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Burnham2017 Porosity and Permeability
Burnham2017 Porosity and Permeability
Burnham2017 Porosity and Permeability
Fuel
journal homepage: www.elsevier.com/locate/fuel
Porosity and permeability of Green River oil shale and their changes
during retorting
Alan K. Burnham
Consultant to Total Exploration and Production, United States
Energy Resources Engineering, 367 Panama St., Stanford University, Stanford, CA 94305, United States
h i g h l i g h t s g r a p h i c a l a b s t r a c t
a r t i c l e i n f o a b s t r a c t
Article history: Oil shales are organic-rich mudstones that generally have little porosity and permeability until kerogen is
Received 2 March 2017 transformed into oil and gas. A simple mathematical model is reported for how porosity and permeability
Received in revised form 19 April 2017 values for the Green River Formation change during retorting under confinement. Unlike when retorted
Accepted 26 April 2017
unconstrained, during which numerous fractures occur due to the limited tensile strength of retorted oil
shale and the permeability increases from micro or nano-Darcy levels to Darcy levels, fracture permeabil-
ity is minor when constrained by lithostatic loads typical of in-situ retorting, so permeabilities increase
Keywords:
only to the milli-Darcy level. The permeability increase is related to an increase in both porosity and pore
Green River oil shale
Porosity
diameter, and measured permeabilities are consistent with measurements and calculations of those
Permeability properties and inter-relationships developed for naturally matured petroleum source rocks.
Retorting 2017 Published by Elsevier Ltd.
Compaction
1. Introduction wanes every few decades as the price and perceived supply issues
for conventional crude oil rise and fall. More recently, production
Although oil shale retorting has been a source of small amounts of natural petroleum (oil and gas) from mature source rocks and
of shale oil for centuries and is important in certain localities, glo- adjacent or interbedded fine-grained yet more permeable layers
bal interest in oil shale as a potential source of shale oil waxes and has greatly increased the knowledge of porosity and permeability
of organic-rich fine-grained rocks. The combination of historical
and recent information gathered for oil shale processing and for
Address: Energy Resources Engineering, 367 Panama St., Stanford University, production of tight oil and shale gas purposes provides some more
Stanford, CA 94305, United States. general insights that can be useful for both applications, although
E-mail address: aburnham@stanford.edu
http://dx.doi.org/10.1016/j.fuel.2017.04.119
0016-2361/ 2017 Published by Elsevier Ltd.
A.K. Burnham / Fuel 203 (2017) 208213 209
the primary intended application for this work is to develop a new 0.3
algorithm for permeability as a function of grade and extent of BH1 850-950 ft (R8)
kerogen decomposition for modeling fluid flow during in-situ oil BH1 950-1150 ft (MZ)
shale processing. BH1 2136-2250 ft (R0-L0)
As in any field, measurement methodologies improve over time. 0.2
Consequently, historical information must be critically evaluated.
However, measurements from the 1960s and 1970s are still among
the best available for some conditions. The current paper attempts
to combine the best of the old literature with more recent mea- 0.1
surements to draw a more comprehensive picture of how porosity
and permeability evolve over the transformation of kerogen under
lithostatic load typical of in-situ retorting, which can be approxi-
Porosity
mated as constant volume. This information is used to develop 0.0
and validate a new, simple algorithm for how porosity and perme- 0 10 20 30 40 50 60 70
ability evolve during retorting at constant volume. More general 0.3
relationships for volume versus mechanical load during retorting BH1 1890-2135 ft (R1-R2)
are still in the development stage. BH1 1151-1347 ft (L5-R6)
The approach developed here combines three simple aspects to
calculate permeability as a function of grade and extent of retort- 0.2
ing. First, an empirical relationship is developed to account for
how the greater ductility of kerogen affects initial porosity as a
function of kerogen content. Second, a correlation is developed
0.1
between total porosity and the matrix permeability of both raw
and retorted shales as expected by Kozeny-Carman and similar
relationships. Third, it is shown that retorting under lithostatic
load corresponding to a few hundred meters overburden yields 0.0
porosities as a function of kerogen conversion roughly equal to 0 10 20 30 40 50 60 70
those calculated at constant volume. These three relationships
are used to create an algorithm for and a plot of permeability as
Grade, gal/ton
a function of conversion for various oil shale grades, which is Fig. 1. Porosity versus grade for five intervals in the Green River Formation in the
needed to model the dissipation of pore pressure generated within Piceance Basin.
the formation during in-situ oil shale retorting.
2.5 with coal being the large-scale example, are obviously load-
bearing, as are organic-rich lamina in lacustrine oil shales. The
0.8+1.3*exp(-gpt/12) depth (or effective stress) and organic content (either kerogen vol-
Young's modulus, GPa
2.0 ume fraction or wt% TOC) effects can be combined into a single
empirical formula
0.076(304.8/DTCO)3.23
1.5
u u0 ead=1k
b
1
where u is porosity, u0 is porosity at zero depth, d is depth, k is
1.0
kerogen volume fraction, and a and b are empirical constants. As
an example, this equation is fitted visually to two intervals for the
0.5 Garden Gulch Member of the Green River Formation. The parame-
ters are not tightly constrained by the data, but good fits shown
in Fig. 3 are obtained for parameters listed in Table 1. Similar results
0.0
could be derived for other intervals in Fig. 1 if desired. Although the
0 10 20 30 40 50
Uniaxial compressive strength, MPa
20 depth does not change during in-situ retorting, this more general
formulation would be useful for basin modeling applications.
6.5+9.5*exp(-gpt/12)
16
3. Permeability of oil shale
0.30
polymethylmethacrylate, and Nylon at room temperature [12]. The R1 Zone
compressive yield strength is also lower than most common room- R1 Zone calc
temperature polymers, with polyethylene being the closest [13]. In 0.25
R0-L0 zone
other words, kerogen is softer than most common synthetic
R0-L0 zone calc
polymers. 0.20
Burnham [14] and White et al. [15] report macroscopic Youngs
Porosity
[20], Saif et al. [21], and Tiwari et al. [22] provided an incremental
Thomas 1966 6.9 MPa
understanding of this fracture formation, and Tiwari et al. estimate
0.6 AMSO cores 16.4 MPa
permeabilities of hundreds of Darcies for rich oil shale. Other stud- swelling?
AMSO cores 0.12 MPa
ies [23,24] examined permeability of rubble columns under load to Retorted LETC
determine whether compaction of rubble chimneys would shut off Raw LETC
permeability as the shale became plastic during kerogen transfor- Retorted (calc) compaction
mation, but those are only indirectly relevant to this work. 0.4
Raw (calc)
Porosity
The early study most relevant to this work is Thomas [17] who
measured the porosity and permeability for cores retorted under Thomas estimates
triaxial confinement from 0.7 to 17 MPa. No apparent cracking 15% compaction
was observed for these confinement pressures. There was an 0.2 for 70 gpt
inverse relationship between confinement pressure and perme-
ability, with a roughly constant permeability of 10 mD parallel to Line from CMR log
the bedding plane for oil shale grades greater than 35 gal/ton and
confinement pressures greater than 5 MPa. 0
Recently, Kibodeaux [25] greatly expanded the published infor- 0 20 40 60 80
mation on porosity and permeability evolution during in-situ con- Grade, gal/ton
fined retorting using cores from inside and outside the retorted
Fig. 5. Porosity for raw and retorted Green River oil shale calculated from the free
region of a field experiment. Those data are shown in Fig. 4 along
volume created by kerogen conversion [1,17] AMSO is American Shale Oil
with data from Thomas, which follow the same trend. The scatter (unpublished data) and LETC is Laramie Energy Technology Center. CMR is
in the data is typical for variability of tight rocks. Three different Combinable Magnetic Resonance from Schlumberger and is presumably a more
calculated curves are also shown, including a modified Kozeny- accurate measure of porosity in a tight rock.
Carman relationship [30u2.5/(1 u)2], the Ergun equation
[110u3/(1 u)], and a cubic power law [200u3]. There is no differ-
ence in the ability of any of these relationships to fit the data well 60
within the measurement variability. All work better than the log-
R0-R3
linear relationship of Li et al. [26]. The dashed line represents their
base case, and they varied the slope and intercept, but their func- 50 Linear (R0-R3)
tional form simply cannot reproduce the correct relationship. Shen
[27] used a similar function but did not disclose parameters.
Given this relationship between permeability and porosity, it is 40
Grade, gal/ton
0
0 5 10 15 20 25 30
TOC, wt%
Fig. 6. Relationship between total organic carbon and Fischer-Assay oil shale grade
for the Garden Gulch Member of the Green River Formation in the Piceance Basin.
u 0:04 0:12egpt=3 2
where gpt is the oil shale grade in gal/ton and the porosity is in vol-
ume fraction. The resulting permeability versus fraction retorted for
various oil shale grades calculated from the modified Kozeny-
Carman relation, assuming 63% of the immature kerogen porosity
is closed, is given in Fig. 7.
Note in Fig. 7 that the initial permeability ranges from 1
to10 lD depending on the initial porosity determined by oil shale
grade. The measured range of permeability in Fig. 4 varies more,
Fig. 4. Comparison of calculated permeability as a function of porosity with presumably due to variability in porosity at constant grade and
measurements from Thomas [17] and Kibodeaux [25]. The samples of Thomas were the possibility of some fracture permeability. For rich oil shale,
retorted under confinement, and the samples of Kibodeaux were recovered from
core both inside and outside an in-situ retort at an unspecified depth. Orientation of
the permeability of retorted shale increases to about 20 mD, which
the measurements is not well documented and could account for some of the is consistent with the largest permeabilities of Thomas [17] shown
scatter. in Fig. 4. In contrast, the increase in permeability as a function of
212 A.K. Burnham / Fuel 203 (2017) 208213
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