Sol1 2

1
AITS-CRT-III-(Paper-1)-PCM (Sol)-JEE(Advanced)/17
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ANSWERS, HINTS & SOLUTIONS

CONCEPT RECAPITULATION TEST III
Integrated School Program & 4423 Students from All Programs have qualified in JEE Advanced, 2016
(Paper1)
ALL INDIA TEST SERIES
Q. No. PHYSICS CHEMISTRY MATHEMATICS
1. BCD ABCD C
2. A ABD D
3. CD AC BD
4. BD ABC AD
5. C A BC
6. D AB AC
7. A ABCD BCD
8. C ABC ACD
9. D AC B
10. AC BCD B
1. 7 3 3
2. 8 4 8
3. 5 3 2
4. 2 9 2
5. 6 6 3
6. 6 9 7
7. 2 5 2
8. 6 3 6
9. 4 2 1
10. 7 5 4
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2
Physics PART I
SECTION A
1. BCD

Thermal resistance of each section R
KA
B C
O
A D
F E
4R
Req
5
B 2R/3 C
R R
R R
A O D
R R
F 2R/3 E
T TP
Hence P A 5
4R
4 P
TD TA
5 KA
Heat current through
P 2R P 3 2 3P
ABCD & AFED =
4R 10 5
2R
2
8R/3
A D
2R
8R/3
4R/3
A 2R D
2P
AOD
5
2P
Temperature drop across AO = R TA T0
5
2P
To TA
5KA
3
2. A
T R3 GM
Time for B to move from B to centre of tunnel is T 2
4 GM R3
Time to move from A to given point is
3R/4 BR/4
O
A
1 1 R 1 3R T
sin sin
A 4 A 4
R 3R
sin1 sin1
A
4A 2
From above
R 3R 9R 2
sin1 cos 1 sin1 1
A 4A
16 A 2

R 9R 2
1
A 16
R2 9R 2 25 R 2
1 1
A2 16 A2 16 A2
5
A R
4
Hence
25R 2 16R 2
V A2 R 2
4
3 3 GM
R
4 4 R
3. CD
Since fractional volume
Vin body

Vbody liquid
Vinf . 1 L T
Bf Bi
Vbody ef 1 B T i
1 L T
xf x i
1 B T
with fall in temperature
xf xi for B 3 B L
4. BD
4
5. C
hc hc
K .Emax
T
hc hc
Ed
T
1
1 eEd
T
hc
6. D
4C
2C
C
2C
4C
Initial
Q in = 3 CV
Final
Q f = 10 CV
7. A
S1
r sin

r sin

2
A B

r sin
2

A=r r sin
SB = b
S2
screen
d S1S2 22r sin .cos 2r sin 2
D = distance between source and screen
b 2r sin2
Hence
Fringe width =

b 2r sin2
2r sin 2
5
8. C
RC
It do not depends on charge on capacitor
6R 6C 36RC
.
11 11 121
9. D
2
V 2 2
N m g
R
2
V 2 2
maT m g
R
2
dv V 2 2
V g
ds R
RVdv
K ds
V 4 R 2g 2
Replacing Z 2 V 4 R 2 g 2
R dz
2 K ds
2 2
z Rg
Replacing z Rg sec
2 K
ln sec tan ds
R
2 K

ln sec sec 2 1
R
s
z z 2 R 2 g 2 2
K
ln s
Rg R

0
V 4 R 2g 2 V 2 2 K
ln S s0
Rg R
V0
10. AC
V L
dI
B V L
dt
B dx LdI
B x LI
B x
I
L
6
SECTION C
1. 7
df r

Let we consider a ring of radius r and thickness dr.
= mass per unit area.
Mass of shaded part rd dr
Friction 1 rd dr
Net horizontal force along x-axis is 0
dfy 1 rd drg cos
/2
1 g rdr cos d
/2
R
21 g rdr 21 g. right half ve y
2
Left part
R
Fy 22 g ve y
2
0.78 0.67 .M
Fnet 1 2 gR 2 .g.R
R
0.11 10 7
a 7 ms 2
22 20
2. 8
V
2V A
V C
B
T
T 2T 4T
AB TV = constant = K1
PV2 = K1 nR
AC TV2 = constant = K2
Pmin at A and maximum C
PB = 4PA and PC = 2PB
P
Hence C 8
PK
3. 5
7
Initial
Let A = cross section area
Net force after x displacement
2 Ax Hg .g m1a
2 A Hg .g
12
m1
water
mercury
Final
Net force after displacement will be
2 Ax Hg .g m1 m2 a
2 A Hg .g
22
m1 m2
1 m1 m2 T1

2 m1 T2
m1 80 m
4. 2
In case of +ve direction proceeding of wave.
Q
P
3
A
A/2 2
x O P Q
In this case PQ will be horizontal if P and Q have same position propagating in opposite direction
it will be in left half at position x.
T T 1 x
For P cos1
12 4 A
T T 1 x
For Q sin1
12 4 A
8
Equating these two

A
x
2
11T
Hence t1
24
In case of propagating ve x direction.
For PQ to be horizontal it will be positon i.e. right half.

1 x T 1 x T
sin1 cos1
A 12 A 12
for P for Q
A T
x hence t 2
2 24
T1
11
T2
5. 6
-1
2 ms
-1
2 ms
Retardation of plank = 4 ms-2 and retardation of block = 1.0 ms-2
Hence relative acceleration of block w.r.t. plank = 3 ms
Skidding distance up to this time
1 1 3
3 m
2 4 8
1 3
Plank is in rest now and block has velocity = 2 1 ms 1
2 2
u2 9
Skidding distance = m.
2.a 8
12
Total skidding distance = m 1.5 m
8
6. 6
E d x i E0 i
Net flux due to Ey = 0
Flux through left most surface is ve and acceleration
Flux through inclined surface
y
a
x
z b
9
c.2 sin .cos

d cos cd .sin dc sin . 2
c.a.b
dc.a
2
a.b.c
Net = 6
2
7. 2
Path difference before slits = path difference after slits.
8. 6
9. 4
e.m.f of rod at any instant
i B v
d
B vc I Bca
dt
Hence net force
2Kx B 2 2ca ma
2Kx m B 2 2 c
a T 2
B c m
2 2 2K
10. 7
Heat lost = heat gained
mi si 0 i m L m s 0 .
10
Chemistry PART II
SECTION A
1. ABCD
H
- + - + -
N N N N N N
Azide ion Hydrazoic acid
2. ABD
rate law equation is
rate = K H HNO2 Br
3. AC
Correct order is
F > N > O > C > Be > B
B > Tl > Ga > Al > In
4. ABC
Facts
5. A
[NiCl4]2- = tetrahedral, sp3 hybridized so there are two odd e-s in t2g orbitals
[Ni(CO)4] = tetrahedral with sp3 hybridization, no electrons unpaired
6. AB
O H3C O
HCl
2
H3C
C
CH3
C CH C CH3 + H2O
H3C
mesilyl oxide
C
H3C CH3 , HCl
- H2O
H3C O CH3
C CH C CH C
H3C CH3
phorone
7. ABCD
Facts
8. ABC
11
N2O3 +
H3C CH2 CH2 NH2 H3C CH2 CH2 N2
+
H3C CH2 CH2 + N2
-
OH
H3C CH2 CH2 OH H3C CH CH3 H3C CH CH2

OH
9. AC
O C H
In NO 2 the carbonyl carbon is more e- deficient hence OH- attacks over it.
10. BCD
O
I2, NaOH
C CH3
COO Na
- +
+ CHI 3
yellow ppt.
(A)
OH
- |
HCN, OH PH C| CH3
CN
O B
- + optically active
C CH3 (i - Pr)2 N Li
O O
|| ||
Et Br
Ph C CH2
Ph C CH2 CH2 CH3
C
Ph - CHO O
||
NaOH Ph C CH CH Ph
D
SECTION C
1. 3
Oxymercuration demercuration doesnt allow rearrangement.
2. 4
(I), (II), (III) & (V) give aromatic species.
12
3. 3
M3 SCN MSCN2

[MSCN ] = 1.5 103 M 1.0 10 5 M 1.49 10 3 M
2+

So, free [M3+] = 2.0 10 3 M 1.49 103 M
-3
= 0.51 10 M
MSCN2
1.49 10 3
K 2.92 10 5 3.0 105
M3 SCN

3
0.51 10 1.0 10 5

4. 9
Mass of 25 protons = 25(1.00783 u) = 25.19575 u
And mass of 30 neutrons = 30(1.00867 u) = 30.2601
Total mass = 55.45585 u
Given mass = 54.9244 u
Mass defect = 55.45585 u 54.9244 u = 0.53145 u
binding energy = 0.53145 u 931.5 MeV / u 495.045675 MeV

BE 495.045675
9 MeV
Nucleon 55 nucleons
5. 6
MnO2, Co3O4, Ni2O3, CoS, HgS, Bi2S3 (blackish brown)
6. 9
2

Fe 3 2H2O
Fe OH H3O
Fe OH 2 H O 0.05 H O
Ka 3 3
3 0.95
Fe

0.05 H 3O
or 5.26 107
0.95
5
H3O 10 , pH 5, pOH 9
7. 5
All Ca containing compounds impart brick red colouration to the flame . Except carnallite, alum &
rock salt all other are Ca containing compounds.
8. 3
(HPO 3)3 O OH
P
O O
HO OH
P P
O O O
13
9. 2
Two stereoisomers are formed.
10. 5
Br Br
Et CH3
Me Me
, ,
H H
H H
I I
CH3CH C C C CHC2 H5 , trans-cyclooctene are chiral.
14
Mathematics PART III

SECTION A
1. C
2n 2
k n n Ck n
2
k n1
Replace k n k
n n
k n!
k n Ck k! n k !
k 1 k 1
n n n 1 !

k 1! n k !
k 1
n 1!
n
k 1 ! n k !
n 2 n1 2
k 2 n Ck n2 n 1
Ck
k 1 k 0
n
2 2n2
Cn1
2. D
k n k
n 1 1
Ck
2 2
Probability having exactly k male tigers
k nk
1 1
Pn n Ck n k
2 2
k nk
nn 1 1
So required probability P Ck
2 2
n k
k
2 P

2P 2P
3. BD
n 2
adj adjA A A
2
n1
adj adjA A
n 2 n 1
so adj adj adjA A adjA
3
n 1
adj adj adj A A
3
n1
A
4. AD
x 12 y 2 2 P2 5
Shifted to (1, 2)
2 2
Let a = P + 5
Equation of line MN is y + x = k
15

= mOA =

k
AB = a
a
A ( )
d O d
M B N
BM2 OM2 OB 2
k2
a2
a2
2 2 2
AM AB BM
2
k k2
d a a2 2
2
d d
d2 2a2 2k
5. BC
Shift to (2, 1)
P acos , b sin
S' S
In PSS
SS 2ae, SP a aecos , SP a aecos
eb sin
h aecos & k
e 1
So locus of incentres
x2 y2
1
a2 e2 be 2

e 1
2e
And its eccentricity =
e 1
6. AC
ex e
f x f 1 x x
x
1
e e e e
So f 2(x) + f 2(1 x) = 1
16
2n 1
r 1 2 2n 1
2fe 2n 2 fe 2n fe 2n ....fe 2n

r 1
1
2 n 1 fe
2
1
2 n 1
2
2n 1
1996
r 1 1996 2 1995 998 999
g 1997 g 1997 g 1997 g 1997 g 1997 ..... g 1997 g 1997
r 1
998
7. BCD
Use the property, foot of perpendicular from focus to tangent lies on the tangent at vertex. Using
this we get equation of tangent at vertex is 6y 4x + 1 = 0
8. ACD
ac
b a c 2b
2
Similary b + d > 2c
a + b + c + d > 2b + 2c
a+d>b+c
and GM HM
2ac
b
ac
ab bc 2ac
GM HM
1 1 2

d b c
1 1 1 1
Now
a d b c
Divide by abc, we get
ab cd 2 ac bd bc
Divide by abcd

2 c 1d1 a 1b1 2 b1d1 a 1c 1 a 1d1
9. B
x
a
x! an 1
x
lim .
x n! x n ! x n
1 a n
x

1 2 1 n
x 1 1 1 ... 1
n
a a x x x
lim 1
x n! x n
a
1
x
an ea 1 an .ea
lim
x n! 1n n!
17
10. B
Numbers of permutation with 2 in first position = 19!
For second position = 10 18!
19! 10 18! 10 9 17! ...10! 9!
Similarly = 0.1
20!
SECTION C
1. 3
a+c=b+d
D
c
C
d
b
A
a
B
2 2 2
a d BD
cos A
2ad
2 2 2
BD a d 2adcos A
and in BCD
2
b2 c 2 BD
cosC
2bc
2
BD b c 2 2bc cosC
2
BD 2 b2 c 2 2bc cos A
ad bc
Compare we get cos A
ad bc
aar 3 arar 2
0, A
a 2
r 3
r 2
2
2. 8
For n = 1 we get 16 triangle
For n = 2 we get 32 triangle
So for n total number of triangle is 16n
3. 2
In AEF
A
B E D F C
18
AE2 + AF2 = 2(AD2 + ED2)

2 2 2
AE + AF 2AD = 2
4. 2
Required volume = 2(volume generate by the revolution about y-axis of the area ALC)
A
L 4a
C
2a
2 x 2 dy
0
2a
y4
2 dy
0 16a2
4a3 1
and a
5 2

10
20
so . 2
10
5. 3
2 2
v1 a2 b 1 i aj a2 b 1 k
v 2 tan Ai tanBj tanCk
Let v1.v 2 3a
tan2 A 3 sec 2
so min tan2 A 3
6. 7
T S

U R

P Q
o
3 360
120o
19
9 36 FB 2
cos120
2 18
r 2 r 2 63
cos cos 120
2r 2
r 2 21
r 21
7. 2
1 x
2sin n x.sin
2 2
In dx
0
1 cos x

In In1 In 2 I0
In I0 I0 In
n
so n2
2
8. 6
x 2 y 2 z 1
L
a b c
a b c
2a b 6c 0 & 1 1 2 0
2 1 6
We get a : b : c 33 : 30 : 16
2a b 33 15
So 6
c c 8 8
9. 1
e x e x 3 5cosx 0
e x e x 5 cos x 3
So only one solution x = 0
10. 4
1 1
sin1 cos1
2 2 2

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ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICS

Equating these two

For PQ to be horizontal it will be positon i.e. right half.

c.2 sin .cos

H3C CH2 CH2 OH H3C CH CH3 H3C CH CH2

Mass defect = 55.45585 u 54.9244 u = 0.53145 u

binding energy = 0.53145 u 931.5 MeV / u 495.045675 MeV

Mathematics PART III

AE2 + AF2 = 2(AD2 + ED2)

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