public class FacetExample

{
public List<Account> accs {set;get;}
public FacetExample()
{
accs=[select Name, phone, industry from Account];
}
}

visual force page:

<apex:page controller="FacetExample">
<apex:form >
<apex:pageBlock title="Account">
<apex:pageBlockTable value="{!accs}" var="a">
<apex:column >
<apex:facet name="header">
<apex:inputCheckbox />
</apex:facet>
<apex:inputCheckbox />
</apex:column>
<apex:column headerValue="Customer Name">
{!a.name}
</apex:column>
<apex:column headerValue="Phone">
{!a.phone}
</apex:column>
<apex:column headerValue="Industry">
{!a.industry}
</apex:column>
<apex:column headerValue="Rating">
{!a.rating}
</apex:column>

</apex:pageBlockTable>
</apex:pageBlock>
</apex:form>
</apex:page>