Physical Chemistry Assignment #2

1.
 2.
ΔHo log ΔHo log M
Methane 890.00 2.95 1.21
Ethane 1560.00 3.19 1.48
Propane 2220.00 3.35 1.64
Butane 2878.00 3.46 1.76
Pentane 3537.00 3.55 1.86
Hexane 4163.00 3.62 1.94
Heptane 4817.00 3.68 2.00
Octane 5471.00 3.74 2.06
Decane 6638.97 3.82 2.15

Log M vs Log ΔHo y = 0.9264x + 1.8274

R² = 0.9998
4.00

3.50
LOG ΔHO

3.00

2.50

2.00
1.00 1.20 1.40 1.60 1.80 2.00 2.20
LOG M

3.
 4.

T (K) 1/T2 Cv (J/ mol K) q SUMMARY OUTPUT

300.00 0.00 20.80 30247.03
400.00 0.00 20.90 30392.45
Regression Statistics
500.00 0.00 21.20 30828.70
600.00 0.00 21.80 31701.21
Multiple R 0.9995
700.00 0.00 22.40 32573.72 R Square 0.9989
800.00 0.00 23.10 33591.65 Adjusted R Square 0.9986
900.00 0.00 23.70 34464.16 Standard Error 0.0575
1000.00 0.00 24.30 35336.67 Observations 9.0000
1100.00 0.00 24.90 36209.18

ANOVA
df SS MS F Significance F
Regression 2 18.38019055 9.1900953 2783.55 1.24785E-09
Residual 6 0.019809445 0.0033016
Total 8 18.4

Coefficients Standard Error t Stat P-value Lower 95% Upper 95% Lower 95.0% Upper 95.0%
Intercept 17.41 0.14 123.58 0.00 17.07 17.76 17.07 17.76
X Variable 1 0.01 0.00 46.10 0.00 0.01 0.01 0.01 0.01
X Variable 2 121239.12 11946.72 10.15 0.00 92006.56 150471.69 92006.56 150471.69

T1 = 461
T2 = 917 Temp vs Cv
T total = 456 26.00
y = 2E-14x5 - 7E-11x4 + 6E-08x3 - 1E-05x2 - 0.0034x + 21.802
polynomial = 5 25.00
R² = 0.9999
24.00
CV

23.00
22.00
21.00
20.00
0.00 200.00 400.00 600.00 800.00 1000.00 1200.00
T

Temp (K) Cv
300 20.79 Temp vs Cv using A,B,C
400 20.88 25.50
500 21.28 y = -2E-14x5 + 8E-11x4 - 1E-07x3 + 0.0001x2 - 0.0394x + 25.663
24.50 R² = 1
600 21.81 23.50
CV

700 22.40 22.50

800 23.02 21.50
900 23.66 20.50
1000 24.30 0 200 400 600 800 1000 1200
1100 24.96 TEMP (K)
 5. A

Isotherms Adiabats
V (L) p (atm) @ 273 p (atm) @ 473 p(atm) @ 273 p (atm) @ 473
0.4 102.54 177.65
0.5 70.80 122.66
0.6 52.31 90.63
0.7 40.50 70.17
0.8 32.45 56.22
0.9 26.68 46.23
1 22.40 38.81 22.40 38.81
2 11.20 19.41 7.09 12.28
3 7.47 12.94 3.62 6.27
4 5.60 9.70 2.24 3.89
5 4.48 7.76 1.55 2.68
6 3.73 6.47 1.14 1.98
7 3.20 5.54 0.89 1.54
8 2.80 4.85 0.71 1.23
9 2.49 4.31 0.58 1.01
 VOLUME VS PRESSURE
isotherms 273 Isotherms 473 Adiabats 273 adiabats 473
200.00
Power (isotherms 273) Power (Isotherms 473) Power (Adiabats 273) Power (adiabats 473)

y = 22.402x-1 y = 38.814x-1 y = 22.402x-1.66 y = 38.814x-1.66

180.00 R² = 1 R² = 1 R² = 1
R² = 1

160.00

140.00
P (ATM @ 273 & 473K

120.00

100.00

80.00

60.00

40.00

20.00

0.00
0 0.5 1 1.5 2 2.5 3 3.5 4
VOLUME (L)