BOMB CALORIMETERS 1) A sample of sucrose, C,H.,0,,, Weighing 4.50 gis burned in a bomb calorimeter, The calorliétet has a water jacket that contains 25,000 grams of water initially at 22.15¢C. When the sucrose is ignited the water Teaches a final temperature of 25.22" C. Calculate the heat of combustion for sucrose from this data. = mc AT = C5 003) (1a(asia2~ 22 19 = 76, 750 cl T7y Peel , Fag, ABT VT. 24, 202 yy 15 mel Gl Jooo J vl c = 40 BE 2) A 4.00 g sample of C,H.0, is burned in a bomb calorimeter. For every degree rise of the bomb calorimeter the calorimeter absorbs 20,460 joules of heat. The combustion produces 87.7:Kj of heat. The initial ‘temperature of the calorimeter is 25.0° C. From this information calculate: 87, W007 =. [2,460 > a) The heat of combustion of C,H,0,, 1 OT = AT ORIET 805. 3026 a ue TEAM: 405 md ERS ) The final temperature of the calorimeter. ATE MATE gaan Bening eecne eer nent eee rises 12.92°C. Ina separate experiment, it is found that the addition of 6.23 Kj of heat to the calorinieter raises its temperature by 1.61° C. Calculate the heat of combustion of C, 628 L eeyur = AE CAT TGl °C *(e-2 1) (292°) we a SOK, 265 - 18 0KT o Treat. * ah valBOMB CALORIMETERS 1) A sample of sucrose, C,H,0,,, Weighing 4.50 g is burned in a bomb calorimeter. ‘The heat &apaclty of the calorimeter is 2.411 x 10° /"C. The temperature rises from 22.15°C to 25.22°C. Calculate the heat of combustion for one mole of sucrose from this data, OTs 2522 Q- Car a Gounziot Fe) (4.07) = 7408S & eee BH Gn (50 a anes pra Rwu NS 2) When 5.00 ml. of ethyl alcohol, C4, 0H, (D=0.789 g/mL) is burned in bomb calorimeter, the temperatuke in a’bomb calorimeter, the temperature in the bomb rises form 19.75°C to 28.67°C. The calorimeter heat eapacity is 13.24 kj/*C. Calculate the heat of combustion for one mole of ethyi alcohol from this data. HeAKS bg Oe ase ore RSS oe eamce SRY = "Sue wire 137753) mass 2 3-995: C47 * ~~ Me 3 AE Gey Ge) = It, ERS 3) A.4.00 g sample of salicylic acid, C,H,0,, is burned in a bomb calorimeter . ‘with a heat capacity of 2.046 x 10°)/°C." The combustion produces 87.7 Ij of heat, and the temperature after combustion is 26.10°C. Calculate the initial temperature. Qe CAT = Cert x01 Z) (aos =7) = 3705 2610 T = 27 2 218%. 4) When 1.00 g 6f acetylene, C,H, gas burns in a bomb calorimeter, the temperature rises 10.94°C. in'a Separate expertment itis found that when 8.16 kj of heat is added to the calorimeter the temperature increases by 1.79C. Calculate the heat of combustion of acetylene. G7) Boks = OF Q=CAT 2 456 EE (454 hott), c= 1S 49.4 KT1. When 23.6 g of calcium chloride was dissolved in wate in calorimeter, the tempers ros, seo log C to 38-70 deg C. Ite het eapacty of de solution andthe calorimeter is 1258 «HC, what sth eat fhe reaction when I male of caletum erie disses in water? ar Cx oT = L2ses (e708 = 25.00%) <7, 2546 BT so 17,2346 5 | 0. Be ky ot Iyasees a9 Les = BLOUe RT FL Oke 28.45 met | yrol Sal 2, ‘The molar heat of combustion of Compound Cis 1,250 fmol, IFT were to burn 0.115 moles of ‘ine compound i a bomb calorimeter with a reservoir hat holds 2.50 L of water, what would the expected temperate increase be? 1asoks, 2.5 eel 2 (YRS KkS = Seeeeeeeeeeeeee A peor 143.75 ES _ 2 28 5 MSE — = IS. ( AT? Gm ~ Be, 12,5004 4. 4, When 153 g of sodium nitrate was dissolved in water in calorimeter, the temperature fom Be 0 dog Cio 21.56 deg C Ifthe heat capacity ofthe solution andthe calorimeter is 1071 des ‘C wat isthe AH when I mole of sodium nitrate disolves in water? os, (sc0'c-2! sic) = 3407 T yr, 85g _ 2087, LE ROS kr Wail, ool ‘mol oe ro] 44. A-sample of ety! alcohol (CaHsOB), weighing 2.4 g wes bumed in an excess of oxygen in Asal inet, The temperature ofthe calorimeter rose from 25.00 degC © 33.73 deg C.1F Teveat capacity ofthe calorimeter and contents was 9.65 kdeg C, what isthe value of@ for burning | mole of ethanol at constant volume and 25.00 deg C? gz 7 Cnet “28% 5 (33.786 -AS.00¢) S407 KS — R407 KS Y6OR = BOY. ES — 1,360 2.845 Pool CatHs0H neni vrol rolTHERMOCHEMICAL REACTIONS _ 1, The sir plltant slr iid ects wth woter in the atmosphere to prodece src acid and heat $0 ay + Hi Oy) ~ HiSOquy + 129564) How much heat (in kilojoules and kilocalores) i released when 583 g of SO, reacts with water? SBI y SOF x Ind SO IPGGKT = gy, Daag Tot RT - FLT reas = [226 kel [ 2. How many grams of product can be formed by the addition of 25.0 keal othe following reaction: Hap thy +928 J+ 2Hhy AS keel x» HIBET AmIHE x Basie sete = Wo Sta * eis Tela ~ 7 3. ‘The change in heat forthe following endothermic reaction is +263 ki. eget Dey + 3COagY— FexOx) + 300 How many kilojoules of energy are needed for 4.39 x 10*atoms of iron to react with an excess of con? 1,31 x 107" chang Fe x fool Fe ea a by a ” btn reahag * Fad Fe i ol 4. The complete combustion of ethene, CH, liberates 1.39 x 10°kI per mole. Calculate the amount of beat released when 1.87 gof ethene reacts with excess oxygen, Ghy yy + 302 5) > AO + BHO + 1392107 T 1.895 Gily x Imlay . LIKE _ 1528 LT d 485 Tad Ghy 5. Given he reaction: CiHay* Hay > Cay +1372, How much nergy i released when 400 g of CH, reacts wih 30 8? = 40-05 lly Towel Gly, 137.24 =/isekr ] 235 Tol by Boy My xe Leb . 2.247 2 706 ke i i aeAlle Cabo yy F ~ SBIR bE ‘THERMOCHEMISTRY I As CS, 0 = +on7 bE 1) Calculate the heat of the following reaction: CaHl10(g) + 13/2 O7%g) > 4 CO) + 5 20%) CrHre gy AC + SH, Ais + AIP a HC 02, > HC2 y, bape ¥E292.0) = SY Sit 0, > Tho a> © (aya) 7407 SUlidiar neat of Ge Btowtiy Haction: [RAE Get] CoH ig). 7/2 Orig. ce 2 CO) + 3 H2@G>) - Ge ys PG Pay SHE FLT rot We 420, > Wey Die 2 (-309,0) 7787 Ty +2, 7 3G Ow Aw 23-2058) 8574 Glog, $B 2 AC zg24 Hb, 3) Calcilate the heat of the following reaction: “S| CS2q) + 3 074g) Yields CO2(™ + 2 502(g)” C82q— RS | AW =~ 89.7 HAL Nee On > C3 Mee - F920 N28 +20, — 280 Ot = 2(6-296.8)= S426 (S20) +202, > Chg + Sy Tom bkr, , | BET ah 4) Calculate the heat of the following reaction: [RRS CaCOa{s) > CaO{s) + COaig) (4.C0p 5, > LR FE IO, A= + 1R004 Et "La BO, 9" CO, bas — 6751 ee ey IE PH Ainnns Ga * C40) F178.7 bij (5)Ais NOs Peetcas Sout ‘THERMOCHEMISTRY IT 1) Find the heat of combustion of NO using the following equation: NO(g) + 1/2 02%) -> NOx) Nog) —> ha 4/8, A= 95.2 Hips IW,+% => Ny Ay = +322 kT fnl Pt % Nay oe Wy) 1 Fim > Ree / 2) Caléulate the heat of the following reaction: Og) + 1/202) > Cox) CO, 2 C+ £0, AHF 40S kT ps C+ 02 > Coy, AH 292 Fr CQe) LOLs? Oxy 283.0 LT fovel [| 3) Calculate the Az tor ee moot NH3 Feacting with oxygen, Use the following equation: 4 NH3(g) + 3 O2(9) > 2Na(g) + 6 H20(g) His —> 2M Bley ay H(4 1.1) = BAY Is Wh + 30, A bho 4H = 6 -2y1.8) =-482.8 ~ HN Hg a) +3 0a Gi a aay, + OH, Oy) 4) Calculate the heat of the following reaction: NH4NO3(s) N20(g) + 2 H20ig) é. = 1G kT Ning Na A bya A= HEE Mat HE Magy ae ea = 2 (DUB) = ~78F-6 br Wt a Zibey eat T HEC —————_— ” Foy / NW o> Nate + 2HOg, - THE SFist‘THERMOCHEMISTRY il i: 1) The heat of combustion of C7Hy 6(g) s 4499 kj/mol. From this information calculate the heat of formation of C7H6(g). Fug FHP) —F CHideay * Mey aH THES f Flic + 70x, —2 7 Deny Peis) © Magy 7 Hracay Bits RAKE or 2) The heat of combustion of C4Hy0(g) is -2657 Ki/mol. From this - 45:2 va information calculate the heat of formation of C4H10(g) Be 4 COxs ~ SHOa, 7 ahora + B Oaegy OH = +2057 Yes + 4 O20) F103 4) one #(-523.5) S Yay + £ onéy 7 Sts ou SAD 2) SE ey 4 Cesy + SHacsy 2 Ca Mrocsy BR 6S or 3) The heat of combustion of octane, CgHy (fis -5112 ki/mol. From _30.1 Kol {this information calculate the heat of formation of octane. E) Bry + THO CMe BGG) BHessue — Mle V7 BO “7 TCOray Aue 8(-343,5) 7 Hp) Sux 9Ger) FT Hyp + 2 Ones: Bey + THeesy —F CoHiseey OHe -22S or 4 ag can be combined with oxygen to give S034, The molar heat ~2- 78h of reaction is - 23 kcal/mol of S02. Calculate the heat of reaction to mol form one mole of S03(g) from S(«) and Oi) Kel 2 23 Bey Nesey —9 SOey oA ey == Syst Ye Py) I SBey ate 4G 2B kal ye HIB LT iat Fe larAC + Na >. GNg 2 Calculate the baat of fomation of Sega) + 5/2 Cae) I DKeun + Ge 6¢ + Fh > Co = eg 3) Calculate the heat of somation of decae, CygHiyp, using the fol equations ‘ leg + Taxog seen Wi + Ko, —» Ugo tt oy catedaes the Habe rote Utara, co, Ae enn BLS EE Deg) + C2 q) yields Op gy 10g) A He -125.6 kcal aol Das Be ooh = Cho + by FIRFG Ct oS > Pea att _ ee) : 7 8 > wee wyaclo HbSiace the tea tomar ne enka CSBaacay + Mi Ope) yield 9.00,e) + 10 HYO¢y, Ate 2299 look an FD > CH MO, + IRC half e+ 3 —> Ihe F C9) loth & $6. 9 eo - 10 bs S FO + 10H. —> Cogn - Bie =OE TeelYeyu7l Prod 4 = £ Reoet J ‘Thermochemistry V ~72t beck HORT & 2260) ig 1. ‘The heat of combustion of CHa is determined to be-781 keainol. Given the fllowing balanced” reaction, determine te heat of formation of Calan. Calan + “Org —+ 6COxg + 3H AH, = [Ate Cea + Ave tba, |- (ABe Cathey, + MMe 0,) eens = (elec) + (288. 4} = [Abe Ge + od - = Ake oe 726 2361 as7. 4] AN aes = Ee Ave Cole Tyeeur| 2. Napthalene can be burned 31M sroduce Cony tO ‘The heat of reaction for the} ‘combustion of naphthalene is -1227 keal/mol. If the formula for naphthalene is CygHyy), calculate ‘hehe of formation of aphtalene. ~ 1227 kik , GIBET 2 = S1ZILTH) ioe keel Coy + 12a 1900, + HthO@ -si24 = [lo(-293. - Wc 208] — Ate Gols Athy Gstl, > Tut / 3. Caleta at ofthe lw ai CO) + "0x > COs Aten = Liza) ]- (0 600s)] = 208 bp] 4. Cakes the eat ofthe lowing rection: ANH Fox AN $F Oy Diteat | 2(#70a) 2-448) | (aC!) ] = [1804 = a4) +R =stC + ror fa ®‘THERMOCHEMISTRY AGAIN 1. Given the following data AH = 1225.6 kd ‘AH = 2967 3 ki AH = 84.2 kd AH = 285.7 kd AYe $2967.38 Py + GCl,—9 UPlz AHIR wwottby6 GPLl, ——>6PClz +6Cla. AH? Fe 2 xe+ 5.2 nwbtbyre /0PCls 15K02 7 10 C15 Ro Ais = 295.7 «Oenss7 Au te 2. When 23.60 g of calcium chloride was dissolved in water ira calor ie temperature rose from 25,00 °C to 38.70°C. Ifthe heat capacity ofthe solution ‘and the calorimeter is 1258 Joules?*C, what is the heat of the reaction when one mole of calcium chloride dissolves in water? KS #7 on fy 3 3. Given the following reaction, calculate the heat of formation of CIF, 2OIF ig }* 2NHag) — Nop) + BHF y + Chg AH=-1196Kd . “Bip E Giprot) — £ GAy reactants) -\46 = (OF (cramn)+0 )— Caste £ Qy- Hl) = than — 2ARear, + 72% poe — Bae abe? = i on — 1b AHe = Ie @4, The complete combustion of 0.1548 g benzoic acid (CrHsO,) Increases the temperature of a bomb calorimeter by 2.54 °C. Calculate the heat capacity of this calorimeter. (UH of benzoic acid is -294.1 kiimol) ‘A 0.2130 g sample of vanilin (CeHgO3) is then burned in the same colorimeter, and the temperature increases by 3.25 SC. What is the heat ‘of combustion per mole of vanilin? C-7 *R.01 0.15485 « He! 0,00126% mo] benzeeercitl PRIN -2e IG 3 122,139 fowl 3 FAMED tages Fol = O, 3728 ES = Q ol C-Exb a Cz, O/at = 23 TBE FT O.NMb 76 ETE HS eof fs 24? 4 O- tek = cae Qe ONES, 3.35% 20477 oe OW gx 5 | serge DF! = LOMIPET 7 82. Yaw. fi 1.349% 107 op 34 sf el} 5. Catal he heat of te toing rea SO; + HO) —H.SOup Mine EAH pratsh) — € (0H renchoh) = > BOT ~ (395.7 es 285,541) —1BRS kT |‘THERMOCHEMISTRY REVIEW \ 1: Cafelate the beat of mation for CHCl given the following reaction: a They. + Shy) F CHCy HHCY A= 24.0bcabmal x LIBLTS 100.3 6 Gat aha yi Hy » THB Wy, Sey Mg Rhy a= 2 ey + i Cat Fiat FCA Cy Cly, [are 6 Hea | 2. The heat of combustion of etheno, Co HOH, is-1356 kh TA g of ean was bused i ‘bomb calorimeter, the temperature ofthe calorimeter rose fiom 25.00°C to 33.76°C. Wha ifthe eat capatty ofthe calorimeter? 2.84, Gea x Mm ye APSO bE = BI. 7KT eelesedh “is Tet Q= Car 2s = Ses ED. SER = 9.s6 HE C= Be” Garenareey OH cal oe 2, “Gacuste the amouit of beat released when 50 g of HCI produied acoiing to the flowing teemnochemicl equation: Hug + Ch > 2HCL + 18510 ausog Bet > Ind 18S er -[ere a] Feky der at HCH 4 Wen 53 g of sot nitrate was dissolved in vister ina calorimeter, the temperature fell fom BBONC to SEC. If te hess capacity of Ge sstuton and the calorimeter is 1071 °C, what isthe AH ‘een one rade of sodfuns tate issn it water? Q= C4T PUBL Q (tZ)G. yet) 7g natty Ie S I6G4T = 3.60kT5, Calculate the heat of formation for CHyCOOHsy using the following information: CHICOOH) + 204 > 200iy + 20m Av—DO8keatmal ~ HABET BG hz eed Ie Peon Dagn > 2G + CHsCoomy, AH +84 Lut m7 Pee 4u=2(393.5) _diagt Ory aBaen — au s26ats-s) RGa) + Aha + Wy, 2 CHICO) Jans 4088 KT foal can Se last, te ts Lata eat Gel heat. Caluste AH in cao forthe phase change represented by the equation: HaO,9 > HaOp PH. by Hed x Lol Hh 7.97 mal Ho ty Bulg br yb kek = fi beh 437 aut GIG ET rd | La 17. ‘The temperature of bomb calorimeter i raised 1.17°C when 1.00 g of hydrazine, No}, is barmed init. Ifthe calorimeter bas afieat capacity of 16.53 KIPC, what i the hat evolved? What isthe eat of reaction forthe caxtbastion of one mole of hydrazine, Q= CAT / 16.57 ur (1 me) eee 14.7 hger Pay my Pale kr ——— aac Tmt al —_—— O35