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Day 1 Calculations
Day 1 Calculations
Day 1 Calculations
14 4 17
a) 7
N + 2He = 8 O + ?
9 4 12
b) 4
Be + 2He = 6 C + ?
9
c) Be (p,α)?
4
30 30
d) 15
P = 14S+ ?
3 3
e) 1
H = 2He + ?
43 46
f) 20
Ca(α,?) 21Sc
1 0 6 0 0
Ans. a) H b) n c) Li d) β e) β f) p
1 1 3 +1 −1
Ans. V= 15.1L
Ans. v= 849.85m/s
Ans. 316.52m/s
V= 454.47m/s
Ans. v= 461.38m/s
Ans. v= 413.7m/s
Ans. 5.23x10^-5m
The root mean square velocity of hydrogen at STP is 1.83x10^5 cm/s and
its mean free path is 1.78x10^-5 cm. calculate the collision number at
STP.
Ans. 9.4769x10^9 /s
Ans. 25.6dynes/cm
How high will sap rise in a plant if the capillaries are 0.01mm
diameter, the density of the fluid is 1.3g/cm3 and its surface tension
0.065N/m
Ans. 2.04m
Ans. 4:1
Ans. 59.09
Predict whether the reaction 2Ag(s) + Zn+2 (aq) = Ag+ (aq) + Zn(s) is
feasible or not.
Ans. E= 0.8221V
Ans. 1.5896V
Ans. K= 1x10^52
Calculate the pressure volume work done when a system containing a gas
expands from 1L to 2L against a constant external pressure of
10atmospheres. Express the answer in calories and joules
Ans. w= -1012.53J
Ans. w= -1717.46J
Find the work done when one mol of the gas is expanded reversibly and
isothermally from 5atm to 1atm at 25C.
Ans.
w= -3988J
Ans. q= 16.012kcal
Three moles of an ideal gas( Cv= 5 cal/degC mol) at 10atm and 0C are
converted to 2atm at 50C. find ΔE and ΔH for the change.
Ans. -22.123kcal
Ans. 22.192kcal
Calculate the ΔH for the reaction CO2(g) + H2(g)= CO(g) + H2O(g) given
that ΔHf for CO2, CO, H2O are -393.5, -111.31 and -241.8kJ/mol
respectively.
Ans. 40.4kJ
Ans. -103.5kJ/mol
Ans. -102.5kcal
Ans. -64.1kcal
Ans. -74.8kJ
Given that energies for H-H, O=O and O-H bonds are 104,118 and
111kcal/mol respectively, calculate the heat of the reaction H2(g) +
½O2(g) = H2O(g)
Ans. -59kcal/mol
Calculate the bond energy of HCl, given that H-H bond energy is
433kJ/mol, Cl-Cl bond energy is 242kJ/mol and ΔHf for HCl is
-91kJ/mol.
Ans. 428.5kJ
Ans. 84.81cal/K
Ans. 2.86J/K
An engine operating between 150C and 25C takes 500J heat from a high
reservoir. Assuming that there are no frictional losses, calculate the
work that can be done by this engine.
Ans. w= 147.75J
Calculate the entropy change when 2mol of an ideal gas are allowed to
expand isothermally at 293K from a pressure of 10atm to a pressure of
2atm.
Ans. T= 1070.4K
For the reaction, N2(g) + 3H2(g) = 2NH3(g). the free energy changes at
25C and 35C are -33.089 and -28.018 kJ respectively. Calculate the
heat of reaction
If the vapour pressure of water at 95C and 100C are 634 and 760mm
respectively, calculate the latent heat of vaporization per mol.
Ans. T= 374K
What is the value of f(T) for a sample of gas whose volume is 2.97L
and pressure is 0.0553atm?what would the volume of the gas be if the
pressure were increased to 1atm?
Ans. T= 88C
Evaluate ΔU for 1mol of oxygen O2, going from -20C to 37C at constant
volume, in the ff cases
a) It is an ideal gas
b) It is a real gas wit Cv= 21.6 + 4.18x10^-3T- 1.67x10^5/T2
Ans. T= 154K
Calculate the work done when 50g of iron reacts with hydrochloric acid
in a) closed vessel of fixed volume b) open beaker at 25C
Ans. 5.9
Ans 0.00044g/mL
Ans. 29.07g/L