TABLE 2-193 Heats of Vaporization of Inorganic and Organic Compounds

Cmpd. C1 Tmin, ∆Hv at Tmax, ∆Hv

no. Name Formula CAS no. Mol wt × 1E−07 C2 C3 C4 K Tmin × 1E−07 K at Tmax
1 Methane CH4 74828 16.043 1.0194 0.26087 −0.14694 0.22154 90.69 0.8724 190.56 0
2 Ethane C2H6 74840 30.070 2.1091 0.60646 −0.55492 0.32799 90.35 1.7879 305.32 0
3 Propane C3H8 74986 44.097 2.9209 0.78237 −0.77319 0.39246 85.47 2.4787 369.83 0
4 n-Butane C4H10 106978 58.123 3.6238 0.8337 −0.82274 0.39613 134.86 2.8684 425.12 0
5 n-Pentane C5H12 109660 72.150 3.9109 0.38681 0 0 143.42 3.3968 469.7 0
6 n-Hexane C6H14 110543 86.177 4.4544 0.39002 0 0 177.83 3.7647 507.6 0
7 n-Heptane C7H16 142825 100.204 5.0014 0.38795 0 0 182.57 4.2619 540.2 0
8 n-Octane C8H18 111659 114.231 5.5180 0.38467 0 0 216.38 4.5898 568.7 0
9 n-Nonane C9H20 111842 128.258 6.0370 0.38522 0 0 219.66 5.0545 594.6 0
10 n-Decane C10H22 124185 142.285 6.6126 0.39797 0 0 243.51 5.4168 617.7 0

11 n-Undecane C11H24 1120214 156.312 7.2284 0.40607 0 0 247.57 5.9240 639 0

12 n-Dodecane C12H26 112403 170.338 7.7337 0.40681 0 0 263.57 6.2802 658 0
13 n-Tridecane C13H28 629505 184.365 8.4339 0.4257 0 0 267.76 6.8015 675 0
14 n-Tetradecane C14H30 629594 198.392 9.0539 0.44467 0 0 279.01 7.2002 693 0
15 n-Pentadecane C15H32 629629 212.419 9.6741 0.45399 0 0 283.07 7.6728 708 0
16 n-Hexadecane C16H34 544763 226.446 10.1560 0.45726 0 0 291.31 8.0225 723 0
17 n-Heptadecane C17H36 629787 240.473 10.4730 0.4374 0 0 295.13 8.3699 736 0
18 n-Octadecane C18H38 593453 254.500 10.9690 0.44327 0 0 301.31 8.7246 747 0
19 n-Nonadecane C19H40 629925 268.527 11.6740 0.45865 0 0 305.04 9.2185 758 0
20 n-Eicosane C20H42 112958 282.553 12.8600 0.50351 0.32986 −0.42184 309.58 9.5933 768 0

21 2-Methylpropane C4H10 75285 58.123 3.1667 0.3855 0 0 113.54 2.7927 408.14 0

22 2-Methylbutane C5H12 78784 72.150 3.7700 0.3952 0 0 113.25 3.3720 460.43 0
23 2,3-Dimethylbutane C6H14 79298 86.177 4.1404 0.38124 0 0 145.19 3.6328 499.98 0
24 2-Methylpentane C6H14 107835 86.177 4.2780 0.384 0 0 119.55 3.8495 497.5 0
25 2,3-Dimethylpentane C7H16 565593 100.204 4.6536 0.37579 0 0 160 4.0747 537.35 0
26 2,3,3-Trimethylpentane C8H18 560214 114.231 4.9910 0.383 0 0 172.22 4.3530 573.5 0
27 2,2,4-Trimethylpentane C8H18 540841 114.231 4.7721 0.37992 0 0 165.78 4.1565 543.96 0

28 Ethylene C2H4 74851 28.054 0.3746 0 0 104 1.6025 282.34 0

29 Propylene C3H6 115071 42.081 2.8694 0.8375 −0.9216 0.5012 87.89 2.4031 365.57 0
30 1-Butene C4H8 106989 56.108 3.2300 0.3747 0 0 87.8 2.9582 419.95 0
31 cis-2-Butene C4H8 590181 56.108 3.4190 0.3754 0 0 134.26 2.9773 435.58 0
32 trans-2-Butene C4H8 624646 56.108 3.3320 0.3736 0 0 167.62 2.7684 428.63 0
33 1-Pentene C5H10 109671 70.134 3.7740 0.37647 0 0 107.93 3.4166 464.78 0
34 1-Hexene C6H12 592416 84.161 4.3236 0.3788 0 0 133.39 3.8483 504.03 0
35 1-Heptene C7H14 592767 98.188 4.8120 0.3685 0 0 154.27 4.2478 537.29 0

36 1-Octene C8H16 111660 112.215 5.3980 0.3835 0 0 171.45 4.7013 566.65 0

37 1-Nonene C9H18 124118 126.242 5.9940 0.3953 0 0 191.78 5.1366 593.25 0
38 1-Decene C10H20 872059 140.269 6.4898 0.39187 0 0 206.89 5.5289 616.4 0
39 2-Methylpropene C4H8 115117 56.108 3.2720 0.383 0 0 132.81 2.8262 417.9 0
40 2-Methyl-1-butene C5H10 563462 70.134 3.9091 0.39866 0 0 135.58 3.4072 465 0
41 2-Methyl-2-butene C5H10 513359 70.134 3.9121 0.3634 0 0 139.39 3.4437 471 0
42 1,2-Butadiene C4H6 590192 54.092 3.5220 0.395 0 0 136.95 3.0540 452 0
43 1,3-Butadiene C4H6 106990 54.092 3.2580 0.373 0 0 164.25 2.7155 425.17 0
44 2-Methyl-1,3-butadiene C5H8 78795 68.119 3.9310 0.425 0 0 127.27 3.4529 484 0

45 Acetylene C2H2 74862 26.038 2.3795 0.375 0 0 192.4 1.6488 308.32 0

46 Methylacetylene C3H4 74997 40.065 3.2775 0.3997 0 0 170.45 2.6297 402.39 0
47 Dimethylacetylene C4H6 503173 54.092 3.8560 0.3737 0 0 240.91 2.9557 473.2 0
48 3-Methyl-1-butyne C5H8 598232 68.119 3.7920 0.3565 0 0 183.45 3.1681 463.2 0
49 1-Pentyne C5H8 627190 68.119 3.9540 0.3512 0 0 167.45 3.4025 481.2 0
50 2-Pentyne C5H8 627214 68.119 4.4158 0.44347 0 0 163.83 3.7321 519 0

51 1-Hexyne C6H10 693027 82.145 4.5740 0.3698 0 0 141.25 4.0640 516.2 0

52 2-Hexyne C6H10 764352 82.145 4.9110 0.4392 0 0 183.65 4.1067 549 0

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53 3-Hexyne C6H10 928494 82.145 4.8080 0.436 0 0 170.05 4.0831 544 0
54 1-Heptyne C7H12 628717 96.172 5.0514 0.41163 0 0 192.22 4.2470 559 0
55 1-Octyne C8H14 629050 110.199 5.6306 0.4148 0 0 193.55 4.7663 585 0
56 Vinylacetylene1 C4H4 689974 52.076 3.6490 0.4 0.043 0 173.15 2.9876 454 0

57 Cyclopentane C5H10 287923 70.134 3.8900 0.361 0 0 179.28 3.3292 511.76 0

58 Methylcyclopentane C6H12 96377 84.161 4.3600 0.38531 0 0 130.73 3.9118 532.79 0
59 Ethylcyclopentane C7H14 1640897 98.188 4.8288 0.37809 0 0 134.71 4.3604 569.52 0
60 Cyclohexane C6H12 110827 84.161 4.4940 0.3974 0 0 279.69 3.3977 553.58 0
61 Methylcyclohexane C7H14 108872 98.188 4.7534 0.39461 0 0 146.58 4.2295 572.19 0
62 1,1-Dimethylcyclohexane C8H16 590669 112.215 5.0402 0.4036 0 0 239.66 4.0862 591.15 0
63 Ethylcyclohexane C8H16 1678917 112.215 5.3832 0.41763 0 0 161.84 4.7318 609.15 0
64 Cyclopentene C5H8 142290 68.119 3.8107 0.3543 0 0 138.13 3.4046 507 0
65 1-Methylcyclopentene C6H10 693890 82.145 4.3541 0.36805 0 0 146.62 3.8769 542 0
66 Cyclohexene C6H10 110838 82.145 4.4405 0.37479 0 0 169.67 3.8791 560.4 0

67 Benzene C6H6 71432 78.114 4.7500 0.45238 0.0534 −0.1181 278.68 3.4909 562.16 0
68 Toluene C7H8 108883 92.141 5.0144 0.3859 0 0 178.18 4.3670 591.8 0
69 o-Xylene C8H10 95476 106.167 5.5330 0.377 0 0 247.98 4.5826 630.33 0
70 m-Xylene C8H10 108383 106.167 5.4600 0.3726 0 0 225.3 4.6097 617.05 0
71 p-Xylene C8H10 106423 106.167 5.3740 0.3656 0 0 286.41 4.2761 616.23 0
72 Ethylbenzene C8H10 100414 106.167 5.4640 0.392 0 0 178.15 4.7811 617.2 0
73 Propylbenzene C9H12 103651 120.194 5.7663 0.3956 −8.9129E−03 0 215.03 5.0574 574.54 2.4695E+07

74 1,2,4-Trimethylbenzene C9H12 95636 120.194 5.9126 0.35632 0 0 229.33 5.0621 649.13 0

75 Isopropylbenzene C9H12 98828 120.194 5.7950 0.3956 0 0 177.14 5.0869 631.1 0
76 1,3,5-Trimethylbenzene C9H12 108678 120.194 6.0380 0.37999 0 0 228.42 5.1010 637.36 0
77 p-Isopropyltoluene C10H14 99876 134.221 6.3314 0.40289 0 0 205.25 5.4387 653.15 0
78 Naphthalene C10H8 91203 128.174 7.0510 0.4612 0 0 353.43 5.2508 748.35 0
79 Biphenyl C12H10 92524 154.211 7.5736 0.3975 0 0 342.2 6.0420 789.26 0
80 Styrene C8H8 100425 104.152 5.7260 0.4055 0 0 242.54 4.7128 636 0
81 m-Terphenyl C18H14 92068 230.309 10.1230 0.3767 0 0 360 8.4070 924.85 0

82 Methanol CH4O 67561 32.042 5.2390 0.3682 0 0 175.47 4.4900 512.64 0

83 Ethanol C2H6O 64175 46.069 5.6900 0.3359 0 0 159.05 5.0245 513.92 0
84 1-Propanol C3H8O 71238 60.096 6.3300 0.3575 0 0 146.95 5.6460 536.78 0
85 1-Butanol C4H10O 71363 74.123 6.7390 0.173 0.2915 0 184.51 6.0575 563.05 0
86 2-Butanol C4H10O 78922 74.123 7.2560 0.4774 0 0 158.45 6.1383 536.05 0
87 2-Propanol C3H8O 67630 60.096 6.3080 0.3921 0 0 185.28 5.2807 508.3 0
88 2-Methyl-2-propanol C4H10O 75650 74.123 7.7320 0.5645 0 0 298.97 4.6703 506.21 0

89 1-Pentanol C5H12O 71410 88.150 8.3100 0.511 0 0 195.56 6.7533 586.15 0

90 2-Methyl-1-butanol C5H12O 137326 88.150 7.7839 0.45313 0 0 203 6.3619 565 0
91 3-Methyl-1-butanol C5H12O 123513 88.150 8.0815 0.50185 0 0 155.95 6.8999 577.2 0
92 1-Hexanol C6H14O 111273 102.177 8.5980 0.513 0 0 228.55 6.7623 611.35 0
93 1-Heptanol C7H16O 111706 116.203 9.6900 0.572 0 0 239.15 7.3822 631.9 0
94 Cyclohexanol C6H12O 108930 100.161 9.2440 0.64825 0 0 296.6 6.2273 650 0
95 Ethylene glycol C2H6O2 107211 62.068 8.2900 0.4266 0 0 260.15 6.8461 719.7 0
96 1,2-Propylene glycol C3H8O2 57556 76.095 8.0700 0.295 0 0 213.15 7.1374 626 0

97 Phenol C6H6O 108952 94.113 7.3060 0.4246 0 0 314.06 5.6577 694.25 0

98 o-Cresol C7H8O 95487 108.140 7.1979 0.40317 0 0 304.19 5.7135 697.55 0
99 m-Cresol C7H8O 108394 108.140 8.0082 0.45314 0 0 285.39 6.3326 705.85 0
100 p-Cresol C7H8O 106445 108.140 8.4942 0.50234 0 0 307.93 6.3649 704.65 0

101 Dimethyl ether C2H6O 115106 46.069 2.9940 0.3505 0 0 131.65 2.6032 400.1 0
102 Methyl ethyl ether C3H8O 540670 60.096 3.5300 0.376 0 0 160 2.9751 437.8 0
103 Methyl n-propyl ether C4H10O 557175 74.123 3.9795 0.3729 0 0 133.97 3.5184 476.3 0
104 Methyl isopropyl ether C4H10O 598538 74.123 3.9305 0.3711 0 0 127.93 3.4876 464.5 0
105 Methyl-n-butyl ether C5H12O 628284 88.150 4.5328 0.3824 0 0 157.48 3.9358 510 0
106 Methyl isobutyl ether C5H12O 625445 88.150 4.2678 0.37995 0 0 150 3.7232 497 0
107 Methyl tert-butyl ether C5H12O 1634044 88.150 4.2024 0.37826 0 0 164.55 3.6096 497.1 0

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TABLE 2-193 Heats of Vaporization of Inorganic and Organic Compounds (Continued )
Cmpd. C1 Tmin, ∆Hv at Tmax, ∆Hv
no. Name Formula CAS no. Mol wt × 1E−07 C2 C3 C4 K Tmin × 1E−07 K at Tmax
108 Diethyl ether C4H10O 60297 74.123 4.0600 0.3868 0 0 156.85 3.4651 466.7 0
109 Ethyl propyl ether C5H12O 628320 88.150 5.4380 0.60624 0 0 145.65 4.4140 500.23 0
110 Ethyl isopropyl ether C5H12O 625547 88.150 4.2580 0.37221 0 0 140 3.7556 489 0
111 Methyl phenyl ether C7H8O 100663 108.140 5.8662 0.37127 0 0 235.65 4.9560 645.6 0
112 Diphenyl ether C12H10O 101848 170.211 6.8243 0.30877 0 0 300.03 5.8546 766.8 0

113 Formaldehyde CH2O 50000 30.026 3.0760 0.2954 0 0 181.15 2.5863 408 0
114 Acetaldehyde C2H4O 75070 44.053 4.6070 0.62 0 0 150.15 3.6199 466 0
115 1-Propanal C3H6O 123386 58.080 4.1492 0.36751 0 0 170 3.5675 504.4 0
116 1-Butanal C4H8O 123728 72.107 4.6403 0.3849 0 0 176.75 3.9797 537.2 0
117 1-Pentanal C5H10O 110623 86.134 5.1478 0.37541 0 0 182 4.4502 566.1 0
118 1-Hexanal C6H12O 66251 100.161 5.6661 0.38533 0 0 217.15 4.7495 591 0
119 1-Heptanal C7H14O 111717 114.188 6.1299 0.37999 0 0 229.8 5.1353 617 0
120 1-Octanal C8H16O 124130 128.214 6.8347 0.41039 0 0 246 5.5966 638.1 0
121 1-Nonanal C9H18O 124196 142.241 7.3363 0.41735 0 0 255.15 5.9779 658 0
122 1-Decanal C10H20O 112312 156.268 7.9073 0.4129 0 0 267.15 6.4201 674.2 0

123 Acetone C3H6O 67641 58.080 4.2150 0.3397 0 0 178.45 3.6390 508.2 0
124 Methyl ethyl ketone C4H8O 78933 72.107 4.6220 0.355 0 0 186.48 3.9704 535.5 0
125 2-Pentanone C5H10O 107879 86.134 5.1740 0.39422 0 0 196.29 4.3663 561.08 0
126 Methyl isopropyl ketone C5H10O 563804 86.134 5.1400 0.3858 0 0 250 4.0753 553 0
127 2-Hexanone C6H12O 591786 100.161 5.6770 0.3817 0 0 217.35 4.7584 587.05 0
128 Methyl isobutyl ketone C6H12O 108101 100.161 5.4000 0.383 0 0 189.15 4.6294 571.4 0
129 3-Methyl-2-pentanone C6H12O 565617 100.161 5.1130 0.3395 0 0 167.15 4.5480 573 0
130 3-Pentanone C5H10O 96220 86.134 5.2359 0.40465 0 0 234.18 4.2075 560.95 0
131 Ethyl isopropyl ketone C6H12O 565695 100.161 5.3880 0.40616 0 0 200 4.5154 567 0
132 Diisopropyl ketone C7H14O 565800 114.188 5.5980 0.3774 0 0 204.81 4.7426 576 0
133 Cyclohexanone C6H10O 108941 98.145 5.5500 0.3538 0 0 242 4.7114 653 0
134 Methyl phenyl ketone C8H8O 98862 120.151 6.6104 0.37425 0 0 292.81 5.4166 709.5 0

135 Formic acid CH2O2 64186 46.026 2.3700 1.999 −5.1503 3.331 281.45 1.9532 588 0
136 Acetic acid C2H4O2 64197 60.053 2.0265 0.11911 −1.3487 1.4227 289.81 2.3185 591.95 0
137 Propionic acid C3H6O2 79094 74.079 2.7290 0.06954 −1.0423 1.1152 252.45 2.9964 600.81 0
138 n-Butyric acid C4H8O2 107926 88.106 7.4996 2.333 −3.8644 2.016 267.95 4.1566 615.7 0
139 Isobutyric acid C4H8O2 79312 88.106 4.4967 1.1615 −2.4573 1.5823 227.15 3.6179 605 0
140 Benzoic acid2 C7H6O2 65850 122.123 10.1900 0.478 0 0 395.45 7.1277 751 0
141 Acetic anhydride C4H6O3 108247 102.090 6.3520 0.3986 0 0 200.15 5.4139 606 0

142 Methyl formate C2H4O2 107313 60.053 4.1030 0.3825 0 0 174.15 3.4644 487.2 0
143 Methyl acetate C3H6O2 79209 74.079 4.4920 0.3685 0 0 175.15 3.8418 506.55 0
144 Methyl propionate C4H8O2 554121 88.106 5.0080 0.3959 0 0 185.65 4.2231 530.6 0
145 Methyl n-butyrate C5H10O2 623427 102.133 5.3781 0.39523 0 0 187.35 4.5694 554.5 0
146 Ethyl formate C3H6O2 109944 74.079 4.5909 0.4123 0 0 193.55 3.7679 508.4 0
147 Ethyl acetate C4H8O2 141786 88.106 4.9330 0.3847 0 0 189.6 4.1490 523.3 0
148 Ethyl propionate C5H10O2 105373 102.133 5.3325 0.401 0 0 199.25 4.4449 546 0

149 Ethyl n-butyrate C6H12O2 105544 116.160 5.6419 0.37985 0 0 175.15 4.9090 571 0
150 n-Propyl formate C4H8O2 110747 88.106 4.9687 0.4025 0 0 180.25 4.2162 538 0
151 n-Propyl acetate C5H10O2 109604 102.133 5.4327 0.407 0 0 178.15 4.6322 549.73 0
152 n-Butyl acetate C6H12O2 123864 116.160 5.7800 0.3935 0 0 199.65 4.8943 579.15 0
153 Methyl benzoate C8H8O2 93583 136.150 6.9650 0.4061 0 0 260.75 5.7500 693 0
154 Ethyl benzoate C9H10O2 93890 150.177 6.3400 0.2911 0 0 238.45 5.6137 698 0
155 Vinyl acetate C4H6O2 108054 86.090 4.7700 0.3765 0 0 180.35 4.0619 519.13 0

156 Methylamine CH5N 74895 31.057 3.8580 0.404 0 0 179.69 3.1006 430.05 0
157 Dimethylamine C2H7N 124403 45.084 4.0900 0.42005 0 0 180.96 3.2678 437.2 0
158 Trimethylamine C3H9N 75503 59.111 3.3050 0.354 0 0 156.08 2.8216 433.25 0

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159 Ethylamine C2H7N 75047 45.084 4.2750 0.5857 −0.332 0.169 192.15 3.2955 456.15 0
160 Diethylamine C4H11N 109897 73.138 4.6133 0.42628 0 0 223.35 3.5761 496.6 0
161 Triethylamine C6H15N 121448 101.192 4.6640 0.3663 0 0 158.45 4.1011 535.15 0

162 n-Propylamine C3H9N 107108 59.111 4.4488 0.39494 0 0 188.36 3.6857 496.95 0
163 di-n-Propylamine C6H15N 142847 101.192 5.4280 0.3665 0 0 210.15 4.5500 550 0
164 Isopropylamine C3H9N 75310 59.111 4.4041 0.43325 0 0 177.95 3.5874 471.85 0
165 Diisopropylamine C6H15N 108189 101.192 5.0070 0.4362 0 0 176.85 4.1823 523.1 0
166 Aniline C6H7N 62533 93.128 7.1950 0.458 0 0 267.13 5.7710 699 0
167 N-Methylaniline C7H9N 100618 107.155 6.3860 0.3104 0 0 216.15 5.6961 701.55 0
168 N,N-Dimethylaniline C8H11N 121697 121.182 6.7900 0.4053 0 0 275.6 5.5162 687.15 0

169 Ethylene oxide C2H4O 75218 44.053 3.6652 0.37878 0 0 160.65 3.1271 469.15 0
170 Furan C4H4O 110009 68.075 4.0050 0.3995 0 0 196.29 3.2647 490.15 0
171 Thiophene C4H4S 110021 84.142 4.5793 0.38557 0 0 234.94 3.7472 579.35 0
172 Pyridine C5H5N 110861 79.101 5.1740 0.38865 0 0 231.51 4.3144 619.95 0

173 Formamide3 CH3NO 75127 45.041 7.3580 0.3564 0 0 275.7 6.2844 771 0
174 N,N-Dimethylformamide C3H7NO 68122 73.095 5.9217 0.37996 0 0 212.72 5.0931 649.6 0
175 Acetamide C2H5NO 60355 59.068 8.1070 0.42 0 0 353.15 6.2386 761 0
176 N-Methylacetamide C3H7NO 79163 73.095 7.3402 0.38974 0 0 301.15 5.9384 718 0
177 Acetonitrile C2H3N 75058 41.053 4.3511 0.34765 0 0 229.32 3.5996 545.5 0
178 Propionitrile C3H5N 107120 55.079 4.9348 0.41873 0 0 180.26 4.2005 564.4 0
179 n-Butyronitrile C4H7N 109740 69.106 5.2200 0.165 0.6692 −0.539 161.25 4.7223 582.25 0
180 Benzonitrile C7H5N 100470 103.123 6.2615 0.35427 0 0 260.4 5.3091 699.35 0

181 Methyl mercaptan CH4S 74931 48.109 3.4448 0.37427 0 0 150.18 2.9825 469.95 0
182 Ethyl mercaptan C2H6S 75081 62.136 3.8440 0.37534 0 0 125.26 3.4489 499.15 0
183 n-Propyl mercaptan C3H8S 107039 76.163 4.4782 0.41073 0 0 159.95 3.8723 536.6 0
184 n-Butyl mercaptan C4H10S 109795 90.189 4.9702 0.41199 0 0 157.46 4.3505 570.1 0
185 Isobutyl mercaptan C4H10S 513440 90.189 4.7420 0.40535 0 0 128.31 4.2664 559 0
186 sec-Butyl mercaptan C4H10S 513531 90.189 4.6432 0.399 0 0 133.02 4.1614 554 0
187 Dimethyl sulfide C2H6S 75183 62.136 3.8690 0.3694 0 0 174.88 3.3042 503.04 0
188 Methyl ethyl sulfide C3H8S 624895 76.163 4.4740 0.4097 0 0 167.23 3.8344 533 0
189 Diethyl sulfide C4H10S 352932 90.189 4.7182 0.3643 0 0 169.2 4.1353 557.15 0

190 Fluoromethane CH3F 593533 34.033 2.4708 0.37014 0 0 131.35 2.0276 317.42 0
191 Chloromethane CH3Cl 74873 50.488 2.9745 0.353 0 0 175.43 2.4520 416.25 0
192 Trichloromethane CHCl3 67663 119.377 4.1860 0.3584 0 0 209.63 3.5047 536.4 0
193 Tetrachloromethane CCl4 56235 153.822 4.3252 0.37688 0 0 250.33 3.4528 556.35 0
194 Bromomethane CH3Br 74839 94.939 3.1690 0.3015 0 0 179.47 2.7379 467 0
195 Fluoroethane C2H5F 353366 48.060 2.7617 0.32162 0 0 129.95 2.4089 375.31 0
196 Chloroethane C2H5Cl 75003 64.514 3.5240 0.3652 0 0 134.8 3.1052 460.35 0
197 Bromoethane C2H5Br 74964 108.966 3.9004 0.38012 0 0 154.55 3.3933 503.8 0

198 1-Chloropropane C3H7Cl 540545 78.541 3.9890 0.37956 0 0 150.35 3.4862 503.15 0
199 2-Chloropropane C3H7Cl 75296 78.541 3.8871 0.38043 0 0 155.97 3.3586 489 0
200 1,1-Dichloropropane C3H6Cl2 78999 112.986 4.7740 0.39204 0 0 200 4.0147 560 0
201 1,2-Dichloropropane C3H6Cl2 78875 112.986 4.6750 0.36529 0 0 172.71 4.0997 572 0
202 Vinyl chloride C2H3Cl 75014 62.499 3.4125 0.4513 0 0 119.36 2.9491 432 0
203 Fluorobenzene C6H5F 462066 96.104 4.5820 0.3717 0 0 230.94 3.7605 560.09 0
204 Chlorobenzene C6H5Cl 108907 112.558 5.1480 0.36614 0 0 227.95 4.3707 632.35 0
205 Bromobenzene C6H5Br 108861 157.010 5.5520 0.37694 0 0 242.43 4.6875 670.15 0

206 Air 132259100 28.951 0.8474 0.3822 0 0 59.15 0.6759 132.45 0

207 Hydrogen H2 1333740 2.016 0.1013 0.698 −1.817 1.447 13.95 0.0913 33.19 0
208 Helium-4 He 7440597 4.003 0.0125 1.3038 −2.6954 1.7098 2.2 0.0097 5.2 0
209 Neon Ne 7440019 20.180 0.2389 0.3494 0 0 24.56 0.1803 44.4 0
210 Argon Ar 7440371 39.948 0.8731 0.3526 0 0 83.78 0.6561 150.86 0
211 Fluorine F2 7782414 37.997 0.8876 0.34072 0 0 53.48 0.7578 144.12 0
212 Chlorine Cl2 7782505 70.905 3.0680 0.8458 −0.9001 0.453 172.12 2.2878 417.15 0
213 Bromine Br2 7726956 159.808 4.0000 0.351 0 0 265.85 3.2323 584.15 0

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TABLE 2-193 Heats of Vaporization of Inorganic and Organic Compounds (Concluded )
Cmpd. C1 Tmin, ∆Hv at Tmax, ∆Hv
no. Name Formula CAS no. Mol wt × 1E−07 C2 C3 C4 K Tmin × 1E−07 K at Tmax
214 Oxygen O2 7782447 31.999 0.9008 0.4542 −0.4096 0.3183 54.36 0.7742 154.58 0
215 Nitrogen N2 7727379 28.014 0.7491 0.40406 −0.317 0.27343 63.15 0.6024 126.2 0
216 Ammonia NH3 7664417 17.031 3.1523 0.3914 −0.2289 0.2309 195.41 2.5298 405.65 0
217 Hydrazine N2H4 302012 32.045 5.9794 0.9424 −1.398 0.8862 274.69 4.5238 653.15 0
218 Nitrous oxide N2O 10024972 44.013 2.3215 0.384 0 0 182.3 1.6502 309.57 0

219 Nitric oxide NO 10102439 30.006 2.1310 0.4056 0 0 109.5 1.4578 180.15 0
220 Cyanogen C2N2 460195 52.036 3.3840 0.3707 0 0 245.25 2.3803 400.15 0
221 Carbon monoxide CO 630080 28.010 0.8585 0.4921 −0.326 0.2231 68.13 0.6517 132.5 915280
222 Carbon dioxide CO2 124389 44.010 2.1730 0.382 −0.4339 0.42213 216.58 1.5202 304.21 0
223 Carbon disulfide CS2 75150 76.143 3.4960 0.2986 0 0 161.11 3.1537 552 0
224 Hydrogen fluoride HF 7664393 20.006 13.4510 13.36 −23.383 10.785 277.56 0.7104 461.15 0
225 Hydrogen chloride HCl 7647010 36.461 2.2093 0.3466 0 0 158.97 1.7498 324.65 0
226 Hydrogen bromide HBr 10035106 80.912 2.4850 0.39 0 0 185.15 1.8817 363.15 0
227 Hydrogen cyanide2 HCN 74908 27.026 3.3490 0.2053 0 0 259.83 2.8176 456.65 0
228 Hydrogen sulfide H2S 7783064 34.082 2.5676 0.37358 0 0 187.68 1.9782 373.53 0
229 Sulfur dioxide SO2 7446095 64.065 3.6760 0.4 0 0 197.67 2.8753 430.75 0
230 Sulfur trioxide SO3 7446119 80.064 7.3370 0.5647 0 0 289.95 4.4303 490.85 0
231 Water H2O 7732185 18.015 5.2053 0.3199 −0.212 0.25795 273.16 4.4733 647.13 0
All substances are listed in alphabetical order in Table 2-6a.
Compiled from Daubert, T. E., R. P. Danner, H. M. Sibul, and C. C. Stebbins, DIPPR Data Compilation of Pure Compound Properties, Project 801 Sponsor Release, July, 1993, Design Institute for Physical
Property Data, AIChE, New York, NY; and from Thermodynamics Research Center, “Selected Values of Properties of Hydrocarbons and Related Compounds,” Thermodynamics Research Center Hydrocarbon
Project, Texas A&M University, College Station, Texas (extant 1994).
Temperatures are expressed in kelvins; heats of vaporization, in J/ kmol.
J/ kmol × 2.390E−04 = cal/gmol; J/ kmol × 4.302106E−04 = Btu/ lbmol.
The heat of vaporization equation used is ∆Hv = C1 × (1 − Tr)C2 + C3 × Tr + C4 × Tr × Tr. Tr is the reduced temperature, T/Tc.
1
Coefficients are hypothetical; compound decomposes violently on heating.
2
For the monomer.
3
Equation coefficients are hypothetical above the decomposition temperature.

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