70.

0%

60.0%

50.0%

f(x) = 0.4695899747 exp( - 0.0140193657 x )

A%

40.0% R² = 0.837731358
A%
Exponential (A
%)
30.0%

20.0%

10.0%

0.0%
0.00 20.00 40.00 60.00 80.00 100.00120.00140.00160.00180.00
Co (mg/L)
 12.00

f(x) = - 0.0002006558x^2 + 0.0806466345x + 3.2088607576

10.00 R² = 0.8314660869
q (mg/g)

8.00

q
6.00 Polynomial (q)

4.00

2.00

0.00
0.00 20.00 40.00 60.00 80.00 100.00120.00140.00160.00180.00
Co (mg/L)
 0.0400

0.0350

0.0300
k (min-1)

f(x) = - 0.0001462698x + 0.0306262419

R² = 0.8541200744
0.0250

k
0.0200 Linear (k)

0.0150

0.0100

0.0050

0.0000
0.00 20.00 40.00 60.00 80.00 100.00120.00140.00160.00180.00
Co (mg/L)
 160.00

140.00 f(x) = 0.0002006558x^2 + 0.9193533655x - 3.2088607576

R² = 0.9994476118
Ce (mg/L)

120.00

100.00

80.00
Ce
Polynomial (Ce)
60.00

40.00

20.00

0.00
.00 .00 .00 .00 .00 .00 .00 .00 .00 .00
0 2 0 4 0 6 0 0
8 0 0 0 0 0
10
Co (mg/L) 12 14 16 18
 A4 A3 A2 A1 methylene blue 1st-2nd αραιωση 5:100 20
0.2941 -1.1677 1.6979 2.9839 3rd αραιωση 10:100 10
Pretreated Ethanol 160 ˚C 20 minWheat Straw H2O: Βρύσης 4th-6th αραιωση 100:100 1

1 lt methylene blue αχυρο (g) 1.00

προσρόφηση σε θ=23C V (L) 1.00
ημερομηνια 11/23/2015
αραιώσεις 1000:1000 500:1000 200:1000 90:1000 50:1000
t (min) abs 1 abs 2 abs 3 abs 1 abs 2 abs 3 abs1 abs 2 abs3 abs1 abs 2 abs3 abs1 abs 2 abs3
0 2.041 2.080 2.071 1.058 1.043 1.048 0.800 0.803 0.803 2.804 2.809 2.066 2.027
5 1.966 1.966 1.849 0.958 0.966 0.972 0.762 0.779 0.759 2.518 2.516 1.822 1.838
10 1.942 1.934 1.939 0.955 0.960 0.983 0.739 0.738 0.737 2.421 2.418 1.682 1.702
15 1.923 1.923 1.914 0.951 0.944 0.962 0.724 0.721 0.738 2.306 2.307 1.543 1.562
20 1.929 1.936 1.949 0.949 0.969 0.970 0.702 0.701 0.702 2.278 2.266 1.474 1.490
25 1.916 1.906 1.900 0.972 0.951 0.951 0.698 0.690 0.696 2.189 2.188 1.410 1.434
30 1.893 1.850 1.875 0.981 0.965 0.966 0.701 0.703 0.699 2.173 2.169 1.386 1.383
35 1.888 1.898 1.897 0.974 0.964 0.960 0.696 0.701 0.704 2.132 2.133 1.318 1.335
40 1.897 1.867 1.859 0.959 0.948 0.974 0.679 0.679 0.691 2.072 2.076 1.291 1.296
45 1.903 1.901 1.904 0.967 0.977 0.957 0.665 0.676 0.681 2.067 2.052 1.280 1.262
50 1.900 1.909 1.904 0.962 0.946 0.962 0.662 0.679 0.677 2.085 2.089 1.236 1.251
55 1.905 1.910 1.901 0.966 0.958 0.968 0.655 0.662 0.662 1.996 1.952 1.218 1.224
60 1.906 1.904 1.915 0.946 0.930 0.940 0.644 0.664 0.669 1.958 1.928 1.185 1.191
65 1.901 1.874 1.897 0.952 0.931 0.948 0.647 0.650 0.691 1.899 1.893 1.880 1.170
70 1.873 1.899 1.890 0.926 0.923 0.931 0.693 0.658 0.655 1.910 1.853 1.164 1.170
75 1.887 1.826 1.854 0.934 0.921 0.924 0.648 0.653 0.658 1.853 1.812 1.132 1.133
80 1.882 1.871 1.852 0.923 0.936 0.921 0.653 0.649 0.649 1.862 1.797 1.112 1.107
85 1.882 1.875 1.889 0.932 0.928 0.912 0.646 0.651 0.658 1.838 1.820 1.105 1.106
90 1.901 1.902 1.911 0.923 0.924 0.925 0.638 0.640 0.639 1.817 1.841 1.061 1.058
95 1.862 1.851 1.991 0.926 0.925 0.936 0.642 0.641 0.642 1.798 1.771 1.043 1.033

t (min) ABS Φ1 ABS Φ2 ABS Φ3 ABS Φ4 ABS Φ5 ABS Φ6

0 2.064 1.050 0.802 2.807 2.047 0.874
5 1.927 0.965 0.767 2.517 1.830 0.619
10 1.938 0.966 0.738 2.420 1.692 0.554
15 1.920 0.952 0.728 2.307 1.553 0.510
20 1.938 0.963 0.702 2.272 1.490 0.466
25 1.907 0.958 0.695 2.189 1.422 0.431
30 1.873 0.971 0.701 2.171 1.385 0.405
35 1.894 0.966 0.700 2.133 1.327 0.394
40 1.874 0.960 0.683 2.074 1.294 0.389
 45 1.903 0.967 0.674 2.060 1.271 0.338
50 1.904 0.957 0.673 2.087 1.244 0.360
55 1.905 0.964 0.660 1.974 1.221 0.378
60 1.908 0.939 0.659 1.943 1.188 0.326
65 1.891 0.944 0.663 1.896 1.525 0.351
70 1.887 0.927 0.669 1.882 1.167 0.367
75 1.856 0.926 0.653 1.833 1.133 0.326
80 1.868 0.927 0.650 1.830 1.110 0.351
85 1.882 0.924 0.652 1.829 1.106 0.367
90 1.905 0.924 0.639 1.829 1.060 0.284
95 1.901 0.929 0.642 1.785 1.038 0.345

t (min) C1 C2 C3 C4 C5 C6
0 169.24 80.19 30.04 14.18 8.37 3.29
5 155.09 73.35 28.61 11.45 7.29 2.26
10 156.21 73.41 27.45 10.70 6.66 2.00
15 154.40 72.30 27.03 9.91 6.06 1.83
20 156.18 73.14 25.98 9.69 5.80 1.65
25 153.16 72.76 25.69 9.17 5.52 1.52
30 149.81 73.79 25.95 9.07 5.37 1.42 αραιώσεις 1000 500 200 90 50 20
35 151.90 73.41 25.92 8.84 5.13 1.37 1000 1000 1000 1000 1000 1000
40 149.97 72.95 25.22 8.52 5.00 1.35 Co 156.0 78.0 31.2 14.0 7.8 3.1
45 152.71 73.49 24.86 8.44 4.91 1.16
50 152.87 72.65 24.80 8.59 4.79 1.24
55 152.97 73.24 24.28 7.99 4.70 1.31
60 153.26 71.19 24.25 7.83 4.57 1.12
65 151.54 71.60 24.40 7.60 5.95 1.21
70 151.22 70.22 24.64 7.53 4.48 1.27
75 148.19 70.19 24.01 7.30 4.34 1.12
80 149.40 70.22 23.90 7.29 4.25 1.21
85 150.71 70.00 23.95 7.28 4.24 1.27
90 152.90 70.00 23.44 7.28 4.05 0.96
95 152.58 70.40 23.55 7.08 3.96 1.19

t (min) T(oC) 1 T(oC) 2 T(oC) 3 T(oC) 4 T(oC) 5 T(oC) 6

0 23.0 23.0 23.0 23.0 23.0 23.0
5 23.0 23.0 23.0 23.0 23.0 23.0
10 23.0 23.0 23.0 23.0 23.0 23.0
15 23.0 23.0 23.0 23.0 23.0 23.0
 20 23.0 23.0 23.0 23.0 23.0 23.0
25 23.0 23.0 23.0 23.0 23.0 23.0
30 23.0 23.0 23.0 23.0 23.0 23.0
35 23.0 23.0 23.0 23.0 23.0 23.0
40 23.0 23.0 23.0 23.0 23.0 23.0
45 23.0 23.0 23.0 23.0 23.0 23.0
50 23.0 23.0 23.0 23.0 23.0 23.0
55 23.0 23.0 23.0 23.0 23.0 23.0
60 23.0 23.0 23.0 23.0 23.0 23.0
65 23.0 23.0 23.0 23.0 23.0 23.0
70 23.0 23.0 23.0 23.0 23.0 23.0
75 23.0 23.0 23.0 23.0 23.0 23.0
80 23.0 23.0 23.0 23.0 23.0 23.0
85 23.0 23.0 23.0 23.0 23.0 23.0
90 23.0 23.0 23.0 23.0 23.0 23.0
95 23.0 23.0 23.0 23.0 23.0 23.0
μ.ο. 23 23 23 66 66 23

t (min) pH 1 pH 2 pH 3 pH 4 pH 5 pH 6
0 8.00 8.00 8.00 8.00 8.00 8.00
5 8.00 8.00 8.00 8.00 8.00 8.00
10 8.00 8.00 8.00 8.00 8.00 8.00
15 8.00 8.00 8.00 8.00 8.00 8.00
20 8.00 8.00 8.00 8.00 8.00 8.00
25 8.00 8.00 8.00 8.00 8.00 8.00
30 8.00 8.00 8.00 8.00 8.00 8.00
35 8.00 8.00 8.00 8.00 8.00 8.00
40 8.00 8.00 8.00 8.00 8.00 8.00
45 8.00 8.00 8.00 8.00 8.00 8.00
50 8.00 8.00 8.00 8.00 8.00 8.00
55 8.00 8.00 8.00 8.00 8.00 8.00
60 8.00 8.00 8.00 8.00 8.00 8.00
65 8.00 8.00 8.00 8.00 8.00 8.00
70 8.00 8.00 8.00 8.00 8.00 8.00
75 8.00 8.00 8.00 8.00 8.00 8.00
80 8.00 8.00 8.00 8.00 8.00 8.00
85 8.00 8.00 8.00 8.00 8.00 8.00
90 8.00 8.00 8.00 8.00 8.00 8.00
95 8.00 8.00 8.00 8.00 8.00 8.00
μ.ο. 8 8 8 8 8 8
20:1000
abs1 abs 2 abs3
0.874 0.873
0.628 0.610
0.554 0.553
0.504 0.516
0.467 0.464
0.432 0.430
0.406 0.404
0.394 0.393
0.389 0.388
0.307 0.369
0.362 0.358
0.382 0.374
0.329 0.323
0.385 0.317
0.369 0.365
0.329 0.323
0.385 0.317
0.369 0.365
0.301 0.267
0.342 0.348
 C=156 C=78 C=31 C=14 C=7,8 C=3,1 C=156 C=78 C=31 C=14 C=7,8 C=3,1 C=156 C=78 C=31 C=14
t (min) mg/L mg/L mg/L mg/l mg/l mg/l mg/L mg/L mg/L mg/l mg/l mg/l mg/L mg/L mg/L mg/l
0 169.2 80.2 30.0 14.2 8.4 3.3 156.3 75.9 28.9 13.0 8.1 2.3 -0.08273 -0.05619 -0.03935 -0.08954
5 155.1 73.4 28.6 11.5 7.3 2.3 155.8 75.3 28.2 12.1 7.5 2.1 0.007791 0.033833 0.010275 0.120198
10 156.2 73.4 27.4 10.7 6.7 2.0 155.4 74.8 27.6 11.2 6.9 2.0 0.000607 0.033121 0.050505 0.178012
15 154.4 72.3 27.0 9.9 6.1 1.8 154.9 74.3 27.1 10.6 6.5 1.8 0.012204 0.047724 0.064997 0.238566
20 156.2 73.1 26.0 9.7 5.8 1.7 154.5 73.8 26.7 10.0 6.1 1.7 0.000819 0.036683 0.101431 0.25583
25 153.2 72.8 25.7 9.2 5.5 1.5 154.1 73.4 26.2 9.5 5.8 1.6 0.020142 0.041669 0.111233 0.295514
30 149.8 73.8 25.9 9.1 5.4 1.4 153.7 73.0 25.9 9.1 5.5 1.5 0.041571 0.028135 0.102365 0.303481
35 151.9 73.4 25.9 8.8 5.1 1.4 153.3 72.7 25.5 8.8 5.3 1.5 0.028228 0.033121 0.103299 0.320613
40 150.0 72.9 25.2 8.5 5.0 1.4 153.0 72.3 25.3 8.5 5.1 1.4 0.040551 0.039176 0.127559 0.345675
45 152.7 73.5 24.9 8.4 4.9 1.2 152.6 72.0 25.0 8.2 4.9 1.3 0.023052 0.032053 0.140146 0.351718
50 152.9 72.6 24.8 8.6 4.8 1.2 152.3 71.7 24.8 8.0 4.8 1.3 0.022014 0.043094 0.14201 0.340202
55 153.0 73.2 24.3 8.0 4.7 1.3 152.0 71.5 24.6 7.9 4.6 1.2 0.02139 0.035258 0.160174 0.386115
60 153.3 71.2 24.3 7.8 4.6 1.1 151.7 71.3 24.4 7.7 4.5 1.2 0.019518 0.062332 0.161105 0.398108
65 151.5 71.6 24.4 7.6 5.9 1.2 151.4 71.0 24.2 7.6 4.4 1.2 0.030498 0.056987 0.155984 0.415858
70 151.2 70.2 24.6 7.5 4.5 1.3 151.1 70.8 24.1 7.5 4.3 1.1 0.032557 0.07516 0.147601 0.421236
75 148.2 70.2 24.0 7.3 4.3 1.1 150.9 70.7 24.0 7.4 4.3 1.1 0.051929 0.075517 0.169483 0.439095
80 149.4 70.2 23.9 7.3 4.3 1.2 150.6 70.5 23.9 7.3 4.2 1.1 0.044221 0.07516 0.173205 0.440173
85 150.7 70.0 24.0 7.3 4.2 1.3 150.4 70.3 23.8 7.3 4.2 1.1 0.035843 0.078011 0.171344 0.440353
90 152.9 70.0 23.4 7.3 4.0 1.0 150.2 70.2 23.7 7.2 4.1 1.1 0.021806 0.078011 0.189014 0.440353
95 152.6 70.4 23.6 7.1 4.0 1.2 150.0 70.1 23.6 7.2 4.1 1.0 0.023882 0.072666 0.185295 0.456158

Ce 145.2 68.6 23.0 6.9 3.9 0.9 14% 14% 24% 51% 54% 71%
Co 156.3 75.9 28.9 13.0 8.1 2.3
k 0.0090 0.0169 0.0239 0.0345 0.0314 0.0266
sum 225.5007 37.69444 2.940188 3.086384 2.978552 1.274559
n-p 18 18 18 18 18 18
s 3.539466 1.447113 0.404158 0.414084 0.406786 0.266099

Co Ce k q A%
156.31 145.23 0.0090 11.08 7.1%
75.92 68.60 0.0169 7.32 9.6%
28.91 22.97 0.0239 5.93 20.5%
13.02 6.94 0.0345 6.08 46.7%
8.06 3.88 0.0314 4.18 51.9%
2.26 0.94 0.0266 1.32 58.5%
C=7,8 C=3,1 C=156 C=78 C=31 C=14 C=7,8 C=3,1
mg/l mg/l mg/L mg/L mg/L mg/l mg/l mg/l D1 D2 D3 D4 D5 D6
-0.0376 -0.45501 0 0 0 0.380381 0.719203 1.036534 167.2344 18.20222 1.293796 1.358178 0.091964 1.061674
0.096208 0.000308 0.003112 0.007813 0.023127 0.427003 0.739621 0.996559 0.535063 3.902742 0.138026 0.363117 0.02859 0.026883
0.173708 0.116215 0.006087 0.014992 0.043648 0.466859 0.757499 0.999732 0.733702 1.894359 0.039289 0.297481 0.075817 0.002086
0.248082 0.192585 0.008931 0.021591 0.061857 0.500931 0.773154 0.994611 0.261696 3.936752 0.00824 0.425142 0.18634 1.04E-06
0.280515 0.270069 0.011651 0.027654 0.078013 0.53006 0.786863 0.999638 2.866812 0.469814 0.458279 0.091831 0.098665 0.004346
0.315368 0.329607 0.014251 0.033227 0.092349 0.554962 0.798867 0.991105 0.84787 0.410788 0.297976 0.113309 0.073486 0.010804
0.334441 0.374121 0.016738 0.038348 0.10507 0.57625 0.809378 0.981642 15.06771 0.601201 0.006113 0.001143 0.021851 0.014395
0.363789 0.393704 0.019115 0.043055 0.116357 0.594449 0.818583 0.987535 2.029227 0.568772 0.142493 0.007292 0.021793 0.008117
0.380425 0.402197 0.021387 0.04738 0.126372 0.610008 0.826642 0.982093 8.972323 0.387963 0.001177 0.002231 0.006286 0.001965
0.391748 0.487186 0.02356 0.051355 0.135259 0.623309 0.8337 0.98982 0.006314 2.147493 0.019955 0.04454 6.31E-06 0.032354
0.405572 0.450344 0.025638 0.055007 0.143144 0.63468 0.83988 0.990279 0.320905 0.818137 0.001076 0.319259 0.001523 0.002172
0.416872 0.419988 0.027624 0.058364 0.150141 0.6444 0.845291 0.990554 0.949491 3.077513 0.084129 0.019392 0.005538 0.004327
0.433435 0.507154 0.029523 0.061449 0.156349 0.652711 0.85003 0.991381 2.445977 0.004486 0.018906 0.016327 0.002402 0.008722
0.262406 0.465451 0.031339 0.064285 0.161858 0.659815 0.854179 0.986532 0.017301 0.30696 0.028828 0.000341 2.312694 0.001191
0.44397 0.438561 0.033075 0.06689 0.166745 0.665888 0.857813 0.985623 0.006567 0.394236 0.306287 0.002596 0.018375 0.015551
0.461276 0.507154 0.034735 0.069285 0.171083 0.671081 0.860994 0.977069 7.222504 0.223869 0.002139 0.009068 0.004041 2.47E-05
0.472814 0.465451 0.036322 0.071485 0.174931 0.675519 0.86378 0.980473 1.524162 0.077854 0.00249 0.001343 0.0008 0.012529
0.474821 0.438561 0.03784 0.073507 0.178346 0.679314 0.86622 0.984172 0.097355 0.116933 0.040967 0.00049 0.003782 0.037057
0.497906 0.576274 0.03929 0.075366 0.181375 0.682558 0.868356 0.990371 7.469102 0.040343 0.048754 0.005414 0.006798 0.01043
0.508701 0.475496 0.040677 0.077074 0.184064 0.685331 0.870226 0.989454 6.892206 0.112008 0.001267 0.007889 0.0178 0.019931

225.5007 37.69444 2.940188 3.086384 2.978552 1.274559

 180.0

160.0
C (mg/L)

140.0
C=156 mg/L
120.0 C=78 mg/L
C=31 mg/L
100.0 C=14 mg/l
C=7,8 mg/l
80.0 C=3,1 mg/l
C=156 mg/L
60.0 C=78 mg/L
C=31 mg/L
40.0 C=14 mg/l
C=7,8 mg/l
20.0
C=3,1 mg/l

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 180.0

170.0
C (mg/L)

160.0

150.0

140.0
C=156
mg/L
130.0

120.0

110.0

100.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 90.0

80.0
C (mg/L)

70.0

60.0
C=78
mg/L

50.0

40.0

30.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 35.0

30.0
C (mg/L)

25.0

20.0

C=31
15.0 mg/L

10.0

5.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 16.0

14.0
C (mg/L)

12.0

10.0

8.0
C=14
mg/l
6.0

4.0

2.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 9.0

8.0

7.0
C (mg/L)

6.0

5.0

4.0 C=7,8
mg/l
3.0

2.0

1.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 3.5

3.0
C (mg/L)

2.5

2.0

1.5 C=3,1
mg/l

1.0

0.5

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 C=156 C=78 C=31 C=14 C=7,8 C=3,1
t (min) mg/L mg/L mg/L mg/l mg/l mg/l
0 3.178581 2.450069 1.955895 1.980187 1.500738 0.856352
5 2.288776 1.558998 1.729133 1.50724 1.225497 0.280266
10 2.396609 1.570308 1.498019 1.324892 1.022754 0.059219
15 2.216276 1.308174 1.399678 1.089783 0.779805 -0.11871
20 2.393588 1.512429 1.098832 1.011211 0.652058 -0.33884
25 2.070943 1.425313 0.99965 0.803091 0.493722 -0.54857
30 1.522305 1.646088 1.089797 0.755529 0.395136 -0.7403
35 1.897384 1.570308 1.08068 0.644874 0.221469 -0.83788
40 1.556525 1.46982 0.808873 0.457141 0.10773 -0.88335
45 2.011899 1.587038 0.632086 0.406065 0.02218 -1.50989
50 2.03337 1.398961 0.60303 0.501253 -0.09327 -1.18953
55 2.046045 1.535984 0.264322 0.051844 -0.19868 -0.98589
60 2.083175 0.951819 0.243443 -0.10857 -0.37653 -1.73889
65 1.842717 1.097338 0.353245 -0.40634 0.725383 -1.30877
70 1.790392 0.480228 0.510441 -0.51737 -0.5087 -1.1055
75 1.086486 0.463347 0.032918 -1.01157 -0.77282 -1.73889
80 1.427598 0.480228 -0.07702 -1.05093 -0.99789 -1.30877
85 1.700755 0.336456 -0.02054 -1.05764 -1.04278 -1.1055
90 2.037612 0.336456 -0.75742 -1.05764 -1.79395 -3.95333
95 1.994399 0.591027 -0.55102 -1.95498 -2.53523 -1.39672

Ce 145.2281 68.59889 22.97474 6.93682 3.882913 0.940348

Co 156.3089 75.92163 28.90754 13.01551 8.064653 2.264528
ln(Co-Ce) 2.4052 1.9910 1.7805 1.8048 1.4307 0.2808
k 0.0090 0.0169 0.0239 0.0345 0.0314 0.0266
R -0.6105 -0.8741 -0.9709 -0.9815 -0.9149 -0.8025
R^2 0.3727 0.7640 0.9426 0.9633 0.8371 0.6441
 4
C=156 mg/L
3 Linear
ln(C-Ce)

(C=156 mg/L)
2 C=78 mg/L
Linear (C=78
1 mg/L)
0 C=31 mg/L
0 50 100 Linear (C=31
-1 mg/L)
C=14 mg/l
-2 Linear (C=14
-3 mg/l)
C=7,8 mg/l
-4 Linear (C=7,8
mg/l)
-5 C=3,1 mg/l
t (min)
ln(C-Ce) 3.5
3
2.5
2
1.5
1 C=156 mg/L
0.5
0
0 10 20 30 40 50 60 70 80 90 100
t (min)
ln(C-Ce) 3
2.5
2
1.5
1
0.5 C=78 mg/L
0
0 10 20 30 40 50 60 70 80 90 100
t (min)
ln(C-Ce) 2.5
2
1.5
1
0.5
0 C=31 mg/L
-0.5
-1
0 10 20 30 40 t 50
(min)
60 70 80 90 100
 2.5
2
ln(C-Ce)

1.5
1
0.5
0
-0.5
-1
-1.5 0 10 C=14
20 mg/l
30 40 50 60 70 80 90 100
-2
-2.5
t (min)
 2
ln(C-Ce) 1.5
1
0.5
0
-0.5
-1
-1.5 0 10 C=7,8
20 30mg/l40 50 60 70 80 90 100
-2
-2.5
-3

t (min)
ln(C-Ce) 2
1
0
0 10 20 30 40 50 60 70 80 90100
-1
-2
-3
-4
-5

t (min)
 C=156 C=78 C=31 C=14 C=7,8 C=3,1
t (min) mg/L mg/L mg/L mg/l mg/l mg/l
0 0.773373 0.459085 0.1754 0.175398 0.07001 0.575559
5 -0.11643 -0.43199 -0.05136 -0.29755 -0.20523 -0.00053
10 -0.0086 -0.42068 -0.28248 -0.4799 -0.40797 -0.22157
15 -0.18893 -0.68281 -0.38082 -0.71501 -0.65092 -0.3995
20 -0.01162 -0.47856 -0.68166 -0.79358 -0.77867 -0.61963
25 -0.33426 -0.56567 -0.78084 -1.0017 -0.93701 -0.82936
30 -0.8829 -0.3449 -0.6907 -1.04926 -1.03559 -1.02109
35 -0.50782 -0.42068 -0.69981 -1.15991 -1.20926 -1.11867
40 -0.84868 -0.52116 -0.97162 -1.34765 -1.323 -1.16415
45 -0.39331 -0.40395 -1.14841 -1.39872 -1.40855 -1.79069
50 -0.37184 -0.59202 -1.17747 -1.30354 -1.524 -1.47033
55 -0.35916 -0.455 -1.51617 -1.75295 -1.62941 -1.26669
60 -0.32203 -1.03917 -1.53705 -1.91336 -1.80725 -2.01969
65 -0.56249 -0.89365 -1.42725 -2.21113 -0.70534 -1.58956
70 -0.61482 -1.51076 -1.27005 -2.32216 -1.93943 -1.38629
75 -1.31872 -1.52764 -1.74758 -2.81636 -2.20355 -2.01969
80 -0.97761 -1.51076 -1.85751 -2.85572 -2.42862 -1.58956
85 -0.70445 -1.65453 -1.80104 -2.86243 -2.47351 -1.38629
90 -0.3676 -1.65453 -2.53792 -2.86243 -3.22468 -4.23412
95 -0.41081 -1.39996 -2.33152 -3.75977 -3.96596 -1.67752

Ce 145.2281 68.59889 22.97474 6.93682 3.882913 0.940348

Co 156.3089 75.92163 28.90754 13.01551 8.064653 2.264528
k 0.0090 0.0169 0.0239 0.0345 0.0314 0.0266
 2
ln[(C-Ce)/(Co-Ce)]
C=156 mg/L
1
Linear (C=156 mg/L)

C=78 mg/L
0
0 10 20 30 40 50 60 70 80 90 100 Linear (C=78 mg/L)

C=31 mg/L
-1
Linear (C=31 mg/L)

-2 C=14 mg/l

Linear (C=14 mg/l)

-3 C=7,8 mg/l

Linear (C=7,8 mg/l)

-4
C=3,1 mg/l

Linear (C=3,1 mg/l)

-5
t (min)
 1

0.5

0 C=156 mg/L
0 f(x)10
= - 0.0089776064x
20 30 40 50 60 70 80 90 100
R² = 0.6881843897 Linear (C=156 mg/L)

-0.5

-1

-1.5
t (min)
 1

C=78 mg/L
0.5
Linear (C=78 mg/L)

0
0 f(x)10
= - 0.0168939914x
20 30 40 50 60 70 80 90 100
R² = 0.9232234229
-0.5

-1

-1.5

-2
t (min)
0.5

0 C=31 mg/L
0 f(x) 10
= - 0.0239114389x
20 30 40 50 60 70 80 90 100 Linear (C=31 mg/L)
R² = 0.9838582813
-0.5

-1

-1.5

-2

-2.5

-3
t (min)
0.5

0
0 f(x) =10
- 0.0344502167x
20 30 40 50 60 70 80 90 100
R² = 0.9898529661
-0.5
C=14 mg/l
-1 Linear (C=14 mg/l)

-1.5

-2

-2.5

-3

-3.5

-4
t (min)
0.5
C=7,8 mg/l
0
0 f(x) =10
- 0.0313557265x
20 30 40 50 60 70 80Linear
90 (C=7,8
100 mg/l)
R² = 0.9502106826
-0.5

-1

-1.5

-2

-2.5

-3

-3.5

-4

-4.5
t (min)
1
C=3,1 mg/l
0 Linear (C=3,1 mg/l)
0 f(x) = 10
- 0.0265572266x
20 30 40 50 60 70 80 90 100
R² = 0.8704876459

-1

-2

-3

-4

-5
t (min)
 25.0

20.0
T (oC)

T(oC) 1
15.0
T(oC) 2
T(oC) 3
T(oC) 4
T(oC) 5
10.0
T(oC) 6

5.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 9.00

8.00

7.00

6.00
pH
1
pH

5.00 pH
2
pH
4.00 3
pH
4
3.00

2.00

1.00

0.00
0 10 20 30 40 50 60 70 80 90 100
t (min)