is ie r u n g d e r S e n s o r s ig n a le D e r K a lib r a tio n s d a te n s a tz b e s ta n d a u s 1 0 8 M e s s u n g e n v o n 3 6 D ie z e it a u fg e l s te n M e s s u n g e n e r la u b e n e in e
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D e r T e s td a te n s a tz b e s ta n d a u s 3 6 G e m is c h e n u n d w a r u n a b h n g ig v o n
A k tiv ie r u n g s fu n k tio n e n d e r U n its : ta n h d e m K a lib r a tio n s d a te n s a tz Z e it a u fg e l s te M e s s u n g e n e r m g lic h e n d a s
E in s t e lle n d e r R e v e r s ib ilt t d e r s e n s it iv e n
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1 0 1 0
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[ V o l. - % ]

[V o l.- % ]

z u k le in e re n K o n z e n tra t io n e n w e r d e n in
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W a h r e K o n z e n tr a tio n [V o l.- % ] W a h r e K o n z e n tr a t io n [V o l.- % ] U n iv e r s it t
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