SPLIT1

COMPRES5 97.2% syngas recycle

Gas Purge
Stream Composition Stream Composition
24
Oxygen
93% oxygen
SYNREC 25 @ 67C, 1 bar
(to furnace for energy)
NGAS 91.6% methane, 5.72% ethane 28 98.6% methanol, 1% water
@ 104 c, 12 bar COMPRES2 52% CO2 O2 93% O2, 2% N2, 1% Ar 29 41.8% water, 40.8% DME, 17% methanol
COMPRES4 23% H2 TURBINE1
104 C, 29.6 bar HX4 HX5 HX6
141 C, 48 bar 12% CO HPSTEAM1 100% water 30 41.8% water, 40.8% DME, 17% methanol
O2 7 5% argon 78 % carbon dioxide
15
51.3% CO2 3% nitrogen 11% methanol HPSTEAM2 100% water 31 71.3% water, 28% methanol
23.5% H2 4.4% hydrogen
HX1
12 13
75 C, 28.3 bar
18 11.8% CO
22 CO2PURGE
2.2 % carbon monoxide 1 91.6% methane, 5.72% ethane 32 99.99% methanol
3.5% methanol @ 25 C, 1 bar
HX2 21
2 91.6% methane, 5.72% ethane 33 98.9% water, 1.1% methanol
940 C, 29 bar 400 C, 28.9 bar 151.7 C, 48.2 bar FLASH2 (to furnace for energy)
1
Preformer @ 68C, 47.5 bar 3 100% water 34 98.9% water, 1.1% methanol
@540C, 33.3 bar 11
4 100% water 35 99.8% water, 0.2% CO2
17
540 C, 33.3 bar
NGAS HX3 14 68 C, 1 bar
5 48% methane, 24% H2, 17% water 36 45% N2, 35% CO2, 15.3% water
2 FLASH3
Natural Gas
52% CO2 @ 25C, 1 bar 6 48% methane, 24% H2, 17% water 37 45% N2, 35% CO2, 15.3% water
5 6 9 10 22.7%
91.63% Methane FLASH1
@ 35 C, 34 bar 7 93% O2, 2% N2, 1% Ar CO2 PURGE 78.4% CO2, 11.2% methanol
V1 940 C, 29.6 bar
@ 75C, 28.9 bar F23
@540 C, 33.3 bar
4 540C, 29.6 bar 8 100% water EMISSION 45% N2, 35% CO2, 15.3% water
Methanol

@ 450 C, 29.6 bar

23
Synthesis 26 9 52% water, 21% O2, 14.5% methane F23 60% methanol, 34.9% water, 4.6% CO2
HX3 Reformer @ 250 C, 48 bar
COMPRES1 59.8% methanol 62.7% methanol
10 52% water, 21% O2, 14.5% methane FREEAIR 78% N2, 21% O2, 1% Ar
@ 940C, 29.6 bar @141C, 48 bar 25C, 15.7 bar
36.9% water
HP Steam 3 Water
35.1% water
4.6% carbon d io xide
11 63.6% water, 18.8% H2, 11.1% CO2 H20PURGE 99.8% water, 0.2% CO2
HPSTEAM1
@ 230 C, 9 bar
COMPRES3
16 35 99.99%
@ 75C, 1 bar PUMP1
12 63.6% water, 18.8% H2, 11.1% CO2 H21 51.3% CO2, 23.5% H2, 11.9% CO, 3.5% methanol
13 63.6% water, 18.8% H2, 11.1% CO2 H23 60% methanol, 34.9% water, 4.6% CO2
HPSTEAM2 8
HP Steam DHX2 98.7% methanol 14 63.6% water, 18.8% H2, 11.1% CO2 HPMETH 99.99% methanol
@ 230 C, 9 bar @147 C, 15.2 bar DHX1
27
15 63.6% water, 18.8% H2, 11.1% CO2 HPWATER 98.9% water, 1.1% methanol
HX9 DME Catalytic Plug Flow Reactor
Dimethyl ether (DME) @ 17 C, 5 bar @ 300 C, 15.1 bar METHA2 16 100% water LDME 98.6% DME, 1% CO2
@ 21 C, 5.1 bar
98.5% 300 C
500 tonne/day LDME VDME 17 50% H2, 29.8% CO2, 13.9% CO VDME 98.6% DME, 1% CO2
@ 17 C, 5 bar 28
18 52.1% CO2, 23.9% H2, 12.1% CO METHA2 98.7% methanol
29 Reactor Dimensions:
HX11 P1
19 50.6% CO2, 25.8% H2, 12.2% CO RECYCLE 99.99% methanol
DHX3 P2 6.15 m in length
1.55 m in diameter
20 50.6% CO2, 25.8% H2, 12.2% CO RECYCLE1 99.99% methanol
Dimethyl Ether
Distillation 40% dimethyl ether
32 21 51.3% CO2, 23.5% H2, 11.9% CO SELL 99.9% methanol
Boilup: 2 40% water 22 52.1% CO2, 23.9% H2, 12.1% CO SYNREC 52.1% CO2, 23.9% H2, 12.1% CO
Reflux: 8.75 18.8% methanol
69 C, 1.2 bar
Stages: 35
@14.5 bar, 300 C 23 60% methanol, 34% water, 4.6% CO2 WATER3 99.99% water
P3 99.99% methanol
@ 67C, 15.2 bar 24 52.1% CO2, 23.9% H2, 12.1% CO
129 C, 5.1 bar
31
25 52.1% CO2, 23.9% H2, 12.1% CO
Methanol and 26 62.8% methanol, 36.8% water
Methanol Water Distillation 27 62.8% methanol, 36.8% water
Recycle Distillation PUMP2 Boilup: 5.21
Boilup: 8 RECYCLE1 Reflux: 1.88 HPWATER
Reflux: 2.1 KREBOIL3 Stages: 30
Stages: 25 KREBOIL2
KREBOIL1
99.99% methanol
99.99% Water @ 67C, 1.1 bar HX10
@ 105 C, 1.2 bar WATER3 30 C, 1 bar Water
Methanol 99.99%
(LPS recycle)
(for sale) 99.99% @ 199.1 Water
RECYCLE METH SELL @ 30C, 1 bar 99.99%
@ 199.1 C, 15.2 bar
SPLIT2
(use as HPS)
99,9% methano l recycle