CALCULATION OF HEATING VALUE

BASED ON ASME PTC 22 STANDART

Standart Fuel Gas

Density Density
Name of Comund Compound Fuel Mole
Fraction Mol. Wt A4 x A3 Fuel Wt.
Fraction

lb/lbmol lb/ft3 lb/ft3

Methane CH4 89.3604 16.04246 1433.560643 0.769504 0.042274 0.03253
Ethane C2H6 3.771 30.06904 113.3903498 0.060865 0.079237 0.004823
Propane C3H8 1.8393 44.09562 81.10507387 0.043535 0.116199 0.005059
Isobutane Iso-C4H10 0.3558 58.1222 20.67987876 0.011101 0.153161 0.0017
n-butane n-C4H10 0.4403 58.1222 25.59120466 0.013737 0.153161 0.002104
isopentane iso-C5H12 0.0998 72.14878 7.200448244 0.003865 0.190123 0.000735
n-pentane n-C5H12 0.0585 72.14878 4.22070363 0.002266 0.190123 0.000431
n-hexane n-C6H14 0.0843 86.17536 7.264582848 0.003899 0.227085 0.000886
n-heptane C7H16 100.2019 0 0 0.264048 0
n-octane C8H18 114.2285 0 0 0.30101 0
n-nonane C9H20 128.2551 0 0 0.337972 0
n-decane C10H22 142.2817 0 0 0.374934 0
carbon monoxide CO 28.0101 0 0 0.073811 0
carbon dioxide CO2 3.6359 44.0095 160.0141411 0.085892 0.115972 0.009961
hydrogen sulfide H2S 34.0809 0 0 0.089808 0
Air Air 28.9651 0 0 0.076328 0
Hydrogen H2 2.0159 0 0 0.005312 0
Oxygen O2 31.9988 0 0 0.084322 0
Nitrogen N2 0.3548 28.0134 9.93915432 0.005335 0.07382 0.000394
Water H2O 18.0153 0 0 0.047473 0
Helium He 4.0026 0 0 0.010547 0
Argon Ar 39.948 0 0 0.105269 0
100.0001 SUM = 1862.96618 SUM = 0.058622

Fuel Gas LHV = 19346.7413 Btu/lb

Fuel Gas HHV = 21426.31013 Btu/lb
Density = 0.058621718 lb/ft3
flow rate = 360000 SCF/h
massflow 21103.81836 lb/h
Heating Value (Dry) Final Heating Value
LHV HHV LHV HHV

btu/lbm btu/lbm btu/lb btu/lb

21511.9 23892.2 16553.5 18385.15

20429.2 22334.1 1243.433 1359.376
19922.2 21654.1 867.322 942.721
19589.8 21232.3 217.4568 235.6894
19657.8 21300.2 270.0354 292.5967
19455.9 21043.7 75.19793 81.33485
19497.2 21085 44.17252 47.76981
19392.9 20943.8 75.62205 81.66974
19314.7 20839.1 0 0
19255.4 20759.7 0 0
19212.3 20701 0 0
19175.5 20651.6 0 0
4342.2 4342.2 0 0
0 0 0 0
6533.8 7094.1 0 0
0 0 0 0
51566.7 61022.3 0 0
0 0 0 0
0 0 0 0
0 1059.8 0 0
0 0 0 0
0 0 0 0
SUM = 19346.74 21426.31
 CALCULATION OF STOICHIOMET
BASED ON ASME PTC 2
CALCULATION OF WET AIR COMPOSITION MOLAR FLOW

Barometric Pressure 0 psi-a bar-atm

Ambient Temperature 32 F0
C
0

Relative Humidity %

Ln (Pvapor) = C1/T + C2 + C3*T + C4*T2 + C5*T3 + C6*T4 + C7*ln(T) Ln(Pvapor) -315.7220591925

Pvapor 7.649831647E-138

For T <= 32 0F For T >= 32 0F

C1 = -1.02E+04 C1 = -1.04E+04
C2 = -4.89E+00 C2 = -1.13E+01
C3 = -5.38E-03 C3 = -2.70E-02
C4 = 1.92E-07 C4 = 1.29E-05
C5 = 3.56E-10 C5 = -2.48E-09
C6 = -9.03E-14 C6 = 0.00E+00
C7 = 4.16E+00 C7 = 6.55E+00

CALCULATION OF HUMIDITY RATIO

T = tambient + 459.67 = 491.67
PH2O = %RH*Pvapor = 0
FDA = (Patm - PH2O)/Patm = #DIV/0!
Humidity Ratio = (1/FDA - 1) x MWH2O / MWdry air = #DIV/0!

CALCULATION OF MOLAR FLOW CHANGE

Fuel Gas mass flow = 21103.818363 lb/h
Fuel gas molar flow = 11.328073796 mol/h

Fuel Normalized Mole Molecular N2 Ratio O2 Ratio O2 mole change

Constituent Fraction Weight Molar Flow N2 Mole Change

CH4 89.3604 16.04246 1433.5606426 0 0 -2 -2024.5624111941

C2H6 3.771 30.06904 113.39034984 0 0 -3.5 -149.5135819901
C3H8 1.8393 44.09562 81.105073866 0 0 -5 -104.1786306605
C4H10 0.7961 58.1222 46.27108342 0 0 -6.5 -58.618817066
C5H12 0.1583 72.14878 11.421151874 0 0 -8 -14.3458726546
C6H14 0.0843 86.17536 7.264582848 0 0 -9.5 -9.0720878991
C7H16 100.2019 0 0 0 -11 0
C8H18 114.2285 0 0 0 -12.5 0
C9H20 128.2551 0 0 0 14 0
C10H22 142.2817 0 0 0 15.5 0
CO 28.0101 0 0 0 -0.5 0
 CO2 3.6359 44.0095 160.01414105 0 0 0 0
H2S 34.0809 0 0 0 -1.5 0
H2 2.0159 0 0 0 -0.5 0
O2 31.9988 0 0 0 1 0
N2 0.3548 28.0134 9.93915432 1 4.0192005826 0 0
H2O 18.0153 0 0 0 0 0
He 4.0026 0 0 0 0 0
Ar 39.948 0 0 0 0 0
Average molecular weight = 1862.9661798
Molar Flow change = ∆MN2 4.0192005826 ∆MO2 2360.2914014644

COMBUSTION AIR FLOW CALCULATION

Mass flow of dry air to combustor
MWair(dry) = 28.9651159
MFO2(dry) = 0.209476
mair,comb(dry) = ∆MO2/MFO2(dry) x MWair(dry)
= 326367.28791 lb/h

Flow of Moist air to the combustor

mair,comb = mair,comb(dry) x (1 + Humidity Ratio)
= #DIV/0! lb/h

Actual Air supplied

O2 in CEMS = 16 % Range for gas turbine (12- 19%)
Excess Air = (21/(21-O2)) x 100
= 420 %

ACTUAL AIR SUPPLIED = mair,comb x (1+(EA/100))

= 1697109.8971 lb/h
235.70970793 kg/s
 OF STOICHIOMETRIC AIR FOR COMBUSTION
D ON ASME PTC 22 - 2005 STANDART

R
0

psi-a

lb H2O/lbdry air

CO2 Ratio CO2 mole change H2O Ratio H2O mole change Ar Ratio Ar mole change SO2 Ratio

1 1012.281205597 2 2024.5624111941 0 0 0
2 85.4363325658 3 128.1544988487 0 0 0
3 62.5071783963 4 83.3429045284 0 0 0
4 36.0731181944 5 45.0913977431 0 0 0
5 8.9661704092 6 10.759404491 0 0 0
6 5.7297397258 7 6.6846963467 0 0 0
7 0 8 0 0 0 0
8 0 9 0 0 0 0
9 0 10 0 0 0 0
10 0 11 0 0 0 0
1 0 0 0 0 0 0
 1 41.1877435131 0 0 0 0 0
0 0 1 0 0 0 1
0 0 1 0 0 0 0
0 0 0 0 0 0 0
0 0 0 0 0 0 0
0 0 1 0 0 0 0
0 0 0 0 1 0 0
0 0 0 0 1 0 0

∆MCO2 1252.1814884016 ∆MH2O 2298.5953131519 ∆MAR 0 ∆MSO2

SO2 mole change

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0