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    ENMMS Vs T (Etanol) ENMMS (R-S) Vs T (Etanol)

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    Areli Cervantes
    The document reports on experiments measuring the density, surface tension, and excess molar enthalpy (ENMMS) of water and ethanol at various temperatures. Density and surface tension of both liquids decreased with increasing temperature from 20-48°C. ENMMS of water was negative and decreased with temperature, while ENMMS of ethanol was positive but decreased with increasing temperature.

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    ENMMS Vs T (Etanol) ENMMS (R-S) Vs T (Etanol)

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    Areli Cervantes
    5 views6 pages
    The document reports on experiments measuring the density, surface tension, and excess molar enthalpy (ENMMS) of water and ethanol at various temperatures. Density and surface tension of both liquids decreased with increasing temperature from 20-48°C. ENMMS of water was negative and decreased with temperature, while ENMMS of ethanol was positive but decreased with increasing temperature.

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    The document reports on experiments measuring the density, surface tension, and excess molar enthalpy (ENMMS) of water and ethanol at various temperatures. Density and surface tension of both liquids decreased with increasing temperature from 20-48°C. ENMMS of water was negative and decreased with temperature, while ENMMS of ethanol was positive but decreased with increasing temperature.

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    5 views6 pages

    ENMMS Vs T (Etanol) ENMMS (R-S) Vs T (Etanol)

    Uploaded by

    Areli Cervantes
    The document reports on experiments measuring the density, surface tension, and excess molar enthalpy (ENMMS) of water and ethanol at various temperatures. Density and surface tension of both liquids decreased with increasing temperature from 20-48°C. ENMMS of water was negative and decreased with temperature, while ENMMS of ethanol was positive but decreased with increasing temperature.

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    of 6

    Disolvente Altura (cm)

    Agua T1=20C T2=30C T3=38C T4=48C MM (g/mol)


    7 6.9 6.8 6.7 18
    Etanol T1=23C T2=32C T3=40C T4=48C
    3 2.9 2.8 2.7 46.07

    ENMMS(R-S) vs T (Etanol) Radio capilar (cm); 0.02095


    ENMMS
    500
    vs T (Etanol) Gravedad (cm/s2): 980
    -380
    f(x) = 400
    2.1199889612x + 1106.9533595965
    R = 0.9994928405
    360
    -S)

    f(x) = 300 - 1.620691561x + 846.2449574991


    S(R
    ENMMS

    340
    M

    R = 0.9994928405
    280300320340
    NM

    320
    E

    300T (K)
    295 300 ENMMS 305 310 315vs320 T
    325(Agua)
    ENMMS (R-S) vs T" (Agua)
    ENMMS

    f(x) =290 T (K)


    - 0.8221717418x
    T.S vs T (agua) 295 300 305 +310 734.4616493053
    ENMMS (R-S)

    315 320 325


    R =f(x) = - 2.1199271378x + 1893.7712193227
    0.9979828707
    R = 0.9979828707 T (K)
    290 300 310 320 330
    75 T.S vs T (etanol)
    T (K)
    Tensinsup. (dyn/cm)

    f(x) = - 0.127726202x + 62.1799163387


    f(x) = -700.1362590174x
    R = 0.9998490523 + 111.7189322315
    R = 0.9975005483
    65 Temperatura (K)
    dy/
    nm
    c)

    290300 310320330
    s
    n n
    isp
    u.(

    Temperatura (K)
    e
    T

    Log

    Agua
    Disolvente Tc (K) Log
    Agua 647.55 log (1-T/Tc)
    Etanol 516.5
    Etanol
    Log
    log (1-T/Tc)

    Van der Waals-Guggenhe

    f(x) = 1.1679193728x + 1.81873728


    R = 0.9997626142
    log

    -0.43 -0.42 -0.41 -0.4 -0.3


    log (1-T/Tc)
    -0.43 -0.42 -0.41 -0.4 -0.3
    log (1-T/Tc)
    T 293.15 303.15 311.15 321.15
    Disolvente Densidad (g/cm3)) Tensin superficial (dyn/cm)
    Agua T1=20C T2=30C T3=38C T4=48C T1=20C T2=30C T3=38C
    0.99808 0.99571 0.99225 0.98802 71.72053168 70.52808093 69.26440815
    Etanol T1=23C T2=32C T3=40C T4=48C T1=23C T2=32C T3=40C
    0.7903574 0.7799 0.77228841 0.762898737 24.34024167 23.21758401 22.19819468
    296.15 305.15 313.15 321.15

    Van der Waals-Guggenheim (Agua)


    1.86
    1.855
    f(x) = 0.6640316611x + 2.0297693534
    R = 0.9976955054 1.85
    1.845
    1.84
    log

    1.835
    1.83
    1.825
    1.82
    -0.3 -0.295 -0.29 -0.285 -0.28 -0.275 -0.27 -0.265 -0.26 -0.255
    log(1-T/Tc)

    log (1-T/Tc)
    T1=20C T2=30C T3=38C T4=48C

    1.8556435 1.848362067 1.840510128 1.832220646


    -0.261779594 -0.274210165 -0.284417321 -0.297523158
    T1=23C T2=32C T3=40C T4=48C

    1.386324886 1.365817026 1.346317656 1.325210767


    -0.369957271 -0.388068074 -0.404826149 -0.42225691

    Van der Waals-Guggenheim (Etanol)


    1.4

    f(x) = 1.1679193728x + 1.818737287 1.38


    R = 0.9997626142
    1.36

    1.34

    1.32

    1.3

    1.28
    3 -0.42 -0.41 -0.4 -0.39 -0.38 -0.37 -0.36
    log (1-T/Tc)
    1.3

    1.28
    3 -0.42 -0.41 -0.4 -0.39 -0.38 -0.37 -0.36
    log (1-T/Tc)
    ENMMS (EOT) X ENMMS (R-S)
    T4=48C T4=48C T1=20C T2=30C T3=38C 4.140355028 T4=48C
    67.95487938 493.2286194174 485.7973683 478.2016379 470.4987696 1271.764379914
    T4=48C T1=23C T2=32C T3=40C T4=48C 1.496062865 T1=23C
    21.14514986 365.9215707499 352.1571849 338.9040712 325.4705104 478.6535015671
    T1=20C T2=30C T3=38C
    1252.603285 1233.018088 1213.156643
    T2=32C T3=40C T4=48C
    460.6486283 443.3125383 425.7404097

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