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Trivedi Effect - A Transcendental Approach To Changing Metal Powder Characteristics
Trivedi Effect - A Transcendental Approach To Changing Metal Powder Characteristics
A transcendental approach
to changing metal
powder characteristics
Its not often that Metal Powder Report departs from
the path of hard facts into the somewhat mushier
area of metaphysics, but opportunities crop up.
While recognising that science has its fair share of
charlatans, one such opportunity was presented
by a paper submitted by an Indian researcher in
which he details work aimed at probing the effects
on powder samples where changes were apparently
generated by thought. Some will laugh, others will
cry, but perhaps among our readers there are those
who might be able to help elucidate further the
phenomena described
A
toms condense to form atoms. Thus the covalent bonds are strong the spacing between neighboring defects
metallic solids due to two giving rise to high strength, high hardness, in nano powders can approach the inter
primary forces. When the brittleness, high melting/ decomposition atomic distance [3]. As the grain size
condensing atoms possess temperature, electrical insulation and low becomes smaller and smaller, a larger
s and p electrons as well as vacant reactivity. and larger fraction of atoms resides on
electron positions in their outer most The transition elements exhibit mixed the single crystal grain boundaries (at
shell, these form metallic bonds. The metallic and covalent bonding combining a 6nm grain size, nearly half the atoms
outer atomic shells overlap causing elec- the best properties of pure metals and pure reside on the grain boundaries), thus
trons to delocalise and hold the now covalent ceramics. The overlap of s and the behaviour of nano-sized powders is
remaining positive atomic/ionic cores p electrons form metallic bonds while often dominated by events at the grain
in fixed arrangement. This would mean the lone d or f electrons form covalent boundaries [4].
that the electrons continuously move as bonds. Due to the extremely small size of the
if they are a cloud or gas among posi- Apart from atoms and molecules the grains and a large fraction of the atoms
tively charged atoms. Thus the metal- next smallest materials available are located at the grain boundaries, these
lic bond is flexible and gives metals powders. These could be single crys- materials have properties like higher
the characteristic malleability, ductility, talline or polycrystalline the particle strength/hardness, enhanced diffusivity,
thermal conductivity and electrical con- size of which is in the micrometric or improved ductility/toughness, reduced
ductivity. nano metric range (<100nm) [1 and 2]. elastic modulus, increased specific
When the outer shells of the condens- Particles exhibit fine microstructures heat, higher electrical resistivity, higher
ing atoms possess uncoupled (single elec- and can contain such a high density of thermal expansion coefficient, lower
trons), these form covalent bonds by cou- defects (point defects, dislocations, sub thermal conductivity, and superior mag-
pling with the electrons of opposite spin (crystallite) boundaries, grain bounda- netic properties much improved over
in the outer shells of the neighbouring ries, inter phase boundaries, etc.) that those exhibited by conventional grain
22 MPR October 2008 0026-0657/08 2008 Elsevier Ltd. All rights reserved.
Table 1. Variation in particle size of treated powders.
METALPOWDER/ Ti V Cr Mn Fe Co Ni Cu Zn
CHARACTERISTIC
peratures, the material relaxes into sub required for dislocation movement are In the present investigation we report
grains separated by low-angle bounda- enormously high due to the HallPetch the use of an unknown and subtle energy
ries, leading to a decrease of atomic level strengthening. Thus nano sized powders (through thought intervention) on various
strain. During subsequent milling the with a minimum grain size are produced transition metal powders obtained from
process of high deformation/sub grain [2]. Titanium powders of about 2 reputed suppliers. The effect of this energy
formation is repeated resulting in the particle size when subjected to high ener- on particle size and crystallite size and the
sub grains becoming finer and finer, and gy attrition milling in an argon atmos- possible causes for the observed changes
the relative orientation of the sub grains phere after 15 hours of milling yielded are discussed.
with respect to each other ultimately an average particle size of 35 nm has Metal powders belonging to first series
becoming completely random. Once been obtained [9]. Thus it is now pos- of transition metals were selected for the
the sub grains reach a critical level of sible to produce large quantities of ultra investigation. One portion of these was
refinement, further refinement becomes fine and nano powders by high energy kept as a control/standard sample while
virtually impossible since the stresses milling. the other portions were exposed to Mr
Results
Average particle size d50 and d99 the
particle sizes below which 99 percent of
the particles are present are given in Table
1 for various powders. The particle sizes
in treated powders in general decreased,
although some powders showed increase
in size. The percent change in particle size
of various treated powders with respect
to control powders is computed using the
formula
Change in average particle size d50 (%)
= 100 x (d50t d50c)/ d50c
In a similar manner the change in par-
ticle size d99 (%) is computed. These
values are given in table 1 and are plotted
in Figure 1.
Both titanium and chromium pow-
ders showed a decrease in d50 and d99.
Evidently the larger particles might have
fractured at the inter particle boundaries
there by reducing the d99 size. Thus the
decrease in the latter was much more than
that observed in d50. Some samples of iron
and cobalt powders showed slight increase
in particle size suggesting that the particles
would have elongated, work hardened and
eventually fractured to smaller particles.
This could be due to the higher ductility
of these metals as compared to titanium
and chromium. The maximum decrease in
size was observed in copper and zinc pow-
ders. The later showed an initial increase
in size possibly due to plastic deformation
and a latter decrease due to fracture at the
ELEMENT Ti V Cr Mn Fe Co Ni Cu Zn
ARRANGEMENT OF 3d24s2 3d34s2 3d54s1 3d54s2 3d64s2 3d74s2 3d84s2 3d104s1 3d104s2
ELECTRONS IN OUTER
SHELL OF THE ATOM
EFFECTIVE NUCLEAR 8.14 8.98 9.76 10.53 11.18 11.86 12.53 13.20 13.88
CHARGE OF THE 3 d 4.82 4.98 5.13 5.28 5.43 5.58 5.71 5.84 5.97
ORBITAL AND OUTER 4
s ORBITAL
bonds making them stronger decreasing The percent change in positive charge Divine Life
lattice constant. From iron onwards,d per unit volume is computed as follows; 2Formerly Professor, IIT Bombay and
electrons start getting coupled making The atomic radius is obtained by divid- Visiting Professor at USC, Los Angeles
the bonds weaker and hence the applied ing the lattice parameter a with 2. r = and OSU, Stillwater, USA. Currently
force stretches the electron cloud increas- a/ 2 Scientific Advisor, Society for Divine
ing the lattice constant. With a decrease Then the volume of the atom is Life, Mumbai.
in volume of the unit cell the density obtained by assuming it to be spherical
increases. Since this implies increase in V = 4 r3 /3