ANSWER - SOLUTION Adva PI PDF

1
AITS-CRT-III (Paper-1)-PCM(Sol)-JEE(Advanced)/14
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ANSWERS, HINTS & SOLUTIONS
CRT III
(Paper-1)
PHYSICS CHEMISTRY MATHEMATICS

ALL INDIA TEST SERIES
1. C A C
2. A D D
3. B D B
4. C A C
5. A B C
6. C C B
7. B B A
8. A, D A, B, D B, C
9. A, B A, D A, C, D
10. C, D A, D B, C
11. B, C A, B, C B, C, D
12. B A D
13. B C C
14. B B B
15. D B A
16. C B C
1. 3 5 4
2. 4 3 2
3. 5 4 9
4. 4 1 5
5. 1 3 7
6. 5 2 3
7. 2 3 5
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2
Physics PART I
4. Apply superposition of currents in each resistor due to each cell to get

current in two resistors zero, E/R in rest four, current drawn from each
cell is 2E/R
5. One particle t/2 before max height, other t/2 after max height
Relative velocity perpendicular to line joining them = gt
Relative separation = ut
Relative angular velocity = gt/ut = g/u
6. Intensity in absence of lens = P/4r2

So intensity at P before placing lens is of intensity at optical center of lens
After crossing lens light becomes parallel rays to intensity does not change further along that ray
7. apply work-energy theorem

2 2
1 mg 1 mg
mgz K z K Fz 0
2 K 2 K
z = 2F/K.
8. = MB sin

ii
f 12
r2
9. a = kx2
da 1
2kx tan 60 = 2k 3 k
dx 2
x2
a
2
dv x2 v 2 x3
v C1 at x = 0, v = 3 m/s
dx 2 2 6
9
C1
2
x3
v2 9
3
hence a = 1.5 and v 3 9
2T cos
10. Capillary height h
rg
h = 59.6 mm
3
here 59.6 mm is greater than the protruding part hence water will rise in the capillary of
insufficient height 25 mm.
2T
Now, R 0.6 mm
hrg
11. Fluid particles passing through the bend are in circular motion. The
centripetal acceleration is provided by the variation in pressure. In the
section as shown maC P2A
P1A P2 A maC 2
P1A
P1 P2 1
applying Bernoulli theorem at 1 and 2
1 1
i.e., P1 1v12 gh1 P2 v 22 gh2
2 2
1 1
P1 1v12 P2 v 22 as h1 h2
2 2
P1 P2
v1 v 2
12. In CM frame
M,Q,2u
C
2M,2Q,u
2b/3
b
13. At closest approach velocity perpendicular to line joining particles

Conserve kinetic + electric potential energy from large separation to closest approach
16. System rotates about CM i.e. middle of 4M and M(Q)

For problem 3, work done by electric field = QLE = I2
Initial torque by electric field = QLE = I
r/2r =
SECTIONC
1. For circular motion of a body tied to a string on a horizontal plane

mv 2 O T
T
r r
here, T mg
mv 12 / r1 M1g T
M
mv 22 / r2 M2 g
v 12r2 8
(i)
v 22r1 1
Now as angular momentum is conserved about pt 0.
mv1r1 mv 2 r2 (ii)
r1
from (i) and (ii) 2
r2
4
2
2 v 2 r1 r1
further
1 v1 r2 r2
2
2 1 1

1 2 4
2 1 2 1 3
1 1
2 1 4 4
Q dT
2. KAA
t dx
dT
in conductor A = slope of graph = 3
dx
Since both conductors are connected in series, same heat current will flow in A and B.
Q 1 1
KB = 200 3 J/m-secC
t dT t A tan 45
A
dn
1 w 1
3. For lens L1, ray must move parallel to the axis after refraction x = 10 cm
x R1
4. f = ma2 a1
2f
= F
I mR
f
a2 = F/4m, f = F/4
a2
5. In steady state potential difference across each capacitor = E
3
6. mAg sin = 5 10 sin 37 = 5 10 = 30 N
5
fmax AB (mC mB )gcos 48 N
hence f = 30 N
7. sin 1
n
1 2 1 1
40
or 20 n 60
Hence number of maxima = 60 20 = 40
5
Chemistry PART II
1. Go RTlnK p
46.5 1000 = - 2 298 lnKp
Kp = 1.3 10 34
15
2. C6H6 O2 6CO2 3H2 O;Q1
2
C O2 CO2 ; Q2
1
H2 O2 H2 O; Q3
2
Required equation: 6C s 3H2
C6H6 ; H 6Q2 3Q3 Q1
3. Cl O
H
KOH O3 / Zn O
Cl2 ,h

C2H5 OH

H2 OH
H
X APAo
4. Mole fraction of A in vapour YA =
X APAo XBPBo
X A 1 PAo 1
&
XB 3 PBo 3
1 1
YA o
0.1
XB PB 1 3.3
1
XA PAo
6. [Cu(CN)4]3 is square planar and contains Cu (I) which is colourless

[NiCl4]2 is tetrahedral and contains Ni(II) which is coloured.
[BF4] is tetrahedral and colourless
14. SO 2 PCl5
SOCl2 POCl3
A
SOCl2 H2 O
SO 2 HCl
A pungent smelling
5.95
15. MSOCl2 5 102 mol / l
119 1
H2 O SOCl2 2AgNO3 2AgCl 2HNO 3 SO 2
100
Moles of AgCl formed = 2 molarity of SOCl2 in 100 ml = 2 5 102 102 moles
1000
Wt. of AgCl = 143.5 102 = 1.435 g
16. IInd part was treated with dil. HCl/BaCl2/H2O2.

SOCl2 H2 O SO2 2HCl
H2 O 2 SO2
SO3 H2 O
6
SO3 H2 O
H2 SO4
BaCl2 H2SO 4
BaSO 4 2HCl
ppt.
10
Mole of BaSO4 formed = 5 102 in 100 ml solution
100
Wt. of BaSO4 formed = 5 10 3 233 1.165 g.
SECTION C
2. Br
Br2 / h
H3C CH CH2
CH3 CH2 CH2 CH3 CH3 CH3 CH2 CH2 CH2Br
(enantiomers)
Br H3C H
H3C CH CH2 CH3

Alcoholic C C cis CH2 CH CH2 CH3
KOH
H CH3
3. Let x% be the decrease in density of Ge crystals. Let a be the total no. of Ge atoms missing and
b be the no. of boron atoms replacing Ge atoms.
b
100 2.376 (i)
a
72.6a 11b
1 1 0.01x
NAV NAV
72.6a 11b
0.01x (ii)
NAV NAV
150NAV
Also, b = 1 0.01x (iii)
106 11
Solving (i), (ii) and (iii)
x = 4%
4. Ksp = [Zn2+][S2-]
10 21
[S2-] 10 19
0.01
2
H S 2
For K a1 .K a2
H2 S
2
H 1019
10
20
H 0.1
0.1
or pH = 1
5. 3Cu + 10HNO3 3Cu(NO3)2 + 3NO2 + NO + 5H2O
6. Only CO and CH4 react with O2, N2 remain uncreative
7. OH OH
P P 6
3
O O O 2
OH OH
7
Mathematics PART III
1. A, B, D are always true but C is true only if the triangle is equilateral
2. f(x) = cos x + cos(x + 2) + cos(x + ) = (2 cos + 1) cos(x + )

As cos (x + ) can take any real value from 1 to 1 x R
But f(x) is constant so (2 cos + 1) = 0 must hold
2
and C = 0
3
2
Hence [C + ] = 0 2
3
2sin3x cos x 2sin3x cos3x

3. 2cos2 x 2cos x cos5x
dx
sin3x cos x cos 3x

cos x cos x cos 5x
dx
2sin3x sin 2x sin x

2cos x cos 3x cos 2x
dx
tan3x tan2x tan x dx = tan3x tan2x tan x dx

2
4. 2 1 sin tdt
0
2
2 1 sin tdt 1 sin tdt
0
2
2 1 1 sin tdt

Put t = + x, 2 1

0
1 sin xdx

x x x x
=
0
cos
2
sin dx = 2 sin cos 4
2 2 2 0
12 42 r
5. We have sin K Let
PA PB PC
C
B
A
42 r
12
P
So K(PB PA) = 42 12 = 30
K(AB) = 30
K[54] = 30
30 5
K=
54 9
8
Now K(PC PB) = r 42

K(BC) = r 42
K[r + 42] = r 42
On solving r = 147
t
6. Let g t f x dx

0
g(t) = f(t)
Now apply Lagranges mean value theorem in [0, 2], we get
g 2 g 0
g' c where c (0, 2)
20
2
f x dx 2g' c where c (0, 2)
0
7. Vector perpendicular to 2i j k and i 3j k is

i j k
2 1 1 2i j 5k
1 3 1
Any general point on the line is (1 + 2, 1 + , 1 ) at the point of intersection. This point satisfy
equation of plane (1 + 2) + 3(1 + ) (1 ) = 9
=1
x3 y2 z
Point of intersection (3, 2, 0) and required line
2 1 5
8. (A) f(x) = cos(sin x)

As f(x + ) = cos(sin( + x)) = cos(sin x) = cos(sin x) = f(x)
(B) As 1 sin x 1
cos 1 cos(sin x) 1

(C) lim f x f x
x / 2 2 2
= lim 2cos cos x 2
x / 2
(D) Clearly f(x) is even function
9. Let the number be (a d), a, (a + d)

3a = 24
a=8
Also (8 d)(8)(8 + d) = 384
d2 = 16
d = 4 or 4
Hence series is 4, 8, 12, ..
Sn = 2n(n + 1) or 12, 8, 4, ..
Sn = 14n 2n2
10. f(x) > 0 and f(x) > 0 for x < 0 (0, 1) 1

f(x) < 0 for x > 0 y
1 x2
1
Now g x
1 0
f
x
9
1 1 1
g' x f ' 2
1 x x
f2
x
So for x < 0 g(x) > 0
x > 0 g(x) < 0
11. As ac = 3 and bc = 4 C
b 4 ba 43 1
(B > A)
a 3 ba 43 7
6 = 4K
B A ba C 3K
tan cot
2 ba 2
1 cos B A 4 3 C A B
cot
1 cos B A 4 3 2 7
C 3
On solving cot 7 cosC
2 4
cos C = cos(A B) or cos C = cos(B A)
C=AB C=BA
(A + B) = A B (A + B) = B A

A (rejected) B
2 2
b 4 b a
But K
a 3 4 3
1
Now ac = 3 3 7K 2 3 K 1/ 4
7
2
R 2K 1/ 4
7
12. y = f(x) = (ln x)2 + 2 ln x

dy 2lna 2 2
1 lna
dx A a, f a a a a
dy f a 0
Also
dx a0
f a 2
1 lna f(a) = 2(1 + ln a)
a a
So (ln a)2 + 2 ln a = 2 + 2 ln a
(ln a)2 = 2 a e 2
or e 2
2 2
Hence a e and b e
So ab = 1
13. 5x f(x) x ln 10 10 = 0
2ln x 2
5x x ln10 10 0
x x
10 ln x + 10 x ln 10 10 = 0
10 ln x = x ln 10
ln x ln10
,x>0
x 10
ln x
As y
x
10
1 ln x
y' so two values of x are possible
x2

ex et 1 ln2 1 t 0
14.-16 We have f x lim 4
0 0 2t3 3 dt form
0
e x e 1 ln2 1
= lim
0 2 3 3 43
e 1 ln2 1 1
= e x lim
4 2 3 3
2
0
ex
=
12
eln 2 1
14. Clearly f(ln 2) =
12 6
x 0
15. We have
g t dt 3x cos2 t g t dt

0 x
On differentiating both side w.r.t x
g(x) = 3 cos2 x g(x)
3
g x
1 cos2 x
3 3
Clearly 3
2 1 cos2 x
/2
16. Let I g x dx
0
/2
3
=
1 cos
0
2
x
dx
/2
3 sec 2 x
=
0
tan2 x 2
dx
3
=
2 2
SECTION C
8 1 2 1 2
1. Tk tan1 2 tan 2 tan 2
k k
1 k 1
4 4
k k
1 1
= tan1 2 2
1 k 1 k 1

2 2
k k
= tan1 1 tan1 1
2 2
11
a c sin 200
2. d .. (1)
cos 200 cos 200
b dsin 200
c .. (2)
cos 200 cos 200
a = d cos(200) + c sin(200) .. (3)
b = c cos(200) d sin(200) .. (4)
a2 + b2 = c2 + d2
2 2 2 2 2 2
(a + b + c + d ) = 2(c + d )
2
ac dc cos 200 c sin 200
bd cdcos 200 d2 sin 200
Also
__________________________
ac bd c 2 d2 sin 200
a2 b2 c 2 d2 2 c 2 d2
So 2 cosec 200
ac bd c 2 d2 sin 200
p=2
AB BD 2 A
3. Since
AC DC 1
Using since law in ABC we get
2 1
1 2 2

sin sin 3 sin3
2 2
3 4 sin2 = 2 3
1 1 B C
sin2 sin = 30 2 = 60 D
4 2
1 3
Area of ABC = 2 1 sin 60 =
2 2
2 3
Hence 12 12 9
4
4. Since diagonal is a member of both the families so it will pass through (1, 0) and (1, 1)
Equation of diagonal AC is x + 2y 1= 0
Since one of the vertex (3, 2) which does not be on AC, so equation of BD is 2x y = 4
9 2
Point of intersection of AC and BD is P ,
5 5
3 14 12 5
If vertex B is (3, 2) then vertex D is , also BD (say d1)
5 5 5
1
Area of rhombus = d1 d2
2

1 12 5
d2 12 5
2 5
d2 = 10
5. We have f(x) = f(3 x) on integrating w.r.t. x

f(x) = f(3 x) + c
Put x = 0
f(0) + f(3) = c
32 + 46 = c
c = 14
12
3
Now let I f x dx

0
.. (1)
3
I f 3 x dx
.. (2)
0
3 3
Adding (1) and (2), we get 2I f x f 3 x dx 14dx 42

0 0
a3 b3 sin3 20 sin3 80
6. =
ab2 sin20 sin2 80
3 sin 20 sin60 3 sin80 sin240
=
4 sin 20 cos2 10
3 sin20 sin80 3 cos30
= 2

4 sin 20 sin 80 4 sin 40 sin 20 sin80
3 cos 30
=
4 sin 20 sin 60 20 s sin 60 20

3 cos 30
= 3
4 1
sin60
4
7. f(x) = 6P 4P cos 4x 5 3 cos 3x > 0

5 3cos3x
2P >
3 2cos 4x
5 3cos3x
2P > max value of
3 2cos 4x
53
2P >
32
P>4
Smallest P is 5

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1

PHYSICS CHEMISTRY MATHEMATICS

4. Apply superposition of currents in each resistor due to each cell to get

6. Intensity in absence of lens = P/4r2

7. apply work-energy theorem

13. At closest approach velocity perpendicular to line joining particles

16. System rotates about CM i.e. middle of 4M and M(Q)

1. For circular motion of a body tied to a string on a horizontal plane

5. In steady state potential difference across each capacitor = E

6. [Cu(CN)4]3 is square planar and contains Cu (I) which is colourless

16. IInd part was treated with dil. HCl/BaCl2/H2O2.

H3C CH CH2 CH3

5. 3Cu + 10HNO3 3Cu(NO3)2 + 3NO2 + NO + 5H2O

6. Only CO and CH4 react with O2, N2 remain uncreative

Mathematics PART III

1. A, B, D are always true but C is true only if the triangle is equilateral

2. f(x) = cos x + cos(x + 2) + cos(x + ) = (2 cos + 1) cos(x + )

2sin3x cos x 2sin3x cos3x

sin3x cos x cos 3x

2sin3x sin 2x sin x

tan3x tan2x tan x dx = tan3x tan2x tan x dx

Now K(PC PB) = r 42

7. Vector perpendicular to 2i j k and i 3j k is

8. (A) f(x) = cos(sin x)

9. Let the number be (a d), a, (a + d)

10. f(x) > 0 and f(x) > 0 for x < 0 (0, 1) 1

12. y = f(x) = (ln x)2 + 2 ln x

5. We have f(x) = f(3 x) on integrating w.r.t. x

7. f(x) = 6P 4P cos 4x 5 3 cos 3x > 0

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