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Chem 28 1st LE Samplex PDF
Chem 28 1st LE Samplex PDF
1. Double indicator titration is used to determine amounts of NaOH, NaHCO 3 and Na2CO3 in a solution.
Phenolphthalein and methyl orange are the indicators used. Which of the following is/are TRUE regarding
double indicator titration?
I. Volumes of indicators used can determine the concentration of the 3 chemicals in solution.
II. Only methyl orange is the necessary indicator to determine the concentration of NaHCO 3.
III. In the continuous titration of a sample containing a mixture of NaOH and Na2CO3, the volume of HCl
used until the endpoint of phenolphthalein is greater than the volume of HCl used until the endpoint
of methyl orange.
A. I only
B. III only
C. II and III
D. I, II and III
2. Which of the following methods do not promote the formation of solid precipitate?
A. Decreasing the temperature of the solution.
B. Slow addition of precipitating agent with vigorous stirring.
C. Diluting the solution.
D. Increasing the solubility of the solution.
4. A 0.5000 g tablet containing CaCO3 was initially titrated with 20.00 mL of 0.1250 M HCl. Afterwards, the
excess acid was titrated using 2.80 mL of 0.1000 M NaOH. What is the % of CaCO 3 in the tablet?
A. 19.42%
B. 22.22%
C. 44.44%
D. 88.88%
5. A chemistry laboratory received 15 mg of soil sample from the geology laboratory. The sample was divided
into three 5 mg samples and was analyzed. What is the classification of the analytes according to amount?
A. Macro
B. Semimicro
C. Micro
D. Ultramicro
10. The process of converting a colloidal suspension into a filterable solid is called
A. Coagulation
B. Peptization
C. Coprecipitation
D. Nucleation
12. A 0.4000 g sample composed of CaO and other impurities is mixed with 14.00 mL of 0.5000 M HCl. The
solution was then titrated with 4.80 mL 0.3000 M NaOH. What is the percent purity of CaO in the sample?
(MM: H = 1.01, Cl = 35.45, Na = 23.00, O = 16.00, Ca = 40.08)
A. 77.95%
B. 49.07%
C. 20.17%
D. 38.98%
13. The amount of phosphorus in a 5.0 g fertilizer sample was found to be 0.047 g. The element can thus be
considered to be what type of constituent?
A. Major
B. Minor
C. Trace
D. Ultratrace
14. Which of the following solutions has the lowest ionic strength?
A. 0.20 M CaCO3 and 0.30 M K2Cr2O7
B. 0.20 M CaCO3 and 0.40 M K2Cr2O7
C. 0.30 M CaCO3 and 0.20 M K2Cr2O7
D. 0.30 M CaCO3 and 0.40 M K2Cr2O7
17. 25.00 mL of solution are found to contain 3.45 10 -8 moles of fluoride ion. What is ppb F - for this solution?
(MW = 19.0)
A. 0.0262 ppb
B. 0.655 ppb
C. 1.38 ppb
D. 26.2 ppb
18. 21.3 mL of 0.10 M NH3 is mixed with 15.6 mL of 0.10 M HCl. What is the pH of the resulting solution? (Kb =
1.75 10-10)
A. 4.32
B. 5.20
C. 8.80
D. 9.68
20. What are the -values of acetic acid with pH 5? (Ka = 1.8 10-5)
A. 0 = 0.643 ; 1 = 0.357
B. 0 = 0.357 ; 1 = 0.643
C. 0 = 0.847 ; 1 = 0.153
D. 0 = 0.153 ; 1 = 0.847
__________________1. Kjeldahl method is the standard method for determining _________ content.
__________________2. If the indicator range for a newly-discovered indicator is between 4.3 and 6.3, find the
pKa of this indicator.
__________________3. Analytical method used to determine amount of analyte from amount of product formed.
__________________4. The type of analysis used to determine amount of certain selected constituents in a
sample.
__________________5. The material taken from the lot for analysis or archiving.
__________________6. The chemical method used to determine moisture in a sample by non-aqueous titration.
__________________7. A type of coprecipitation wherein a contaminant compound is trapped within a pocket
formed during rapid crystal growth.
__________________8. It is a process by which a precipitate is formed by slow generation of a precipitating
agent homogeneously throughout a solution.
__________________9. The _________ of a solution is the mass of a pure substance that is chemically equivalent to
1 mL of the solution.
__________________10. An ultrapure compound that serves as the reference material for a titrimetric method of
analysis.
1. While searching through a storage room, a curious scientist ran through a reagent bottle which was labeled
5000 ppm X2-, 7500 ppm Y-. This scientist used gravimetric analysis to determine the identities of X2- and
Y-. Separate 50.00 mL solutions were poured onto each beaker, and each beaker was treated with excess
Mg2+ and Pb2+, respectively.
In the beaker treated with Pb2+, after filtering the solution, the recorded weight was determined to be 3.812
g. However, the scientist forgot to oven dry the precipitate. After oven-drying, the weight was determined
to be 3.773 g. In the beaker treated with Mg2+, the recorded weight, after oven drying, was determined to be
0.6430 g. It was then determined that only MgY 2 was present using one of your earlier Chem 16
experiments.
The following is a list of possible identities of X2- and Y-, with their corresponding molecular weights:
MW (g/mol) MW (g/mol)
Cl- 35.453 60.0089
Br- 79.904 96.0626
I- 126.9045 80.0632
OH- 17.0073 115.9937
62.0049 S2- 32.065
59.0439 112.1282
88.019
2. (Quantitative Chemical Analysis, Harris, 7th ed. 27-20) A 1.475 g sample containing NH4Cl (FM = 53.492),
K2CO3 (FM = 138.21), and inert ingredients was dissolved to give 0.100 L of solution. A 25.0 mL aliquot was
-
acidified and treated with excess sodium tetraphenylborate, Na +B , to precipitate K+ and ions
completely:
FM = 358.33
FM = 337.27
The resulting precipitate amounted to 0.617 g. A fresh 50.0 mL aliquot of the original solution was made
alkaline and heated to drive off all the NH3:
It was then acidified and treated with sodium tetraphenylborate to give 0.554 g of precipitate.
A. Find the amount of K+ ions (in mol) in the 25.0 mL and 50.0 mL aliquots.
B. Find the mass of K2CO3 found in the sample.
C. Find the amount of ions (in mol) in the 25.0 mL aliquot.
D. Find the mass of NH4Cl found in the sample.
E. Find the weight percent of K2CO3 and NH4Cl in the sample.
3. Two Chem 28 students, Keena and Lorainne, were asked to determine the contents of two different 200 mL
soda ash samples by titration with 0.1600 M HCl as the titrant.
Lorainne, assigned with Sample B, titrated a 50 mL aliquot of Sample B with 5 mL titrant until the
phenolphthalein endpoint was reached. She titrated another 50 mL aliquot with 57.81 mL titrant until
methyl orange endpoint was reached.
4. A 1.15 g sample containing only NaBr, CaBr2 and Na2CO3 yielded 1.08 g KBr and 0.682 g Na2SO4 in separate
precipitations. Find the percent composition of each compound in the original sample.
5. In an acid-base titration, 25.00 mL of 0.1000 M oxalic acid was titrated with 0.1000 M NaOH ( = 5.6
10-2 ; = 5.4 10-5). Calculate the following: