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EFKA Guide
EFKA Guide
Ciba Specialty Chemicals trademarks (All trademarks mentioned are either property of or licensed
to Ciba Specialty Chemicals and registered in relevant countries)
Contents
Defoamers 5
Ciba EFKA 2000
Dispersants 7
Ionic Dispersants 7
Ciba DISPEX, Ciba EFKA
Non-Ionic Dispersants 8
Ciba EFKA 4000 High molecular weight dispersants
Ciba EFKA 5000 Low molecular weight dispersants
FAME (Fatty Acid Modified Emulsifiers) 11
Ciba EFKA
Rheology Modifiers 12
Ciba VISCALEX, Ciba RHEOVIS
Miscellaneous 14
Ciba EFKA 6000
Product Selection Guide for Surface Modifying, Dispersion and Rheology Additives Ciba Specialty Chemicals 2006
Introduction
This booklet provides a comprehensive list of additives in For more detailed information on specific applications
the Ciba Specialty Chemicals range for Dispersion, and product control please consult our marketing
Rheology and Surface Modification. department or local sales organizations.
The products are divided into five main categories: Further technical product information and details on use
defoamers, slip and leveling agents, dispersants, rheol- in food packaging materials, toys and other consumer
ogy modifiers and grinding resins. goods (EHS data) are available on our Internet site at:
The dispersant classes are subdivided into Ionic, Non-
Ionic and FAME dispersants.
www.cibasc.com Products
Products, processes and services from Ciba Specialty Chemicals enable you to create effects that add performance,
protection, color and strength to your coatings.
Registered trademark
Recommended
4
Product Selection Guide for Surface Modifying, Dispersion and Rheology Additives Ciba Specialty Chemicals 2006
Defoamers
Ciba EFKA 2000 defoamers are used to inhibit the build-up of foam and reduce foam or trapped air by causing the
bubbles to burst and so release the air. This series provides two kinds of defoamers:
Silicone-free
Silicone containing
Solventborne coatings
Waterborne coatings
% Active content
% Dosage *
Product name Chemical type Description/Application Incorporation
Silicone-free
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Product Selection Guide for Surface Modifying, Dispersion and Rheology Additives Ciba Specialty Chemicals 2006
Solventborne coatings
Waterborne coatings
Slip and leveling agents based on polysiloxane
% Active content
Reactive slip and leveling agents based on polysiloxane
% Dosage *
Silicone-free leveling agents
Solvent blend of high-boiling Flow agent, prevent surface defects, cob-web- During or after the
EFKA 3037 3-5
aromatics, ketones and esters bing, streaking, chilling, shorten setting time batch preparation
Solvent blend of high-boiling Flow agent, prevent surface defects, blistering,
EFKA 3038 Any stage 5-7
aromatics, ketones and esters cob-webbing, chilling, shorten setting time
Fluorocarbon modified polymer Solvent-free version of EFKA 3777
EFKA 3277 End of process 0.5-2.0 100
Polymeric fluorocarbon Very strong substrate wetting and
EFKA 3500 End of process 0.1-0.5 50
compound anticratering properties
Fluorocarbon modified Excellent substrate wetting, leveling
EFKA 3570 End of process 0.5-1.5 60
polyacrylate and anticratering
Polymeric fluorocarbon Stoving enamels based on alkyd, acrylic and
EFKA 3600 compound polyester resins, polyurethane, two-pack epoxy End of process 0.1-0.5 100
and air-dried alkyd systems
Polymeric fluorocarbon Modified version of EFKA 3600
EFKA 3650 End of process 0.1-1.0 50
compound
Fluorocarbon modified Strong anticratering
EFKA 3772 End of process 0.5-2.0 60
polyacrylate
Fluorocarbon modified Solventborne or solvent-free systems,
EFKA 3777 End of process 0.5-1.0 70
polyacrylate coil coatings, OEM and industrial coatings
Acrylic polymer Coil coatings, solventborne
EFKA 3778 End of process 0.5-2.0 70
or solvent-free systems
* Dosage: % on total formulation ** Dosage: % on polyol component
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Product Selection Guide for Surface Modifying, Dispersion and Rheology Additives Ciba Specialty Chemicals 2006
Dispersants
Dispersants are additives that increase the stability of a suspension of powders (pigments) in a liquid medium. They are
used during the dispersion process. Ciba Specialty Chemicals offers 3 kinds of dispersants:
Ionic dispersants
Non-Ionic dispersants
FAME (Fatty Acid Modified Emulsifiers)
Ionic Dispersants
Ciba DISPEX dispersants are tightly defined dispersants based on acrylic chemistry. Their narrow molecular weight
distributions provide optimum dispersion efficiency, translating into maximum performance at the lowest possible
formulation cost.
Neutralizing agent
% Active content
Supplied at PH
Density g.cm-1
Product form
Product name Chemical type
DISPEX N40
Sodium polyacrylate liquid 4000 40 7.5 NaOH 1.30
DISPEX R50
Polyacrylic acid liquid 4000 50 3.0 - 1.26
Ammonium polyacrylate
DISPEX GA40 liquid 6000 40 7.5 NH3 1.13
copolymer
DISPEX G40
Sodium polyacrylate copolymer liquid 6000 40 7.5 NaOH 1.20
DISPEX HDN Sodium polyacrylate copolymer liquid 20000 40 7.2 NaOH 1.20
Ciba EFKA 5071 is an ionic wetting and dispersing agent to prevent % Dosage *
settling and flooding of pigments.
Solventborne coatings
Waterborne coatings
% Active content
Bentonite
Inorganic
Organic
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Product Selection Guide for Surface Modifying, Dispersion and Rheology Additives Ciba Specialty Chemicals 2006
Non-Ionic Dispersants
Ciba Specialty Chemicals offers a wide range of products that can be classified in two main groups:
High molecular weight dispersants
Low molecular weight dispersants
The Ciba EFKA 4000 series contains the high molecular weight dispersants. They are linear or branched molecules
with a polyurethane or polyacrylate structure, and have molecular weights of between 5000 and 30000 g/mol. These
products have pendant anchoring groups, which adsorb onto the surface of the organic pigment particles. They are
also effective with inorganic pigments.
% Dosage *
Solventborne coatings
Waterborne coatings
% Active content
Carbon black
Inorganic
Organic
Product name Chemical type Description/Application Incorporation
High molecular weight dispersants for inorganic and organic pigments, based on polyurethanes
Modified polyurethane Butylacetate-free version of EFKA 4009 In the mill base before
EKFA 4008 polymer for architectural paints adding pigments 10 25-50 20 60
Modified polyurethane General-use industrial coatings where cost In the mill base before
EKFA 4009 polymer effective performance is vital adding pigments 10 25-50 20 ** 60
Modified polyurethane General-use industrial coatings In the mill base before
EFKA 4046 polymer adding pigments 25-50 20 ** 40
Modified polyurethane High quality industrial finishes including In the mill base before
EFKA 4047 polymer automotive OEM and refinish adding pigments 10 25-50 20 ** 35
Modified polyurethane Water- and solventborne coatings, as well In the mill base before
EFKA 4520 polymer as RMPC adding pigments 10 25-50 20 ** 33
New generation General-use industrial coatings including coil In the mill base before 20-40 30-60
EFKA 4010 polyurethane polymer coatings and decorative finishes adding pigments 5-10 50
New generation Solventborne industrial coatings. Low viscosity In the mill base before 20-40 30-60
EFKA 4015 polyurethane polymer in high pigmented systems adding pigments 5-10 50
New generation Aromatic-free and low odor dispersing agent for solvent- In the mill base before 20-40 30-60
EFKA 4020 polyurethane polymer borne coatings and universal pigment concentrates adding pigments 5-10 65
New generation High quality industrial coatings as well as resin In the mill base before
EFKA 4050 polyurethane polymer minimal pigment concentrate adding pigments 10 25-50 20 45
New generation General-use industrial coatings as well as resin minimal In the mill base before
EFKA 4055 polyurethane polymer pigment concentrate adding pigments 10 25-50 20 40
New generation High quality industrial finishes, very strong viscosity In the mill base before
EFKA 4060 polyurethane polymer depressing properties adding pigments 10 25-50 20 30
New generation Gives low viscosity in mill-base In the mill base before
EFKA 4080 polyurethane polymer adding pigments 10 25-50 20 ** 30
New generation high molecular weight dispersants based on acrylic block copolymers
High molecular weight dispersing agent for In the mill base before
EFKA 4300 Acrylic block copolymer deflocculation of all pigments in solventborne systems adding pigments 10 25-50 20 80
High molecular weight dispersing agent for In the mill base before
EFKA 4330 Acrylic block copolymer
deflocculation of all pigments in solventborne systems adding pigments 10 25-50 20 70
High molecular weight dispersing agent for In the mill base before
EFKA 4340 Acrylic block copolymer solventborne high-end performance coatings adding pigments - 25-50 20-40 55
High molecular weight dispersants for inorganic and organic pigments, based on modified polyacrylates
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Product Selection Guide for Surface Modifying, Dispersion and Rheology Additives Ciba Specialty Chemicals 2006
% Dosage *
Solventborne coatings
Waterborne coatings
% Active content
Carbon black
Inorganic
Organic
Product name Chemical type Description/Application Incorporation
Modified polyacrylate Resin minimal pigment concentrates based In the mill base before
EFKA 4403
polymer on alkyd resins adding pigments 10 25-50 20 ** 55
Polyester modified Developed for areas were nitrocellulose and acrylic In the mill base before
EFKA 4406 polyacrylates coating systems, also for RMPC adding pigments 10 25-50 20 50
Modified polyacrylate Waterborne industrial coatings In the mill base before
EFKA 4500 with self-emulsifying adding pigments 10 25-50 20 ** 50
properties
Modified polyacrylate Water- and solventborne industrial coatings In the mill base before
EFKA 4510 10 25-50 20 ** 50
polymer adding pigments
Modified polyacrylate Waterborne industrial coatings. Solventborne RMPCs In the mill base before
EFKA 4530 10 25-50 20 ** 50
polymer including NC lacquers adding pigments
Modified polyacrylate Considered suitable for VOC-free applications in In the mill base before
EFKA 4540 10 25-50 20 50
polymer industrial coatings adding pigments
Modified polyacrylate Considered suitable for VOC-free applications, In the mill base before
EFKA 4550 10 25-50 20 50
polymer PH independent adding pigments
Polyacrylic Considered suitable for VOC-free pigment concentrates In the mill base before
EFKA 4560 10 25-50 20 40
for waterborne decorative paints adding pigments
Modified polyacrylate Water- and solventborne coatings, In the mill base before
EFKA 4570 10 25-50 20 60
polymer considered suitable for RMPCs and RFPCs adding pigments
Acrylic polymer High molecular weight pH-independent dispersant for In the mill base before
EFKA 4580 emulsion deflocculation of all pigments in aqueous coatings and adding pigments 10 25-50 20 40
pigment concentrates
Modified polyacrylate Waterborne industrial coatings where cost effective In the mill base before
EFKA 4590 20-30 30-70 60 40
polymer performance is vital adding pigments
Modified polyacrylates UV-curing industrial coatings In the mill base before
EFKA 4800 10 25-50 20 40
in a reactive diluent adding pigments
* Dosage: Inorganic % of Oil absorption ** Dosage: carbon black- % of DBP based on solid dispersant
Organic % of BET value Dosage: % on pigment weight
Carbon black % on DBP value
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Product Selection Guide for Surface Modifying, Dispersion and Rheology Additives Ciba Specialty Chemicals 2006
% Dosage *
Solventborne coatings
Waterborne coatings
% Active content
Bentonite
Inorganic
Organic
Product name Chemical type Description/Application Incorporation
Acidic polyester polyamide All types of industrial coatings, Mill based
EFKA 5010
especially for inorganic pigments
5-10** - - 50
Unsaturated polyamide Solventborne or solvent-free coating In the mill-base before
EFKA 5044 & acid ester salts systems. Also for bentonite gels adding pigments
0.2-2.0 2.0-5.0 30-50 52
Carboxylic acid salts Non-polar to medium polar coating In the mill-base before
EFKA 5054 systems. Also for bentonite gels adding pigments
0.2-2.0 2.0-5.0 30-50 52
Carboxylic salts of polyamine amides Similar to EFKA 5054, but gives In mill-base, add
EFKA 5055 improved antisettling an anti sagging before grinding 0.5-2.0 - 30-50 52
performances in high built coatings
Partial amide and salt of Industrial coatings from medium In the mill-base before
EFKA 5063 0.2-2.0 2.0-5.0 - 52
unsaturated carboxylic acid to polar systems adding pigments
Partial amide and salt of unsaturated Industrial coatings from medium In the mill-base before
EFKA 5064 carboxylic acid, combined with to high polar systems adding pigments 0.2-2.0 2.0-5.0 - 52
organically modified poly-siloxane
Unsaturated carboxylic acid, Polyurethane systems and stoving In the mill-base before
EFKA 5065 combined with a paint compatible enamels. Also for orientation of adding pigments 0.5-2.5 - - 52
organically poly-siloxane aluminum pigments
Unsaturated carboxylic acid Polyurethane systems and stoving In the mill-base before
EFKA 5066 0.5-2.5 - - 52
enamels. Strong antisettling effect adding pigments
Unsaturated poly-carboxylic acids and Similar to EFKA 5065 but with In the mill-base before
EFKA 5070 esters, combined with a compatible better compatibility in less adding pigments 0.5-4.0 8-16 - 52
organically modified polysiloxane polar systems
Alkylol ammonium salt of Water- and solventborne systems. In the mill-base before
EFKA 5071 0.5-2.0 2.5-5.0 - 52
carboxylic acid Strong anti-settling effects adding pigments
Hydroxyl functional unsaturated Solventborne architectural and In the mill-base before
EFKA 5207 3.0-5.0 ** 2.0-5.0 - 100
modified carboxylic acid decorative paints adding pigments
Unsaturated polyamide and Solvent-free version of EFKA 5044 In the mill-base 0.2-2.0
EFKA 5244 2.0-5.0 30-50 100
acid ester salts before grinding
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Product Selection Guide for Surface Modifying, Dispersion and Rheology Additives Ciba Specialty Chemicals 2006
Solventborne coatings
Waterborne coatings
% Active content
Product name Chemical type Description/Application Incorporation
Improve compatibility and color acceptance of In the mill-base or used
EFKA 6220
Fatty acid modified polyester 100
universal colorants in base paints as post additive
Dispersant agent for universal colorants In the mill-base or used
EFKA 6225 Fatty acid modified polyester 100
for tinting systems as post additive
Aliphatic polyether with acidic Dispersing agent for inorganic pigments and fillers In the mill-base adding
EFKA 6230 100
groups for decorative and industrial coatings before grinding
Solution of fatty acid modified Stabilizes all kind of pigment and extenders in water- In the mill-base or used
EFKA 6525 50
polyester in water borne coatings, especially in decorative coatings as post additive
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Product Selection Guide for Surface Modifying, Dispersion and Rheology Additives Ciba Specialty Chemicals 2006
Rheology Modifiers
Ciba VISCALEX range provides shear-thinning rheology to give good suspending power and sag resistance, but low
high-shear viscosity for ease of application.
Ciba RHEOVIS range is less shear-thinning than VISCALEX, or more Newtonian in rheology. This provides the best
leveling for gloss systems while avoiding spattering problems.
Calcium carbonate
% Active content
Chemistry type*
Gypsum based
Supplied at PH
Density g.cm-1
based systems
Product form
Product name Chemical type
VISCALEX HV100
Anionic polyacrylate copolymer Powder AS 99 - -
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Product Selection Guide for Surface Modifying, Dispersion and Rheology Additives Ciba Specialty Chemicals 2006
Solventborne coatings
Waterborne coatings
% Active content
Product name Chemical type Description/Application
EFKA 1101
Modified polyacrylate Hydroxy functional acrylic resin for solventborne RMPC 60
EFKA 1120 Acrylic modified alkyd resin Acrylic-modified alkyd resin for RMPC 65
EFKA 1125 Specially modified alkyd resin Modified alkyd resin with very large compatibility for solventborne RMPC 70
EFKA 1500 Fatty acid modified polymer Modified polyester resin for water- and solventborne RMPC 90
EFKA 1501 Fatty acid modified polymer Solvent-free version of EFKA 1500 100
EFKA 1502 Fatty acid modified polymer Modified polyester considered suitable for VOC-free pigment concentrates 95
Self-emulsifying polyester considered suitable for VOC-free pigment
EFKA 1503 Fatty acid modified polymer 75
concentrates, for decorative paints
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Product Selection Guide for Surface Modifying, Dispersion and Rheology Additives Ciba Specialty Chemicals 2006
Miscellaneous
The Ciba EFKA 6000 series features more miscellaneous products including conductivity agents, waxes, synergists,
antigelling agents, light stabilizers and rheology modifiers.
Solventborne coatings
Waterborne coatings
% Active content
% Dosage *
Product name Chemical type Description/Application Incorporation
Ketoxime with phosphorus Antigelling agent for air-drying
EFKA 6700
Before processing 0.5-1.0 15
ester salt and stoving enamels
Derivative of 2,4 Dihydroxy Cross-linking UV-absorber for air-drying
EFKA 6725 End of process ** >95
Benzophenone paints and varnishes
Synergist to aid dispersion of
EFKA 6745 Blue powder phthalocyanine pigments, give lower In the mill-base 3-5 100
viscosity of concentrates
Synergist to aid dispersion of yellow and
EFKA 6750 Yellow powder In the mill-base 3-5 100
red organic pigments
Industrial coatings, improving
EFKA 6780 Cationic compounds End of process 0.2-2.0 80
conductivity
Halogen-free, Increase the conductivity of coatings, espe-
EFKA 6781 End of process 0.2-2.0 75
cationic compounds cially necessary for electrostatics paints
EFKA 6782 Cationic compounds Conductivity agent for industrial coatings End of process 0.1-1.0 70
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Edition 2006
Copyright 2006 Ciba Specialty Chemicals Inc. All rights reserved.
All trademarks mentioned are either property of or licensed to Ciba Specialty Chemicals and registered in relevant
countries.
IMPORTANT: The following supersedes Buyers documents. SELLER MAKES NO REPRESENTATION OR WARRANTY,
EXPRESS OR IMPLIED, INCLUDING OF MERCHANTABILITY OR FITNESS FOR PURPOSES OTHER THAN THE INTEND-
ED PURPOSE. No statements herein are to be construed as inducements to infringe any relevant patent. Under no
circumstances shall Seller be liable for incidental, consequential or indirect damages for alleged negligence, breach
of warranty, strict liability, tort or contract arising in connection with the product(s). Buyers sole remedy and Sellers
sole liability for any claims shall be Buyers purchase price. Data and results are based on controlled or lab work and
must be confirmed by Buyer by testing for the intended conditions of use. The product(s) has (have) not been
tested for, and is (are) therefore not recommended for, uses for which prolonged contact with mucous membranes,
abraded skin, or blood is intended; or for uses for which implantation within the human body is intended.
Please note that products may differ from country to country. If you have any queries, kindly contact your local
Ciba Specialty Chemicals representative. Further information at website: www.cibasc.com/coatingeffects