Oxbow Calcining LLC

MATERIAL SAFETY DATA SHEET

SECTION I IDENTIFICATION
EMERGENCY PHONE PRODUCT NAME CAS NO.
281 775 - 4741 64743 05 -01
Calcined Petroleum Coke

COMPANY NAME and ADDRESS TRADE NAME AND SYNONYMS

Oxbow Calcining LLC Calcined Petroleum Coke
1450 Lake Robbins Dr. CHEMICAL NAME AND SYNONYMS
Suite 320 Calcined Petroleum Coke
The Woodlands, TX 77380
QUESTIONS CONCERNING THE MSDS EFFECTIVE NFPA Rating
CAN BE DIRECTED TO: 10/20/10 0 Least, 1 Slight, 2 Moderate, 3 High, 4 Extreme
Corporate Technical Manager SUPERSEDES
Telephone 281 775 - 4741 11/05/07 Health: 0 Flammability: 1 Reactivity: 0

SECTION II HEALTH HAZARD DATA

MATERIAL INFORMATION

Calcined petroleum coke is not considered to be hazardous as defined by OSHAs Hazard Communication Standard 29 CFR
1910.1200. Calcined petroleum coke is considered to be an inert material.

Calcined Petroleum Coke CAS NO. 64743 05 - 01

EXPOSURE LIMITS

OSHA: PEL = 15 mg/m3 as total dust; 5 mg/m3 as respirable fraction

ACGIH: PEL = 10 mg/m3 as total dust; 3 mg/m3 as respirable fraction

SYMPTOMS OF OVEREXPOSURE

Route(s) of Entry: Inhalation, skin, and eye contact.

This product is nontoxic. The nuisance dust exposure values that are listed apply to any inert substance capable of producing
airborne particulates. Excessive concentrations of calcined petroleum coke may reduce visibility, cause unpleasant deposits in the
eye, ears, and nasal passages, or irritate the skin or mucous membranes by mechanical means. However, normal workplace
exposure has not been determined to cause a significant health effect. Calcined petroleum coke, as with many petroleum products,
may cause minor skin, eye, or lung irritation, but good hygienic practices can minimize these effects.

See Section VIII for additional health data.

Is product listed as Carcinogen or Potential Carcinogen by: NTP? No IARC? No OSHA? No

RECOMMENDED FIRST AID TREATMENT

Inhalation: Remove to fresh air. If breathing has stopped, administer artificial respiration and supply oxygen. If problems persist,
seek medical attention.
Eye Contact: In case of contact, immediately flush eyes with plenty of water until irritation subsides. If irritation persists, seek
medical attention.
Skin Contact: Normal skin contact is not known to cause a significant health effect. Particles should be periodically washed off of
skin with soap and water.
Ingestion: If swallowed, do not induce vomiting. Immediately give water. Never give anything by mouth to an unconscious
person. If symptoms develop, seek medical attention.
MSDS Calcined Petroleum Coke
SECTION III PHYSICAL DATA
BOILING POINT (O F) BULK DENSITY (LB/FT3)

Solid 50 to 55

MELTING POINT (o F) VAPOR DENSITY (Air = 1)

Nonmelting solid Not Applicable

SOLUBILITY IN WATER ODOR

Not Soluble None

PERCENT VOLATILE BY VOLUME APPEARANCE

0.3 Max Dark gray to black

SECTION IV FIRE AND EXPLOSION HAZARD DATA

FLASH POINT (Method used) AUTO IGNITION TEMPERATURE FLAMMABLE LIMITS % BY VOLUME
See Unusual Fire and Explosion Hazards LEL UEL
No Data Available Section below No Data Available No Data Available

EXTINGUISHING MEDIA
Water Fog, Dry Chemical, Foam, or Carbon Dioxide

SPECIAL FIRE FIGHTING PROCEDURES Most reported coke fires have occurred when produced calcined coke is
inadequately cooled and stored in a manner that allows the movement of air through the coke bed. Coke should be well quenched
or cooled before it is stored in a pile out of doors or placed in silos or bins. Storage should be arranged to prevent movement of air
through the coke. Should a fire occur, its locations and extent should be determined as quickly as possible. The best procedure is
to dig out and remove the coke in the heated zone. The hot coke should be drenched with water as it is exposed. Because of the
possibility of steam explosion, great care should be used introducing water into confined storage such as a silo. Whenever
possible, bulk material in silos should be removed and material drenched in an open area. Products of combustion may contain
carbon monoxide, carbon dioxide and sulfur dioxide. Do not enter permitted confined space or enclosed area without proper PPE.
There is no dust explosion hazard from calcined petroleum coke.

UNUSUAL FIRE AND EXPLOSION HAZARDS

May burn if exposed to temperatures greater 1290 oF (700oC).

SECTION V REACTIVITY DATA

STABILITY HAZARDOUS POLYMERIZATION

Unstable May Occur

Stable X Will Not Occur X

INCOMPATIBILITY (Materials to avoid)

Strong oxidizing acids; other strong oxidants

HAZARDOUS DECOMPOSITIONS PRODUCTS

CO, CO2, SO2

CONDITIONS TO AVOID

Extreme heat and open flames. May burn if exposed to temperatures above 1290 oF (700oC).
MSDS Calcined Petroleum Coke

SECTION VI SPILL OR LEAK PROCEDURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED

Material is not toxic and can be picked up by sweeping, shoveling, or vacuuming. Provisions should be made to prevent washing,
draining, or directing material to storm or sanitary sewers.
WASTE DISPOSAL METHOD

All Federal, State, and Local regulations regarding health and pollution must be followed for disposal of calcined petroleum coke.

SECTION VII SPECIAL PROTECTION INFORMATION

RESPIRATORY PROTECTION (Specify type)

Select appropriate NIOSH-approved protection where necessary to maintain exposures below the acceptable limits in the Health
Hazard Section. Proper respiratory selection should be determined by adequately trained personnel and based on the
contaminant(s), the degree of potential exposure and published respirator protection factors.
VENTILATION

Dust should be controlled at point of operation.

PROTECTIVE GLOVES

None

EYE PROTECTION

None required. Recommend using dust goggles in areas of high dust concentrations.

OTHER PROTECTIVE EQUIPMENT

None

SECTION VIII ADDITIONAL HEALTH DATA

Petroleum coke was found to be non-carcinogenic in mice in chronic skin painting studies with coke dust. Petroleum coke was
found not to be carcinogenic in monkeys and rats in a two-year inhalation study at concentrations up to 30 mg/m3. Chronic
inflammatory changes similar to those produced by non-specific respiratory irritants were observed in some rats at the highest
exposure level.

Petroleum coke was found not to be mutagenic in a rat in vivo Bone Marrow Cytogenetic test, a mouse Lymphoma assay, and an
Ames Mutagenicity assay.

SECTION IX SHIPPING INFORMATION

DEPARTMENT OF TRANSPORATION (DOT)

Proper Shipping Name : Regulated by water mode only, when temperature exceeds 130 oF, Petroleum coke, calcined.
Hazard Class : ORM ( other regulated material ) C
Dot Label(s) : None
DOT Placard : None

INTERNATIONAL MARITIME ORGANIZATION (IMO)

Proper Shipping Name : Petroleum coke, calcined. Not regulated by IMO

Special Information : Must not be loaded in cargo vessels when temperatures exceed 225 oF. (46 CFR 148.04-17)
MSDS Calcined Petroleum Coke

The information and recommendations contained herein are, to the best of Oxbow Carbon and Minerals (OCM) knowledge and belief,
accurate and reliable as of the date issued. OCM does not warrant or guarantee their accuracy or reliability, and OCM shall not be liable for
any loss or damage arising out of the use thereof.

The information and recommendations are offered for the users consideration and examination, and it is the users responsibility to satisfy
itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure
proper health, safety and other necessary information is included on the container.