Chapter(3((Questions(

1.! Calculate!the!wavelength!of!light!in!nm!with!a!frequency!of!78.8!MHz.!

2.! Calculate!the!energy!of!a!photon!of!light!that!has!a!wavelength!of!458!nm.!

3.! Determine!the!wavelength!of!light!absorbed!in!an!electron!transition!from!n!=!2!to!
n!=!4!in!a!hydrogen!atom.!

4.! !

5.! Calculate!the!wavelength!(in!nm)!of!light!that!is!emitted!when!electrons!jump!from!
n!=!3!to!n!=!5!state!of!the!hydrogen!atom.!!

6.! !

!
!
!
!
!
!
7.!

CONFIDENTIAL 8 AS/NOV 2005/CHM138

CONFIDENTIAL AS/OCT 2004/CHM138

9

QUESTION 4

a)QUESTION
Bichromate
5 ion, Cr2O72", reacts with ethanol, C2H5OH, in an acidic solution to produce
3+
Cr carbon dioxide.
ionad

a) Balance following redox equation reaction acidic medium

i) Write balanced redox equation this reaction,
i)

the

for forthe

ina

by
the ion-electron method.
a

Identify oxidizing agent reducing agent

i)

the

and

(5 marks)
Cu + HNO3 - Cu2+ + NO + H2O
b) Assign oxidation numbers to all of the atoms in each of the following: (5 marks)

i) ii) H2Identify
S the oxidizing agent and the reducing agent for the above equation.
!!!!
ii) Na2CrO4 (2 marks)
(3 marks)
b) Calculate the energy in Joules of a photon of red light having a frequency of
c) Explain
4.0 x 10name butanolis the
14 Hz. What specific,
energywhereas
of 1 molename
of thisbutanone
photon.
whyte

isnot

the

represents specific compound. (3 marks)

one

marks)
c) X-ray beam, frequency 1018 Calculate wavelength this (2
An

has

of1.5x

Hz.

the

of

d) Explain
light 2-ethylheptane IUPAC name.
why

isnota

(2 marks)
inm.

(2 marks)
e) Draw structures isomers pentane.
d) Calculate the wavelength of a photon (nm) emitted during the transition(3from ni = 5 to
the

ofal

of

marks)
the n f = 2 in hydrogen atom.
(3 marks)
QUESTION 5 !

a) Calculate wavelength light with frequency 96.1 MHz.

the

of

of

QUESTION PAPER (2 marks)

ENDOF

b) Calculate the energy of a photon of light that has a frequency of 2.3 X 1014 s"1.
marks)
(3

c) What wavelength light emitted when hydrogen atom drops from

isthe

of

n=4to

state?
n=2

(4 marks)
!
d) Name following compounds.
the

i) (CH3)3CCH(C2H5)CH2CH3
ii) CH3CHCH(CH2)3CH(CH3)CH(CH3)2
iii) CH3CH2CH(OH)CH(CH3)CH2CH3
(6 marks)
e) hydrocarbon with molar mass g/mol contains 82.66% carbon. Calculate

of58

the
empirical formula molecular formula this hydrocarbon.

and

for
(4 marks)

QUESTION

5
a) Calculate

i) wavelength light with frequency 98.9 MHz.

the

of

of
marks)

(2
ii) the energy of a photon of light that has a wavelength of 578 nm.
(2 marks)
iii) the wavelength, in nanometers, that corresponds to the radiation required to
raise an electron from n=4 to n=6 energy level of a hydrogen atom.
(3 marks)

b) Define:

i) Unsaturated hydrocarbons
Aromatic compounds
i)

(2 marks)

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