(S1) c1 Prepabac 2016 unit4 srie2

NH3 (S1) (1 :
r
xf
(n) M : Remila (2) 3S-3TM
V 200mL 25C [CH3COOH]
c1.10pH 1 : pH V
[CH3COO ] V HCOOH -I
CH3COO H CH3COO pK A
NH3 2% 25C pH 2, 9 c 10 2 mol L
KA
[NH 4 ] 1 f : / 1
: K A 10PH
[NH 3 ] 49
(S 2 ) Veau 2
NH 4 NH 3 pK a1 (S1) pH1
9, 75mSm 1 2
9, 2
[CH3COO ] f 3
(n) C1 (S 2 ) PH
pK a 4
[CH3COOH]
HCOOH HCOO
C 2 C1 (C 2H 5 )2NH (S 2 ) (2 Veau (S 2 ) c2
K 5
3,17 10 11 (C 2H 5 )2 NH 2 (C 2H 5 )2 NH Ka 2 (Na OH ) Vb (S1) 3
C ( HA ) -II
NH3 ( C 2H 5 )2NH 4, 76 pH cb 0,1mol L
[A ] [A ]
pH f (log )
Ke 1 f
[HA] [HA ]
:
[CH3COO ]
Ka 2 . Ka 2 PH
C 2 f2 [CH3COOH] pH 1
pH 2 f OH CH 3COOH

[A ]
HA A pK a
2 (S 2 ) [HA ]
pK a 2
CH COO 4,1 O 35 : mSm 2 .mol 1 Vb
2

3
H3

HA HA A
0, 2mo V 1L
NH3
[A ] :
( Na CH3COO) 0, 2mo HCOOH log
[HA]
0 1
1 AB 1
pK A Acide Base HA 3
K a 2 K a1 K 2 cb 10 2 mol .L1 S1
4, 76 CH 3COOH CH 3COO HCOOH
pK a 1(HCOOH HCOO ) 3, 8 : 19, 9 NH 7, 34 : 25C 10, 9mSm 1

4

OH
4
4, 2 C 6H5COOH C 6H5COO
pK a 2 (CH 3COOH CH 3COO ) 4, 8

2
3, 8 HCOOH HCOO
f K 3 pK A NH 4 NH 3 KA 3
4, 87 C 2H 5COOH C 2H 5COO

K K 4
f f : 4 CH3COOH (S1) 1
1 K K KA K 5
PH 5 800mL m 0, 72g
6
-6 3, 3 pH 25C