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HW 2
HW 2
Homework 2
(Due date: October 11, 2017)
1. (Prob.3.13 in the text book)
(a) Evaluate the partition function and the major thermodynamic properties of an ideal
gas consisting of N1 molecules of mass m1 and N2 molecules of mass m2 , confined to a space
of volumne V at temperature T . Assume that the molecules of a given kind are mutually
indistinguishable, while those of one kind are distinguishable from those of the other kind.
(b) Compare your results with the ones pertaining to an ideal gas consisting of (N1 + N2 )
molecules, all of one kind, of mass m, such that m(N1 + N2 ) = m1 N1 + m2 N2 .
2. (Prob.3.15 in the text book)
Show that the partition function QN (V, T ) of an extreme relativistic gas consisting of
N monatomic molecules with energy-momentum relationship = pc, c being the speed of
light, is given by
{ ( )3 }N
1 kT
QN (V, T ) = 8V . (1)
N! hc
1
Verify that for an ideal gas
( )2 ( )3
E 2 E 8
= and = . (5)
U 3N U 9N 2
u2 1/2
m0 2 (1 ) = 3kT, (6)
c2
where m0 is the rest mass of the particle and is its speed. Check that in the extreme
relativistic case, the mean thermal energy per particle is twice its value in the nonrelativisitc
case.
6. (Prob. 3.26 in the text book)
The energy eigenvalues of an s-dimensional harmonic oscillator can be written as
s
j = (j + ); j = 0, 1, 2, ... (7)
2
Show that the jth energy level has a multiplicity (j+s1)!/[j!(s1)!]. Evaluate the partition
function, and the major thermodynamic properties, of a system of N such oscillators, and
compare your results with a corresponding system of sN one-dimensional oscillators. Show,
in particular, that the chemical potential s = s1 .
7. (Prob. 3.42 in the text book)
Consider the system of N magnetic dipoles, studied in Section 3.10, in the microcanonical
ensemble. Enumerate the number of microstates, (N, E) accessible to the system at energy
E and evaluate the quantities S(N, E) and T (N, E). Compare your results with equations
(3.10.8) and (3.10.9).