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    GOC Sheets

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    IIT Kalrashukla DPP for GOC

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    SUT? CHEMISTRY KALRASHUKLA DPP Roll No. Date (JEE ADVANCED -2018) Frectoa Pecblome Name :_Kudhygra Sonoma Branch: |—__ Daly Practice Pro Batch : 12" BATCH (2016-18) GENERAL ORGANIG GHEMISTRY n=” HYPERCONJUGATION se Write the number of a-Hydrogen in the followings He. He, cn, - J Te ae ieee hue 4, a cH, H.C CH, CH, S & § CH, CH, Ke Me HC CH, peo 1” Arrange the following in decreasing order of stability of the followings (most stable —> least stable) HE, HC ren CH, BLA fo oO ce a ae ay i CH, ‘CH, CH, Ho w ae cn) ca cn ct, PF ON cas = cal a CH, oF: CH, mx O&A o ati i ‘thy 0, a cH, H, HC, HG HG cH, CH, YS HC S A we Oo ay ay vA © CH CCH, (i) CH, -CH=CH-CH, CH. cis (iy CH, -CH=CH-CH, (IV) CH; - Ch - CH= Cb Trans oe, cH, : HCH), eo We 6 @ Oo a Oo avy) 31¢ The maximum number of no bond resonating structure around a carbocation ? (32% The number of no bond resonating structure is/are: 8 (CH, ),C-CH-CH(CH,), 3K Which of the following o-bonds participate in hypreonjugation ? 1 1 H H+ CH, ai i IV tl (A) Tand IL (B) Land V (Manav () Mand Iv HEAT OF HYDROGENATION 34 Heat of hydrogenating is minimum of (A) CH= CH (B) CHs— CH=CH; (©) Clh- Ch - CH () CH ~ CH ~ C= CH CH CHs 38 Rank the following alkenes in order of decreasing heats of hydrogenation (largest first) “NF Saat EN 1 3 4 (A)2>3>4>1 B) 24>3>1 (O1>3>4>2 MD) 1>4>a>Z, CH, ce CH, ae U o CH, On oO (a) (i) Which of the following orders is correct for heat of hydrogenation of these compounds ? (@)I> > (B) I> U>1 (u> m1 ()M> I> 3% Which of the following has the most negative heat of hydrogenation ? SS “ ‘Ce ® Ge oO oe ©) ol Incorrect order of Heat of hydrogenation per n- bond is wA—,. \_/ OO HEAT OF COMBUSTION el «El Oone< aX a Cc) a O Arrange the following in decreasing order of their heat of combustion: fe op>—<] o><] wo <> ey) Sa cL of my wl (WE >Wt 4%. Arrange the following in increasing order of their heat of combustion: A a) (ir) {> ie “oy ra sor an cam) oar) £ 5. Which one of the following has the smallest heat of combustion ? cH, cH, on, a) (A) ® © ©) HC HC HY uf (CH). CCH), C(CH))s C(CH,), a) ; 6 0) oe & © os @) 10, (11) 1. 6) 12, 13. (10) 14.) 15. (5) 16 (4) 17. 18. (8) 19. @) 20. M>I>Il 21. 2, U>lt>l 23. MW>1>T 24. I>H>I 25)? SSE 26. I> > 27. I= nl 28, «I> 29, [> I> > IV 30. [> 11> I>1V a.) 32.) 3. @) 34. (D) 35. ©) 36. © 37. (A) 38. ©) 39. W>M>1 40, >>I 41. W> I> TVaT 42, 1 least stable) St x A + Oo OM ap aN ay) aS oJ CH, -NO, CH, NO, Oo No,-cH, -¢° a clegHee CH, -NO, CH, -CL NO, ie dl) NO, -C® (IV) CH,-C® NO, _+ cx, oO @ e @ CH, (oy Cu, Cu, a oO, ap oO a © CH, gnc OD to, CT, eu, Ch, oy, xo o A a 3) Oo CH, CH-CH, CHCl, cH, “ a) aly ie ® wo Le a ay KX of i of 152 wsiong XK ® cy @ ap i da Cy (vy) oO (vy) or os “CH, 2 x oO a Q am ay) od CH, cH, 4/ wenec-cn, EH, (I) CH: = CH CH -CH, a CH, 2 CH, OH ) {O @ ay ae Reon. @ eu, CH, eu, CH, ”~ 0 @ On ap @ ‘CH, at Hy SH ad °CH, “ca, “CH, wo Co a ©. ay ‘OCH, Ten at ICH, 21 gama e Sy eu, a, No, JE Oo @ amy 2 NO, w I NO, Bo bi a (O)- (a > 3 <) wy) ca, —C—cH, CH, 36. Which one of the following is most stable carbocation? ae: &Q Pade? ZA. Which one of the following is most stable carbocation? ® 6 (@ H,C=CH (a) A (aD CH, (dv) CH, —CH=CH ANION STABILITY Arrange the following in decreasing order of stability of the following anion (most stable + least stable) 2%. ()°CH; (1) CH;—CH:° (II) CH;—°CH-CH; (IV) Cit = foe CH, CH, ° ° OOH, -CH-CH, CH, CH, cH, CHG CARD CH,-CH, CH, ~CH, -F F ca -t a a a 2 wcr-cu® ay CH, CH, iy C-cH-@H, avy ci-c-n, | +L t “2 (oe = at ioe + eh (OSCHs () CHs-CH.° (Ul) CH, = CH® qv) cH=c® “I _ ER. a 2 wy O CH,-CH, (y cH=e (ip CH, aca (IV) Phe x +) * ad oO ay ch, 2 cH CH, a) a. by BS ae eu, eu, CN 7 cat & Oo w Pat ' -1 8 Su, & &, Ser, NR, NH, a) a a) Drew ae cu, cu, ca, Mo eee ay wo w(lO aD “) cu,*4 cp, +t CAT cu, eH, cu, cu, or ro wo) wOl, ool ©, Lig ol “I a = ‘ cHy-CH, “CH “CH, “CH, ren cites pp o ay Co) ay a) © Ko; = i CH, Tea Tyo oe cH, ©cH,- CH, be a “nut Qt, ~Iy mn 8 CH, CH, Ko ee D @ CH, OCH, EO “Tem ° CH, OMe gx © [OJ Kn" se x » © al cc. pacer oO NO, 4 OS lem i ACH 3 o [0 swat oO OCH, # of e of) a a ay ® qa) ap ay oO CH, CH, oO ay © CH, at nee CH, CH, oO qa (9) Eres Bn tu, cH, (mye © HB sore © A o — Co o oO ay © NO, NO, o o (0] (a © pe cu, * yet o oO Oo a © “<™0cH, OCH, 4 ay av) FREE RADICAL STABILITY ‘Arrange the following in decreasing order of stability of the following anion (most stable + least stable) x o éy,, QD CHa-CH, (HD) CH CH-CHs avy chs E-cHs CH Nos F yx Ohh ay ch 45, Rankin order ob radical stability (1 = most stable). oC ® Oo a Ger w) ri BP 2 Allylic FE Alyhe ad Rank the following alkyl radicals in order of increasing stability leas <<< most) Ph oo 66 i es 3 @Macaci<3 — 3Velves 2, MxI 4. > M>1>1V 5, IVv>l>M>i 6 W> > Dae 7, I> Il>W>1Vv 8. 1xl> I> IV>V 9. > i>¥ 10. Iv>1>m>IL i eT 12 V>l>Iv>t>Il 2B, [> Wl 14, W> Ha 15. M>I>0 16, I> I> V7. Webi 18, W>Il>1 19, 1>H>1V> Il 20. ©) a 22. [>W>M>1Vv 23. 1>I>Il 24. >> WT 2s. W>it>1>l 26, U>Iv>il>T 27. W>1>0t 2g, I> 1> I 29, 1>IL>Ill 30, Iv>I>Il>1 31. 1> 11> I> 1V 32, I> Il>I>1V 33. IVMf> 1 35. W>M>1 36, W>T> tll 37, HRT Co 38. I> 39, 1> > TL 40. W>Il>T 41. 1>1>1l 42, 1>Iv>i>1 43. IV> I> T>T 44, Iv I> i>t 46. © 47, A,B,BOd Name: Roll N Date Batch : 12" BATCH (2016-18) MILT 7 KALRASHUKLA Branch: CHEMISTRY DPP Daily Practice Problems (JEE ADVANCED -2018) on} ACIDIC STRENGTH Arrange the followings in decreasing order of their acidie strength x McK (i) NEb (I) H20 (vy) HF ? i Tt Octet on qa) cnr B oat (aly Coe coe cl ca X— ()F-CHy-CH;-O0-H (1) NOy-CH,-CH,-O-H ® (11D) Br-CH,-CH;-O-H (IV) NH-CH>-CH,-O-H 4. (CH () PhCH (il) PhC= CH a) Cita Laos ‘i oO fe zz (1) CH3;-CH-O-H_ = (II) fe eres ap co ark CH; CH; «x of \ ON af \ COOH ‘COOH COOH COOH ‘COOH, ‘CH;-COOH x of a) cH amy COOH “=o CH,-COOH, i i 8 ONorcH-C-0-H (I) PCH C-O- t i aly prc t-o-H (IV) CH;-CH;-C-O-H OH OH 2. OA mM“ (ay A” Pllutic A. ia, Br ch OH oO F (® CHCOOH (i) CH;CH,OH © Ph—CO,H (HD) Ph—CO,H OH oO (il) HC =C-OH “Spats oH OH 0 0 wey NO. * Geed'r OH 6 @ @ oan -0H aw cl RAL OH ay Br Br (UD) CoHOH (IV) Cal4SO3H (i) Ph—CH, —OH avyph—cx, —NH, () CH= CH-OH OH of) Br OH oH lta a wo 292 2? a) : ou Ou - 6 H fevers oH GH NO; NO: 102 a av) NO, NO; a Bbseding ye 3, “Q cH, ~Loam = H, ca. ap ay Eat FC 2 wpe en axe { 05 ‘NO, tn Saye q COH CH; «iy TH orthneliyd COOH ‘Br ay, = Tem a ° Ii oe I COn ~-O-H a OL, ay cri ‘OMe g -O-H a oy NG: ima NH, a) Cr (UD PLNE, wo) Br 35. Which is weakest acid in 1? (AVA (@)B @c @)@) 36. — Which is the strongest acid in 2? (AYA ()B @c (@)) a7. Which is weakest acid in 2? A BB Oc Oo) 38. Which is the strongest acid in 3 ? (AA @)B oc 0) as Which weakest acid in 3? is 2 (a ®B oc ©) 40. Which is the strongest acid in 4? (AA ®B oc ©) ©) 41. Which is weakest acid in 4? aA ®)B oc @)®) Tdentity the most acidic hydrogen containing compound from the following. 2D @©) Qo oH, or 43. eS oe on © 44. (a) 0) CH.CH, 0 6 oA, © AA Cass CH; ae 46. (a) oy on ‘Arrange the following in increasing order of pKa values 31. () HINO; 32. (1) PhCH (i) 120, (i) HCH (IV) CH;CO2H (V) PhOH a Cae CHEM ll ° 0 (HD CF;COnH (Vv) Nis 33, @PhCHs a) HON (1) HCO3H (ly) HOH Paragraph Q. from 34 to 41: Problem A B C D ie eo Cor en Co 2. On OCH, Ce ie oO cy 5 ON \ 3. 9 <5 = a NH “ F Te q eel| oN ‘CON oN ON 1c 1 cot Cre Cros Orbe a j 34. Which is the strongest acid in 1? AA @®)B @c ©) ©) 47. Which of the following is the strongest Bronsted acid? NA, NH, OH on ie Og OQ o O o O 48. Among the given pairs, in which pair second compound is more acidic than first? 0 0 I Il (A) BrCH:NO> and sci (B) CH, -CCH,CN and CH, ~C-CH, “G9 Ge 49. Rank the hydrogen atoms (Hl, Hs, H.) in the following molecules according to their acidic strengths Ajarb>e @)b>a>e (©b>e>a @)a>e>b 50. Arrange the following in inereasing order of acid strength. oo H OH o, COOH @ HOS al HCH, CHSH (A)c SOs COOH COOH COOH a OH. °O-O ~O-6 ocr, COOH IV>ii>>T 2 >>I 3. IV> I> I> TE TRIS WK IV 5. I> > 6. I>u>1 1> >I 8. 1>1I>MI>IV 9. I>I> ml >> M. IV>I> I> 1 12, U=I>IV> WUXI XIV 4. W>1> nv 15. IV>Il>0I>1 1> > Wl 17, IV>MI>I>1 18. I> >I M> >I 20. IM>I>T 21. >I m>1 23, I> II>1 24. T>1> 1 TITS 1V XI 26. I> U>M 27. I> I> I>v u>1> 1 29. I>IV> I> 1 30. WI>1>0 1>V>IV>HI>1 32, I>IV> >IT 33. [>IV>1>m @) 35. (A) 36. ©) @) 38. (A) 39. @) @) 4. 42. (©) ®) 44. @B) 45. (B) ® 47. ©) 48.) © 30. (D) SI. b>e>d>arc a>c>b>d 53. R>T>P>Q>S 54. ©) SS SUT? __ CHEMISTRY KALRASHUKLA DPP Daily Practice Problems (JEEADVANCED -2018) Roll No. Batch : 12" BATCH (2016-18) BASIC STRENGTH Arrange the followings in decreasing order of their basic strength SK Ment, (ft) Me,N (ID MeN, .,.,,.., (IV) NHs Protic solvent) a eye : 2. ()EuNH “BUN (Uy) EINH, (IV) NHs (Protic solvent) AE Men (1) Me:NH (I) Me-NH2 IV) NH (vapour phase) kK Ot, @y NA, (ay on” - ayy / @ ° e é A (OCH; (y NH, (uy OH ave 8 2 8 ° 6 wf @ cl (a Br ays 7. ONES HO (ay ths (IV) PHs ONE ()-0H (a) -cH (IV) CHSCHy 9. (70H ()CHs-O 5 (ll) CH-OH (IV) CHs-CH-OH 10. (-CHs (I) CH= CH- ° i i. OH (ty H-C-0 t 2 @cr () H-C-0® (I) CH= C~ ° ° 00° goo? i li e 6-08 -c-0° 13. H-C-0° (fy CH,-C-O' mO avy) NO: NO; 20. 21. NH, oO @RNK of NH Nn, ® } R NEL oO e NHy Ochy-CHNiy o Cu 6, ay Crete NH o fs ' H in oJ h i N-cH, #6) (1) Ph-NH2 aQ me N mM £ iin, @ oO cr (1) CHs-CH=Nit “0 CH,-N~CH, ay (a RENE 0 ay O it , cm £0) Nu, » CHS ()cH;-cat (I) CHy-CH. NH, +1 QV) Nig NH (VY) NH3 1 cH,-N-CH, avy) NE av) H 24. @ ay NO; oN et ~ Tam Ni Nn, 25, 6) NO» NO; NMey, NMex 2% 00 oO) ‘OMe OMe Ne. Nu, Me, Me 2 @ [LO wm. fo Me: Me an of So ° s Sdn, fa, SH-CH,-CH, 28.) CS qa) am) Nn, fin, 29. ay pe (ay Pearce er x TH H Nu fin NH, S cH 30. OL) qa) i (ay NH, a of a (HD) CHE, & Owl 2 an) Nx IV) « 32. 0 N qu) * ay) x Lstahyed a ae pascateed 6 serene) Aaa © cons H NO NO 34. i fp ay to aD é > ayy HN iaham van : E 1 w WN ofoen {Ss if Mat, 1 3. © Jt mC Ong Ee HN “HN HN cH, ane ia ° 36. of) a O Lin Bain PSondad 32. © yu oC ya 0 iy Oo Nt OD aH) NA Coot of F ah (rhamnaye Sicha ee ) H,c-Cu,Ra (I) HC-CH,ONa (IV) HCeGNa 5 “heel 4 (Opn ®0)-cr,-Ni a} NH IV) ‘C_NH; a ( Oy 2 NO: incertae) © 2. ieee is eoueel: we B) v wy 2s? ®) NMe, NMe, : Me. Me M Dre “or : © NMe, NMe, ©) NMe, NMe, Me. Me Me > > git ste 43, Correct order of basicity is : (Ay3>1>2>4 (B)3<1<2<4 — (©)3<4<1<2 — D)3>4>1>2 44, Which of the following acids would have a stronger conjugate Base ? 9 NH NH MHS vs HO «ay vs CO) i 2 0 3 4 (ill) CH,C=CH vs CH,CH=CH, & 6 (A)2,4,6 (B)1,3,5 (©)2,3,5 ()1,3,6 fe Correct energy profile for amine inversion and hybridization of nitrogen in transition state is : AN a? rt Hpt = \yQ/ i @ ®) sp sp ®) “ /\. B) 7 ® & 1a Estee L____, te gp - © J\ ) ~~ Pj ®& Several factors (steric, electronic orbital interactions etc.) can affect the inversion barrier of an amine. In the given pair which data is correctly placed? pe \ x, vs N Me i-pé ‘Me Dkealimol AG’ = 0.2 keal/mol » A ‘Me AG? =20.5 kcal/mol AG’ =7.0 keal/mol Me Gt M vs N © MO Me Nc AG’ =7.9 kcal/mol AG = 22.9 keal/mol ©) All of these lll SSS Select the strongest base in following compounds - “ Q “QO © O © O i i H H H 49. oD ° oo °& "0 H I H H . Me | | i N ; ‘y oo > T>Il> I>I>M>IV . >i I >IV 4. I>I>I>Iv 3. I>I>m>Iv 6 [>> TI> Iv 7. T>>IV>T1 8 IVa M>I>1 9. I>I>Iv>m 10, WRIT MW. [>>0 12, M>m>1 13. >I>IV>m M4. I> IV>I> 1 15. I> I>1>1V 16. 1>1>II1 17. MI>M>1 18. MI>I>01 19. 1>M>1 20. I> IV>I>1 21. I> n> a 22, IV>MI> >I 23. >>I 24. IV>IN>U>1 25. >>I 26. I>I>Il 27. >I 28. T>m>1 29. > m>1 30. >> 31. I> I>T 32. I>I>Ivem 33, >>I 34, IV>TI>1>1 35. I> I> IT>1V 36. M>I>T1 37. 1> I> 38. >>I 39. [>> 40. Pep Welt Es yy 41. >1>m>Wv 2 ©) 8. ©) 44. (A) 45. () 46.) 47. D) 48. B) 49. © 50. (A) SIT a CHEMISTRY KALRASHUKLA DPP Bela Apert Daily Practice Problems (JEE ADVANCED -2018) Name: Branch : Roll No. Date Batch : 12" BATCH (2016-18) [GENERAL ORGANIC! ELECTROPHILE AND NUCLEOPHILE Y¥ Which one of the following iShatRophile in character? (ANE; By cc (CIRC = CH: @) AIC Gandkss be swe 6 Anelectrophile among the following is— (A) NH (B) CH3NE2 (ko @) AIC oA Which of the following species is an electrophile? (A) NH @®) Or (©) CH (D) SO; 4 Which is not considered as electrophile. (A) -NH, @)- (-cr (®) -No, RESONANCE Arrange the followings in decreasing order of stability ° ° SS (A)CH,-O-CH, © @) CH, =b-CH, (order of stability) o o of | Hs @n-t-one (B) H-C= ° | I -H«> (C) H-C-0-He (@) H-C-O-H 7 w& AZ - 8) ae é © ON : © ay be oe Be ate ; & AYN aso ®) AX a © AA ® wi 2s 12. AL. 14, Which of the following is not resonating structure of each other? (A) CH; —-N=C=S and CH; —s— @) cH, —C=0and cH, —C=6 ° i (© CH, —C—OH andcH, —C= (©) CH, = CH—CEN and CH, —CH=C=N- Some pir of ions are given below Jn which par, first ion is more stable than second? (A) CH, —CH- ~ CH, and CH, CH OCH, tore bes stot , 8) CH=CH cu—cn, . ana CH, =CH—CH, CH, ADYLE moe stable, ou, én, © ee and or CH,—CH—CH, | | CH,—N—cH, ©) and i CH, —b,—cH, CH, —C°—CH, ‘The most a Tepresentation of resonance structures of p-nitrophenoxide ion is : Q 9 “ a 4 “A ‘0 \¢ “ 0 ®) o © G © oO o oO ‘Write the resonating steuctures of followings: Oe JZ t t @ O ®) ©n-c-o-n — O)n-c-iy>x (B)x> (C)y>x>z @)x>z>y ME C-Cy bond length shortest present in i-C=CH 1 C=CH, 1 du —CH; L @) CY ® oF © Ear © Ci 19, Arrange the following compound, in order C-N bond length. M Me ie e fe a ) @®) No, = NO, Me NO, Q Me © = ©) Me No, 20. 21. 22. 23. 24, 25. Arrange in order of C-H bond energy a HOH, H-CH-CH-C-CH, Te Ib He CH, tee H Compare the bond strength ofthe indicated bonds inthe given compound: H, (ay1>3>2 (B)3>1>2 (C)2>1>3 @)2>3>1 Compare the bond strength of the indicated bonds inthe given. Compound : K ; (AJL >3>2 (B)3>1>2 ape ()2>3>1 Compare the bond strength of the indicated bonds in the given compound : (a) 2 (B)1=2 ©2>1 (D) can not be predicted Which of the following sequences regarding ease of abstraction of hydrogen atom is correct? (Ay3e>2°> 12 @B)3°<2P< 1° (C)3°<2°>12— M)3°>2°< 1° Which C—N bond having more bond strength. Be Na, Na, © Na, (A) 1H, )) CL. (c) CHO @) O.. Which one of the following statement is not correct? (A) Amines are stronger bases than water. (B) Basic strength of amines decreases in the following order : R3N > R:NH > RNHb (In gaseous state). (C) Carbon-nitrogen bond length in aniline is shorter than that of C — N bond length in hydrogen cyanide. () Aromatic compound has (4n + 2)z electrons in the loop. 30. @ 8 Js Compare the bond lengths ofthe indicated bonds in the given compound rele (Aya>b (Byab=c (C)azb=e (D) Cannot be compared Compare the bond lengths of the indicated bonds in the given compound : oP en, (AA>d B)ad (Baxb (a=b (D) Cannot be predicted Compare the bond lengths of the indicated bonds in the given compound : 659 (Aya>c>b @)e>a>b (Qb>c>a (D)b>arc ‘Compare the bond lengths of the re in % piven compound on (A)a>c>b (B)e>a>b @vreta @)b>a>c Compare the bond order of the indicated bonds in the given compound : ° ° all ell, H, —C+0° CH, —S-£0° 4 (Aja=b=e=d Bee (C\a=bB>C>D < B>C>D>A A>C>B>D ot) 10. @) ML. 2. 3 Q ap al 0. we a, - a, J a sats De) oro orks Oo: O “OO Bog Resonance Hybrid Ai Hs Nis Nib » Mh »&- G-- 8 8.8 = Resonance Hybrid oF 3 © wh, HCNH,SH-C=NH. H Resonance Hybrid ) 4 © 15. @B) 16. @) 18. (D) 19. D>C>A>B d

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