[1]

ORGANIC CHEMISTRY
Daily Practice Paper

XII Batch DPP-1

OBJECTIVE
1. The total number of possible structural isomers of C4H10 10. The possible number of structural isomers of C5H10
is which do not decolourise the reddish brown colour of
(a) 1 (b) 4 Br2 water is:
(c) 2 (d) 3 (a) 5 (b) 3
JHA SIR C
(c) 2 (d) 6
2. The total number of possible structural isomers of C5H12 JHA SIR C
is
11. The number of possible structural isomers of C5H10
(a) 1 (b) 4
which decolourise the reddish brown colour of Br2 water
(c) 2 (d) 3
is
JHA SIR D
(a) 4 (b) 5
3. The total number of possible structural isomers of C6H14
(c) 6 (d) 8
is
JHA SIR D
(a) 4 (b) 5
12. The possible number of structural isomers of C5H10
(c) 6 (d) 7
which do not decolourise the pink colour of Bayer’s
JHA SIR B

4. The total number of possible structural isomers of C7H16 reagent (1% alkaline KMnO4) is
is? (a) 5 (b) 7
(a) 6 (b) 7 (c) 6 (d) 3
(c) 8 (d) 9 JHA SIR A

JHA SIR D 13. The total number of possible structural isomers of C3H4
5. The total number of possible structures of C3H6 is is
(a) 1 (b) 4 (a) 4 (b) 3
(c) 2 (d) 3 (c) 5 (d) 6
JHA SIR C JHA SIR B

6. The total number of acyclic structural isomers of C4H8 14. The total possible number of structural isomers of C4H6
is is
(a) 4 (b) 3 (a) 7 (b) 9
(c) 1 (d) 2 (c) 6 (d) 5
JHA SIR B JHA SIR B

7. The total number of structural isomers of C4H8 is: 15. The total possible number of structural isomers of C6H10
(a) 3 (b) 4 of alkyne which do not give red precipitate with
(c) 5 (d) 6 ammoniacal cuprous chloride is
JHA SIR C (a) 4 (b) 3
8. The total number of possible acyclic structural isomers (c) 5 (d) 2
of C5H10 (excluding cycloalkane) is JHA SIR B

(a) 4 (b) 5 16. The possible number of structural isomers of C6H10,

(c) 3 (d) 2 which give white ppt. with ammoniacal silver nitrate is
JHA SIR B (a) 2 (b) 3
9. The total number of possible cyclic structures of C5H10 (c) 4 (d) 5
is JHA SIR C

(a) 4 (b) 5 17. The total number of possible structural isomers of

(c) 3 (d) 2 C3H7X is
JHA SIR B (a) 2 (b) 3
CA T J E E N e a r A k a s h w a n i , R a m a n N i w a s , M ah m o o r g a n j V a r a n a s i . P h . ( 0 5 4 2 ) – 2 3 6 3 4 5 5
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(c) 1 (d) 4 NaHSO3 is

JHA SIR A (a) 5 (b) 2
18. The total number of possible structural isomers of (c) 3 (d) 4
C4H9X is JHA SIR C

(a) 2 (b) 4 28. The total number of possible structural isomers of

(c) 3 (d) 6 C5H10O which give red precipitate with Fehling’s
JHA SIR B solution and Benedict’s solution is:
19. The total number of possible structural isomers of (a) 7 (b) 3
C5H11X is (c) 5 (d) 4
(a) 9 (b) 6 JHA SIR D

(c) 8 (d) 7 29. The total number of possible structural isomers of

JHA SIR C C5H10O which give the positive haloform test is
20. The total number of possible structural isomers of (a) 4 (b) 2
C2H4X2 is (c) 3 (d) 6
(a) 4 (b) 2 JHA SIR D

(c) 5 (d) 3 30. The total number of possible structural isomers of

JHA SIR B C2H7N is
21. The total number of possible structural isomers of (a) 1 (b) 2
C3H6X2 is (c) 4 (d) 3
(a) 2 (b) 3 JHA SIR B

(c) 4 (d) 5 31. The total number of possible structural isomers of

JHA SIR C C3H9N which give negative carbylamine test is
22. The total number of possible structural isomers of (a) 4 (b) 1
C2H6O is (c) 3 (d) 2
(a) 2 (b) 4 JHA SIR D

(c) 3 (d) 5 32. The total number of possible structural isomers of

JHA SIR A C4H11N which give obnoxious (i.e. foul) smell with
23. The total number of possible structural isomers of CHCl3+KOH is
C3H8O is (a) 8 (b) 6
(a) 2 (b) 4 (c) 4 (d) 3
(c) 3 (d) 1 JHA SIR C

JHA SIR C 33. Assign the various structures of C4H8O2

24. The total number of possible structural isomers of (a) that can give iodoform test and gives white turbidity
C4H10O is on heating with Lucas reagent
(a) 2 (b) 5 (b) that can give iodoform test, reduces Tollen’s reagent.
(c) 7 (d) 4 (c) that can be decarboxylated to propane
(d) that can be dehydrolyse to form CH3COOH and
JHA SIR C
alcohol
25. The total number of possible structural isomers of
(e) that can reduce Tollen’s reagent but does not give
C5H12O, which give pale yellow ppt. with I2 + NaOH is
iodoform test.
(a) 8 (b) 4
JHA SIR
(c) 2 (d) 3
34. The total number of possible structural isomers of
JHA SIR C
C3H6O2 is (excluding cyclic and unsaturated structure)
26. The total number of possible structural isomers of
is
C3H6O is
(a) 3 (b) 5
(a) 5 (b) 8
(c) 4 (d) 6
(c) 9 (d) 7
JHA SIR D
JHA SIR C
35. The total number of possible structural isomers of
27. The total number of possible structural isomers of
C4H8O2 which gives effervescence with NaHCO3 is
C4H8O which form white crystalline compound with

CA T J E E N e a r A k a s h w a n i , R a m a n N i w a s , M ah m o o r g a n j V a r a n a s i . P h . ( 0 5 4 2 ) – 2 3 6 3 4 5 5
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(a) 9 (b) 4 43. The number of primary, secondary and tertiary amines
(c) 2 (d) 3 possible with the molecular formula C3H9N respectively
JHA SIR C is:
36. The total number of possible benzenoid structure of (a) 1, 2, 2 (b) 1, 2, 1
C8H10 is (c) 2, 1, 1 (d) 3, 0, 1
(a) 3 (b) 5 JHA SIR C

(c) 4 (d) 2 44. C7H7Cl shows how many benzenoid aromatic isomers:
JHA SIR C (a) 4 (b) 3
37. The total number of possible benzenoid structure of (c) 5 (d) 6
C9H12 is JHA SIR A

(a) 8 (b) 5 45. The total number of possible benzenoid structures of

(c) 6 (d) 9 C8H8O2, which give positive iodoform test is
JHA SIR A (a) 2 (b) 4
38. Benzenoid structure of C7H8O is (c) 3 (d) 5
(a) 4 (b) 5 JHA SIR C

(c) 6 (d) 3 46. The total number of possible benzenoid structures of

JHA SIR B C8H8O2, which give effervescence with NaHCO3 is
39. The total number of possible structural isomers of (a) 2 (b) 4
primary amines for the formula C4H11N is (c) 3 (d) 5
(a) 2 (b) 3 JHA SIR B

(c) 4 (d) 5 47. An organic compound having molecular formula C8H10O

JHA SIR C on being heated with I2 and dil. NaOH gives a yellow
40. How many structural isomer are possible when one of precipitate. The expected compound is
the hydrogen is replaced by a chlorine atom in (a) C6H5CH2CH2OH (b) C6H4(CH3)CH2OH
anthracene. (c) C6H3(CH3)2OH (d) C6H5CH(OH)CH3
(a) 3 (b) 7 JHA SIR D

(c) 4 (d) 6 48. Find out the total number of cyclic structural isomers
JHA SIR A of C6H12:
41. The number of isomers of dibromoderivative of alkene (a) 9 (b) 12
(molar mass 186 g mol–1) is (excluding stereoisomers) (c) 8 (d) 10
JHA SIR B
(a) 2 (b) 3
49. Molecular formula C5H10O can have:
(c) 4 (d) 6
(a) 6–Aldehyde, 4–ketone
JHA SIR A
(b) 5–Aldehyde, 3–ketone
42. Compound (X) C7H9N reacts with CHCl3 and KOH to
(c) 4–Aldehyde, 3–ketone
give foul smell. Compound will be:
(d) 5–Aldehyde, 2–ketone
JHA SIR C
NH2
50. Molecular formula C3H6Br2 can have (excluding stereo
isomers)
(a) C6H5CH2NH2 (b) (a) two gem–dibromide (b) one vic–dibromide
CH 3 (c) two ter–dibromide (d) two sec–dibromo alkane
JHA SIR AB

51. The number of isomers of C3H5Br3 is (excluding stereo

NHCH3 NH2 isomers)
(a) 4 (b) 5
(c) (d) (c) 6 (d) 7
CH 3 JHA SIR B

JHA SIR ABD

CA T J E E N e a r A k a s h w a n i , R a m a n N i w a s , M ah m o o r g a n j V a r a n a s i . P h . ( 0 5 4 2 ) – 2 3 6 3 4 5 5
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INTEGER
52. The number of possible benzenoid structures of C9H10,
which decolourises 1% alkaline KMnO 4 (Bayer ’s
reagent) is
ARUN SIR 6
53. The possible number of structural isomers of C3H7NO
when hydrolysed with aqueous KOH gives amine along
with monobasic acid is
JHA SIR 3
54. The possible number of benzenoid structures of the
molecular formula C8H9NO, when hydrolysed with
aqueous KOH gives ammonia alongwith monobasic acid
is
JHA SIR 3
55. Calculate the number of Benzenoid isomers possible for
C6H3ClBrI.
JHA SIR 10
56. Calculate total number of structural isomers of 3° amines
for the molecular formula C6H15N are
JHA SIR 7
57. How many cyclopentane structures (excluding
stereoisomers) are possible for C7H14.
JHA SIR 4

ANSWERS
1. c 2. d 3. b 4. d 5. c
6. b 7. c 8. b 9. b 10. c
11. c 12. a 13. b 14. b 15. b
16. c 17. a 18. b 19. c 20. b
21. c 22. a 23. c 24. c 25. c
26. c 27. c 28. d 29. d 30. b
31. d 32. c 33. 34. d 35. c
36. c 37. a 38. b 39. c 40. a
41. a 42. abd 43. c 44. a 45. c
46. b 47. d 48. b 49. c 50. ab
51. b 52. 6 53. 2 54. 4 55. 10
56. 7 57. 4

CA T J E E N e a r A k a s h w a n i , R a m a n N i w a s , M ah m o o r g a n j V a r a n a s i . P h . ( 0 5 4 2 ) – 2 3 6 3 4 5 5