KELARUTAN NAFTALENA DALAM CAMPURAN TOLUENA DAN HEKSANA

UNIFAC Subgroup Parameter

m Main Group Subgroup k Rk Qk NOTES

CH3 1 0.9011 0.848 i=1
1 "CH2"
CH2 2 0.6744 0.54 i=2
ACH 10 0.5313 0.4 i=3
3 "ACH"
AC 11 0.3652 0.12
4 "ACCH2" ACCH3 12 1.2663 0.968

k Qk vk(1) vk(2) vk(3) vk(1) Qk vk(2) Qk vk(3) Qk

1 0.848 0 0 2 0 0 1.696
2 0.54 0 0 4 0 0 2.16
10 0.4 8 5 0 3.2 2 0
11 0.12 2 0 0 0.24 0 0
12 0.968 0 1 0 0 0.968 0
qi 3.44 2.968 3.856

k Rk vk(1) vk(2) vk(3) vk(1) Rk vk(2) Rk vk(3) Rk

1 0.9011 0 0 2 0 0 1.8022
2 0.6744 0 0 4 0 0 2.6976
10 0.5313 8 5 0 4.2504 2.6565 0
11 0.3652 2 0 0 0.7304 0 0
12 1.2663 0 1 0 0 1.2663 0
ri 4.9808 3.9228 4.4998

UNIFAC Interaction Parameter

amk (K)
m=1 m=3 m=4
amk (K) k=1 k=2 k=10 k=11 k=12
k=1 0 0 61.13 61.13 76.5
m=1
k=2 0 0 61.13 61.13 76.5
k=10 -11.12 -11.12 0 0 167
m=3
k=11 -11.12 -11.12 0 0 167
m=4 k=12 -69.7 -69.7 -146.8 -146.8 0

mk
323.15 m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 1 1 0.8276465 0.8276465 0.7892026
m=1
k=2 1 1 0.8276465 0.8276465 0.7892026
 k=10 1.035010182 1.0350102 1 1 0.5964333
m=3
k=11 1.035010182 1.0350102 1 1 0.5964333
m=4 k=12 1.240716839 1.2407168 1.5750361 1.5750361 1

ik
i k=1 k=2 k=10 k=11 k=12
1 1.035010182 1.0350102 1 1 0.5964333
2 1.102100493 1.1021005 1.1875455 1.1875455 0.7280548
3 1 1 0.8276465 0.8276465 0.7892026

k=1 0.0723113
k=2 0.0920946
k k=10 0.6968127
k=11 0.0363953
k=12 0.1023861

Sk
k=1 k=2 k=10 k=11 k=12
1.050315799 1.050315799 1.0305398 1.0305398 0.6694453

Ji 1.097212992
Li 1.032187052

ln ic 0.028322798 0.0712576 0.0907526 0.7041467

ln i r
0.015457586
ln i 325
0.043780384
i 1.04475289 320

ln xAL -0.65356997 315

xAL 0.52018541 310

Suhu, K

1.029256513 305

300

1:2 T:H
295
xperc xperh T
0.242294 0.26116 303.15 290
0.338014 0.35499 313.15 0.2 0.25 0.3

0.472488 0.47969 323.15 Fra

1:1 T:H
xperc xperh T
325

320

315
 0.298908 0.293177 303.15 325
0.402607 0.3893 313.15
320
0.510688 0.5061 323.15
315
2:1 T:H
310
xperc xperh T

Suhu, K
0.30177 0.31167 303.15 305
0.395736 0.405809 313.15
300
0.505399 0.52018 323.15
295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena

325

320

315

310
Suhu, K

305

300

295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena
k=2
 Solvent (T:H)
Naphtalene V Total Solven
Toluene V Toluene
Hexane V Hexane
Toluene (26 C)
Heksana (26 C)

eki m Naphtalen mula-mula

k Naftalen Toluen Heksana m Naphtalen tersisa
1 0 0 0.439834 m Naphtalen larut
2 0 0 0.560166
10 0.930232558 0.6738544474 0
11 0.069767442 0 0
12 0 0.3261455526 0

Bahan Ikatan Main Group k vk rk qk

ACH 3 10 5 0.5313 0.4
Toluen
ACCH3 4 12 1 1.2663 0.968
ACH 3 10 8 0.5313 0.4
Naftalen
AC 3 11 2 0.3652 0.12
CH2 1 2 4 0.6744 0.54
N-Heksana
CH3 1 1 2 0.9011 0.848

i=1 i=2
0 0 0 0 0 0 0
0 0 0 0 0 0 0
 0.9628002 0.9628001691 0.930232558 0.9302325581 0.5548217 0.6974462 0.6974462
0.07221 0.0722100127 0.069767442 0.0697674419 0.0416116 0 0
0 0 0 0 0 0.4046543 0.4046543
1.0350102 1.0350101818 1 1 0.5964333 1.1021005 1.1021005

Suhu Perb k k Suhu Perb k

1 1
2 2
1:2 10 1:2 10
11 11
12 12
1 1
2 2
30 1:1 10 30 1:1 10
11 11
12 12
1 1
2 2
2:1 10 2:1 10
11 11
12 12

0.0374156 0.0912194983

Percobaa n
Pehi tungan

0.25 0.3 0.35 0.4 0.45 0.5

Fraksi Naftalena
 Percoba an
Pehi tungan

0.3 0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena

Percobaa n
Perhi tunga n

0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena
 2 : 1 m Toluene 86.2483556542 gram
150 mL m Hexane 32.5215421182 gram
100 mL
50 mL BM Toluene 92.13 g/mol
0.8624836 g/mL BM Hexane 86.18 g/mol
0.6504308 g/mL BM naftalen 128.19 g/mol

en mula-mula gram x Naphtalen 0.5053991942

gram x Toluene 0.352505254
172.0572 gram x Hexane 0.1420955518
1

massa terlarut naftalen k

30 0.0430556
0.0423611
0.0840278
40 0.0430556
0.0423611
0.0840278
50 0.0430556
0.0423611
0.0840278

i=3
0 0 0 0.439834 0.4398340249 0.3640271 0.3640271
0 0 0 0.560166 0.5601659751 0.4636194 0.4636194
0.6738544 0.6738544 0.4019092 0 0 0 0
0 0 0 0 0 0 0
0.513691 0.513691 0.3261456 0 0 0 0
1.1875455 1.1875455 0.7280548 1 1 0.8276465 0.8276465

k Suhu Perb Massa naftalen terlarut k k

1 0.226769
2 0.28881
1:2 50.1254 10 0.387524
11 0.016626
12 0.080271
1 0.156699
2 0.19957
30 1:1 69.3098 10 0.511614
11 0.021181
12 0.110936
1 0.154358
2 0.196587
2:1 72.7736 10 0.51787
11 0.021907
12 0.109278
1
2
1:2 80.0388 10
11
12
1
2
40 1:1 109.5061 10
11
12
1
2
2:1 110.2736 10
11
12
1
2
1:2 140.4019 10
11
12
1

50 1:1 169.6688
 2
50 1:1 169.6688 10
11
12
1
2
2:1 172.0572 10
11
12
 aquadest 0.996513 gram/cc
Pikno kosong 16.5508 gram
Pikno + heksana 32.3824 gram 26
Pikno + toluene 37.5438 gram 26
Pikno + aquadest 40.8061 gram 27

heksana 0.6504308 g/mL

toluena 0.8624836 g/mL

0.3471182
0.4420845
 0
0
0
0.7892026

Sk
KELARUTAN NAFTALENA DALAM CAMPURAN TOLUENA DAN HEKSANA

UNIFAC Subgroup Parameter

m Main Group Subgroup k Rk Qk NOTES

CH3 1 0.9011 0.848 i=1
1 "CH2"
CH2 2 0.6744 0.54 i=2
ACH 10 0.5313 0.4 i=3
3 "ACH"
AC 11 0.3652 0.12
4 "ACCH2" ACCH3 12 1.2663 0.968

k Qk vk(1) vk(2) vk(3) vk(1) Qk vk(2) Qk vk(3) Qk

1 0.848 0 0 2 0 0 1.696
2 0.54 0 0 4 0 0 2.16
10 0.4 8 5 0 3.2 2 0
11 0.12 2 0 0 0.24 0 0
12 0.968 0 1 0 0 0.968 0
qi 3.44 2.968 3.856

k Rk vk(1) vk(2) vk(3) vk(1) Rk vk(2) Rk vk(3) Rk

1 0.9011 0 0 2 0 0 1.8022
2 0.6744 0 0 4 0 0 2.6976
10 0.5313 8 5 0 4.2504 2.6565 0
11 0.3652 2 0 0 0.7304 0 0
12 1.2663 0 1 0 0 1.2663 0
ri 4.9808 3.9228 4.4998

UNIFAC Interaction Parameter

amk (K)
m=1 m=3 m=4
amk (K) k=1 k=2 k=10 k=11 k=12
k=1 0 0 61.13 61.13 76.5
m=1
k=2 0 0 61.13 61.13 76.5
k=10 -11.12 -11.12 0 0 167
m=3
k=11 -11.12 -11.12 0 0 167
m=4 k=12 -69.7 -69.7 -146.8 -146.8 0

mk
323.15 m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 1 1 0.8276465 0.8276465 0.7892026
m=1
k=2 1 1 0.8276465 0.8276465 0.7892026
 k=10 1.035010182 1.0350102 1 1 0.5964333
m=3
k=11 1.035010182 1.0350102 1 1 0.5964333
m=4 k=12 1.240716839 1.2407168 1.5750361 1.5750361 1

ik
i k=1 k=2 k=10 k=11 k=12
1 1.035010182 1.0350102 1 1 0.5964333
2 1.102100493 1.1021005 1.1875455 1.1875455 0.7280548
3 1 1 0.8276465 0.8276465 0.7892026

k=1 0.1088502
k=2 0.1386299
k k=10 0.6394421
k=11 0.0360169
k=12 0.0770608

Sk
k=1 k=2 k=10 k=11 k=12
1.042197787 1.042197787 1.0016587 1.0016587 0.6752391

Ji 1.085347776
Li 1.010876023

ln ic 0.04105509 0.1080995 0.1376739 0.6399249

ln i r
0.030159571
ln i 325
0.071214661
i 1.07381171 320

ln xAL -0.68100425 315

xAL 0.50610848 310

Suhu, K

0.991032347 305

300

1:2 T:H
295
xperc xperh T
0.242294 0.26116 303.15 290
0.338014 0.35499 313.15 0.2 0.25 0.3

0.472488 0.47969 323.15 Fra

1:1 T:H
xperc xperh T
325

320

315
 0.298908 0.293177 303.15 325
0.402607 0.3893 313.15
320
0.510688 0.5061 323.15
315
2:1 T:H
310
xperc xperh T

Suhu, K
0.30177 0.31167 303.15 305
0.395736 0.405809 313.15
300
0.505399 0.52018 323.15
295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena

325

320

315

310
Suhu, K

305

300

295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena
k=2
 Solvent (T:H)
Naphtalene V Total Solven
Toluene V Toluene
Hexane V Hexane
Toluene (26 C)
Heksana (26 C)

eki m Naphtalen mula-mula

k Naftalen Toluen Heksana m Naphtalen tersisa
1 0 0 0.439834 m Naphtalen larut
2 0 0 0.560166
10 0.930232558 0.6738544474 0
11 0.069767442 0 0
12 0 0.3261455526 0

Bahan Ikatan Main Group k vk rk qk

ACH 3 10 5 0.5313 0.4
Toluen
ACCH3 4 12 1 1.2663 0.968
ACH 3 10 8 0.5313 0.4
Naftalen
AC 3 11 2 0.3652 0.12
CH2 1 2 4 0.6744 0.54
N-Heksana
CH3 1 1 2 0.9011 0.848

i=1 i=2
0 0 0 0 0 0 0
0 0 0 0 0 0 0
 0.9628002 0.9628001691 0.930232558 0.9302325581 0.5548217 0.6974462 0.6974462
0.07221 0.0722100127 0.069767442 0.0697674419 0.0416116 0 0
0 0 0 0 0 0.4046543 0.4046543
1.0350102 1.0350101818 1 1 0.5964333 1.1021005 1.1021005

Suhu Perb k k Suhu Perb k

1 1
2 2
1:2 10 1:2 10
11 11
12 12
1 1
2 2
30 1:1 10 30 1:1 10
11 11
12 12
1 1
2 2
2:1 10 2:1 10
11 11
12 12

0.0360729 0.0680672318

Percobaa n
Pehi tungan

0.25 0.3 0.35 0.4 0.45 0.5

Fraksi Naftalena
 Percoba an
Pehi tungan

0.3 0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena

Percobaa n
Perhi tunga n

0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena
 1 : 1 m Toluene 64.6862667407 gram
150 mL m Hexane 48.7823131773 gram
75 mL
75 mL BM Toluene 92.13 g/mol
0.8624836 g/mL BM Hexane 86.18 g/mol
0.6504308 g/mL BM naftalen 128.19 g/mol

en mula-mula gram x Naphtalen 0.5106881538

gram x Toluene 0.2709062092
169.6688 gram x Hexane 0.2184056371
1

massa terlarut naftalen k

30 0.0430556
0.0423611
0.0840278
40 0.0430556
0.0423611
0.0840278
50 0.0430556
0.0423611
0.0840278

i=3
0 0 0 0.439834 0.4398340249 0.3640271 0.3640271
0 0 0 0.560166 0.5601659751 0.4636194 0.4636194
0.6738544 0.6738544 0.4019092 0 0 0 0
0 0 0 0 0 0 0
0.513691 0.513691 0.3261456 0 0 0 0
1.1875455 1.1875455 0.7280548 1 1 0.8276465 0.8276465

k Suhu Perb Massa naftalen terlarut k k

1 0.226769
2 0.28881
1:2 50.1254 10 0.387524
11 0.016626
12 0.080271
1 0.156699
2 0.19957
30 1:1 69.3098 10 0.511614
11 0.021181
12 0.110936
1 0.154358
2 0.196587
2:1 72.7736 10 0.51787
11 0.021907
12 0.109278
1
2
1:2 80.0388 10
11
12
1
2
40 1:1 109.5061 10
11
12
1
2
2:1 110.2736 10
11
12
1
2
1:2 140.4019 10
11
12
1

50 1:1 169.6688
 2
50 1:1 169.6688 10
11
12
1
2
2:1 172.0572 10
11
12
 aquadest 0.996513 gram/cc
Pikno kosong 16.5508 gram
Pikno + heksana 32.3824 gram 26
Pikno + toluene 37.5438 gram 26
Pikno + aquadest 40.8061 gram 27

heksana 0.6504308 g/mL

toluena 0.8624836 g/mL

0.3471182
0.4420845
 0
0
0
0.7892026

Sk
KELARUTAN NAFTALENA DALAM CAMPURAN TOLUENA DAN HEKSANA

UNIFAC Subgroup Parameter

m Main Group Subgroup k Rk Qk NOTES

CH3 1 0.9011 0.848 i=1
1 "CH2"
CH2 2 0.6744 0.54 i=2
ACH 10 0.5313 0.4 i=3
3 "ACH"
AC 11 0.3652 0.12
4 "ACCH2" ACCH3 12 1.2663 0.968

k Qk vk(1) vk(2) vk(3) vk(1) Qk vk(2) Qk vk(3) Qk

1 0.848 0 0 2 0 0 1.696
2 0.54 0 0 4 0 0 2.16
10 0.4 8 5 0 3.2 2 0
11 0.12 2 0 0 0.24 0 0
12 0.968 0 1 0 0 0.968 0
qi 3.44 2.968 3.856

k Rk vk(1) vk(2) vk(3) vk(1) Rk vk(2) Rk vk(3) Rk

1 0.9011 0 0 2 0 0 1.8022
2 0.6744 0 0 4 0 0 2.6976
10 0.5313 8 5 0 4.2504 2.6565 0
11 0.3652 2 0 0 0.7304 0 0
12 1.2663 0 1 0 0 1.2663 0
ri 4.9808 3.9228 4.4998

UNIFAC Interaction Parameter

amk (K)
m=1 m=3 m=4
amk (K) k=1 k=2 k=10 k=11 k=12
k=1 0 0 61.13 61.13 76.5
m=1
k=2 0 0 61.13 61.13 76.5
k=10 -11.12 -11.12 0 0 167
m=3
k=11 -11.12 -11.12 0 0 167
m=4 k=12 -69.7 -69.7 -146.8 -146.8 0

mk
323.15 m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 1 1 0.8276465 0.8276465 0.7892026
m=1
k=2 1 1 0.8276465 0.8276465 0.7892026
 k=10 1.035010182 1.0350102 1 1 0.5964333
m=3
k=11 1.035010182 1.0350102 1 1 0.5964333
m=4 k=12 1.240716839 1.2407168 1.5750361 1.5750361 1

ik
i k=1 k=2 k=10 k=11 k=12
1 1.035010182 1.0350102 1 1 0.5964333
2 1.102100493 1.1021005 1.1875455 1.1875455 0.7280548
3 1 1 0.8276465 0.8276465 0.7892026

k=1 0.1586705
k=2 0.2020803
k k=10 0.5504994
k=11 0.0325841
k=12 0.0561656

Sk
k=1 k=2 k=10 k=11 k=12
1.033933878 1.033933878 0.9701206 0.9701206 0.6886416

Ji 1.080303658
Li 0.98846738

ln ic 0.06687276 0.1588357 0.2022907 0.5392361

ln i r
0.057938546
ln i 325
0.124811306
i 1.13293465 320

ln xAL -0.73460089 315

xAL 0.47969687 310

Suhu, K

1.01525766 305

300

1:2 T:H
295
xperc xperh T
0.242294 0.26116 303.15 290
0.338014 0.35499 313.15 0.2 0.25 0.3

0.472488 0.47969 323.15 Fra

1:1 T:H
xperc xperh T
325

320

315
 0.298908 0.293177 303.15 325
0.402607 0.3893 313.15
320
0.510688 0.5061 323.15
315
2:1 T:H
310
xperc xperh T

Suhu, K
0.30177 0.31167 303.15 305
0.395736 0.405809 313.15
300
0.505399 0.52018 323.15
295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena

325

320

315

310
Suhu, K

305

300

295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena
k=2
 Solvent (T:H)
Naphtalene V Total Solven
Toluene V Toluene
Hexane V Hexane
Toluene (26 C)
Heksana (26 C)

eki m Naphtalen mula-mula

k Naftalen Toluen Heksana m Naphtalen tersisa
1 0 0 0.439834 m Naphtalen larut
2 0 0 0.560166
10 0.930232558 0.6738544474 0
11 0.069767442 0 0
12 0 0.3261455526 0

Bahan Ikatan Main Group k vk rk qk

ACH 3 10 5 0.5313 0.4
Toluen
ACCH3 4 12 1 1.2663 0.968
ACH 3 10 8 0.5313 0.4
Naftalen
AC 3 11 2 0.3652 0.12
CH2 1 2 4 0.6744 0.54
N-Heksana
CH3 1 1 2 0.9011 0.848

i=1 i=2
0 0 0 0 0 0 0
0 0 0 0 0 0 0
 0.9628002 0.9628001691 0.930232558 0.9302325581 0.5548217 0.6974462 0.6974462
0.07221 0.0722100127 0.069767442 0.0697674419 0.0416116 0 0
0 0 0 0 0 0.4046543 0.4046543
1.0350102 1.0350101818 1 1 0.5964333 1.1021005 1.1021005

Suhu Perb k k Suhu Perb k

1 1
2 2
1:2 10 1:2 10
11 11
12 12
1 1
2 2
30 1:1 10 30 1:1 10
11 11
12 12
1 1
2 2
2:1 10 2:1 10
11 11
12 12

0.0314713 0.0486451365

Percobaa n
Pehi tungan

0.25 0.3 0.35 0.4 0.45 0.5

Fraksi Naftalena
 Percoba an
Pehi tungan

0.3 0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena

Percobaa n
Perhi tunga n

0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena
 1 : 2 m Toluene 43.1241778271 gram
150 mL m Hexane 65.0430842364 gram
50 mL
100 mL BM Toluene 92.13 g/mol
0.8624836 g/mL BM Hexane 86.18 g/mol
0.6504308 g/mL BM naftalen 128.19 g/mol

en mula-mula gram x Naphtalen 0.4724878139

gram x Toluene 0.2019256695
140.4019 gram x Hexane 0.3255865166
1

massa terlarut naftalen k

30 0.0430556
0.0423611
0.0840278
40 0.0430556
0.0423611
0.0840278
50 0.0430556
0.0423611
0.0840278

i=3
0 0 0 0.439834 0.4398340249 0.3640271 0.3640271
0 0 0 0.560166 0.5601659751 0.4636194 0.4636194
0.6738544 0.6738544 0.4019092 0 0 0 0
0 0 0 0 0 0 0
0.513691 0.513691 0.3261456 0 0 0 0
1.1875455 1.1875455 0.7280548 1 1 0.8276465 0.8276465

k Suhu Perb Massa naftalen terlarut k k

1 0.226769
2 0.28881
1:2 50.1254 10 0.387524
11 0.016626
12 0.080271
1 0.156699
2 0.19957
30 1:1 69.3098 10 0.511614
11 0.021181
12 0.110936
1 0.154358
2 0.196587
2:1 72.7736 10 0.51787
11 0.021907
12 0.109278
1
2
1:2 80.0388 10
11
12
1
2
40 1:1 109.5061 10
11
12
1
2
2:1 110.2736 10
11
12
1
2
1:2 140.4019 10
11
12
1

50 1:1 169.6688
 2
50 1:1 169.6688 10
11
12
1
2
2:1 172.0572 10
11
12
 aquadest 0.996513 gram/cc
Pikno kosong 16.5508 gram
Pikno + heksana 32.3824 gram 26
Pikno + toluene 37.5438 gram 26
Pikno + aquadest 40.8061 gram 27

heksana 0.6504308 g/mL

toluena 0.8624836 g/mL

0.3471182
0.4420845
 0
0
0
0.7892026

Sk
KELARUTAN NAFTALENA DALAM CAMPURAN TOLUENA DAN HEKSANA

UNIFAC Subgroup Parameter

m Main Group Subgroup k Rk Qk NOTES

CH3 1 0.9011 0.848 i=1
1 "CH2"
CH2 2 0.6744 0.54 i=2
ACH 10 0.5313 0.4 i=3
3 "ACH"
AC 11 0.3652 0.12
4 "ACCH2" ACCH3 12 1.2663 0.968

k Qk vk(1) vk(2) vk(3) vk(1) Qk vk(2) Qk vk(3) Qk

1 0.848 0 0 2 0 0 1.696
2 0.54 0 0 4 0 0 2.16
10 0.4 8 5 0 3.2 2 0
11 0.12 2 0 0 0.24 0 0
12 0.968 0 1 0 0 0.968 0
qi 3.44 2.968 3.856

k Rk vk(1) vk(2) vk(3) vk(1) Rk vk(2) Rk vk(3) Rk

1 0.9011 0 0 2 0 0 1.8022
2 0.6744 0 0 4 0 0 2.6976
10 0.5313 8 5 0 4.2504 2.6565 0
11 0.3652 2 0 0 0.7304 0 0
12 1.2663 0 1 0 0 1.2663 0
ri 4.9808 3.9228 4.4998

UNIFAC Interaction Parameter

amk (K)
m=1 m=3 m=4
amk (K) k=1 k=2 k=10 k=11 k=12
k=1 0 0 61.13 61.13 76.5
m=1
k=2 0 0 61.13 61.13 76.5
k=10 -11.12 -11.12 0 0 167
m=3
k=11 -11.12 -11.12 0 0 167
m=4 k=12 -69.7 -69.7 -146.8 -146.8 0

mk
313.15 m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 1 1 0.8226619 0.8226619 0.783259
m=1
k=2 1 1 0.8226619 0.8226619 0.783259
 k=10 1.036148153 1.0361482 1 1 0.5866712
m=3
k=11 1.036148153 1.0361482 1 1 0.5866712
m=4 k=12 1.249292061 1.2492921 1.5980513 1.5980513 1

ik
i k=1 k=2 k=10 k=11 k=12
1 1.036148153 1.0361482 1 1 0.5866712
2 1.105664091 1.1056641 1.1950518 1.1950518 0.7214765
3 1 1 0.8226619 0.8226619 0.783259

k=1 0.0889793
k=2 0.1133227
k k=10 0.6430088
k=11 0.028703
k=12 0.1259863

Sk
k=1 k=2 k=10 k=11 k=12
1.055688533 1.055688533 1.0394705 1.0394705 0.6785151

Ji 1.12138348
Li 1.039606252

ln ic 0.0438 0.0873323 0.1112251 0.6546032

ln i r
0.0225
ln i 325
0.0663
i 1.0685 320

ln xAL -0.9018709 315

xAL 0.40580972 310

Suhu, K

1.025456243 305

300

1:2 T:H
295
xperc xperh T
0.242294 0.26116 303.15 290
0.338014 0.35499 313.15 0.2 0.25 0.3

0.472488 0.47969 323.15 Fra

1:1 T:H
xperc xperh T
325

320

315
 0.298908 0.293177 303.15 325
0.402607 0.3893 313.15
320
0.510688 0.5061 323.15
315
2:1 T:H
310
xperc xperh T

Suhu, K
0.30177 0.31167 303.15 305
0.395736 0.405809 313.15
300
0.505399 0.52018 323.15
295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena

325

320

315

310
Suhu, K

305

300

295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena
k=2
 Solvent (T:H)
Naphtalene V Total Solven
Toluene V Toluene
Hexane V Hexane
Toluene (26 C)
Heksana (26 C)

eki m Naphtalen mula-mula

k Naftalen Toluen Heksana m Naphtalen tersisa
1 0 0 0.439834 m Naphtalen larut
2 0 0 0.560166
10 0.930232558 0.6738544474 0
11 0.069767442 0 0
12 0 0.3261455526 0

Bahan Ikatan Main Group k vk rk qk

ACH 3 10 5 0.5313 0.4
Toluen
ACCH3 4 12 1 1.2663 0.968
ACH 3 10 8 0.5313 0.4
Naftalen
AC 3 11 2 0.3652 0.12
CH2 1 2 4 0.6744 0.54
N-Heksana
CH3 1 1 2 0.9011 0.848

i=1 i=2
0 0 0 0 0 0 0
0 0 0 0 0 0 0
 0.9638587 0.9638587474 0.930232558 0.9302325581 0.5457406 0.698213 0.698213
0.0722894 0.0722894061 0.069767442 0.0697674419 0.0409305 0 0
0 0 0 0 0 0.407451 0.407451
1.0361482 1.0361481535 1 1 0.5866712 1.1056641 1.1056641

Suhu Perb k k Suhu Perb k

1 1
2 2
1:2 10 1:2 10
11 11
12 12
1 1
2 2
30 1:1 10 30 1:1 10
11 11
12 12
1 1
2 2
2:1 10 2:1 10
11 11
12 12

0.0303139 0.1089328149

Percobaa n
Pehi tungan

0.25 0.3 0.35 0.4 0.45 0.5

Fraksi Naftalena
 Percoba an
Pehi tungan

0.3 0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena

Percobaa n
Perhi tunga n

0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena
 2 : 1 m Toluene 86.2483556542 gram
150 mL m Hexane 32.5215421182 gram
100 mL
50 mL BM Toluene 92.13 g/mol
0.8624836 g/mL BM Hexane 86.18 g/mol
0.6504308 g/mL BM naftalen 128.19 g/mol

en mula-mula gram x Naphtalen 0.3957357736

gram x Toluene 0.4306630966
110.2736 gram x Hexane 0.1736011298
1

massa terlarut naftalen k

30 0.0430556
0.0423611
0.0840278
40 0.0430556
0.0423611
0.0840278
50 0.0430556
0.0423611
0.0840278

i=3
0 0 0 0.439834 0.4398340249 0.3618347 0.3618347
0 0 0 0.560166 0.5601659751 0.4608272 0.4608272
0.6738544 0.6738544 0.395331 0 0 0 0
0 0 0 0 0 0 0
0.5211973 0.5211973 0.3261456 0 0 0 0
1.1950518 1.1950518 0.7214765 1 1 0.8226619 0.8226619

k Suhu Perb Massa naftalen terlarut k k

1 0.226769
2 0.28881
1:2 50.1254 10 0.387524
11 0.016626
12 0.080271
1 0.156699
2 0.19957
30 1:1 69.3098 10 0.511614
11 0.021181
12 0.110936
1 0.154358
2 0.196587
2:1 72.7736 10 0.51787
11 0.021907
12 0.109278
1
2
1:2 80.0388 10
11
12
1
2
40 1:1 109.5061 10
11
12
1
2
2:1 110.2736 10
11
12
1
2
1:2 140.4019 10
11
12
1

50 1:1 169.6688
 2
50 1:1 169.6688 10
11
12
1
2
2:1 172.0572 10
11
12
 aquadest 0.996513 gram/cc
Pikno kosong 16.5508 gram
Pikno + heksana 32.3824 gram 26
Pikno + toluene 37.5438 gram 26
Pikno + aquadest 40.8061 gram 27

heksana 0.6504308 g/mL

toluena 0.8624836 g/mL

0.344504
0.438755
 0
0
0
0.783259

Sk
KELARUTAN NAFTALENA DALAM CAMPURAN TOLUENA DAN HEKSANA

UNIFAC Subgroup Parameter

m Main Group Subgroup k Rk Qk NOTES

CH3 1 0.9011 0.848 i=1
1 "CH2"
CH2 2 0.6744 0.54 i=2
ACH 10 0.5313 0.4 i=3
3 "ACH"
AC 11 0.3652 0.12
4 "ACCH2" ACCH3 12 1.2663 0.968

k Qk vk(1) vk(2) vk(3) vk(1) Qk vk(2) Qk vk(3) Qk

1 0.848 0 0 2 0 0 1.696
2 0.54 0 0 4 0 0 2.16
10 0.4 8 5 0 3.2 2 0
11 0.12 2 0 0 0.24 0 0
12 0.968 0 1 0 0 0.968 0
qi 3.44 2.968 3.856

k Rk vk(1) vk(2) vk(3) vk(1) Rk vk(2) Rk vk(3) Rk

1 0.9011 0 0 2 0 0 1.8022
2 0.6744 0 0 4 0 0 2.6976
10 0.5313 8 5 0 4.2504 2.6565 0
11 0.3652 2 0 0 0.7304 0 0
12 1.2663 0 1 0 0 1.2663 0
ri 4.9808 3.9228 4.4998

UNIFAC Interaction Parameter

amk (K)
m=1 m=3 m=4
amk (K) k=1 k=2 k=10 k=11 k=12
k=1 0 0 61.13 61.13 76.5
m=1
k=2 0 0 61.13 61.13 76.5
k=10 -11.12 -11.12 0 0 167
m=3
k=11 -11.12 -11.12 0 0 167
m=4 k=12 -69.7 -69.7 -146.8 -146.8 0

mk
313.15 m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 1 1 0.8226619 0.8226619 0.783259
m=1
k=2 1 1 0.8226619 0.8226619 0.783259
 k=10 1.036148153 1.0361482 1 1 0.5866712
m=3
k=11 1.036148153 1.0361482 1 1 0.5866712
m=4 k=12 1.249292061 1.2492921 1.5980513 1.5980513 1

ik
i k=1 k=2 k=10 k=11 k=12
1 1.036148153 1.0361482 1 1 0.5866712
2 1.105664091 1.1056641 1.1950518 1.1950518 0.7214765
3 1 1 0.8226619 0.8226619 0.783259

k=1 0.1332136
k=2 0.1696588
k k=10 0.574356
k=11 0.0284627
k=12 0.094309

Sk
k=1 k=2 k=10 k=11 k=12
1.045301262 1.045301262 1.0026908 1.0026908 0.6851928

Ji 1.106201924
Li 1.013310347

ln ic 0.062868052 0.1320471 0.1681732 0.5753144

ln i r
0.044944369
ln i 325
0.107812421
i 1.11383879 320

ln xAL -0.94339029 315

xAL 0.38930573 310

Suhu, K

0.966963102 305

300

1:2 T:H
295
xperc xperh T
0.242294 0.26116 303.15 290
0.338014 0.35499 313.15 0.2 0.25 0.3

0.472488 0.47969 323.15 Fra

1:1 T:H
xperc xperh T
325

320

315
 0.298908 0.293177 303.15 325
0.402607 0.3893 313.15
320
0.510688 0.5061 323.15
315
2:1 T:H
310
xperc xperh T

Suhu, K
0.30177 0.31167 303.15 305
0.395736 0.405809 313.15
300
0.505399 0.52018 323.15
295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena

325

320

315

310
Suhu, K

305

300

295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena
k=2
 Solvent (T:H)
Naphtalene V Total Solven
Toluene V Toluene
Hexane V Hexane
Toluene (26 C)
Heksana (26 C)

eki m Naphtalen mula-mula

k Naftalen Toluen Heksana m Naphtalen tersisa
1 0 0 0.439834 m Naphtalen larut
2 0 0 0.560166
10 0.930232558 0.6738544474 0
11 0.069767442 0 0
12 0 0.3261455526 0

Bahan Ikatan Main Group k vk rk qk

ACH 3 10 5 0.5313 0.4
Toluen
ACCH3 4 12 1 1.2663 0.968
ACH 3 10 8 0.5313 0.4
Naftalen
AC 3 11 2 0.3652 0.12
CH2 1 2 4 0.6744 0.54
N-Heksana
CH3 1 1 2 0.9011 0.848

i=1 i=2
0 0 0 0 0 0 0
0 0 0 0 0 0 0
 0.9638587 0.9638587474 0.930232558 0.9302325581 0.5457406 0.698213 0.698213
0.0722894 0.0722894061 0.069767442 0.0697674419 0.0409305 0 0
0 0 0 0 0 0.407451 0.407451
1.0361482 1.0361481535 1 1 0.5866712 1.1056641 1.1056641

Suhu Perb k k Suhu Perb k

1 1
2 2
1:2 10 1:2 10
11 11
12 12
1 1
2 2
30 1:1 10 30 1:1 10
11 11
12 12
1 1
2 2
2:1 10 2:1 10
11 11
12 12

0.0285738 0.0807486001

Percobaa n
Pehi tungan

0.25 0.3 0.35 0.4 0.45 0.5

Fraksi Naftalena
 Percoba an
Pehi tungan

0.3 0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena

Percobaa n
Perhi tunga n

0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena
 1 : 1 m Toluene 64.6862667407 gram
150 mL m Hexane 48.7823131773 gram
75 mL
75 mL BM Toluene 92.13 g/mol
0.8624836 g/mL BM Hexane 86.18 g/mol
0.6504308 g/mL BM naftalen 128.19 g/mol

en mula-mula gram x Naphtalen 0.4026066086

gram x Toluene 0.3307452707
109.5601 gram x Hexane 0.2666481207
1

massa terlarut naftalen k

30 0.0430556
0.0423611
0.0840278
40 0.0430556
0.0423611
0.0840278
50 0.0430556
0.0423611
0.0840278

i=3
0 0 0 0.439834 0.4398340249 0.3618347 0.3618347
0 0 0 0.560166 0.5601659751 0.4608272 0.4608272
0.6738544 0.6738544 0.395331 0 0 0 0
0 0 0 0 0 0 0
0.5211973 0.5211973 0.3261456 0 0 0 0
1.1950518 1.1950518 0.7214765 1 1 0.8226619 0.8226619

k Suhu Perb Massa naftalen terlarut k k

1 0.226769
2 0.28881
1:2 50.1254 10 0.387524
11 0.016626
12 0.080271
1 0.156699
2 0.19957
30 1:1 69.3098 10 0.511614
11 0.021181
12 0.110936
1 0.154358
2 0.196587
2:1 72.7736 10 0.51787
11 0.021907
12 0.109278
1
2
1:2 80.0388 10
11
12
1
2
40 1:1 109.5061 10
11
12
1
2
2:1 110.2736 10
11
12
1
2
1:2 140.4019 10
11
12
1

50 1:1 169.6688
 2
50 1:1 169.6688 10
11
12
1
2
2:1 172.0572 10
11
12
 aquadest 0.996513 gram/cc
Pikno kosong 16.5508 gram
Pikno + heksana 32.3824 gram 26
Pikno + toluene 37.5438 gram 26
Pikno + aquadest 40.8061 gram 27

heksana 0.6504308 g/mL

toluena 0.8624836 g/mL

0.344504
0.438755
 0
0
0
0.783259

Sk
KELARUTAN NAFTALENA DALAM CAMPURAN TOLUENA DAN HEKSANA

UNIFAC Subgroup Parameter

m Main Group Subgroup k Rk Qk NOTES

CH3 1 0.9011 0.848 i=1
1 "CH2"
CH2 2 0.6744 0.54 i=2
ACH 10 0.5313 0.4 i=3
3 "ACH"
AC 11 0.3652 0.12
4 "ACCH2" ACCH3 12 1.2663 0.968

k Qk vk(1) vk(2) vk(3) vk(1) Qk vk(2) Qk vk(3) Qk

1 0.848 0 0 2 0 0 1.696
2 0.54 0 0 4 0 0 2.16
10 0.4 8 5 0 3.2 2 0
11 0.12 2 0 0 0.24 0 0
12 0.968 0 1 0 0 0.968 0
qi 3.44 2.968 3.856

k Rk vk(1) vk(2) vk(3) vk(1) Rk vk(2) Rk vk(3) Rk

1 0.9011 0 0 2 0 0 1.8022
2 0.6744 0 0 4 0 0 2.6976
10 0.5313 8 5 0 4.2504 2.6565 0
11 0.3652 2 0 0 0.7304 0 0
12 1.2663 0 1 0 0 1.2663 0
ri 4.9808 3.9228 4.4998

UNIFAC Interaction Parameter

amk (K)
amk (K) m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 0 0 61.13 61.13 76.5
m=1
k=2 0 0 61.13 61.13 76.5
k=10 -11.12 -11.12 0 0 167
m=3
k=11 -11.12 -11.12 0 0 167
m=4 k=12 -69.7 -69.7 -146.8 -146.8 0

mk
313.15 m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 1 1 0.8226619 0.8226619 0.783259
m=1
k=2 1 1 0.8226619 0.8226619 0.783259
 k=10 1.036148153 1.0361482 1 1 0.5866712
m=3
k=11 1.036148153 1.0361482 1 1 0.5866712
m=4 k=12 1.249292061 1.2492921 1.5980513 1.5980513 1

ik
i k=1 k=2 k=10 k=11 k=12
1 1.036148153 1.0361482 1 1 0.5866712
2 1.105664091 1.1056641 1.1950518 1.1950518 0.7214765
3 1 1 0.8226619 0.8226619 0.783259

k=1 0.1985352
k=2 0.2528515
k k=10 0.4550943
k=11 0.0232421
k=12 0.0702768

Sk
k=1 k=2 k=10 k=11 k=12
1.034810437 1.034810437 0.9619811 0.9619811 0.7044558

Ji 1.102880825
Li 0.985569897

ln ic 0.108007654 0.1987919 0.2531784 0.4370241

ln i r
0.092075234
ln i 325
0.200082889
i 1.221504 320

ln xAL -1.03566076 315

xAL 0.35499174 310

Suhu, K

1.050228211 305

300

1:2 T:H
295
xperc xperh T
0.242294 0.26116 303.15 290
0.338014 0.35499 313.15 0.2 0.25 0.3

0.472488 0.47969 323.15 Fra

1:1 T:H
xperc xperh T
325

320

315
 0.298908 0.293177 303.15 325
0.402607 0.3893 313.15
320
0.510688 0.5061 323.15
315
2:1 T:H
310
xperc xperh T

Suhu, K
0.30177 0.31167 303.15 305
0.395736 0.405809 313.15
300
0.505399 0.52018 323.15
295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena

325

320

315

310
Suhu, K

305

300

295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena
k=2
 Solvent (T:H)
Naphtalene V Total Solven
Toluene V Toluene
Hexane V Hexane
Toluene (26 C)
Heksana (26 C)

eki m Naphtalen mula-mula

k Naftalen Toluen Heksana m Naphtalen tersisa
1 0 0 0.439834 m Naphtalen larut
2 0 0 0.560166
10 0.930232558 0.6738544474 0
11 0.069767442 0 0
12 0 0.3261455526 0

Bahan Ikatan Main Group k vk rk qk

ACH 3 10 5 0.5313 0.4
Toluen
ACCH3 4 12 1 1.2663 0.968
ACH 3 10 8 0.5313 0.4
Naftalen
AC 3 11 2 0.3652 0.12
CH2 1 2 4 0.6744 0.54
N-Heksana
CH3 1 1 2 0.9011 0.848

i=1 i=2
0 0 0 0 0 0 0
0 0 0 0 0 0 0
 0.9638587 0.9638587474 0.930232558 0.9302325581 0.5457406 0.698213 0.698213
0.0722894 0.0722894061 0.069767442 0.0697674419 0.0409305 0 0
0 0 0 0 0 0.407451 0.407451
1.0361482 1.0361481535 1 1 0.5866712 1.1056641 1.1056641

Suhu Perb k k Suhu Perb k

1 1
2 2
1:2 10 1:2 10
11 11
12 12
1 1
2 2
30 1:1 10 30 1:1 10
11 11
12 12
1 1
2 2
2:1 10 2:1 10
11 11
12 12

0.0214564 0.058526599

Percobaa n
Pehi tungan

0.25 0.3 0.35 0.4 0.45 0.5

Fraksi Naftalena
 Percoba an
Pehi tungan

0.3 0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena

Percobaa n
Perhi tunga n

0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena
 1 : 2 m Toluene 43.1241778271 gram
150 mL m Hexane 65.0430842364 gram
50 mL
100 mL BM Toluene 92.13 g/mol
0.8624836 g/mL BM Hexane 86.18 g/mol
0.6504308 g/mL BM naftalen 128.19 g/mol

en mula-mula gram x Naphtalen 0.3380139049

gram x Toluene 0.2534007536
80.0388 gram x Hexane 0.4085853416
1

massa terlarut naftalen k

30 0.0430556
0.0423611
0.0840278
40 0.0430556
0.0423611
0.0840278
50 0.0430556
0.0423611
0.0840278

i=3
0 0 0 0.439834 0.4398340249 0.3618347 0.3618347
0 0 0 0.560166 0.5601659751 0.4608272 0.4608272
0.6738544 0.6738544 0.395331 0 0 0 0
0 0 0 0 0 0 0
0.5211973 0.5211973 0.3261456 0 0 0 0
1.1950518 1.1950518 0.7214765 1 1 0.8226619 0.8226619

k Suhu Perb Massa naftalen terlarut k k

1 0.226769
2 0.28881
1:2 50.1254 10 0.387524
11 0.016626
12 0.080271
1 0.156699
2 0.19957
30 1:1 69.3098 10 0.511614
11 0.021181
12 0.110936
1 0.154358
2 0.196587
2:1 72.7736 10 0.51787
11 0.021907
12 0.109278
1
2
1:2 80.0388 10
11
12
1
2
40 1:1 109.5061 10
11
12
1
2
2:1 110.2736 10
11
12
1
2
1:2 140.4019 10
11
12
1

50 1:1 169.6688
 2
50 1:1 169.6688 10
11
12
1
2
2:1 172.0572 10
11
12
 aquadest 0.996513 gram/cc
Pikno kosong 16.5508 gram
Pikno + heksana 32.3824 gram 26
Pikno + toluene 37.5438 gram 26
Pikno + aquadest 40.8061 gram 27

heksana 0.6504308 g/mL

toluena 0.8624836 g/mL

0.344504
0.438755
 0
0
0
0.783259

Sk
KELARUTAN NAFTALENA DALAM CAMPURAN TOLUENA DAN HEKSANA

UNIFAC Subgroup Parameter

m Main Group Subgroup k Rk Qk NOTES

CH3 1 0.9011 0.848 i=1
1 "CH2"
CH2 2 0.6744 0.54 i=2
ACH 10 0.5313 0.4 i=3
3 "ACH"
AC 11 0.3652 0.12
4 "ACCH2" ACCH3 12 1.2663 0.968

k Qk vk(1) vk(2) vk(3) vk(1) Qk vk(2) Qk vk(3) Qk

1 0.848 0 0 2 0 0 1.696
2 0.54 0 0 4 0 0 2.16
10 0.4 8 5 0 3.2 2 0
11 0.12 2 0 0 0.24 0 0
12 0.968 0 1 0 0 0.968 0
qi 3.44 2.968 3.856

k Rk vk(1) vk(2) vk(3) vk(1) Rk vk(2) Rk vk(3) Rk

1 0.9011 0 0 2 0 0 1.8022
2 0.6744 0 0 4 0 0 2.6976
10 0.5313 8 5 0 4.2504 2.6565 0
11 0.3652 2 0 0 0.7304 0 0
12 1.2663 0 1 0 0 1.2663 0
ri 4.9808 3.9228 4.4998

UNIFAC Interaction Parameter

amk (K)
m=1 m=3 m=4
amk (K) k=1 k=2 k=10 k=11 k=12
k=1 0 0 61.13 61.13 76.5
m=1
k=2 0 0 61.13 61.13 76.5
k=10 -11.12 -11.12 0 0 167
m=3
k=11 -11.12 -11.12 0 0 167
m=4 k=12 -69.7 -69.7 -146.8 -146.8 0

mk
303.15 m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 1 1 0.8173815 0.8173815 0.7769725
m=1
k=2 1 1 0.8173815 0.8173815 0.7769725
 k=10 1.037362579 1.0373626 1 1 0.5764409
m=3
k=11 1.037362579 1.0373626 1 1 0.5764409
m=4 k=12 1.258498296 1.2584983 1.6229553 1.6229553 1

ik
i k=1 k=2 k=10 k=11 k=12
1 1.037362579 1.0373626 1 1 0.5764409
2 1.10948501 1.109485 1.2031741 1.2031741 0.7145828
3 1 1 0.8173815 0.8173815 0.7769725

k=1 0.1034529
k=2 0.131756
k k=10 0.5962882
k=11 0.0220233
k=12 0.1464796

Sk
k=1 k=2 k=10 k=11 k=12
1.06096644 1.06096644 1.0482967 1.0482967 0.6856505

Ji 1.142957211
Li 1.046048706

ln ic 0.060208573 0.1011513 0.1288248 0.6126922

ln i r
0.029335194
ln i 325
0.089543767
i 1.0936752 320

ln xAL -1.16580607 315

xAL 0.31167133 310

Suhu, K

1.032805582 305

300

1:2 T:H
295
xperc xperh T
0.242294 0.26116 303.15 290
0.338014 0.35499 313.15 0.2 0.25 0.3

0.472488 0.47969 323.15 Fra

1:1 T:H
xperc xperh T
325

320

315
 0.298908 0.293177 303.15 325
0.402607 0.3893 313.15
320
0.510688 0.5061 323.15
315
2:1 T:H
310
xperc xperh T

Suhu, K
0.30177 0.31167 303.15 305
0.395736 0.405809 313.15
300
0.505399 0.52018 323.15
295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena

325

320

315

310
Suhu, K

305

300

295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena
k=2
 Solvent (T:H)
Naphtalene V Total Solven
Toluene V Toluene
Hexane V Hexane
Toluene (26 C)
Heksana (26 C)

eki m Naphtalen mula-mula

k Naftalen Toluen Heksana m Naphtalen tersisa
1 0 0 0.439834 m Naphtalen larut
2 0 0 0.560166
10 0.930232558 0.6738544474 0
11 0.069767442 0 0
12 0 0.3261455526 0

Bahan Ikatan Main Group k vk rk qk

ACH 3 10 5 0.5313 0.4
Toluen
ACCH3 4 12 1 1.2663 0.968
ACH 3 10 8 0.5313 0.4
Naftalen
AC 3 11 2 0.3652 0.12
CH2 1 2 4 0.6744 0.54
N-Heksana
CH3 1 1 2 0.9011 0.848

i=1 i=2
0 0 0 0 0 0 0
0 0 0 0 0 0 0
 0.9649884 0.964988446 0.930232558 0.9302325581 0.5362241 0.6990314 0.6990314
0.0723741 0.0723741334 0.069767442 0.0697674419 0.0402168 0 0
0 0 0 0 0 0.4104536 0.4104536
1.0373626 1.0373625794 1 1 0.5764409 1.109485 1.109485

Suhu Perb k k Suhu Perb k

1 1
2 2
1:2 10 1:2 10
11 11
12 12
1 1
2 2
30 1:1 10 30 1:1 10
11 11
12 12
1 1
2 2
2:1 10 2:1 10
11 11
12 12

0.0242994 0.1231485092

Percobaa n
Pehi tungan

0.25 0.3 0.35 0.4 0.45 0.5

Fraksi Naftalena
 Percoba an
Pehi tungan

0.3 0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena

Percobaa n
Perhi tunga n

0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena
 2 : 1 m Toluene 86.2483556542 gram
150 mL m Hexane 32.5215421182 gram
100 mL
50 mL BM Toluene 92.13 g/mol
0.8624836 g/mL BM Hexane 86.18 g/mol
0.6504308 g/mL BM naftalen 128.19 g/mol

en mula-mula gram x Naphtalen 0.3017715408

gram x Toluene 0.4976320246
72.7736 gram x Hexane 0.2005964346
1

massa terlarut naftalen k

30 0.0430556
0.0423611
0.0840278
40 0.0430556
0.0423611
0.0840278
50 0.0430556
0.0423611
0.0840278

i=3
0 0 0 0.439834 0.4398340249 0.3595122 0.3595122
0 0 0 0.560166 0.5601659751 0.4578693 0.4578693
0.6738544 0.6738544 0.3884373 0 0 0 0
0 0 0 0 0 0 0
0.5293196 0.5293196 0.3261456 0 0 0 0
1.2031741 1.2031741 0.7145828 1 1 0.8173815 0.8173815

k Suhu Perb Massa naftalen terlarut k k

1 0.226769
2 0.28881
1:2 50.1254 10 0.387524
11 0.016626
12 0.080271
1 0.156699
2 0.19957
30 1:1 69.3098 10 0.511614
11 0.021181
12 0.110936
1 0.154358
2 0.196587
2:1 72.7736 10 0.51787
11 0.021907
12 0.109278
1
2
1:2 80.0388 10
11
12
1
2
40 1:1 109.5061 10
11
12
1
2
2:1 110.2736 10
11
12
1
2
1:2 140.4019 10
11
12
1

50 1:1 169.6688
 2
50 1:1 169.6688 10
11
12
1
2
2:1 172.0572 10
11
12
 aquadest 0.996513 gram/cc
Pikno kosong 16.5508 gram
Pikno + heksana 32.3824 gram 26
Pikno + toluene 37.5438 gram 26
Pikno + aquadest 40.8061 gram 27

heksana 0.6504308 g/mL

toluena 0.8624836 g/mL

0.3417389
0.4352336
 0
0
0
0.7769725

Sk
KELARUTAN NAFTALENA DALAM CAMPURAN TOLUENA DAN HEKSANA

UNIFAC Subgroup Parameter

m Main Group Subgroup k Rk Qk NOTES

CH3 1 0.9011 0.848 i=1
1 "CH2"
CH2 2 0.6744 0.54 i=2
ACH 10 0.5313 0.4 i=3
3 "ACH"
AC 11 0.3652 0.12
4 "ACCH2" ACCH3 12 1.2663 0.968

k Qk vk(1) vk(2) vk(3) vk(1) Qk vk(2) Qk vk(3) Qk

1 0.848 0 0 2 0 0 1.696
2 0.54 0 0 4 0 0 2.16
10 0.4 8 5 0 3.2 2 0
11 0.12 2 0 0 0.24 0 0
12 0.968 0 1 0 0 0.968 0
qi 3.44 2.968 3.856

k Rk vk(1) vk(2) vk(3) vk(1) Rk vk(2) Rk vk(3) Rk

1 0.9011 0 0 2 0 0 1.8022
2 0.6744 0 0 4 0 0 2.6976
10 0.5313 8 5 0 4.2504 2.6565 0
11 0.3652 2 0 0 0.7304 0 0
12 1.2663 0 1 0 0 1.2663 0
ri 4.9808 3.9228 4.4998

UNIFAC Interaction Parameter

amk (K)
m=1 m=3 m=4
amk (K) k=1 k=2 k=10 k=11 k=12
k=1 0 0 61.13 61.13 76.5
m=1
k=2 0 0 61.13 61.13 76.5
k=10 -11.12 -11.12 0 0 167
m=3
k=11 -11.12 -11.12 0 0 167
m=4 k=12 -69.7 -69.7 -146.8 -146.8 0

mk
303.15 m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 1 1 0.8173815 0.8173815 0.7769725
m=1
k=2 1 1 0.8173815 0.8173815 0.7769725
 k=10 1.037362579 1.0373626 1 1 0.5764409
m=3
k=11 1.037362579 1.0373626 1 1 0.5764409
m=4 k=12 1.258498296 1.2584983 1.6229553 1.6229553 1

ik
i k=1 k=2 k=10 k=11 k=12
1 1.037362579 1.0373626 1 1 0.5764409
2 1.10948501 1.109485 1.2031741 1.2031741 0.7145828
3 1 1 0.8173815 0.8173815 0.7769725

k=1 0.1566995
k=2 0.1995701
k k=10 0.511614
k=11 0.0211806
k=12 0.1109359

Sk
k=1 k=2 k=10 k=11 k=12
1.048583323 1.048583323 1.0040467 1.0040467 0.6948721

Ji 1.126977826
Li 1.015656998

ln ic 0.08889685 0.1550227 0.1974345 0.5133087

ln i r
0.061819575
ln i 325
0.150716425
i 1.16266691 320

ln xAL -1.22697873 315

xAL 0.29317701 310

Suhu, K

0.980826614 305

300

1:2 T:H
295
xperc xperh T
0.242294 0.26116 303.15 290
0.338014 0.35499 313.15 0.2 0.25 0.3

0.472488 0.47969 323.15 Fra

1:1 T:H
xperc xperh T
325

320

315
 0.298908 0.293177 303.15 325
0.402607 0.3893 313.15
320
0.510688 0.5061 323.15
315
2:1 T:H
310
xperc xperh T

Suhu, K
0.30177 0.31167 303.15 305
0.395736 0.405809 313.15
300
0.505399 0.52018 323.15
295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena

325

320

315

310
Suhu, K

305

300

295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena
k=2
 Solvent (T:H)
Naphtalene V Total Solven
Toluene V Toluene
Hexane V Hexane
Toluene (26 C)
Heksana (26 C)

eki m Naphtalen mula-mula

k Naftalen Toluen Heksana m Naphtalen tersisa
1 0 0 0.439834 m Naphtalen larut
2 0 0 0.560166
10 0.930232558 0.6738544474 0
11 0.069767442 0 0
12 0 0.3261455526 0

Bahan Ikatan Main Group k vk rk qk

ACH 3 10 5 0.5313 0.4
Toluen
ACCH3 4 12 1 1.2663 0.968
ACH 3 10 8 0.5313 0.4
Naftalen
AC 3 11 2 0.3652 0.12
CH2 1 2 4 0.6744 0.54
N-Heksana
CH3 1 1 2 0.9011 0.848

i=1 i=2
0 0 0 0 0 0 0
0 0 0 0 0 0 0
 0.9649884 0.964988446 0.930232558 0.9302325581 0.5362241 0.6990314 0.6990314
0.0723741 0.0723741334 0.069767442 0.0697674419 0.0402168 0 0
0 0 0 0 0 0.4104536 0.4104536
1.0373626 1.0373625794 1 1 0.5764409 1.109485 1.109485

Suhu Perb k k Suhu Perb k

1 1
2 2
1:2 10 1:2 10
11 11
12 12
1 1
2 2
30 1:1 10 30 1:1 10
11 11
12 12
1 1
2 2
2:1 10 2:1 10
11 11
12 12

0.021377 0.0920284441

Percobaa n
Pehi tungan

0.25 0.3 0.35 0.4 0.45 0.5

Fraksi Naftalena
 Percoba an
Pehi tungan

0.3 0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena

Percobaa n
Perhi tunga n

0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena
 1 : 1 m Toluene 64.6862667407 gram
150 mL m Hexane 48.7823131773 gram
75 mL
75 mL BM Toluene 92.13 g/mol
0.8624836 g/mL BM Hexane 86.18 g/mol
0.6504308 g/mL BM naftalen 128.19 g/mol

en mula-mula gram x Naphtalen 0.2989080887

gram x Toluene 0.3881576819
69.3098 gram x Hexane 0.3129342294
1

massa terlarut naftalen k

30 0.0430556
0.0423611
0.0840278
40 0.0430556
0.0423611
0.0840278
50 0.0430556
0.0423611
0.0840278

i=3
0 0 0 0.439834 0.4398340249 0.3595122 0.3595122
0 0 0 0.560166 0.5601659751 0.4578693 0.4578693
0.6738544 0.6738544 0.3884373 0 0 0 0
0 0 0 0 0 0 0
0.5293196 0.5293196 0.3261456 0 0 0 0
1.2031741 1.2031741 0.7145828 1 1 0.8173815 0.8173815

k Suhu Perb Massa naftalen terlarut k k

1 0.226769
2 0.28881
1:2 50.1254 10 0.387524
11 0.016626
12 0.080271
1 0.156699
2 0.19957
30 1:1 69.3098 10 0.511614
11 0.021181
12 0.110936
1 0.154358
2 0.196587
2:1 72.7736 10 0.51787
11 0.021907
12 0.109278
1
2
1:2 80.0388 10
11
12
1
2
40 1:1 109.5061 10
11
12
1
2
2:1 110.2736 10
11
12
1
2
1:2 140.4019 10
11
12
1

50 1:1 169.6688
 2
50 1:1 169.6688 10
11
12
1
2
2:1 172.0572 10
11
12
 aquadest 0.996513 gram/cc
Pikno kosong 16.5508 gram
Pikno + heksana 32.3824 gram 26
Pikno + toluene 37.5438 gram 26
Pikno + aquadest 40.8061 gram 27

heksana 0.6504308 g/mL

toluena 0.8624836 g/mL

0.3417389
0.4352336
 0
0
0
0.7769725

Sk
KELARUTAN NAFTALENA DALAM CAMPURAN TOLUENA DAN HEKSANA

UNIFAC Subgroup Parameter

m Main Group Subgroup k Rk Qk NOTES

CH3 1 0.9011 0.848 i=1
1 "CH2"
CH2 2 0.6744 0.54 i=2
ACH 10 0.5313 0.4 i=3
3 "ACH"
AC 11 0.3652 0.12
4 "ACCH2" ACCH3 12 1.2663 0.968

k Qk vk(1) vk(2) vk(3) vk(1) Qk vk(2) Qk vk(3) Qk

1 0.848 0 0 2 0 0 1.696
2 0.54 0 0 4 0 0 2.16
10 0.4 8 5 0 3.2 2 0
11 0.12 2 0 0 0.24 0 0
12 0.968 0 1 0 0 0.968 0
qi 3.44 2.968 3.856

k Rk vk(1) vk(2) vk(3) vk(1) Rk vk(2) Rk vk(3) Rk

1 0.9011 0 0 2 0 0 1.8022
2 0.6744 0 0 4 0 0 2.6976
10 0.5313 8 5 0 4.2504 2.6565 0
11 0.3652 2 0 0 0.7304 0 0
12 1.2663 0 1 0 0 1.2663 0
ri 4.9808 3.9228 4.4998

UNIFAC Interaction Parameter

amk (K)
m=1 m=3 m=4
amk (K) k=1 k=2 k=10 k=11 k=12
k=1 0 0 61.13 61.13 76.5
m=1
k=2 0 0 61.13 61.13 76.5
k=10 -11.12 -11.12 0 0 167
m=3
k=11 -11.12 -11.12 0 0 167
m=4 k=12 -69.7 -69.7 -146.8 -146.8 0

mk
303.15 m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 1 1 0.8173815 0.8173815 0.7769725
m=1
k=2 1 1 0.8173815 0.8173815 0.7769725
 k=10 1.037362579 1.0373626 1 1 0.5764409
m=3
k=11 1.037362579 1.0373626 1 1 0.5764409
m=4 k=12 1.258498296 1.2584983 1.6229553 1.6229553 1

ik
i k=1 k=2 k=10 k=11 k=12
1 1.037362579 1.0373626 1 1 0.5764409
2 1.10948501 1.109485 1.2031741 1.2031741 0.7145828
3 1 1 0.8173815 0.8173815 0.7769725

k=1 0.2267692
k=2 0.2888098
k k=10 0.3875244
k=11 0.0166256
k=12 0.080271

Sk
k=1 k=2 k=10 k=11 k=12
1.035850003 1.035850003 0.955851 0.955851 0.7138303

Ji 1.119535014
Li 0.983517776

ln ic 0.144113624 0.2271003 0.2892315 0.3634204

ln i r
0.12223121
ln i 325
0.266344834
i 1.30518505 320

ln xAL -1.34260714 315

xAL 0.26116389 310

Suhu, K

1.077878168 305

300

1:2 T:H
295
xperc xperh T
0.242294 0.26116 303.15 290
0.338014 0.35499 313.15 0.2 0.25 0.3

0.472488 0.47969 323.15 Fra

1:1 T:H
xperc xperh T
325

320

315
 0.298908 0.293177 303.15 325
0.402607 0.3893 313.15
320
0.510688 0.5061 323.15
315
2:1 T:H
310
xperc xperh T

Suhu, K
0.30177 0.31167 303.15 305
0.395736 0.405809 313.15
300
0.505399 0.52018 323.15
295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena

325

320

315

310
Suhu, K

305

300

295

290
0.25 0.3 0.35 0.4
Fraksi Naftalena
k=2
 Solvent (T:H)
Naphtalene V Total Solven
Toluene V Toluene
Hexane V Hexane
Toluene (26 C)
Heksana (26 C)

eki m Naphtalen mula-mula

k Naftalen Toluen Heksana m Naphtalen tersisa
1 0 0 0.439834 m Naphtalen larut
2 0 0 0.560166
10 0.930232558 0.6738544474 0
11 0.069767442 0 0
12 0 0.3261455526 0

Bahan Ikatan Main Group k vk rk qk

ACH 3 10 5 0.5313 0.4
Toluen
ACCH3 4 12 1 1.2663 0.968
ACH 3 10 8 0.5313 0.4
Naftalen
AC 3 11 2 0.3652 0.12
CH2 1 2 4 0.6744 0.54
N-Heksana
CH3 1 1 2 0.9011 0.848

i=1 i=2
0 0 0 0 0 0 0
0 0 0 0 0 0 0
 0.9649884 0.964988446 0.930232558 0.9302325581 0.5362241 0.6990314 0.6990314
0.0723741 0.0723741334 0.069767442 0.0697674419 0.0402168 0 0
0 0 0 0 0 0.4104536 0.4104536
1.0373626 1.0373625794 1 1 0.5764409 1.109485 1.109485

Suhu Perb k k Suhu Perb k

1 1
2 2
1:2 10 1:2 10
11 11
12 12
1 1
2 2
30 1:1 10 30 1:1 10
11 11
12 12
1 1
2 2
2:1 10 2:1 10
11 11
12 12

0.0142433 0.0648214098

Percobaa n
Pehi tungan

0.25 0.3 0.35 0.4 0.45 0.5

Fraksi Naftalena
 Percoba an
Pehi tungan

0.3 0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena

Percobaa n
Perhi tunga n

0.35 0.4 0.45 0.5 0.55

Fraksi Naftalena
 1 : 2 m Toluene 43.1241778271 gram
150 mL m Hexane 65.0430842364 gram
50 mL
100 mL BM Toluene 92.13 g/mol
0.8624836 g/mL BM Hexane 86.18 g/mol
0.6504308 g/mL BM naftalen 128.19 g/mol

en mula-mula gram x Naphtalen 0.242294443

gram x Toluene 0.2900410757
50.1254 gram x Hexane 0.4676644813
1

massa terlarut naftalen k

30 0.0430556
0.0423611
0.0840278
40 0.0430556
0.0423611
0.0840278
50 0.0430556
0.0423611
0.0840278

i=3
0 0 0 0.439834 0.4398340249 0.3595122 0.3595122
0 0 0 0.560166 0.5601659751 0.4578693 0.4578693
0.6738544 0.6738544 0.3884373 0 0 0 0
0 0 0 0 0 0 0
0.5293196 0.5293196 0.3261456 0 0 0 0
1.2031741 1.2031741 0.7145828 1 1 0.8173815 0.8173815

k Suhu Perb Massa naftalen terlarut k k

1 0.226769
2 0.28881
1:2 50.1254 10 0.387524
11 0.016626
12 0.080271
1 0.156699
2 0.19957
30 1:1 69.3098 10 0.511614
11 0.021181
12 0.110936
1 0.154358
2 0.196587
2:1 72.7736 10 0.51787
11 0.021907
12 0.109278
1
2
1:2 80.0388 10
11
12
1
2
40 1:1 109.5061 10
11
12
1
2
2:1 110.2736 10
11
12
1
2
1:2 140.4019 10
11
12
1

50 1:1 169.6688
 2
50 1:1 169.6688 10
11
12
1
2
2:1 172.0572 10
11
12
 aquadest 0.996513 gram/cc
Pikno kosong 16.5508 gram
Pikno + heksana 32.3824 gram 26
Pikno + toluene 37.5438 gram 26
Pikno + aquadest 40.8061 gram 27

heksana 0.6504308 g/mL

toluena 0.8624836 g/mL

0.3417389
0.4352336
 0
0
0
0.7769725

Sk
Suhu Perbandingan Toluenea:Heksana k k Sk m
1 0.2268 1.0359
1
2 0.2888 1.0359
1:2 10 0.3875 0.9559
3
11 0.0166 0.9559
12 0.0803 0.7138 4
1 0.1567 1.0486
2 0.1996 1.0486
30 1:1 10 0.5116 1.0040 k
11 0.0212 1.0040 1
12 0.1109 0.6949 2
1 0.1035 1.0610 10
2 0.1318 1.0610 11
2:1 10 0.5963 1.0483 12
11 0.0220 1.0483
12 0.1465 0.6857
Suhu Perbandingan Toluenea:Heksana k k Sk k
1 0.1985 1.0348 1
2 0.2529 1.0348 2
1:2 10 0.4551 0.9620 10
11 0.0232 0.9620 11
12 0.0703 0.7045 12
1 0.1332 1.0453
2 0.1697 1.0453
40 1:1 10 0.5744 1.0027
11 0.0285 1.0027
12 0.0943 0.6852 amk (K)
1 0.0890 1.0557
2 0.1133 1.0557 m=1
2:1 10 0.6430 1.0395
11 0.0287 1.0395 m=3
12 0.1260 0.6785
Suhu Perbandingan Toluenea:Heksana k k Sk m=4
1 0.1587 1.0339
2 0.2021 1.0339
1:2 10 0.5505 0.9701 303.15
11 0.0326 0.9701
12 0.0562 0.6886
m=1
1 0.1089 1.0422
2 0.1386 1.0422
m=3
50 1:1 10 0.6394 1.0017
11 0.0360 1.0017 m=4
12 0.0771 0.6752
1 0.0723 1.0503
313.15
2:1
50

2 0.0921 1.0503 313.15

2:1 10 0.6968 1.0305
11 0.0364 1.0305
m=1
12 0.1024 0.6694
m=3

m=4

323.15

m=1

m=3

m=4
 Main Group Subgroup k Rk Qk
CH3 1 0.9011 0.848
"CH2" Suhu, C
CH2 2 0.6744 0.54
ACH 10 0.5313 0.4
"ACH"
AC 11 0.3652 0.12 30
"ACCH2" ACCH3 12 1.2663 0.968

40
Qk vk(1) vk(2) vk(3) vk(1) Qk vk(2) Qk vk(3) Qk
0.848 0 0 2 0 0 1.696
0.54 0 0 4 0 0 2.16 50
0.4 8 5 0 3.2 2 0
0.12 2 0 0 0.24 0 0
0.968 0 1 0 0 0.968 0
qi 3.44 2.968 3.856
Suhu, C
Rk vk(1) vk(2) vk(3) vk(1) Rk vk(2) Rk vk(3) Rk
0.9011 0 0 2 0 0 1.8022
0.6744 0 0 4 0 0 2.6976 30
0.5313 8 5 0 4.2504 2.6565 0
0.3652 2 0 0 0.7304 0 0
1.2663 0 1 0 0 1.2663 0 40
ri 4.9808 3.9228 4.4998

50
amk (K)
amk (K) m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12 Suhu, C
k=1 0.0000 0.0000 61.1300 61.1300 76.5000
k=2 0.0000 0.0000 61.1300 61.1300 76.5000 30
k=10 -11.1200 -11.1200 0.0000 0.0000 167.0000
k=11 -11.1200 -11.1200 0.0000 0.0000 167.0000
k=12 -69.7000 -69.7000 -146.8000 -146.8000 0.0000 40

mk
303.15 m=1 m=3 m=4 50
k=1 k=2 k=10 k=11 k=12
k=1 1.0000 1.0000 0.8174 0.8174 0.7770
k=2 1.0000 1.0000 0.8174 0.8174 0.7770
k=10 1.0374 1.0374 1.0000 1.0000 0.5764
k=11 1.0374 1.0374 1.0000 1.0000 0.5764
k=12 1.2585 1.2585 1.6230 1.6230 1.0000

mk
313.15
313.15 m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 1.0000 1.0000 0.8227 0.8227 0.7833
k=2 1.0000 1.0000 0.8227 0.8227 0.7833
k=10 1.0361 1.0361 1.0000 1.0000 0.5867
k=11 1.0361 1.0361 1.0000 1.0000 0.5867
k=12 1.2493 1.2493 1.5981 1.5981 1.0000

mk
323.15 m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 1.0000 1.0000 0.8276 0.8276 0.7892
k=2 1.0000 1.0000 0.8276 0.8276 0.7892
k=10 1.0350 1.0350 1.0000 1.0000 0.5964
k=11 1.0350 1.0350 1.0000 1.0000 0.5964
k=12 1.2407 1.2407 1.5750 1.5750 1.0000
 ik
Komponen
k=1 k=2 k=10 k=11 k=12
1 1.0374 1.0374 1.0000 1.0000 0.5764
2 1.1095 1.1095 1.2032 1.2032 0.7146
3 1.0000 1.0000 0.8174 0.8174 0.7770
1 1.0361 1.0361 1.0000 1.0000 0.5867
2 1.1057 1.1057 1.1951 1.1951 0.7215
3 1.0000 1.0000 0.8227 0.8227 0.7833
1 1.0350 1.0350 1.0000 1.0000 0.5964
2 1.1021 1.1021 1.1875 1.1875 0.7281
3 1.0000 1.0000 0.8276 0.8276 0.7892

Perbandingan Toluena:Heksana ln ic ln ir ln i i

1:2 0.1441 0.1222 0.2663 1.3052

1:1 0.0889 0.0618 0.1507 1.1627
2:1 0.0602 0.0293 0.0895 1.0937
1:2 0.1080 0.0921 0.2001 1.2215
1:1 0.0629 0.0449 0.1078 1.1138
2:1 0.0438 0.0225 0.0663 1.0685
1:2 0.0669 0.0579 0.1248 1.1329
1:1 0.0411 0.0302 0.0712 1.0738
2:1 0.0283 0.0155 0.0438 1.0448

Perbandingan Toluena:Heksana x persamaan x percobaan %error

1:2 0.2612 0.2423 7.23
1:1 0.2932 0.2989 1.95
2:1 0.3117 0.3018 3.18
1:2 0.3550 0.3380 4.78
1:1 0.3893 0.4026 3.42
2:1 0.4058 0.3957 2.48
1:2 0.4797 0.4725 1.50
1:1 0.5061 0.5107 0.90
2:1 0.5202 0.5054 2.84
 Perbandingan
Suhu, C xpercobaan F q ln(gcomb)
Toluena:Heksana
1:2 0.2423 0.2713 0.2383 0.1441
30 1:1 0.2989 0.3369 0.3036 0.0889
2:1 0.3018 0.3449 0.3157 0.0602
1:2 0.3380 0.3728 0.3331 0.1080
40 1:1 0.4026 0.4454 0.4080 0.0629
2:1 0.3957 0.4438 0.4114 0.0438
1:2 0.4725 0.5104 0.4670 0.0669
50 1:1 0.5107 0.5543 0.5162 0.0411
2:1 0.5054 0.5545 0.5217 0.0283

Perbandingan
Suhu, C Si(qitij) qj/Si(qitij) Sj{qjtkj/(Siqitij)} ln(gresid)
Toluena:Heksana
1:2 1.1425 0.2086 0.8415 0.0872
30 1:1 1.1048 0.2748 0.8643 0.1239
2:1 1.0776 0.2929 0.8773 0.1652
1:2 1.1203 0.2974 0.8653 0.0726
40 1:1 1.0860 0.3757 0.8897 0.0957
2:1 1.0644 0.3865 0.9007 0.1270
1:2 1.0929 0.4274 0.8960 0.0523 60
50 1:1 1.0678 0.4834 0.9145 0.0683 50
2:1 1.0506 0.4966 0.9252 0.0878
40

Suhu, K
Perbandingan 30
Suhu, C xpercobaan g xperhitungan %error
Toluena:Heksana
1:2 0.2730 11.23% 20
0.2423 1.2603
30 1:1 0.2989 1.2371 0.2781 7.50% 10
2:1 0.3018 1.2529 0.2746 9.91%
0
1:2 0.3380 1.1979 0.3653 7.47% 0.2000 0.2500
40 1:1 0.4026 1.1718 0.3734 7.81%
2:1 0.3957 1.1862 0.3689 7.27%
1:2 0.4725 1.1265 0.4869 2.95%
50 1:1 0.5107 1.1155 0.4917 3.87%
2:1 0.5054 1.1231 0.4883 3.49% 60

50
0.2423 0.2730 30
0.3380 0.3653 40 40
2:1 0.4725 0.4869 50
Suhu, K

30

0.2989 0.2781 30 20
0.4026 0.3734 40
10
1:1 0.5107 0.4917 50
0
0.2500 0.3000 0.3500 0.4
Fraksi N
 20

10

0
0.2500 0.3000 0.3500 0.4
0.3018 0.2746 30
Fraksi N
0.3957 0.3689 40
2:1 0.5054 0.4883 50

60

50

40

Suhu, K
30

20

10

0
0.2500 0.3000 0.3500
Fra
 1.1195350141

2:1
60

50

40
Suhu, K

30 Pers amaa n
Percoba an
20

10

0
0.2000 0.2500 0.3000 0.3500 0.4000 0.4500 0.5000 0.5500
Fraksi Naftalen

1:1
60

50

40

30 Perhi tungan
Percobaa n
20

10

0
0.2500 0.3000 0.3500 0.4000 0.4500 0.5000 0.5500
Fraksi Naftalen
 20

10

0
0.2500 0.3000 0.3500 0.4000 0.4500 0.5000 0.5500
Fraksi Naftalen

1:2
60

50

40
Suhu, K

30 Perhitungan
Percoba an
20

10

0
0.2500 0.3000 0.3500 0.4000 0.4500 0.5000 0.5500
Fraksi Naftalen
ln xperhit
-1.29843
-1.27991
-1.29254
-1.00704
-0.98498
-0.99715
-0.71979
-0.70995
-0.71673

ln(gcomb)
 aquadest ref 0.996513 gram/cc
Pikno kosong 16.5508 gram
Pikno + heksana 32.3824 gram 26 C
Pikno + toluene 37.5438 gram 26 C
Pikno + aquadest 40.8061 gram 27 C

heksana 0.650430842 g/mL

toluena 0.862483557 g/mL

BM Toluene 92.13 g/mol

BM Hexane 86.18 g/mol
BM naftalen 128.19 g/mol

Solvent (T:H) 1 : 1
V Total Solven 150 mL
V Toluene 75 mL
V Hexane 75 mL
m Naphtalen mula-mula gram
m Naphtalen tersisa gram
m Naphtalen larut gram

1 2 3
Name Naftalene Toluene Heksane
x 0.242294443 0.290041076 0.467664481
gamma

r 4.9808 3.9228 4.4998

q 3.44 2.968 3.856
F 0.271257113 0.255737403 0.473005484
q 0.238300892 0.246120152 0.515578956
Sixiri 4.448989926
Sixiqi 3.497649037

amk (K)
m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 0 0 61.13 61.13 76.5
m=1
k=2 0 0 61.13 61.13 76.5
k=10 -11.12 -11.12 0 0 167
m=3
k=11 -11.12 -11.12 0 0 167
m=4 k=12 -69.7 -69.7 -146.8 -146.8 0
 mk
313.15 m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 1 1 0.822662 0.822662 0.783259
m=1
k=2 1 1 0.822662 0.822662 0.783259
k=10 1.036148153 1.036148153 1 1 0.586671
m=3
k=11 1.036148153 1.036148153 1 1 0.586671
m=4 k=12 1.249292061 1.249292061 1.598051 1.598051 1

ln(gcomb) 0.144113624 0.00344314 0.069523854

Si(qitij) 1.13742653 1.13742653 1.13742653
qj/Si(qitij) 0.209508821 0.21638334 0.453285503
Sj{qjtkj/(Siqitij)} 0.742559098 #VALUE! #VALUE!
ln(gresid)
 m=1 m=3 m=4
m=1 1 0.822662 0.783259
m=2 1.036148 1 0.586671
m=3 1.249292 1.598051 1
Perbandingan Toluene : Heksana 1:2 Perbandingan Toluene : Heksana

T = 30 T = 30
Massa penambahan Massa penambahan
1 20.318 gram 1 20.0728 gram
2 20.0298 gram 10.3158 2 20.058 gram
3 20.0934 gram 60.4412 50.1254 3 20.0013 gram
4 20.0189 gram
T = 40 T = 40
Massa penambahan 0.4124 Massa penambahan
1 20.01 gram 80.4512 80.0388 1 20.0524 gram
2 20.1783 gram
T = 50
Massa penambahan T = 50
1 20.0031 gram Massa penambahan
2 20.0406 gram 0.1243 1 20.0846 gram
3 20.0313 gram 140.5262 140.4019 2 20.0981 gram
3 20.0515 gram

Naftalen terlarut
ne : Heksana 1:01 Perbandingan Toluene : Heksana 2:1

T = 30
Massa penambahan
1 20.0336 gram
2 20.0158 gram
10.8412 3 20.1331 gram 7.491
80.151 69.3098 4 20.0821 gram 80.2646 72.7736
T = 40
Massa penambahan
10.8216 1 20.0576 gram 10.1284
120.3817 109.5601 2 20.0798 gram 120.402 110.2736

T = 50
Massa penambahan
1 20.1694 gram
10.9471 2 20.4814 gram 9.2824
180.6159 169.6688 3 20.2868 gram 181.3396 172.0572
KELARUTAN NAFTALENA DALAM CAMPURAN TOLUENA DAN HEKSANA

Perbandingan solven 1 1 m Toluene 64.7325 gram

V Total Solven 150 mL m Hexane 49.5225 gram
V Toluene 75 mL
V Hexane 75 mL BM Toluene 92.13 gram/mol
Toluene 0.8631 g/mL BM Hexane 86.18 gram/mol
Heksana 0.6603 g/mL BM naftalen 128.19 gram/mol

m Naphtalen mula-mula 200 gram x Naphtalen 0.422934

m Naphtalen tersisa 80 gram x Toluene 0.317444
m Naphtalen larut 120 gram x Hexane 0.259622

Molecule Maingroup m Subgroup k Rk Qk vk (vk).(Qk)

"ACH" 3 ACH 10 0.5313 0.4 8 3.2
Naphtalene "ACH" AC 2 0
"ACCH3" 4 ACCH3 12 1.2663 0.968 1 0.968
Toluene "ACH" 3 ACH 10 0.5313 0.4 5 2
"CH2" 1 CH3 1 0.9011 0.848 2 1.696
Hexane "CH2" 1 CH2 2 0.6744 0.54 4 2.16

UNIFAC Interaction Parameter

mk
k Interaksi m Interaksi amk (K) 303.15 313.15 323.15
1 a(1,1) 1 a(1,1) 0 1 1 1
a(1,2) a(1,1) 0 1 1 1
a(1,10) a(1,3) 61.13 0.817381 0.822662 0.827647
a(1,12) a(1,4) 76.5 0.776973 0.783259 0.789203
1 1 1
2 a(2,1) 1 a(1,1) 0 1 1 1
a(2,2) a(1,1) 0 1 1 1
a(2,10) a(1,3) 61.13 0.817381 0.822662 0.827647
a(2,12) a(1,4) 76.5 0.776973 0.783259 0.789203
1 1 1
10 a(10,1) 3 a(3,1) -11.12 1.037363 1.036148 1.03501
a(10,2) a(3,1) -11.12 1.037363 1.036148 1.03501
a(10,10) a(3,3) 0 1 1 1
a(10,12) a(3,4) 167 0.576441 0.586671 0.596433
1 1 1
12 a(12,1) 4 a(4,1) -69.7 1.258498 1.249292 1.240717
a(12,2) a(4,1) -69.7 1.258498 1.249292 1.240717
a(12,10) a(4,3) -146.8 1.622955 1.598051 1.575036
a(12,12) a(4,4) 0 1 1 1
1 1 1
(vk).(Rk) qi ri eki
4.2504 1
0 3.2 4.2504 0
1.2663 0.326146
2.6565 2.968 3.9228 0.673854
1.8022 0.439834
2.6976 3.856 4.4998 0.560166
KELARUTAN NAFTALENA DALAM CAMPURAN TOLUENA DAN HEKSANA
SUHU 40C
UNIFAC Subgroup Parameter

m Main GroupSubgroup k Rk Qk
CH3 1 0.9011 0.848 i=1 Naphtalene
1 "CH2"
CH2 2 0.6744 0.54 i=2 Toluene
ACH 10 0.5313 0.4 i=3 Hexane
3 "ACH"
AC 11 0.3652 0.12
4 "ACCH2" ACCH3 12 1.2663 0.968

k Qk vk(1) vk(2) vk(3) vk(1) Qk vk(2) Qk vk(3) Qk

1 0.848 0 0 2 0 0 1.696
2 0.54 0 0 4 0 0 2.16
10 0.4 8 5 0 3.2 2 0
11 0.12 2 0 0 0.24 0 0
12 0.968 0 1 0 0 0.968 0
qi 3.44 2.968 3.856

k Rk vk(1) vk(2) vk(3) vk(1) Rk vk(2) Rk vk(3) Rk

1 0.9011 0 0 2 0 0 1.8022
2 0.6744 0 0 4 0 0 2.6976
10 0.5313 8 5 0 4.2504 2.6565 0
11 0.3652 2 0 0 0.7304 0 0
12 1.2663 0 1 0 0 1.2663 0
ri 4.9808 3.9228 4.4998

UNIFAC Interaction Parameter

amk (K)
m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12
k=1 0 0 61.13 61.13 76.5
m=1 k=2 0 0 61.13 61.13 76.5
k=10 -11.12 -11.12 0 0 167
m=3 k=11 -11.12 -11.12 0 0 167
m=4 k=12 -69.7 -69.7 -146.8 -146.8 0

mk
T=303,15 m=1 m=3 m=4
k=1 k=2 k=10 k=11 k=12 i=1
k=1 1 1 0.817381 0.817381 0.776973 0
m=1 k=2 1 1 0.817381 0.817381 0.776973 0
k=10 1.037363 1.037363 1 1 0.576441 0.964988
m=3
 m=3 k=11 1.037363 1.037363 1 1 0.576441 0.072374
m=4 k=12 1.258498 1.258498 1.622955 1.622955 1 0
1.037363
ik
i k=1 k=2 k=10 k=11 k=12
1 1.037363 1.037363 1 1 0.576441
2 1.109485 1.109485 1.203174 1.203174 0.714583
3 1 1 0.817381 0.817381 0.776973

k=1 0.102792
k=2 0.130915
k k=10 0.60005
k=11 0.022772
k=12 0.143471

Sk
k=1 k=2 k=10 k=11 k=12
1.060357 1.060357 1.046697 1.046697 0.684075

Ji 1.140167
Li 1.044744

ln ic 0.058662 0.100563 0.128076 0.615735 0.02494

ln i r
0.029054
ln i 0.087716
i 1.091678

ln xAL -1.16398
xA L
0.312241

0.999446
 Perbandingan solven 2 1
Naphtalene V Total Solven 150 mL
V Toluene 100 mL
V Hexane 50 mL
Toluene 0.8631 g/mL
Heksana 0.6603 g/mL

eki m Naphtalen mula-m 200 gram

k i=1 i=2 i=3 m Naphtalen tersisa 80 gram
1 0 0 0.439834 m Naphtalen larut 76.87882 gram
2 0 0 0.560166
10 0.930233 0.673854 0
11 0.069767 0 0
12 0 0.326146 0

i=2
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0.964988 0.930233 0.930233 0.536224 0.699031 0.699031 0.673854 0.673854 0.388437
0.072374 0.069767 0.069767 0.040217 0 0 0 0 0
0 0 0 0 0.410454 0.410454 0.52932 0.52932 0.326146
1.037363 1 1 0.576441 1.109485 1.109485 1.203174 1.203174 0.714583

0.120897
m Toluene 86.31 gram
m Hexane 33.015 gram

BM Toluene 92.13 gram/mol

BM Hexane 86.18 gram/mol
BM naftalen 128.19 gram/mol

x Naphtalen 0.312414
x Toluene 0.488021
x Hexane 0.199565

i=3
0.439834 0.439834 0.359512 0.359512 0.341739
0.560166 0.560166 0.457869 0.457869 0.435234
0 0 0 0 0
0 0 0 0 0
0 0 0 0 0
1 1 0.817381 0.817381 0.776973