LAMPIRAN B

PERHITUNGAN NERACA PANAS / NERACA ENERGI

Basis perhitungan : 1 jam operasi

Satuan operasi : kj/jam
Temperature basis : 25oC
Table L.B1.Kapasitas panas gas , Cpg = a + bT + cT2 + dT3 + eT4 [ J/mol K ]
komposisi A b c D e
C2H6O2 35,8417 1,08695E-02 2,90598E-04 -4,52216E-07 1,86584E-10
C4H10O3 44,6173 1,44518E-01 6,82006E-04 -9,75239E07 3,91107E-10
C3H6O3 40,991 1,28E-02 4,88E-04 -6,59E-07 2,77E-10
C2H4O 17,9573 2,43445E-02 3,51051E-04 -4,78345E-07 1,90011E-10
CO2 19,0223 7,96291E-02 -7,37067E-05 3,74572E-08 -8,13304E-12
H2 O 34,0471 -9,65064E-03 3,29983E-05 -2,04467E-08 4,30228-12

(Sumber : Reklaitis, 1983)

Tabel L.B2.Kapasitas panas liquid, Cpl = a + bT + cT2 + dT3 [ J/mol K ]
komposisi A B C D
C2H6O2 31,0224 1,10034 -2,84571E-03 2,88921E-06
C4H10O3 26,5129 1,26205 -2,6983E-03 2,5629E-06
C3H6O3 28,52 1,1805 -2,75E-03 2,69E-06
C2H4O 7,41259 7,42687E-01 -2,71320E-03 3,90092E-06
CO2 11,0417 1,15955 -7,23130E-03 1,55019E-05
H2 O 18,2964 4,72118E-01 -1,33878E-03 1,31424E-06
(Sumber : Reklaitis, 1983)
Tabel L.B3.Panas Laten [ J/mol ]
komposisi BM BP [K] Hvl [J/mol]
C2H6O2 62 470,6 49629,6
C4H10O3 106 518,8 53214,6
C3H6O3 88,05 487 50200
 C2H4O 44,053 283,661 25526,2
CO2 44,01 194,681 16560,9
H2 O 18 373,161 40656,2
(Sumber : Reklaitis, 1983)
Tabel L.B4. Panas Reaksi Pembentukan [ kkal/mol ]
komposisi Hf
C2H6O2 -93,05
C4H10O3 -136,5
C3H6O3 -102,5
C2H4O -12,58
CO2 -94,05
H2 O -57,8
(Sumber : Reklaitis, 1983)
Tabel L.B5.Data tekanan uap Antoine ; ln P (kPa) = A - (B/(T+C))
komposisi A b c
C2H6O2 16,1847 4493,79 -82,1026
C4H10O3 17,6738 6034,08 -53,2122
C3H6O3 13,1897 3985,44 -68,9974
C2H4O 14,5116 2478,12 -33,1582
CO2 15,3768 1956,25 -2,1117
H2 O 16,5362 3985,44 -38,9974
(Sumber : Reklaitis, 1983)
Tabel L.B6.Data Air Pemanas dan Air Pendingin yang digunakan
T (OC) H (kJ/kg) (kJ/kg)
Air 30 125,7 -
55 230,2 -
Saturated Steam 260 - 1661,6538
B.1 Heater 1 (E-101)

Saturated steam
260oC

1 2
CO2 (g) HEATER 1 CO2 (g)
14,5 bar 31oC E-101 14,5 bar 100oC

kondensat
260oC

,
Panas masuk Heater I = ,
304,15 304,15

= a + bT + cT2 + dT3 + eT4 dT

298,15 298,15

2
= aT + (2 12 ) + (23 13 ) + (24 14 ) + (25 15 )
2 3 4 5
7,96291102 7,37067 105
= 19,0223 (6) + (3613,8) + (1632497,805)
2 3
3,74572 108 8,13304 1012
+ (655545650,9) + (2,467964531 1011)
4 5

= 223,6642
,
Panas Keluar Heater I = ,
423,15 423,15

= a + bT + cT2 + dT3 + eT4 dT

298,15 298,15

2
= aT + (2 12 ) + (23 13 ) + (24 14 ) + (25 15 )
2 3 4 5
7,96291102 7,37067 105
= 19,0223 (125) + (90162,5) + (49263939,69)
2 3
3,74572 108 8,13304 1012
+ (2,415898282 1010 ) +
4 5
13
(1,121062865 10 )
 = 4965,202721

Table L.B7 Panas masuk Heater 1 (E-101)

Komponen

CO2 464,0706561 223,6642 103.786,7106

Total 103.786,7106

2 423,15
Panas keluar Heater 1 = 298,15
Tabel L.B8 Panas keluar Heater 1 (E-101)
Komponen

CO2 464,0706561 4965,202721 2.304.204,884

Total 2.304.204,884

Neraca energi total system :

dQ/dt = Qout-Qin
= 2.304.204,884- 103.786,7106
= 2.200.418,174 kJ/jam

Steam yang diperlukan adalah :

/
m = (260)
2.200.418,174kJ/jam
= 1661,6538 /

= 1.324,233829 kg/jam
Alur masuk (kJ/jam) Alur keluar (kJ/jam)
Umpan 103.786,7106 -
Produk - 2.304.204,884
Steam 2.200.418,174 -
TOTAL 2.304.204,884 2.304.204,884
B.2 Heater 2 (E-102)

Saturated steam
260oC

3 4
C2H4O(g) HEATER 2 C2H4O(g)
14,5 bar 31oC E-102 14,5 bar 100oC

kondensat
260oC
,
Panas masuk Heater 2= ,
304,15 304,15

= a + bT + cT2 + dT3 + eT4 dT

298,15 298,15

2
= aT + (2 12 ) + (23 13 ) + (24 14 ) + (25 15 )
2 3 4 5
2,43445102 3,51051104
= 17,9573 (6) + (3613,8) + (1632497,805)
2 3
4,78345 107 1,90011 1010
+ (655545650,9) + (2,467964531 1011)
4 5

= 273,7464347
,
Panas keluar Heater 2= ,
423,15 423,15

= a + bT + cT2 + dT3 + eT4 dT

298,15 298,15

2
= aT + (2 12 ) + (23 13 ) + (24 14 ) + (25 15 )
2 3 4 5
2,43445102 3,51051104
= 17,9573 (125) + (90162,5) + (49263939,69)
2 3
4,78345 107 1,90011 1010
+ (2,415898282 1010 ) + (1,121062865
4 5
1013 )
= 6643,807815
 3 304,15
Panas masuk Heater 2 = 298,15
Table L.B9 Panas masuk Heater 2 (E-102)

Komponen

C2H4O 414,0173935 273,7464347 113.335,7854

Total 113.335,7854

4 423,15
Panas keluar Heater 2 = 298,15
Tabel L.B10 Panas keluar Heater 2 (E-102)
Komponen

C2H4O 414,0173935 6643,807815 2.750.651,994

Total 2.750.651,994

Neraca energi total system :

dQ/dt = Qout-Qin
= 2.750.651,994 - 113.335,7854
=2.637.316,209 kJ/jam

Steam yang diperlukan adalah :

/
m = (260)
2.637.316,209 kJ/jam
= 1661,6538 /

= 1.587,163469 kg/jam
Alur masuk (kJ/jam) Alur keluar (kJ/jam)
Umpan 113.335,7854 -
Produk - 2.750.651,994
Steam 2.637.316,209 -
TOTAL 2.750.651,994 2.750.651,994

B.3 Heater 3 (E-103)

Saturated steam
260oC

5 6
H2O(l) HEATER 3 H2O(g)
14,5 bar 30oC E-103 14,5 bar 150oC

kondensat
260oC
,
Panas masuk Heater 3= ,
305,15 305,15

= a + bT + cT2 + dT3 + eT4 dT

298,15 298,15

2
= aT + (2 12 ) + (23 13 ) + (24 14 ) + (25 15 )
2 3 4 5
4,72118101 1,33878103
= 18,2964(7) + (4223,1) + (1910932,923)
2 3
1,31424 106
+ (768646198,7)
4

= 524,7490317
,
Panas keluar Heater 3= ,
423,15 423,15

= a + bT + cT2 + dT3 + eT4 dT

298,15 298,15

2
= aT + (2 12 ) + (23 13 ) + (24 14 ) + (25 15 )
2 3 4 5
4,72118101 1,33878103
= 18,2964(125) + (90162,5) + (49263939,69)
2 3
1,31424 106
+ (2,415898282 1010 )
4
 = 9523,869255

5 305,15
Panas masuk Heater 3 = 298,15
Table L.B11 Panas masuk Heater 3 (E-103)

Komponen

H2O 556,0770269 524,7490317 291.800,8814

Total 291.800,8814

5 423,15
Panas keluar Heater 3 = 298,15
Tabel L.B12 Panas keluar Heater 3 (E-103)
Komponen

H2O 556,0770269 9523,8693 5.296.004,925

Total 5.296.004,925

Neraca energi total system :

dQ/dt = Qout-Qin
= 5.296.004,925- 291.800,8814
= 5.004.204,044 kJ/jam

Steam yang diperlukan adalah :

/
m =
(260)
5.004.204,044 kJ/jam
= 1661,6538 /

= 3.011,580417 kg/jam

Alur masuk (kJ/jam) Alur keluar (kJ/jam)

Umpan 291.800,8814 -
Produk - 5.296.004,925
Steam 5.004.204,044 -
TOTAL 5.296.004,925 5.296.004,925

B.4 Reaktor karbonasi (R-101)

Air pendingin
30oC

2
CO2(g)
Alur masuk Alur keluar 7 C3H4O3(l)
14,5 bar 100oC
REAKTOR KARBONASI C2H4O(l)
4 (kJ/jam) (kJ/jam)
C2H4O(l) (R-101) CO2(g) Alur masuk Alur keluar
14,5 bar 100oC
Umpan 4140,818951 - 100oC
14,5 bar(kJ/jam)
Alur masuk Alur keluar (kJ/jam)
Produk - 531,8314425
(kJ/jam) (kJ/jam) Umpan 4140,818951 -
Steam - 3608,987509
Umpan 4140,818951 - Produk - 531,8314425
Air pendingin
TOTAL 4140,818951 4140,818951
Produk - o
531,8314425 Steam - 3608,987509
55 C
Steam - 3608,987509 TOTAL 4140,818951 4140,818951
Panas masuk reaktor 1 = panas keluar heater 1dan 2 = 11.609,01054 kj/jam
TOTAL 4140,818951 4140,818951
Reaksi yang berlangsung didalam reaktor 1 antara lain :
Reaksi 1 : C2H4O(l) + CO2(g) C3H4O3(l)
H = Hf (produk) - Hf (reaktan)
= [ -102,5 (12,58 94,5)] kkal/mol x 4,148 kJ/kkal x 1000 mol/kmol
= - 17279,9200 kJ/mol

H1(260oC) = H1(25oC) + s cp dT
= - 17279,9200+((1x16208,63096)-(1x7432,88992)-(1x2905,477083))
= - 11409,6561 kJ/kmol
Nilai r1 didapat dari perhitungan neraca massa reaktor karbonasi
Panas total Hr = r1 x H1
= 411,6812602 x (- 11409,6561)
 = - 4.697.141,602 kJ/jam

7 373,15
Panas keluar reaktor 1 = 298,15
Tabel L.B13 Panas keluar Reaktor 1 (R-101)

Komponen

C3H4O3 411,6812602 - 16208,63096 6.672.789,62

C2H4O 52,38939594 - 7432,889924 389.404,6132

CO2 2,336133348 2905,477083 - 6.787,581905
Total 466,4067896 7.068.981,815

Neraca energi total system :

dQ/dt = (Qout-Qin )+ Hr
= (7.068.981,815 - 4.425.692,367) + (- 4.697.141,602)
= -2.053.852,154 kJ/jam
Air pendingin yang diperlukan adalah :
mH + dQ/dt = 0
dQ/dt
= (55)(30)
(2.053.852,154) kJ/jam
= (230,2125,7)

= 19.654,0876 kg/jam
Alur masuk (kJ/jam) Alur keluar (kJ/jam)
Umpan 4.425.692,367 -
Produk - 7.068.981,815
Hr 4.697.141,602 -
Air Pendingin - 2.053.852,154
TOTAL 9122833,969 9122833,969
B.5 Heater 4 (E-104)

Saturated steam
260oC

C3H4O3(l)
12 C3H4O3(l)
C2H4O(l) 11
HEATER 4 C2H4O(l)
CO2(g) E-104 CO2(g)
14,5 bar 100oC
14,5 bar 150oC

kondensat
260oC

11 373,15
Panas masuk Heater 4 = 298,15
Table L.B11 Panas masuk Heater 4 (E-104)

Komponen

C3H4O3 411,56304 - 16208,6301 6.670.873,078

C2H4O 1,992469858 - 5671,8679 11.301,02583

CO2 26,0482761 2905,4771 - 75.682,6697
Total 439,603786 6.757.856,774

12 423,15
Panas keluar Heater 4 = 298,15
Tabel L.B12 Panas keluar Heater 4 (E-104)

Komponen

C3H4O3 411,56304 - 27795,5782 11.439.632,66

C2H4O 1,992469858 - 9523,8693 18.976,02251

CO2 26,0482761 2905,4771 - 75.682,6697
 Total 439,603786 11.534.291,35

Neraca energi total system :

dQ/dt = Qout-Qin
= 11.534.291,35- 6.757.856,774
= 4.776.434,578 kJ/jam

Steam yang diperlukan adalah :

/
m = (260)
4.776.434,578 kJ/jam
= 1661,6538 /

= 2.874,507841 kg/jam
Alur masuk (kJ/jam) Alur keluar (kJ/jam)
Umpan 6.757.856,774 -
Produk - 11.534.291,35
Steam 4.776.434,578 -
TOTAL 11.534.291,35 11.534.291,35

B.6 Reaktor Hidrolisis (R-102)

Air pendingin
30oC

12
H2O(l)
13 C2H6O2(l)
14,5 bar 150oC
11 REAKTOR HIDROLISIS C4H10O3(l)
C2H6O2(l) (R-102) C3H4O3(l)
C4H10O3(l) C2H4O(l)
C3H4O3(l) CO2(g)
C2H4O(l) H2O(l)
CO2(g) 14,5 bar 150oC
14,5 bar 150oC Air pendingin
55oC
Panas masuk reaktor 2 = panas keluar heater 3 + panas keluar heater 4
= 5.296.004,925 + 11.534.291,35
= 16.830.296,28 kJ/jam

Reaksi yang berlangsung dalam reaktor 2 antara lain :

Reaksi 1 : C3H4O3 + H2O C2H6O2 + CO2

H = Hf (produk) - Hf (reaktan)
= -93,05+(-94,05)(-102,5)(-57,8)kkal/mol x 4,148 kJ/kkal x 1000 mol/kmol
= - 112.131,2 kJ/mol

H1(260oC) = H1(25oC) + s cp dT
= - 112.131,2 +((1x24202,3010)+(1x4965,2027)-(1x27795,5782)
-(1x4248,8534))
= -120283 kJ/kmol

Reaksi II : 2C3H4O3 + 2H2O C4H10O3 + 2CO2

H2 = Hf (produk) - Hf (reaktan)
= -93,05+2(-94,05)2(-102,5)2(-57,8)kkal/mol x 4,148 kJ/kkal x
1000 mol/kmol
= -16736 kJ/mol

H2(260oC) = H2(25oC) + s cp dT
= -16736+((1x24202,3010)+(2x4965,2027)-(2x27795,5782)
-(2x4248,8534))
= -50.066,3998 kJ/kmol
Nilai r1 dan r2 didapat dari neraca massa reaktor hidrolisis
Panas total Hr = r1 x H1 + r2 x H2
= (403,81318 x(-120283))+(3,67103x(-50.066,3998))
= -48.755.655,99 kJ/jam
 13 423,15
Panas keluar Reaktor 2 = 298,15
Table LB.16 Panas Keluar Reaktor 2 (R-102)

Komponen

C2H6O2 403,81318 - 24202,3010 9.773.208,13

C4H10O3 3,67103 - 31378,0896 115.189,9083
C3H4O3 148,5928169 - 27795,5782 4.130.223,262
C2H4O 0,4078 - 13414,0898 5.470,26582
CO2 422,5193961 4965,2027 - 2.097.894,446
H2O 1,992469858 - 9523,8693 18.976,02251
Total 980,9967828 4965,2027 106313,9279 16.140.962.03

Neraca energi total system :

dQ/dt = (Qout-Qin )+ Hr
= (16.140.962.03- 16.830.296,28) +(-48.755.655,99)
= -49.444.990,02 kJ/jam
Air pendingin yang diperlukan adalah :
mH + dQ/dt = 0
dQ/dt
= (55)(30)
(49.444.990,024 ) kJ/jam
=
(230,2125,7)

= 473.157,7992 kg/jam
Alur masuk (kJ/jam) Alur keluar (kJ/jam)
Umpan 16.830.296,28 -
Produk - 16.140.962.03
Hr -48.755.655,99 -
Air Pendingin - 459.964,8013
TOTAL -31.925.359,71 16.614.119,83
B.7 Cooler 1 (E-105)
Air pendingin
30oC
C2H6O2(l) C2H6O2(l)
C4H10O3(l) 14 15 C4H10O3(l)
C3H4O3(l) Cooler 1
C3H4O3(l)
C2H4O(l) (E-105)
C2H4O(g)
CO2(g) CO2(g)
H2O(l)
14 423,15
Panas masuk Cooler 1 = Air
pendingin
298,15
55oC
Table L.B17 Panas masuk Cooler 1 (E-105)

Komponen

C2H6O2 403,81318 - 24.202,3010 9.773.208,13

C4H10O3 3,67103 - 31.378,0896 115.189,9083
C3H4O3 148,5928169 - 27.795,5782 4.130.223,262
C2H4O 0,4078 -2.222,2793 - -906.2454985
CO2 422,5193961 6.826,7272 - 2.884.424,654
H2O 1,992469858 3.415,4537 - 6.805,188549
Total 980,9967828 16.908.944,9

15 373,15
Panas keluar Cooler 1 = 298,15

Komponen

C2H6O2 403,81318 - 14177,6582 5.725.125,243

C4H10O3 3,67103 - 18223,8004 66.900,11798
C3H4O3 148,5928169 - 16208,6310 2.408.486,138
C2H4O 0,4078 3750,0438 - 1.529,267862
CO2 422,5193961 2905,4771 - 1.227.620,43
H2O 1,992469858 2536,0564 - 5.053,0115935
Total 980,9967828 9.434.714,213
Neraca energi total system :
dQ/dt = Qout-Qin
= 9.434.714,213- 16.908.944,9
= -7.565.230,687 kJ/jam
Air pendingin yang diperlukan adalah :
mH + dQ/dt = 0
dQ/dt
= (55)(30)
(7.565.230,687) kJ/jam
= (230,2125,7)

= 72.394,55203 kg/jam
Alur masuk (kJ/jam) Alur keluar (kJ/jam)
Umpan 16.908.944,9 -
Produk - 9.434.714,213
Steam - 7.565.230,687
TOTAL 16.908.944,9 16.908.944,9

B.8 Evaporator (FE-101)

Saturated steam
260oC
C2H6O2(l)
C2H6O2(l)
C4H10O3(l) 20
18 C4H10O3(l)
C3H4O3(g) EVAPORATOR
C3H4O3(g)
C2H4O(g) FE-101
C2H4O(g)
CO2(g)
CO2(g)

kondensat
260oC

18 373,15
Panas masuk Evaporator = 298,15
Tabel L.B19 Panas Masuk Evaporator (FE-101)
 Komponen

C2H6O2 403,81318 - 14177,6582 5725125,243

C4H10O3 3,67103 - 18223,800 66900,11651
C3H4O3 0,4078 - 16208,6310 6609,879722
C2H4O 0,4383834 4870,2158 - 2135,021761
CO2 6,8444376 3718,3192 - 25449,80374
H2O 134,131179 7741,4743 - 1038373,075
Total 549,3061 6864593,14

19 383,15
Panas Keluar Evaporator = 298,15
Table L.B20 Panas Keluar Evaporator (FE-101)

Komponen

C2H4O 0,4383834 1708,2895 - 748,8857592

CO2 6,8444376 1814,6763 - 12420,4387
H2O 134,131179 3233,5608 - 433721,3225
Total 446890,6469

18 383,15
Panas Keluar Evaporator = 298,15
Table L.B21 Panas Keluar Evaporator (FE-101)

Komponen

C2H6O2 403,81318 - 18125,3419 7319251,951

C4H10O3 3,67103 - 23385,9669 85850,58607
C3H4O3 0,4078 - 20763,7314 8467,449665
Total 7413569,987
Neraca energi total system :
dQ/dt = (Qout-Qin )
= (446890,6469+7413569,987) - 6864593,14
= 995867,4936 kJ/jam
Air pendingin yang diperlukan adalah :
mH + dQ/dt = 0
dQ/dt
= (55)(30)
(995867,4936 ) kJ/jam
= (230,2125,7)

= - 9529,832475 kg/jam
Alur masuk (kJ/jam) Alur keluar (kJ/jam)
Umpan 6864593,14 -
Produk - 7860460,634
Steam 995867,4936 -
TOTAL 7860460,634 7860460,634

B.9 Heater 5 (E-106)

Saturated steam
260oC

C2H6O2(l) 21 C2H6O2(l)
20
C4H10O3(l) HEATER 5
C4H10O3(l)
H2O(l) E-106
H2O(l)

kondensat
260oC

20 383,15
Panas masuk Heater 5 = 298,15
Table L.B22 Panas masuk Heater 5 (E-106)
 Komponen

C2H6O2 403,81318 18125,3419 7319251,951

C4H10O3 3,67103 23385,9669 85850,58607
C3H4O3 0,4078 20763,7314 8467,449665
Total 7413569,987

21 468,15
Panas keluar Heater 5 = 298,15
Tabel L.B12 Panas keluar Heater 5 (E-106)

Komponen

C2H6O2 403,81318 34185,6979 13804635,38

C4H10O3 3,67103 44557,0648 163570,3216
C3H4O3 0,4078 39362,1822 16051,8979
Total 407,89201 118104,9449 13984257,6

Neraca energi total system :

dQ/dt = Qout-Qin
=13984257,6 - 7413569,987
= 6570687,613 kJ/jam

Steam yang diperlukan adalah :

/
m = (260)
6570687,613 kJ/jam
= 1661,6538 /

= 3954,306013 kg/jam
Alur masuk (kJ/jam) Alur keluar (kJ/jam)
Umpan 7413569,987 -
Produk - 13984257,6
Steam 6570687,613 -
TOTAL 13984257,6 13984257,6

B.10 Kondensor (E-107)

Air pendingin
30oC
C2H6O2(l) C2H6O2(l)
C4H10O3(l) 22 23 C4H10O3(l)
H2O(g) Kondensor
H2O(g)
1 bar 197oC (E-107)
1 bar 195oC

Air pendingin
55oC

Untuk mengetahui suhu pada destilat, diperlukan perhitungan suhu umpan masuk
hingga Kixi = 1 terpenuhi

Trial titik didih umpan pada bagian atas kolom distilasi.

T = 197oC = 470,15 K
P = 1 bar = 100 kPa

Tekanan uap Antoine : ln () = ()+

Tabel L.B24 Titik Didih Umpan Pada Bagian Atas Kolom Distilasi
Komponen Yif Pi Ki Xif=Yif/Ki if= Ki/Khk
C2H6O2 0,9900 99,9012 0,9990 0,9910 4,0664
C4H10O3 0,0090 24,5675 0,2457 0,0366 1
C3H4O3 0,0010 1469,2572 14,6926 0,0001 59,8049
Total 1 1,0276

Maka, suhu bagian atas kolom distilasi adalah 197oC

Untuk mengetahui suhu pada destilat, maka perlu perhitungan trial dew point sampai
syarat yid/ki = 1 terpenuhi.
Trial dew point destilat
T = 100oC = 373,15 K
P = 1 bar = 100 kPa
Tabel LB.25 Dew Point Kondensor
Komponen Yid Pi Ki Yif/Ki id
C2H6O2 0,9941 94,0839 0,9408 1,0566 4,1063
C4H10O3 0,0059 22,9122 0,2291 0,0257 1
C3H4O3 0 1407,3073 14,0731 0 61,4218
Total 1 1,0823
Maka, suhu destilat (D) adalah 468,15 K dan suhu Ld 468,15 K
22 468,15
Panas masuk kondensor = 298,15
Tabel LB.26 Panas Masuk Kondensor (E-107)

Komponen

C2H6O2 582,0444 - 34185,6979 19897594,02

C4H10O3 5,838651 - 44557,0648 260153,151
C3H4O3 - - - -
Total 587,883051 20157747,17
25 453,15
Panas Keluar kondensor = 298,15
Tabel LB.27 Panas Keluar Kondensor (E-107)

Komponen

C2H6O2 582,0444 - 14177,65818 8252026,549

C4H10O3 5,838651 - 18223,80038 106402,4103
C3H4O3 - - - -
Total 587,883051 8358428,959
Neraca energi total system :
dQ/dt = (Qout-Qin )
= 8358428,959 - 20157747,17
= -11799318,21 kJ/jam
Air pendingin yang diperlukan adalah :
mH + dQ/dt = 0
dQ/dt
= (55)(30)
(11799318,21) kJ/jam
= (230,2125,7)

= 112912,136 kg/jam
Alur masuk (kJ/jam) Alur keluar (kJ/jam)
Umpan 20157747,17 -
Produk - 8358428,959
Steam - 11799318,21
TOTAL 20157747,17 20157747,17

B.11 Cooler 2 (E-108)

Air pendingin
30oC

C2H6O2(l)
27 28 C2H6O2(l)
C4H10O3(l)
Cooler 2 C4H10O3(l)
1 bar, 195oC
(E-108) 1 bar, 30oC

Air pendingin
55oC

27 453,15
Panas masuk Cooler 2 = 298,15
Tabel LB.28 Panas Masuk Cooler 2 (E-108)
 Komponen

C2H6O2 582,0444 14177,6582 8252026,56

C4H10O3 5,838651 18223,8004 106402,4104
Total 8358428,97

28 303,15
Panas Keluar Cooler 2 = 298,15
Tabel LB.29 Panas Keluar Cooler 2 (E-108)

Komponen

C2H6O2 582,0444 915,65509 532951,9175

C4H10O3 5,838651 1158,469313 6763,898013
Total 539715,8155

Neraca energi total system :

dQ/dt = (Qout-Qin )
= 539715,8155 - 8358428,97
= -7818713,155 kJ/jam
Air pendingin yang diperlukan adalah :
mH + dQ/dt = 0
dQ/dt
= (55)(30)
(7818713,155) kJ/jam
= (230,2125,7)/

= 74820,22158 kg/jam
Alur masuk (kJ/jam) Alur keluar (kJ/jam)
Umpan 8358428,97 -
Produk - 539715,8155
Steam - 7818713,155
TOTAL 8358428,97 8358428,97
B.12 Reboiler
C2H6O2(V)
C4H10O3(v)
1,2 bar, 250oC

(30)

Reboiler
Steam 260 oC .......... .......... kondensor 260 oC
(E-109)

C2H6O2(l) (29) (31) C2H6O2(l)

C4H10O3(l) C4H10O3(l)
1 bar, 197oC 1 bar, 250oC

Untuk mengetahui suhu pada Vb, maka perlu perhitungan trial bubble point sampai syarat
Ki.xi = 1 terpenuhi.
Trial bubble point bottom
T = 252oC = 522,15 K
P = 1,41 bar = 141 kPa
Tabel LB.30 Buble point Reboiler (E-109)
Komponen Xid Pi Ki Yid/Ki id
C2H6O2 0,2482 401,7360 3,9776 0,7073 3,1068
C4H10O3 0,6263 125,6666 1,2442 0,5582 1
C3H4O3 0,1255 82,6114 0,8179 0,0735 0,6574
Total 1,3390
Maka suhu Vb adalah 521,15 K
29 468,15
Panas masuk Reboiler = 298,15
Tabel LB.31 Panas Masuk Reboiler (E-109)

Komponen

C2H6O2 45,18907904 34185,6979 1544820,204

C4H10O3 114,0286874 44557,0648 5080783,614
C3H4O3 22,8494336 39362,1822 899403,5685
Total 182,0672 7525007,387
 30 518,15 31 453,15
Panas Keluar Reboiler = 298,15 + 298,15
Tabel LB.32 Panas Keluar Vb Reboiler (E-109)

Komponen

C2H6O2 44,68383319 14170,0860 633173,7591

C4H10O3 112,753766 36461,3820 4111158,134
C3H4O3 22,59396078 20373,2688 460312,8362
Total 180,03156 5204644,729

Tabel LB.33 Panas Keluar B Reboiler (E-109)

Komponen

C2H6O2 0,50524 46368,3910 23427,16587

C4H10O3 1,27492 60561,2185 77210,70869
C3H4O3 0,25547 53416,7214 13646,36982
Total 2,03564 114284,2444

Panas keluar Reboiler = 114284,2444 + 5204644,729

= 5318928,973 kJ/jam
Neraca energi total system :
dQ/dt = Qout-Qin
=5318928,973 - 7525007,387
= -2206078,414 kJ/jam

Steam yang diperlukan adalah :

/
m = (260)
(2206078,414) kJ/jam
= 1661,6538 /

= 1327,640218 kg/jam
 Alur masuk (kJ/jam) Alur keluar (kJ/jam)
Umpan 7525007,387 -
Produk - 5318928,973
Steam -2206078,414 -
TOTAL 5318928,973 5318928,973

B.13 Kondensor Subcooler (E-110)

Air Pendingin
1 bar, 30oC

C2H6O2(l) (33) (34) C2H6O2(l)

C4H10O3(l) Cooler 3
C4H10O3(l)
1 bar, 250oC (E-110)
1 bar, 100oC

Air Pendingin
1 bar, 55oC

32 518,15
Panas masuk Kondensor Subcooler = 298,15
Tabel LB.34 Panas Masuk kondensor subcooler

Komponen

C2H6O2 0,50524 14170,0860 7159,294251

C4H10O3 1,27492 36461,3820 46485,34514
Total 53644,63939

33 303,15
Panas keluar Kondensor Subcooler = 298,15
Tabel LB.35 Panas Keluar kondensor subcooler

Komponen

C2H6O2 0,50524 915,65509 462,6255777

C4H10O3 1,27492 1158,468313 1476,954422
 Total 1939,579999

Neraca energi total system :

dQ/dt = (Qout-Qin )
= 1939,579999 - 53644,63939
= -51705,05939 kJ/jam
Air pendingin yang diperlukan adalah :
mH + dQ/dt = 0
dQ/dt
= (55)(30)
(51705,05939) kJ/jam
= (230,2125,7)/

= 494,7852573 kg/jam
Alur masuk (kJ/jam) Alur keluar (kJ/jam)
Umpan 53644,63939 -
Produk - 1939,579999
Steam - 51705,05939
TOTAL 53644,63939 53644,63939

B.14 Cooler 3 (E-111)

Air Pendingin
1 bar, 30oC

(35) (36) C
C3H4O3(l) Cooler 3 C23HH64O
O2(l)
3(l)

1 bar, 250oC (E-111) C 4 H 10O

1 bar, 1003(l) oC
1 bar, 100oC

Air Pendingin
1 bar, 55oC
 34 518,15
Panas masuk Cooler 3 = 298,15
Tabel LB.35 Panas Masuk Cooler 3

Komponen

C3H4O3 0,25547 53416,7214 13646,36982

Total 13646,36982

35 303,15
Panas keluar Cooler 3 = 298,15
Tabel LB.36 Panas keluar Cooler 3

Komponen

C3H4O3 0,25547 16208,63096 4140,818951

Total 4140,818951

Neraca energi total system :

dQ/dt = (Qout-Qin )
=4140,818951 - 13646,36982
= -9505,550869 kJ/jam
Air pendingin yang diperlukan adalah :
mH + dQ/dt = 0
dQ/dt
m= (55)(30)
(9505,550869 ) kJ/jam
= (230,2125,7)/

= 90,96220927 kg/jam
Alur masuk (kJ/jam) Alur keluar (kJ/jam)
Umpan 13646,36982 -
Produk - 4140,818951
Steam - 9505,550869
TOTAL 13646,36982 13646,36982
B.15 Cooler 4 (E-112)

Air Pendingin
1 bar, 30oC

C3H4O3(l) (35) (36)

Cooler 1 C3H4O3(l)
o
1,41 bar, 100 C 1,41 bar, 35oC
(E-112)

Air Pendingin
1 bar, 55oC

35 518,15
Panas Masuk Cooler 4 = 298,15
Tabel LB.37 Panas masuk Cooler 4

Komponen

C3H4O3 0,25547 16208,63096 4140,818951

Total 4140,818951

36 373,15
Panas Keluar Cooler 4 = 298,15
Tabel LB.38 Panas keluar Cooler 4

Komponen

C3H4O3 0,25547 2081,7765 531,8314425

Total 531,8314425

Neraca energi total system :

dQ/dt = (Qout-Qin )
=531,8314425 - 4140,818951
= -3608,987509 kJ/jam
Air pendingin yang diperlukan adalah :
mH + dQ/dt = 0
dQ/dt
m= (55)(30)
(3608,987509 ) kJ/jam
= (230,2125,7)/

= 34,53576564 kg/jam
Alur masuk (kJ/jam) Alur keluar (kJ/jam)
Umpan 4140,818951 -
Produk - 531,8314425
Steam - 3608,987509
TOTAL 4140,818951 4140,818951